CN105828801A - Composition comprising cyclodextrin and its derivative, anionic surfactant and polyalkylene glycol ether of alcohol, and use thereof - Google Patents
Composition comprising cyclodextrin and its derivative, anionic surfactant and polyalkylene glycol ether of alcohol, and use thereof Download PDFInfo
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- CN105828801A CN105828801A CN201380081669.1A CN201380081669A CN105828801A CN 105828801 A CN105828801 A CN 105828801A CN 201380081669 A CN201380081669 A CN 201380081669A CN 105828801 A CN105828801 A CN 105828801A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/738—Cyclodextrins
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Abstract
The invention discloses a composition comprising cyclodextrin and its derivative, anionic surfactant and polyalkylene glycol ether of alcohol, and use thereof. The composition comprises cyclodextrin or its derivatives, anionic surfactants, and polyalkylene glycol ether of alcohols of alcohol of formula (II), CH 3(CH 2) a (OR) bOH (II) is provided, wherein: a is an integer of 4 to 14; b is an integer of 2 to 30; and R is an alkylene group.
Description
Technical field
The present invention relates to field of hair care.More particularly, it relates to be used for nursing keratin material, especially hair
Compositions, and the method using described compositions.
Background of invention
The known product with iridescent colors, moire or metal appearance, particularly cosmetics, with their aesthetic properties and abundant
Outward appearance is by the extensive appreciation of consumer.Produce the reagent of this effect be generally comprise crystal pearling agent (pearlescent or
Nacreous agents), it remains dispersed in compositions and reflects light.
Cyclodextrin has been used for preparing pearlescent composition.But, comprise the pearlescent composition of cyclodextrin over time
Passage has poor stability.EP 1499280, US2009/0074698 and EP1779840 disclose the stability with improvement
The particular composition comprising cyclodextrin with pearl effect.
In order to stablize described compositions, US2009/0074698 discloses and comprises specific cationic polymer and cyclodextrin
Cosmetic composition.
It is also known that cosmetic composition, good foam performance and the good conditioning performance of especially shampoo are to disappear
The person of expense is interested, especially under atmospheric factor effect or under mechanically or chemically process effect, such as dyeing, drift
White and/or hair-waving (permanent-waving) and there are those of sensitization (the most impaired and/or brittle) hair in various degree.
The most still there are the needs for new compositions, it has pearlescent appearance, has the stability of improvement, and
Good foaming and conditioning effect (that is, hair, untiing of the hair being especially dried is provided for hair after applying
(disentangling)).
Summary of the invention
It is an object of the invention to provide a kind of compositions, its comprise at least one cyclodextrin or derivatives thereof, at least one the moon from
Sub-surface activating agent and the polyalkylene glycol ethers of at least one alcohol.
More specifically, it is an object of the present invention to provide the compositions of the following component being included in aqueous phase:
A) at least one cyclodextrin or derivatives thereof；
B) at least one anion surfactant；With
C) polyalkylene glycol ethers of the alcohol of at least one formula (II),
CH3(CH2)a(OR)bOH (II)
Wherein:
A is the integer of 4-14；
B is the integer of 2-30；With
R is alkylidene.
It is a further object of the present invention to provide a kind of use above-mentioned composition for nursing keratin material, especially hair
Method.
Term " keratin material " refer to (around health, face and eyes) skin, hair, eyelashes, eyebrow, chaeta,
Fingernail, lip or mucosa.Preferably, it refers to keratin fiber, especially hair.
Find that this compositions has the stability of improvement, foaming and conditioning effect.
According to the present invention, described " conditioning effect " refers in particular to the hair being dried after applying compositions as above
Untie.
Detailed Description Of The Invention
According to the present invention, described compositions is included in aqueous phase:
A) at least one cyclodextrin or derivatives thereof；
B) at least one anion surfactant；With
D) polyalkylene glycol ethers of the alcohol of at least one formula (II),
CH3(CH2)a(OR)bOH (II)
Wherein:
A is the integer of 4-14；
B is the integer of 2-30；With
R is alkylidene.
