CN106398887A - Multiuse high-efficiency and environment-friendly cleaning solution and preparation method thereof - Google Patents

Multiuse high-efficiency and environment-friendly cleaning solution and preparation method thereof Download PDF

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Publication number
CN106398887A
CN106398887A CN201610812642.0A CN201610812642A CN106398887A CN 106398887 A CN106398887 A CN 106398887A CN 201610812642 A CN201610812642 A CN 201610812642A CN 106398887 A CN106398887 A CN 106398887A
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China
Prior art keywords
efficiency environment
clean liquid
protecting clean
multipurpose high
sodium
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CN201610812642.0A
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CN106398887B (en
Inventor
罗义斌
孙力斌
杨粟
朱心涵
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Nanjing Lian Easyjet Automotive Service Co Ltd
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Nanjing Lian Easyjet Automotive Service Co Ltd
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Priority to CN201610812642.0A priority Critical patent/CN106398887B/en
Publication of CN106398887A publication Critical patent/CN106398887A/en
Priority to US16/331,116 priority patent/US20190233762A1/en
Priority to PCT/CN2017/100310 priority patent/WO2018045925A1/en
Priority to EP17848098.4A priority patent/EP3511401A4/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/362—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a multiuse high-efficiency and environment-friendly cleaning solution and a preparation method thereof. The cleaning solution comprises sodium polyacrylate, a surface active agent and deionized water. The surface active agent comprises combination of any two of or more than two of alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyoxyethylene ether or laurinol polyoxyethylene ether. The preparation method includes the steps of adding sodium polyacrylate into deionized water, stirring until full dissolution at a room temperature, and adjusting the system pH (potential of hydrogen) to obtain first mixed liquor; adding the alkyl-polyoxyethylene ether acetate, the plant polyenoid phenol polyoxyethylene ether and the laurinol polyoxyethylene ether into the deionized water, warming and stirring until full dissolution, and adjusting the system pH to obtain second mixed liquor; adding the second mixed liquor into the first mixed liquor, adding remaining deionized water, adjusting the system pH, and stirring and mixing uniformly to obtain the multiuse high-efficiency and environment-friendly cleaning solution. The multiuse high-efficiency and environment-friendly cleaning solution is wide in application and can have a good cleaning effect after being applied to several fields.

Description

Multipurpose high-efficiency environment-protecting clean liquid and preparation method thereof
Technical field
The invention belongs to daily cleaning field is and in particular to multipurpose high-efficiency environment-protecting clean liquid and preparation method thereof.
Background technology
Current daily cleaning agent on the market is different with mechanism due to the material of cleaning, is the stronger cleaning of specificity mostly Agent, the such as cleaner special such as glass, leather, floor.
As CN201510495699.8 discloses a kind of glass cleaner, surfactant is 1 by mass ratio:1-1:3 Anion surfactant and nonionic surfactant composition.CN201510503024.3 discloses a kind of glass curtain wall cleaning The preparation method of agent, has dodecylbenzene sodium sulfonate, sodium methyl cocoyl taurate, sodium xylene sulfonate, dicarboxyl in formula Methylalanine trisodium.
CN201510718084.7 discloses a kind of leather sofa quickly potent detergent, pungent containing maleic acid di-secondary Ester sodium sulfonate.Belong to anion surfactant.CN201610287635.3 discloses a kind of abluent to leather maintaining cleaning, Containing acetone, inflammable, poisonous, have specific characteristics acrid odors, ethyl acetate hypotoxicity, and ethanol is irritant, harmful, and And glazing coating effects are not had to leather.
CN201410699255.1 discloses a kind of furniture detergent, contains sodium silicate, sodium silicate liquid or mist in formula There is intense irritation to eye, conjunctiva and corneal ulcer can be caused.Skin contact liq can cause dermatitis or burn.Second is contained in formula Glycol, octylene glycol, also contains ethanol irritant.
