CN111218219A - Water-based resin cleaning and polishing agent - Google Patents

Water-based resin cleaning and polishing agent Download PDF

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Publication number
CN111218219A
CN111218219A CN202010110414.5A CN202010110414A CN111218219A CN 111218219 A CN111218219 A CN 111218219A CN 202010110414 A CN202010110414 A CN 202010110414A CN 111218219 A CN111218219 A CN 111218219A
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Prior art keywords
parts
namely
water
polishing agent
ethanol
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CN202010110414.5A
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Chinese (zh)
Inventor
丁丽丽
余桂林
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Liaoning Deljia New Material Technology Co Ltd
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Liaoning Deljia New Material Technology Co Ltd
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Priority to CN202010110414.5A priority Critical patent/CN111218219A/en
Publication of CN111218219A publication Critical patent/CN111218219A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/14Other polishing compositions based on non-waxy substances
    • C09G1/16Other polishing compositions based on non-waxy substances on natural or synthetic resins
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/74Carboxylates or sulfonates esters of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a water-based resin cleaning and polishing agent which comprises the following raw materials in parts by weight: 1-7 parts of acrylic resin, 5-30 parts of ethanol, 5-25 parts of butyl acetate, 0.1-3 parts of silicone oil, 1-5 parts of oleic acid, 801-10 parts of tween and 50-80 parts of water. The polishing agent prepared by combining the water-based resin with the solvent and the surfactant has higher cleaning and polishing effects on wooden furniture and leather products, and is low in cost, non-toxic, odorless, economical and environment-friendly.