Aqueous phase
The compositions of the present invention comprises aqueous phase.
Described aqueous phase comprises water and can comprise miscible organic solvents (under the room temperature of 20-25 ° of C), such as, contain
The monohydric alcohol of 2-6 carbon atom, such as ethanol or isopropanol；Polyhydric alcohol, especially contains 2-20 carbon atom, preferably comprises 2-10
Individual carbon atom and the polyhydric alcohol preferably comprising 2-6 carbon atom, such as glycerol, propylene glycol, butanediol, pentanediol, hexanediol, dipropyl
Glycol or diethylene glycol；Glycol ethers (especially containing 3-16 carbon atom) such as single-, two-or tripropylene glycol (C1-C4) alkyl ether,
Single-, two-or triethylene glycol (C1-C4) alkyl ether, and mixture.
Especially, the compositions of the present invention comprises 45 weight %-85 weight % based on the gross weight of described compositions, especially
It is 50 weight %-75 weight % and the aqueous phase of more preferably 55 weight %-65 weight %.
Cyclodextrin and derivant thereof
The compositions of the present invention comprises at least one cyclodextrin or derivatives thereof.
The oligosaccharide of cyclodextrin especially formula (I):
(I)
Wherein x is equal to 4 (its corresponding alpha-cyclodextrins), 5 (beta-schardinger dextrin-s) or 6 (gamma-cyclodextrins).
Wacker company especially can be used with title Cavamax®The beta-schardinger dextrin-that W7 sells, or Shandong newly reaches finely
The beta-schardinger dextrin-that chemical company (Shandong Xinda Fine Chemical) sells with title Beta-Cyclodextrin,
Wacker company is with title Cavamax®The gamma-cyclodextrin that W8 sells, or their mixture.
For the purposes of the present invention, term " cyclodextrin " is also represented by substituted cyclodextrin derivative, such as Methyl flamprop,
Particularly Wacker company is with title Cavasol®The methyl-B-cyclodextrin that W7 sells.
Preferably, the cyclodextrin of the present invention is unsubstituted.
Even further preferably, beta-schardinger dextrin-will be used.
According to the present invention, described cyclodextrin can represent 0.5 weight %-15 weight based on the gross weight of final composition
Amount %, preferably 1 weight %-10 weight %, preferably 1 weight %-5 weight % and be the most more preferably 1 weight %-2.5 weight %.
Anion surfactant
The compositions of the present invention comprises at least one anion surfactant or " surface-active agents ".
Anion surfactant is understood to refer to amphiphilic compound, and wherein hydrophobic part is with having usually
The anionic hydrophilic group of the cation counterbalancing ion of metal (alkali metal, such as Na or K) or ammonium；Described hydrophilic group is thus pole
Property and generation anion of can dissociating in aqueous.
The anionicsite of the most described anion surfactant belongs to selected from following group: C (O) OH, C
(O)O-、-SO3H、-S(O)2O-、-OS(O)2OH、-OS(O)2O-、-P(O)OH2、-P(O)2O-、-P(O)O2 -、-P(OH)2、=P(O)
OH、-P(OH)O-、=P(O)O-、=POH、=PO-, described anionicsite comprises the cation (cationic of counter anion
Counter anion) such as alkali metal such as sodium, or alkaline-earth metal such as magnesium, or the organic cation of counter anion such as ammonium salt, amine
Salt or amino alkoxide.Described surfactant can also occur with the form of its acid.As anion surfactant or surface
Active agent it is mentioned that and comprises following surfactant or surface-active agents: carboxylate radical, sulfate radical, sulfonate radical,
Sulfoacetic acid root, sulfosuccinic acid group, phosphate radical, hydroxyethylsulfonic acid. root, sarcosine root, glutamate, lactylate or cattle sulphur
Acid radical anion group, the salt of fatty acid, the salt of galactose iduronic acid (galactosiduronic acids), ether carboxylic acid
The salt of surfactant and their mixture.
