CN101812383A - Disinfecting detergent and preparation method thereof - Google Patents
Disinfecting detergent and preparation method thereof Download PDFInfo
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- CN101812383A CN101812383A CN201010177957A CN201010177957A CN101812383A CN 101812383 A CN101812383 A CN 101812383A CN 201010177957 A CN201010177957 A CN 201010177957A CN 201010177957 A CN201010177957 A CN 201010177957A CN 101812383 A CN101812383 A CN 101812383A
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Abstract
The invention provides a disinfecting detergent and a preparation method thereof. The disinfecting detergent contains didecyldimethylammonium chloride, didecyldimethylammonium bromide, poly(hexamethylene biguanide) hydrochloride, dodecyldimethylbenzylammonium chloride, fatty alcohol-polyoxyethylene ether (9), fatty alcohol polyoxyethylen ether (7), fatty alcohol polyoxyethylen ether (8), alkyl polyglucoside, alkanolamides of fatty acids, lauramidopropyl betaine, essence, citric acid monohydrate food grade and deionized water. The method has the advantages of environmentally-friendliness, combination of disinfection and cleaning, synchronous completion of stain removal and disinfection, safety, unstimulating property, and resource conservation.
Description
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Technical field
The invention belongs to the detergent composition field, specifically a kind of washing composition and preparation method thereof with sterilizing function.
Background technology
Raising along with standard of living and quality of life; the human consumer strengthens gradually to the protection consciousness of self health; especially the appearance of severe acute respiratory syndrome associated coronavirus in 2003, and, make the sterilizing article increase in demand at present just in the propagation of popular A (H 1 N 1) virus.
Sterilization is a kind of demand of clothing " thoroughly " cleaning.Visible can reach that the clothes disinfector of sterilisation effect can only be simple on the market to the clothing sterilization, and can not clean spot, also needs clothing is washed in addition, removes dirt; The washing composition that has sterilization effect then can not reach disinfecting power again, does not satisfy the demand of " thoroughly " cleaning of human consumer.
Therefore, need a kind of laundry detergent on the market, only, both can remove the spot that produces owing to dress, can reach the usefulness of high sterilizing rate again by conventional washing.The water power consumption of saving cleaning time and needing thus.
Summary of the invention
The purpose of this invention is to provide a kind of detergent with sterilizing and preparation method thereof, contain two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing; The present invention is environmentally friendly, will sterilize and cleaning function combines together, removes stain, sterilization is finished simultaneously, and nontoxic non-stimulated, economizes on resources.
The objective of the invention is to realize by following technical proposals:
A kind of detergent with sterilizing contains two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing; The weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70;
Detersive power of the present invention reaches national sector standard QB1224 requirement; Sterilizing power of the present invention reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The objective of the invention is to realize by following another technical scheme:
A kind of preparation method of detergent with sterilizing contains two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing; The weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70;
This preparation method's steps in sequence is as follows:
A. change material:
A. with 40%~50% in 40 ℃~50 ℃ the described deionized water, in the addingization material still, add described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, fatty acid alkyl amide, alkyl-glucoside, lauryl amido propyl betaine successively according to said ratio respectively then, stir, obtain mixed liquor A;
B. in described mixed liquor A, add described pair of decyl alkyl dimethyl ammonium chloride, two decyl dimethyl brometo de amonio, dodecyl benzyl dimethyl ammonium chloride, hexamethylene and remaining described deionized water according to said ratio, stir, obtain mixed liquid B;
C. in described mixed liquid B, add described essence, regulate pH value to 6.5~8.0, obtain stoste with described Citric acid monohydrate Food grade according to said ratio;
D. described stoste is stirred, carry out filtration treatment, obtain described detergent with sterilizing, stand for standby use; In the described filtration treatment, adopt 200 order nylon screens;
B. described detergent with sterilizing is detected, can, decals, detection vanning, get product.
Compared with the prior art the present invention has following beneficial effect:
1. the present invention adopts two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio and dodecyl benzyl dimethyl ammonium chloride, hexamethylene composite, by penetration enhancer aliphatic alcohol polyethenoxy (8) ether effect, make it useful effect in harmful microorganism, improve sterilizing power, and can stably store;
2. the present invention adopts nonionogenic tenside: aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, fatty acid alkyl amide, alkyl-glucoside play emulsification, infiltration, soil-removing action as the major surfaces promoting agent, composite with gentle, the low amphoterics lauryl amido propyl betaine that stimulates, the texture of increase fabric sofetening in clean textile.
3. the present invention is neutral prescription, by rational composite and interpolation cosurfactant, not only reduced the negative impact that cats product is removed dirt, and sterilization effect has been played synergy, and given the present invention and do not hindered fabric, the gentle characteristic of skin irritation not.