Description

Water-based resin cleaning and polishing agent
Technical Field
The invention relates to a water-based resin cleaning and polishing agent.
Background
The glazing agent is a surface protection article, also called as glazing wax, brightener and the like, and is generally used for cleaning, decontaminating, glazing, protecting and the like of the surfaces of materials such as vehicles, ship bodies, household equipment, furniture, floors, partition boards, instruments, electrical appliances and the like, and is used for short-term surface maintenance. The simple preparation method is that various natural waxes (glazing auxiliary agents) with the brightening effect are dissolved in solvents such as turpentine and the like to prepare soft paste, the soft paste is coated on the surface of a material to be glazed when the soft paste is used, and then the soft paste is uniformly wiped by using a rag. With the rapid development of the petrochemical industry, various novel glazing aids have been developed in the development and research of modern glazing agents, and besides natural wax as a main raw material, novel glazing aids such as dimethyl silicone oil, white oil and the like are used as effective glazing components. In addition, the polishing agent is also added with petroleum solvent, emulsifying assistant, decontamination assistant, antioxidant assistant, antiseptic and bactericidal assistant, antistatic assistant, antirust assistant, ultraviolet absorption assistant and other components, so that the expanded use performance and the product quality of the polishing agent are further improved. However, the cost of the natural wax agent is high, and the glazing agent prepared by the natural wax agent needs to be fully mixed before use, otherwise, the glazing uniformity is extremely easy to reduce.
The patent CN200910179339.1 discloses an environment-friendly antibacterial glazing agent and a preparation method thereof, and the adopted raw materials comprise 0.6-5.0 parts of wax agent, 1.0-8.0 parts of silicone oil, 2.0-9.0 parts of natural solvent oil, 3.0-10.0 parts of surfactant, 0.1-1.2 parts of bactericide, 0.05-0.3 part of preservative, 0.1-0.8 part of essence, 0.05-1.0 part of stabilizer and 100 parts of deionized water. It also uses a small amount of wax as raw material, and adds a large amount of solvent oil (such as oleic acid, etc.) to make the wax and other components fully mixed, so that the cost of said polishing agent is high and its odor is bad. The polishing agent prepared from the raw materials which can replace the wax agent has high uniformity and stability, higher polishing effect, reduced production cost and no toxicity and odor, and is the problem to be solved by the industry at present.
Disclosure of Invention
Based on the above, the invention aims to provide a non-toxic, odorless, economical and environment-friendly water-based resin cleaning and glazing agent. The water-based resin is used as a raw material to replace a wax agent to prepare a low-cost glazing agent, and the glazing agent can form a thin compact bright layer on the surface of an object and has an obvious glazing effect.
In order to achieve the purpose, the invention provides the following scheme:
a water-based resin cleaning and polishing agent comprises the following raw materials in parts by weight:
1-7 parts of acrylic resin,
5-30 parts of ethanol, namely,
5-25 parts of butyl acetate, namely,
0.1 to 3 portions of silicone oil,
1-5 parts of oleic acid, namely,
the weight portion of the Tween 801-10,
50-80 parts of water.
Specifically, in some embodiments, the aqueous resin cleaning glazing agent of the present invention comprises the following raw materials in parts by weight:
1-4 parts of acrylic resin,
10-20 parts of ethanol, namely ethanol,
5-15 parts of butyl acetate, namely,
0.5 to 2 portions of silicone oil,
1-3 parts of oleic acid, namely,
the weight portion of the Tween 803-8,
60-70 parts of water.
Further, the water-based resin cleaning and polishing agent comprises the following raw materials in parts by weight:
2 parts of acrylic resin, namely 2 parts of acrylic resin,
15 parts of ethanol, namely 15 parts of ethanol,
10 parts of butyl acetate, namely 10 parts of butyl acetate,
1 part of silicone oil, namely 1 part of silicone oil,
2 parts of oleic acid, namely 2 parts of oleic acid,
805 parts of Tween, and a pharmaceutically acceptable carrier,
and 65 parts of water.
The polishing agent is used for floors, other wooden furniture and leather products, and can remove stains on the surface by wiping the polishing agent and form a compact bright layer on the surface.
Compared with the prior art, the invention discloses the following technical effects: the polishing agent is prepared by taking water-based resin as a raw material and combining the other components, has good cleaning capability on floors, wooden furniture and leather products, high glossiness and strong water resistance, overcomes the defect that other cleaning can not polish, and has the advantages that when an object is scrubbed, a thin compact and bright layer is formed on the surface of the object, the shape of the object is not influenced, and the functions of decontamination, water prevention and polishing protection are realized. The glazing agent is nontoxic, odorless, economical and environment-friendly, and the liquid is in a uniform and transparent state and can be directly used.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to specific embodiments, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention aims to provide a water-based resin cleaning and polishing agent.
The present invention will be described in further detail with reference to specific embodiments in order to make the above objects, features and advantages more apparent and understandable.
Example 1
The water-based resin cleaning and polishing agent is prepared by uniformly mixing the following raw materials in parts by weight:
2 parts of acrylic resin, namely 2 parts of acrylic resin,
15 parts of ethanol, namely 15 parts of ethanol,
10 parts of butyl acetate, namely 10 parts of butyl acetate,
1 part of silicone oil, namely 1 part of silicone oil,
2 parts of oleic acid, namely 2 parts of oleic acid,
805 parts of Tween, and a pharmaceutically acceptable carrier,
and 65 parts of water.
Comparative example 1
A glazing agent is prepared according to the technical scheme disclosed in embodiment 1 of patent CN200910179339.1, and the specific steps are as follows:
adding 7.0 parts of olive oil and 3.5 parts of wax agent (the weight parts of beeswax and carnauba wax are 1: 6, and the mixture is uniform) into a reaction kettle, and stirring and dissolving at the rotating speed of 400 r/min; sequentially adding 6.0 parts of silicone oil (uniform mixture of medical dimethyl silicone oil and amino siloxane in a weight ratio of 5: 1) at a rotating speed of 800r/min, span-602.0 parts and 1.0 part of deionized water, and stirring for 20 min; heating and dissolving 5.0 parts of surfactant (an even mixture of alkyl polyglycoside and tween-80 in a weight ratio of 3: 2), 0.8 part of bactericide (an even mixture of water-soluble chitosan and nano-silver in a weight ratio of 3: 5) and 0.1 part of sorbic acid in 6.0 parts of deionized water at 50 ℃ to prepare a premixed solution; slowly adding the premixed solution into the reaction kettle at the rotating speed of 1000r/min, and stirring for 30 min; adding the rest deionized water at the rotating speed of 1400r/min, and stirring for 50 min; cooling to room temperature, adding 0.4 part of pineapple essence and 1.0 part of edible acetic acid, stirring uniformly at the rotating speed of 200r/min, and obtaining an environment-friendly antibacterial glazing agent liquid material with the quality inspection pH value of 7.0 +/-0.5; taking 200g of the prepared environment-friendly antibacterial glazing agent liquid material, mixing with deodorized Liquefied Petroleum Gas (LPG) according to the weight ratio of 5: 1, filling into a 450mL aerosol sealing tank through a professional aerosol filling process, and matching with a valve and a press head to obtain a finished product.
Comparative example 2
The glazing agent is prepared by uniformly mixing the following raw materials in parts by weight:
15 parts of ethanol, namely 15 parts of ethanol,
10 parts of butyl acetate, namely 10 parts of butyl acetate,
1 part of silicone oil, namely 1 part of silicone oil,
2 parts of oleic acid, namely 2 parts of oleic acid,
805 parts of Tween, and a pharmaceutically acceptable carrier,
and 65 parts of water.
Comparative example 3
The glazing agent is prepared by uniformly mixing the following raw materials in parts by weight:
2 parts of acrylic resin, namely 2 parts of acrylic resin,
15 parts of ethanol, namely 15 parts of ethanol,
1 part of silicone oil, namely 1 part of silicone oil,
2 parts of oleic acid, namely 2 parts of oleic acid,
805 parts of Tween, and a pharmaceutically acceptable carrier,
and 65 parts of water.
The glazing agents prepared in example 1 of the present invention and comparative documents 1 to 3 were used for automobile interior leather, and the test results are shown in table 1.
TABLE 1
Figure BDA0002389795730000051
As can be seen from Table 1, the polishing agent prepared in example 1 of the present invention has a good cleaning effect and an excellent polishing effect on leather products. The glazing agent of the invention is non-toxic and odorless, and has low cost.
The embodiments in the present description are described in a progressive manner, each embodiment focuses on differences from other embodiments, and the same and similar parts among the embodiments are referred to each other. For the system disclosed by the embodiment, the description is relatively simple because the system corresponds to the method disclosed by the embodiment, and the relevant points can be referred to the method part for description.
The principles and embodiments of the present invention have been described herein using specific examples, which are provided only to help understand the method and the core concept of the present invention; meanwhile, for a person skilled in the art, according to the idea of the present invention, the specific embodiments and the application range may be changed. In view of the above, the present disclosure should not be construed as limiting the invention.