More particularly, anion surfactant or surface-active agents according to the present invention are selected from:
·(C6-C30) alkyl sulfate, (C6-C30) alkyl ether sulfate, (C6-C30) alkylamidoether sulfates, alkylaryl
Polyether thiourea hydrochlorate or monoglyceride sulfates；For the type anion surfactant preferably, use (C6-C30) alkane
Base ether sulfate, alkyl aryl polyether sulfate or mixture.It is mentioned that the sulfate of the ether of lauryl alcohol and oxyalkylene,
It contains 1-50 oxyalkylene group.
It is highly preferred that described anion surfactant is selected from lauryl alcohol and the sulfate of the ether of oxyalkylene, it contains 1-4
Individual oxyalkylene group, especially ethylene oxide group.Such as, Cognis company (BASF) is with title Texapon® AOS 225 UP、
Rhodia is with title Rhodapex®Esb-70/fla3 and Clariant is with title Genapol®Containing that LRO L ' O sells is flat
The sodium laureth sulfate of equal 2.2 ethylene oxide groups, and Zhejiang Zanyu Technology company with
The sodium laureth sulfate containing average 1 ethylene oxide group that title SLES (N1EO) is sold.
·(C6-C30) alkylsulfonate, (C6-C30) alkylamide sulfonates, (C6-C30) alkylaryl sulfonates, α-alkene
Sulfonated hydrocarbon, paraffin sulfonate；
·(C6-C30) alkylphosphonic；
·(C6-C30) alkyl sulfo succinate, (C6-C30) alkyl ether sulfo succinate or (C6-C30) alkylamide sulfo group
Succinate；
·(C6-C30) alkyl sulfoacetate；
·(C6-C24) acyl sarcosinates；
·(C6-C24) acyl glutamate；
·(C6-C30) APG ether carboxylic acid (alkylpolyglycoside carboxylic ethers)；
·(C6-C30) APG sulfosuccinate；
·(C6-C30) alkyl sulfosuccinates amide hydrochlorate；
·(C6-C24) acyl-hydroxyethyl sulfonate, such as lauroyl methyl isethionate, cocoyl hydroxyethylsulfonic acid.
Sodium (sodium cocoyl isthionate)；It is mentioned that lauroyl methyl isethionate, it is with trade name
ISELUX®LQ-CLR-SB is by Innospec Active Chemicals Company；
·N-[(C6-C24) acyl group] taurate；
The salt of fatty acid；
·(C8-C20) acyl group lactylates；
·(C6-C30) salt of alkyl-D-galactose iduronic acid；
·(C6-C30) salt of alkyl polyoxyalkylene ether carboxylic acid, (C6-C30) alkylaryl polyoxyalkylenated ether carboxylic acid salt or
(C6-C30) salt of alkylamide polyoxyalkylenated ether carboxylic acid；
Mixture with them.
Alkyl or the acyl group of these various different anion surfactants preferably comprise 12-20 carbon atom.
It addition, described oxyalkylenated or polyoxyalkylenated anion surfactant or surface-active agents are preferably wrapped
Containing 1-50 oxyalkylene group, more preferably 1-4 oxyalkylene group, particularly ethylene oxide group.
Advantageously, according to an embodiment, the present invention comprises at least one anion surfactant, and it is selected from (C6-
C30) alkyl sulfate, (C6-C30) alkyl ether sulfate, (C6-C30) alkylamidoether sulfates, alkyl aryl polyether sulfate,
Monoglyceride sulfates, (C6-C24) acyl-hydroxyethyl sulfonate, or its mixture.
According to one embodiment of the invention, described anion surfactant is preferably selected from laureth
Sodium sulfate, lauroyl methyl isethionate, sodium cocoyl isethionate or its mixture.
The most described anion surfactant is the lauryl polyoxyethylene containing average 2.2 ethylene oxide groups
Ether sodium sulfate.