CN201510773917.X discloses a kind of strong detergent, writes in description：" abluent to cast iron, cast aluminium, Leather, fabric, rubber, plastics etc. have no side effect ", formula contains dodecylbenzene sodium sulfonate, is anionic surfactant. Containing nonyl phenol poly- atmosphere ethylene ether sodium sulfate, there is hypotoxicity, being irritating to the skin property.
CN201510209702.5 discloses a kind of no marking glazing cleaning cleaning agent, preparation method and its usage, formula Middle ammonium benzoate:High poison, stimulates eyes, respiratory system and skin.There is ammonia taste or have ammonium benzoate abnormal smells from the patient.Gradually divide in atmosphere Solution releases ammonia.Thiourea:Decomposes, release the poisonous gass such as nitrogen, sulfur oxide health.Sodium lauryl sulphate, dodecane Base benzene sulfonic acid sodium salt, sodium lignin sulfonate is all anion surfactant.
Multiple daily cleaning agent (liquid) on existing market are most to contain substantial amounts of ionic surfactant, or from Subtype surfactant and nonionic surfactant are used in mixed way.Because ionic surfactant is mainly to skin, eye The zest of the tissues such as eyeball and sensitization, safety and mildness are difficult to ensure that.
The daily cleaning agent commonly used at present usually contains nitrogen, phosphorus, ammonia, benzene plasma or group, containing these ions or base Although the compound of group can reach the effect of quick, thorough cleaning, these chemical combination in traditional daily cleaning product Thing has certain environmental hazard in itself, user of service and use environment can be caused certain pollution and infringement make With, and the waste liquid after cleaning directly discharge can cause directly to pollute to environment.Therefore, how to develop that one kind is nitrogenous, phosphorus, The environment friendly and pollution-free multipurpose of ammonia, benzene plasma or group, performance can reach or better than commonly using at present containing being harmful to above again The cleaning solution of ion, is provided simultaneously with daily life and the clean environment product of more maintenance functions, is a big heat of current research Point.
Content of the invention
It is an object of the invention in order to overcome above the deficiencies in the prior art to provide multipurpose high-efficiency environment-protecting clean Liquid and preparation method thereof, during cleaning directly use it is not necessary to additionally using water.With fiber towel or special non-woven fabric hair Appropriate cleaning solution drawn by towel, uniformly wipes the article surface that need to clean, then uses hydrophilic towel, can be to article surface The mixed dirts such as greasy dirt, dust, grit carry out Rapid Cleaning, reach thorough cleaning, glazing, the effect of plated film integration, simultaneously Article surface will not be damaged.Multipurpose high-efficiency environment-protecting clean liquid is not nitrogenous, the oxious component such as phosphorus, benzene, ammonia, in pH value Property, tasteless non-stimulated, harmless, environmentally safe.Skin, skin care is protected during use.Cleanable thing Product mainly have all kinds of glass：High level and compound glass curtain wall, house door glass etc..Each metalloid：Rustless steel, aluminum, gold, silver, Surfaces such as copper, alloy etc..All kinds of lacquer paintings：Metal lacquer painting, furniture lacquer painting, floor lacquer painting etc..Each class leather：Natural and dermatine Product, such as lodge, sofa, tables and chairs etc..Pottery：Ceramic, such as washing basin, bathtub etc..Natural marble, artificial ground and platform Face.Surface of plastic products.Rubber article.It is adaptable to multiple daily living article in addition to the article of kitchen severe grease place Cleaning with living environment.
Technical scheme is as follows：
Multipurpose high-efficiency environment-protecting clean liquid, this cleaning solution includes following components：Sodium polyacrylate, surfactant and go from Sub- water.
Further, described multipurpose high-efficiency environment-protecting clean liquid, surfactant can be alkyl polyoxyethylene ether second Two or more combination any in acid esters, plant polyenoid phenol polyethenoxy ether or polyoxyethylene lauryl ether.
Further, described multipurpose high-efficiency environment-protecting clean liquid, also includes sodium stearate or glycol distearate One of or two kinds.
Further, described multipurpose high-efficiency environment-protecting clean liquid, also includes soy broth lecithin, Kazon or carboxymethyl Any one or a few in sodium cellulosate.