4. detersive power of the present invention reaches national sector standard QB1224 requirement; Sterilizing power of the present invention reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
5. product of the present invention is easy to use, can accomplish to wash that sterilization is once finished, the cost performance height; The laundry cost only is 40% of a market like product.Save energy is raised the efficiency.
6. the present invention is environmentally friendly, and is nontoxic, non-stimulated.
Embodiment
Embodiment 1:
A kind of preparation method of detergent with sterilizing contains two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing; The weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70;
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment is technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each component in the described detergent with sterilizing can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio and dodecyl benzyl dimethyl ammonium chloride, hexamethylene are cats product in the present embodiment, composite have a sterilizing function, can be in the process of normal washing the kill harmful microorganism; The composite of above-mentioned several materials makes it useful effect in harmful microorganism by penetration enhancer aliphatic alcohol polyethenoxy (8) ether effect, improves sterilizing power, and can stably store;
Aliphatic alcohol polyethenoxy in the present embodiment (9) ether, aliphatic alcohol polyethenoxy (8) ether aliphatic alcohol polyethenoxy (7) ether, fatty acid alkyl amide, alkyl-glucoside is composite to have good wetting, infiltration, foaming, dispersion, emulsifying capacity, the soil removability that the system of giving is good can effectively be removed dirts such as greasy dirt that clothing is infected with, dish stain.
Lauryl amido propyl betaine, alkyl-glucoside can reduce the pungency of system, foam exquisiteness, gentleness, the texture of giving fabric sofetening in the present embodiment.
Present embodiment adopts nonionogenic tenside: aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, fatty acid alkyl amide, alkyl-glucoside play emulsification, infiltration, soil-removing action as the major surfaces promoting agent, composite with gentle, the low amphoterics lauryl amido propyl betaine that stimulates, the texture of increase fabric sofetening in clean textile.
Present embodiment is neutral prescription, by rational composite and interpolation cosurfactant, not only reduced the negative impact that cats product is removed dirt, and sterilization effect has been played synergy, and given the present invention and do not hindered fabric, the gentle characteristic of skin irritation not.
The detersive power of present embodiment reaches national sector standard QB1224 requirement; The sterilizing power of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The present embodiment product is easy to use, can accomplish to wash that sterilization is once finished, the cost performance height; The laundry cost only is 40% of a market like product.Save energy is raised the efficiency.
Present embodiment is environmentally friendly, and is nontoxic, non-stimulated.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 4
Two decyl dimethyl brometo de amonios 1
Hexamethylene 0.5
Dodecyl benzyl dimethyl ammonium chloride 3
Aliphatic alcohol polyethenoxy (9) ether 10
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 5
Alkyl-glucoside 5
Fatty acid alkyl amide 3
Lauryl amido propyl betaine 2
Essence 0.25
Citric acid monohydrate Food grade 0.05
Deionized water 65.2;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 4
Two decyl dimethyl brometo de amonios 2
Hexamethylene 3
Dodecyl benzyl dimethyl ammonium chloride 0.5
Aliphatic alcohol polyethenoxy (9) ether 15
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 8
Fatty acid alkyl amide 1
Lauryl amido propyl betaine 2
Essence 0.35
Citric acid monohydrate Food grade 0.2
Deionized water 59.95;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 6
Two decyl dimethyl brometo de amonios 1
Hexamethylene 1
Dodecyl benzyl dimethyl ammonium chloride 2
Aliphatic alcohol polyethenoxy (9) ether 10
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (8) ether 5
Alkyl-glucoside 1
Fatty acid alkyl amide 2
Lauryl amido propyl betaine 5
Essence 0.3
Citric acid monohydrate Food grade 0.05
Deionized water 64.65;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2
Two decyl dimethyl brometo de amonios 3
Hexamethylene 1.5
Dodecyl benzyl dimethyl ammonium chloride 2
Aliphatic alcohol polyethenoxy (9) ether 11
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 6
Fatty acid alkyl amide 3
Lauryl amido propyl betaine 8
Essence 0.3
Citric acid monohydrate Food grade 0.15
Deionized water 59.05;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 6:
Present embodiment is the preparation method of embodiment 1~5.
A kind of preparation method of detergent with sterilizing contains two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing; The weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70;
This preparation method's steps in sequence is as follows:
A. change material:
A. with 40%~50% in 40 ℃~50 ℃ the described deionized water, in the addingization material still, add described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, fatty acid alkyl amide, alkyl-glucoside, lauryl amido propyl betaine successively according to said ratio respectively then, stir, obtain mixed liquor A;
B. in described mixed liquor A, add described pair of decyl alkyl dimethyl ammonium chloride, two decyl dimethyl brometo de amonio, dodecyl benzyl dimethyl ammonium chloride, hexamethylene and remaining described deionized water successively according to said ratio, stir, obtain mixed liquid B;
C. in described mixed liquid B, add described essence, regulate pH value to 6.5~8.0, obtain stoste with described Citric acid monohydrate Food grade according to said ratio;
D. described stoste is stirred, carry out filtration treatment, obtain described detergent with sterilizing, stand for standby use; In the described filtration treatment, adopt 200 order nylon screens;
B. the sterilization of described washing composition is detected, can, decals, detection vanning, get product.
In above-mentioned preparation process, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can buy to obtain on market.