Advantageously, the content of anion surfactant is calculated as 1 weight %-50 weight relative to the weight of described compositions
Amount %, preferably with respect to weight meter 5 weight %-30 weight % of described compositions, or 10 weights based on the weight of described compositions
Amount %-25 weight %.
The polyalkylene glycol ethers of alcohol
The compositions of the present invention comprises the polyalkylene glycol ethers of at least one alcohol, and it may be defined as formula (II),
CH3(CH2)a(OR)bOH (II)
Wherein:
A is the integer of 4-14；
B is the integer of 2-30；With
R is alkylidene.
It is highly preferred that according to one embodiment of the invention,
A be the integer of 6-12, more preferably a be 11；
B is the integer of 4-12；
R is ethylidene or propylidene, preferably ethylidene.
It is mentioned that polyglycol ether and the mixture thereof of lauryl alcohol.
More particularly, it can be mentioned be lauryl polyoxyethylene (4) ether or lauryl polyoxyethylene (12) ether, such as
Evonik Goldschmidt company is with title Rewopal®12, Ecogreen Oleochemicals is with title Ifralan
L12 or Clariant is with title Genapol®LA 120 L ' O product sold.
Preferably, the amount that the polyalkylene glycol ethers of at least one alcohol described exists in the present invention is relative to described combination
The gross weight meter of thing is at 0.01 weight %-10 weight %, preferably 0.1 weight %-5 weight %, more preferably 0.2 weight %-2.5 weight % model
In enclosing.
Supplementary element
The compositions of the present invention comprises one or more following supplementary elements further.
Amphoteric surfactant or zwitterionic surfactant
According to one embodiment of the invention, described compositions comprises at least one amphoteric surfactant or both sexes further
Ionic surface active agent.
The both sexes that can use in the present invention or zwitterionic surfactant can be containing at least one anion base
Group, the quaternized aliphatic secondary amine of such as carboxylate radical, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical or tertiary amines derived thing, and
The aliphatic group wherein with line style or side chain comprises 8-22 carbon atom.
It is mentioned that (C especially8-C20) alkyl betaine, sulfobetaines, (C8-C20Alkyl) amide (C2-C8Alkane
Base) glycine betaine and (C8–C20Alkyl) amide (C2-C8Alkyl) sulfobetaines.The most described both sexes or amphion surface activity
Agent is selected from cocamido propyl betaine (cocoylamidopropylbetaine), cocoyl glycine betaine, alkali-metal N-
Coconut oleoyl amine carboxymethyl glycinate, or its mixture.
In described both sexes or zwitterionic surfactant, it can be mentioned be the change of hereafter corresponding structure (III)
Compound:
(III)
Wherein R represents the alkyl derived by Oleum Cocois.
Preferably mention that cocoyl glycine betaine, such as Rhodia company are sold with title Mirataine BB/FLA
Cocoyl glycine betaine.
Advantageously, relative to the gross weight of described compositions, described amphoteric surfactant (if present) exists
Amount in terms of the weight of surfactant in 1 weight %-15 weight %, preferably 3 weight %-12 weight %, more preferably 5 weight %-10 weights
In the range of amount %.
Cationic polymer
According to an embodiment, the compositions of the present invention can contain cationic polymer.
For the purposes of the present invention, term " cationic polymer " represents containing cation group and/or can be with ionizing
Any polymer for the group of cation group.
These polymer preferably have usual number-average molecular weight between 1000 and 100 000.
The polymer of the type is especially described in FR 2 320 330, FR 2 270 846, FR 2 316 271, FR
2 336 434, FR 2 413 907, US 2 273 780, US 2 375 853, US 2 388 614, US 2 454
547, US 3 206 462, US 2 261 002, US 2 271 378, US 3 874 870, US 4 001 432, US
3 929 990, US 3 966 904, US 4 005 193, US 4 025 617, US 4 025 627, US 4 025
In 653, US 4 026 945 and US 4 027 020.