Multipurpose high-efficiency environment-protecting clean liquid, this cleaning solution includes following component in parts by weight：
Sodium polyacrylate 0.2-0.4 part, deionized water 97.9-99.0 part and surfactant；Wherein surfactant choosing From alkyl-polyoxyethylene ether acetate 0.3-0.6 part, plant polyenoid phenol polyethenoxy ether 0.2-0.5 part or lauryl alcohol polyethylene glycol oxide In ether 0.3-0.6 part any two or three.
Further, described multipurpose high-efficiency environment-protecting clean liquid, also includes ethylene glycol bisthioglycolate stearic acid in parts by weight One of ester 0.02-0.03 part or sodium stearate 0.1-0.5 part or two kinds.
Further, described multipurpose high-efficiency environment-protecting clean liquid, also includes sodium carboxymethyl cellulose in parts by weight Any one or a few in 0.3-0.5 part, soy broth lecithin 0.05-0.08 part or Kazon 0.1-0.2 part.
The preparation method of above-described multipurpose high-efficiency environment-protecting clean liquid, comprises the following steps：
Step one, weighs each component according to weight portion；
Step 2, takes sodium polyacrylate to be added in 10-20 part deionized water, stirs to being completely dissolved, adjust under room temperature System pH is 7.0-7.2, obtains mixed liquor one；
Step 3, surfactant is added in 5-10 part deionized water, is warming up to 70-80 DEG C, drops after stirring and dissolving To room temperature, and regulation system pH is 7.0-7.2, obtains mixed liquor two；
Step 4, mixed liquor two is added in mixed liquor one, is subsequently adding surpluses water, and regulation system pH is 7.0-7.2, It is uniformly mixed, obtain multipurpose high-efficiency environment-protecting clean liquid.
Further, the preparation method of described multipurpose high-efficiency environment-protecting clean liquid, the regulator used by regulation system pH For acetic acid or citric acid.
Further, the preparation method of described multipurpose high-efficiency environment-protecting clean liquid, adds with weight portion in step 2 Glycol distearate in parts by weight is added in sodium carboxymethyl cellulose 0.3-0.5 part of meter and/or step 3 Add with weight in one of 0.02-0.03 part or soy broth lecithin 0.05-0.08 part or two kinds and/or step 4 Kazon 0.1-0.2 part of part meter or one of sodium stearate 0.1-0.5 part or two kinds.
Sodium polyacrylate is to manufacture the material nontoxic, Pollution-free detergent is ideal as builder.Sodium polyacrylate It is a kind of new and effective environment friendly washing auxiliary agent, the tripolyphosphate commonly using in current detergent and other aluminum can be replaced Salt, thus eliminate the pollution to environment because of the waste water discharged using sodium tripolyphosphate and aluminium salt.Helping of sodium polyacrylate is washed Performance is far superior to traditional sodium tripolyphosphate, and clean result is equivalent to 5 times of sodium tripolyphosphates with weight, and that is, consumption is only three The 1/5 of polyphosphate sodium, it is possible to decrease the cost of detergent.Sodium polyacrylate as the mechanism of action of builder is：Sodium polyacrylate There is chelation to metal ion, play alkaline buffer effect, have good cohesion to soliquid, come from its surface The neutralization characteristic of electric charge, that is, it constitutes quasi- ionic bond, at this moment due to electrostatic repulsion, polyacrylic acid with positively charged suspended particles The carboxyl of sodium makes flexible polymer suitably stretch, and so that the absorption of suspended particles, the crosslinking between cohesion, and particle is easily entered OK.If there being Na around polymer+Ion and Ca2+In the presence of ion, then Ca2+Ion is easier to adsorb and fixing.With polymolecular It is absorption surface charge reversal, increases with hydrophilic that display Protection glue effect makes particle dispersion system stable.Polyacrylic acid Sodium is a kind of efficient washing assisant, so that dirt is departed from car body surface and prevent dirt to car body surface attachment deposition again.