Claims (7)
1. a detergent with sterilizing contains two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this washing composition; The weight ratio of each component is in this washing composition:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70.
2. detergent with sterilizing according to claim 1 is characterized in that: the weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 4
Two decyl dimethyl brometo de amonios 1
Hexamethylene 0.5
Dodecyl benzyl dimethyl ammonium chloride 3
Aliphatic alcohol polyethenoxy (9) ether 10
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 5
Alkyl-glucoside 5
Fatty acid alkyl amide 3
Lauryl amido propyl betaine 2
Essence 0.25
Citric acid monohydrate Food grade 0.05
Deionized water 65.2.
3. detergent with sterilizing according to claim 1 is characterized in that: the weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 4
Two decyl dimethyl brometo de amonios 2
Hexamethylene 3
Dodecyl benzyl dimethyl ammonium chloride 0.5
Aliphatic alcohol polyethenoxy (9) ether 15
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 8
Fatty acid alkyl amide 1
Lauryl amido propyl betaine 2
Essence 0.35
Citric acid monohydrate Food grade 0.2
Deionized water 59.95.
4. detergent with sterilizing according to claim 1 is characterized in that: the weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 6
Two decyl dimethyl brometo de amonios 1
Hexamethylene 1
Dodecyl benzyl dimethyl ammonium chloride 2
Aliphatic alcohol polyethenoxy (9) ether 10
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (8) ether 5
Alkyl-glucoside 1
Fatty acid alkyl amide 2
Lauryl amido propyl betaine 5
Essence 0.3
Citric acid monohydrate Food grade 0.05
Deionized water 64.65.
5. detergent with sterilizing according to claim 1 is characterized in that: the weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2
Two decyl dimethyl brometo de amonios 3
Hexamethylene 1.5
Dodecyl benzyl dimethyl ammonium chloride 2
Aliphatic alcohol polyethenoxy (9) ether 11
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 6
Fatty acid alkyl amide 3
Lauryl amido propyl betaine 8
Essence 0.3
Citric acid monohydrate Food grade 0.15
Deionized water 59.05.
6. the preparation method of a detergent with sterilizing is characterized in that: contain two decyl alkyl dimethyl ammonium chlorides, two decyl dimethyl brometo de amonio, hexamethylene, dodecyl benzyl dimethyl ammonium chloride, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, fatty acid alkyl amide, lauryl amido propyl betaine, essence, Citric acid monohydrate Food grade, deionized water in this detergent with sterilizing;
The weight ratio of each component is in this detergent with sterilizing:
Two decyl alkyl dimethyl ammonium chlorides 2~6
Two decyl dimethyl brometo de amonios 1~3
Hexamethylene 0.5~3
Dodecyl benzyl dimethyl ammonium chloride 0.5~3
Aliphatic alcohol polyethenoxy (9) ether 10~15
Aliphatic alcohol polyethenoxy (7) ether 1~2
Aliphatic alcohol polyethenoxy (8) ether 3~5
Alkyl-glucoside 1~8
Fatty acid alkyl amide 1~3
Lauryl amido propyl betaine 2~8
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 55~70;
Preparation method's steps in sequence is as follows:
A. change material:
A. with 40%~50% in 40 ℃~50 ℃ the described deionized water, in the addingization material still, add described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (8) ether, fatty acid alkyl amide, alkyl-glucoside, lauryl amido propyl betaine successively according to said ratio respectively then, stir, obtain mixed liquor A;
B. in described mixed liquor A, add described pair of decyl alkyl dimethyl ammonium chloride, two decyl dimethyl brometo de amonio, dodecyl benzyl dimethyl ammonium chloride, hexamethylene and remaining described deionized water according to said ratio, stir, obtain mixed liquid B;
C. in described mixed liquid B, add described essence, regulate pH value to 6.5~8.0, obtain stoste with described Citric acid monohydrate Food grade according to said ratio;
D. described stoste is stirred, carry out filtration treatment, obtain described detergent with sterilizing, stand for standby use;
B. described detergent with sterilizing is detected, can, decals, detection vanning, get product.
7. the preparation method of detergent with sterilizing according to claim 6, it is characterized in that: described filtration treatment adopts 200 order nylon screens.
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CN103131547B (en) * | 2011-11-24 | 2016-05-25 | 段海平 | A kind of for Endowment Service Institution disinfecting and foreign flavor removing cleaning solution |
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