Claims (4)

1. The water-based resin cleaning and polishing agent is characterized by comprising the following raw materials in parts by weight:
1-7 parts of acrylic resin,
5-30 parts of ethanol, namely,
5-25 parts of butyl acetate, namely,
0.1 to 3 portions of silicone oil,
1-5 parts of oleic acid, namely,
the weight portion of the Tween 801-10,
50-80 parts of water.
2. The aqueous resin cleaning glazing agent according to claim 1, characterized by comprising the following raw materials in parts by weight:
1-4 parts of acrylic resin,
10-20 parts of ethanol, namely ethanol,
5-15 parts of butyl acetate, namely,
0.5 to 2 portions of silicone oil,
1-3 parts of oleic acid, namely,
the weight portion of the Tween 803-8,
60-70 parts of water.
3. The aqueous resin cleaning glazing agent according to claim 2, characterized by comprising the following raw materials in parts by weight:
2 parts of acrylic resin, namely 2 parts of acrylic resin,
15 parts of ethanol, namely 15 parts of ethanol,
10 parts of butyl acetate, namely 10 parts of butyl acetate,
1 part of silicone oil, namely 1 part of silicone oil,
2 parts of oleic acid, namely 2 parts of oleic acid,
805 parts of Tween, and a pharmaceutically acceptable carrier,
and 65 parts of water.
4. The use of the aqueous resin cleaning and polishing agent according to any one of claims 1 to 3, wherein the raw materials are mixed uniformly in proportion to form the aqueous resin cleaning and polishing agent, and then the aqueous resin cleaning and polishing agent is used for wiping floors, other wooden furniture and leather products to form a compact and bright layer on the surface of an object.
CN202010110414.5A 2020-02-24 2020-02-24 Water-based resin cleaning and polishing agent Pending CN111218219A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112694837A (en) * 2020-12-24 2021-04-23 广东好顺欧迪斯科技股份有限公司 Furniture cleaning, sterilizing and polishing agent and preparation method thereof, and furniture cleaning, sterilizing and polishing aerosol and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109490A (en) * 1994-03-31 1995-10-04 广东省测试分析研究所 Multipurpose dirt removing and polishing agent
CN101418188A (en) * 2008-12-01 2009-04-29 广东三和化工科技有限公司 Coloring and glazing emulsification paste and preparation method, colored leather lustering agent and canning method
CN101705055A (en) * 2009-09-25 2010-05-12 广东三和化工科技有限公司 Environment-friendly antibiosis glazing agent and preparation method thereof
CN104863013A (en) * 2015-04-24 2015-08-26 句容市鼎盛纸箱包装有限公司 Carton lustering agent and preparation method thereof
CN107097460A (en) * 2017-04-10 2017-08-29 滁州卷烟材料厂 It is a kind of that there is the moistureproof corrugated case with anti-dust performance
US20190233762A1 (en) * 2016-09-08 2019-08-01 Linkage Technology Switzerland SA Multiuse, high-efficiency and environment-friendly cleaning solution and preparation method therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109490A (en) * 1994-03-31 1995-10-04 广东省测试分析研究所 Multipurpose dirt removing and polishing agent
CN101418188A (en) * 2008-12-01 2009-04-29 广东三和化工科技有限公司 Coloring and glazing emulsification paste and preparation method, colored leather lustering agent and canning method
CN101705055A (en) * 2009-09-25 2010-05-12 广东三和化工科技有限公司 Environment-friendly antibiosis glazing agent and preparation method thereof
CN104863013A (en) * 2015-04-24 2015-08-26 句容市鼎盛纸箱包装有限公司 Carton lustering agent and preparation method thereof
US20190233762A1 (en) * 2016-09-08 2019-08-01 Linkage Technology Switzerland SA Multiuse, high-efficiency and environment-friendly cleaning solution and preparation method therefor
CN107097460A (en) * 2017-04-10 2017-08-29 滁州卷烟材料厂 It is a kind of that there is the moistureproof corrugated case with anti-dust performance

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112694837A (en) * 2020-12-24 2021-04-23 广东好顺欧迪斯科技股份有限公司 Furniture cleaning, sterilizing and polishing agent and preparation method thereof, and furniture cleaning, sterilizing and polishing aerosol and preparation method thereof

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Application publication date: 20200602