Sodium polyacrylate emulsion dispersion good stability, and heat-resisting, good mechanical stability, can close trace metal ion, and Nontoxic.Lubricity and the stability of cleaning solution can be improved.
Sodium carboxymethyl cellulose：The stable homogeneous emulsion of forming properties.Because it is safe and reliable, therefore, its consumption is not subject to National food hygienic standard ADI limits, and is recognized as safe food additive.Play the effect of flocculation, chelating, emulsifying, Increased cleaning solution lubricity, so that cleaning solution is wiped convenient, time saving and energy saving.
The present invention adopts nonionic surfactant completely：Alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyoxy Vinyl Ether, polyoxyethylene lauryl ether, are compounded from two or more, and the compatibility using above-mentioned surface activity can make cleaning The surfactant concentration of liquid drops to 0.1-0.3%, reduces cost, reduces the surface tension of solution, increased wettability. Solve the zest mainly to tissues such as skin, eyes for the ionic surfactant and sensitization it is ensured that cleaning solution use in Safety and mildness, body of not hurting sb.'s feelings, protect skin.Alkyl-polyoxyethylene ether acetate biological degradability is good, and skin is made With gentle, the obstruction to enzyme is few, has good stability in hard water and detergency.Polyoxyethylene lauryl ether has excellent washing Wash, emulsifying, dispersion, moistening, the function such as solubilising, and foaming power is strong, easily rinses, and detergency is excellent；It is to skin in surfactant One of minimum kind of skin zest.It can reduce their zest with various surfactant compounds, improves the property of product Energy.Wherein, described plant polyenoid phenol polyethenoxy ether preferably uses to be had by Jiangsu Province, China Changshu resistance to element biomaterial science and technology Limit company produce, and the application propose before market sale model NSF 10E plant polyenoid phenol polyoxy second Alkene ether, key component comes from natural plants, and biological degradability is very good.There is efficient washing performance, to animal and plant fat Removal ability is strong, water emulsification performance good to machinery oil, mineral oil washability, and foam is low, has well with other surfaces activating agent Compatibility.
Ethylene glycol bisthioglycolate stearic acid：Good with the surfactant intermiscibility that the present invention provides, it is combined in above-mentioned surfactant In thing, heating is configured to Pearl Concentrate, and can embody its stable pearl effect, the pearly-lustre relatively fruit of generation fine and smooth so that after cleaning Car body lacquer painting optical effect more preferably., skin care non-stimulated to skin.Also there is antistatic property, prevent dust from sticking.
Sodium stearate：Due to sodium stearate good water solubility, with respect to traditional silicone oil, palm wax, wipe more in use Convenient, the quick protective film that formation is uniform and smooth, light is durable can be painted in car after use, sodium stearate has skin moistening to make simultaneously With.
Soy broth lecithin：There is good emulsibility, play protection skin effect.
Kazon：It is that safe efficient, the broad spectrum activity chemical product generally acknowledged in the world limits the use of preservative, play bactericidal effect, Increase cleaning solution stability and effect duration.
The present invention provide multipurpose high-efficiency environment-protecting clean liquid in cleaning process, by sodium polyacrylate and metal ion Chelation and offer alkaline buffer condition and cohesion so that general dirt, grease, dust etc. be easier with The surfactant that the present invention provides combines, and accelerates cleaning efficiency, makes it difficult to dirt, grease of cleaning etc. simultaneously and is easier Be combined with the surfactant in the present invention, improve degree of cleaning；In cleaning process, sodium stearate can be in cleaned object table Face forms one layer of uniform protecting film, and ethylene glycol bisthioglycolate stearic acid cooperation sodium stearate forms brightness enhancement layer in protecting film, improves The brightness on cleaned object surface, enhances the stability of protecting film simultaneously.The surfactant adopting in the present invention can be right The stearic upper photosensitiveness of ethylene glycol bisthioglycolate plays potentiation, improves polishing effect further.Using ethylene glycol bisthioglycolate in the present invention Stearic acid, as glazing agent, mutually collaborative with sodium stearate can not only collectively form protecting film in use, and have Have and be easy to clean the advantage being easily dispersed, can be easy to uniformly wipe it in cleaned object surface formation glazing layer.The present invention Sodium carboxymethyl cellulose in cleaning solution and sodium polyacrylate cooperate, and enhance lubricity so that cleaning process is easier In carry out.
The multipurpose high-efficiency environment-protecting clean liquid that the present invention provides, easy to use, only need to use and soak cleaning solution of the present invention Fiber towel the article surface dirt that need clean is wiped, reuse clean absorbent towels after wiping and article surface wiped Wipe clean it becomes possible to reach thorough cleaning, plated film, the effect of glazing integration.
The cleaning solution that the present invention provides is not nitrogenous, the oxious component such as phosphorus, benzene, ammonia, environmentally safe.
The cleaning solution that the present invention provides directly is diluted using it is not necessary to add water during clean article, saves Substantial amounts of water resource.
The cleaning solution that the present invention provides improves the mildness of cleaning solution using nonionic surfactant, is effectively reduced Zest.Reduce the surface tension of solution, increased wettability.Usage amount is few simultaneously, low cost.
In the cleaning solution that the present invention provides, ethylene glycol bisthioglycolate stearic acid and non-ionic surface active use cooperatively, and can produce substantially Pearl effect, also there is skin care and antistatic property.
The cleaning solution wiping that the present invention provides is convenient, can paint quick formation in car uniform and smooth, bright after use Durable protective film, using the no variable color of rear paint film, foaming, obscission, no loss of gloss, no color differnece.
Specific embodiment：
The formula composition of example 1 below-embodiment 7 is as follows：
1. formula composition
Proportioning raw materials (mass ratio) configuration is by 1000 grams of calculating
Raw material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Sodium polyacrylate 2 2 2.5 2 3.5 4 4
Sodium carboxymethyl cellulose 4 3 5
Alkyl-polyoxyethylene ether acetate 3 6 5 3 4 6
Plant polyenoid phenol polyethenoxy ether 2 3 2 5 4 5
Polyoxyethylene lauryl ether 3 3 5 3 4 6 6
Soy broth lecithin 0.8 0.5 0.5
Glycol distearate 0.2 0.2 0.3 0.3 0.2
Sodium stearate 2 3 1 4 5
Kazon 1.5 2 1.5 1
Deionized water 990 983.8 978.0 983.2 976.2 975.8 979
The preparation method of above example 1- embodiment 7 is as follows：
Step one, weighs each component according to weight portion；
Step 2, takes sodium polyacrylate to be added in 10-20 part deionized water, stirs to being completely dissolved, adjust under room temperature System pH is 7.0-7.2, obtains mixed liquor one；
Step 3, by alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyethenoxy ether and polyoxyethylene lauryl ether It is added in 5-10 part deionized water, is warming up to 70-80 DEG C, after stirring and dissolving, is down to room temperature, and regulation system pH is 7.0- 7.2, obtain mixed liquor two；
Step 4, mixed liquor two is added in mixed liquor one, is subsequently adding surpluses water, and regulation system pH is 7.0-7.2, It is uniformly mixed, obtain multipurpose high-efficiency environment-protecting clean liquid.
In above example 1- embodiment 7, in formula, it is related to sodium carboxymethyl cellulose, glycol distearate, Semen sojae atricolor Liquid lecithin, sodium stearate and Kazon, in concrete preparation process, sodium carboxymethyl cellulose adds in step 2, Semen sojae atricolor Liquid lecithin or glycol distearate add in step 3, and sodium stearate or Kazon add in step 4.More than The regulator that in preparation method, regulation system pH uses is acetic acid or citric acid.
The multipurpose high-efficiency environment-protecting clean liquid that above example 1-7 prepares is processed food and food additive through country Plus the detection of agent Quality Supervision and Inspection Center (Nanjing) Nanjing Quality Supervision and Examination Institute, with reference to GB 9985-2000《Hand washing Tableware detergent》Standard, test result：Gross activity thing content ＞ 16%, pH (25 DEG C, 1% solution) 7.0-7.2, formaldehyde is not Detection, detergency is all higher than standard dish washing detergent.
According to HJ636-2012, GB11893-89 standard testing, ammonia-nitrogen content HJ636-2012 standard detection is 0, and phosphorus contains Amount GB11893-89 standard detection is 0.
Take acrylic acid paint film test plate (panel) to put in cleaning solution, soak 2 days, test result is：Paint film no variable color, bubbles, comes off Phenomenon, no loss of gloss, no color differnece.
In order to further illustrate the impact of performance of the multipurpose high-efficiency environment-protecting clean liquid of present invention offer, the present invention is in research and development During carried out a series of performance comparison checking test, below choose wherein several illustrating：
The cleaning solution that prepare the embodiment of the present invention 4 and the domestic applications patent of Application No. 201510209702.5 The product obtaining carries out automobile clean performance comparison, specific as follows：
The cleaning solution that prepare the embodiment of the present invention 4 and the domestic applications patent of Application No. 201610287635.3 The product obtaining carries out suitcase clean-up performance contrast, specific as follows：
Test content The embodiment of the present invention 4 201610287635.3
Cleannes 98% 85%
Brightness effect Good No
Pearly-lustre coating effects Uniform coated, light No
Vestige remains No Have
Using rear feel Salubrious lubrication Crude
Odor Odorless non-stimulated Pungent
Bacteriostasis Food stage sterilizes Have
Harmful to the person Harmless Harmful
The cleaning solution that prepare the embodiment of the present invention 4 and the domestic applications patent of Application No. 201410699255.1 The product obtaining carries out furniture clean-up performance contrast, specific as follows：
Test content The embodiment of the present invention 4 201610287635.3
Cleannes 98% 80%
Brightness effect Good No
Pearly-lustre coating effects Uniform coated, light No
Vestige remains No Have
Using rear feel Salubrious lubrication Crude
Odor Odorless non-stimulated Pungent
Bacteriostasis Food stage sterilizes Have
Harmful to the person Harmless Harmful
The multipurpose high-efficiency environment-protecting clean liquid providing for the present invention, inventor has carried out a series of on stream Performance comparison is tested, and chosen below several illustrates：
Test one, using succinic acid dibutyl ester sodium sulfonate, sucrose ester, alkyl phenol polyoxyethyl ether, aliphatic alcohol polyethenoxy Ether, 2-Sulfosuccinic acid diisobutyl ester sodium sulfonate, dodecylbenzene sodium sulfonate, nonylphenol polyethylene oxide ether ammonium sulfate are lived as surface Property agent, above surfactant carries out two or three of compounding interpolation, replaces the surfactant in the embodiment of the present invention 1, The car washing liquid preparing is used for car surface and cleans, and result test shows that the decontamination speed of cleaning solution is low with completeness aspect Cleaning agent in embodiment 1；After removing the sodium polyacrylate component in embodiment 1 simultaneously, the cleaning solution performance for preparing The cleaning solution obtaining significantly lower than embodiment 1.Illustrate that the surfactant providing in the present invention is mutually reached with sodium polyacrylate Coordinated effect, improves cleaning performance jointly.Present invention research shows, in cleaning process, sodium polyacrylate can There is provided alkaline buffer condition and simultaneously being chelated with the metal ion in dirt, there is provided cohesion is so that typically Dirt, grease, dust etc. the surfactant that is easier to provide with the present invention be combined, accelerate cleaning efficiency, simultaneously so that It is difficult to dirt, grease of cleaning etc. to be easier to be combined with the surfactant in the present invention, improve degree of cleaning.Grind further Study carefully discovery, the surfactant in cleaning solution of the present invention has not only acted as fast decontaminating effect, ethylene glycol bisthioglycolate can be strengthened simultaneously The polishing effect of stearate.
Test two, prepares cleaning solution using inventive formulation, but does not add sodium stearate, body surface meeting after cleaning Form certain polishing effect, but glazing degree is poor, somewhat firmly wiping will be clearly visible bright finish and is destroyed, and cleaning After terminating body surface natural drying, the glazing layer on surface is highly susceptible to pollute, and illustrates that light stability is bad；Add Hard Fat After sour sodium, one layer of fine and close protecting film can be left in body surface after cleaning, and the stability of film is very well, dries stablizing of caudacoria Property very well, and be not easy to be contaminated again.Sodium stearate and both the glycol distearates adopting in the present invention is described In the cleaning liquid system that the present invention provides can mutual Synergistic, reach more preferable plated film glossiness-giving effect.

Claims (10)

1. multipurpose high-efficiency environment-protecting clean liquid is it is characterised in that this cleaning solution includes following components：Live in sodium polyacrylate, surface Property agent and deionized water.
2. multipurpose high-efficiency environment-protecting clean liquid according to claim 1 is it is characterised in that surfactant is alkyl polyoxy Two or more group any in vinyl Ether acetass, plant polyenoid phenol polyethenoxy ether or polyoxyethylene lauryl ether Close.
3. multipurpose high-efficiency environment-protecting clean liquid according to claim 1 is it is characterised in that also include sodium stearate or second two One of alcohol distearate or two kinds.
4. multipurpose high-efficiency environment-protecting clean liquid according to claim 1 is it is characterised in that also include soy broth lecithin Any one or a few in fat, Kazon or sodium carboxymethyl cellulose.
5. multipurpose high-efficiency environment-protecting clean liquid is it is characterised in that this cleaning solution includes following component in parts by weight：
Sodium polyacrylate 0.2-0.4 part, deionized water 97.9-99.0 part and surfactant；Wherein surfactant is selected from alkane Base polyethenoxy ether acetic acid ester 0.3-0.6 part, plant polyenoid phenol polyethenoxy ether 0.2-0.5 part or polyoxyethylene lauryl ether In 0.3-0.6 part any two or three.
6. multipurpose high-efficiency environment-protecting clean liquid according to claim 5 is it is characterised in that also include second in parts by weight One of glycol distearate 0.02-0.03 part or sodium stearate 0.1-0.5 part or two kinds.
7. multipurpose high-efficiency environment-protecting clean liquid according to claim 5 is it is characterised in that also include carboxylic in parts by weight In sodium carboxymethylcellulose pyce 0.3-0.5 part, soy broth lecithin 0.05-0.08 part or Kazon 0.1-0.2 part any one or Several.
8. the preparation method of the multipurpose high-efficiency environment-protecting clean liquid described in claim 5 is it is characterised in that comprise the following steps：
Step one, weighs each component according to weight portion；
Step 2, takes sodium polyacrylate to be added in 10-20 part deionized water, stirs to being completely dissolved, regulation system under room temperature PH is 7.0-7.2, obtains mixed liquor one；
Step 3, surfactant is added in 5-10 part deionized water, is warming up to 70-80 DEG C, be down to room after stirring and dissolving Temperature, and regulation system pH is 7.0-7.2, obtains mixed liquor two；
Step 4, mixed liquor two is added in mixed liquor one, is subsequently adding surpluses water, and regulation system pH is 7.0-7.2, stirring Mix homogeneously, obtains multipurpose high-efficiency environment-protecting clean liquid.
9. the preparation method of multipurpose high-efficiency environment-protecting clean liquid according to claim 8 is it is characterised in that regulation system pH Regulator used is acetic acid or citric acid.
10. the preparation method of multipurpose high-efficiency environment-protecting clean liquid according to claim 8 is it is characterised in that in step 2 Add the second two adding in sodium carboxymethyl cellulose 0.3-0.5 part in parts by weight and/or step 3 in parts by weight In one of alcohol distearate 0.02-0.03 part or soy broth lecithin 0.05-0.08 part or two kinds and/or step 4 Add one of Kazon 0.1-0.2 part in parts by weight or sodium stearate 0.1-0.5 part or two kinds.
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