More particularly, described cationic polymer is selected from cation cyclic polymer cyclopolymers of alkyldiallylamine or dialkyl group two
Allyl-ammonium, it can be the homopolymer or altogether of unit of the corresponding formula (IV) containing the key component as chain or (V)
Polymers:
(IV)
(V)
Its Chinese style d and e are equal to 0 or 1, and d+e sum is equal to 1；R32Represent hydrogen atom or methyl；R30And R31Separate earth's surface
Show C1-C8Alkyl, wherein alkyl are C1-C5Hydroxyalkyl, wherein alkyl be C1-C4Amidoalkyl group；R30And R31Can also be with attached
The nitrogen-atoms in them and represent heterocyclic group such as piperidyl or morpholinyl together；R30And R31The most preferably represent C1-
C4Alkyl；Y-it is organic or inorganic anion such as bromide ion, chloride ion, acetate, borate, citrate, tartrate anion, sulfur
Acid hydrogen radical, bisulfite, sulfate radical or phosphate radical.These polymer are particularly described in FR 2 080 759 and FR 2 190
In 406.
In polymer defined above, particularly it is mentioned that Nalco company and sell with title " Merquat 100 "
The dimethyl diallyl ammonium chloride homopolymer (and homologue of lower molecular wt) sold and selling with title Merquat 550
The diallyldimethylammonium chloride sold and the copolymer of acrylamide.
Advantageously, the cation copolymer used in the present invention is in the composition with the gross weight relative to described compositions
Counting 0.1 weight %-5 weight %, preferably 0.5 weight %-2.5 weight %, more preferably 0.5 weight %-1 weight % exists.
Adjuvant
It addition, according to the compositions of the present invention it is of course possible to contain, for keratin material, especially field of hair care is met
The all standard excipients arrived, such as, such as silicone, spice, preservative, chelating agen, thickening agent, wetting agent (hydrating
Agents), dandruff removing agent or lipotropism bleeding, vitamin, sunscreen, suspending agent, stabilizer, such as sodium chloride, magnesium chloride or sulfur
Acid magnesium, gellant, film forming polymer or surfactant, pH adjusting agent etc..
Especially, described compositions can comprise one or more silicone (volatile or nonvolatile), or volatilization
Property and the mixture of nonvolatile silicone.It may be mentioned that such as, selected from the line containing hydroxydimethylsilyl end group
The nonvolatile silicone of type polydialkysiloxane race, such as the oil of the 48 V series from RHONE-POULENC, Dow
Corning product sold Xiameter®PMX-200 silicone oil 60000CS.
Galenic form
Compositions according to the present invention can take liquid, cream or gel form.They can also take lotion to be rinsed
Form.
Another aspect of the present invention be use compositions as described above for nursing keratin material, especially hair
Method.
The method of the present invention preferably comprises foaming step and the step rinsed well.
More particularly, the method for the present invention is used for washing hair.
Give the non-limiting example of the explanation present invention.
Embodiment
The present composition and the preparation of Comparative composition
Prepare following compositions (inv compo represents the present composition, and compa compo represents Comparative composition):
Preparation scheme:
Prepare the Comparative composition 1 of each 100 g and 2 and the present composition 1 in accordance with the following steps:
A) by 2.8g sodium laureth sulfate, 0.6 g lauryl polyoxyethylene (12) ether (if present) with
Water mixes, melted at a temperature of 80 ° of C, until described mixture dissolves well；And then mix with 2 g cyclodextrin until
It dissolves well, and then mixture is cooled to room temperature, mixes with 0.3 g sodium chloride (if present),
B) 18.6 g sodium laureth sulfates, 10 g coco betaine (cocobetaine), 0.75 g are gathered
(dimethyl diallyl ammonium chloride) mixes under room temperature (25 ° of C) with water, then with the carbomer of 0.2 g and the poly-diformazan of 3 g
Radical siloxane mixes；And then mix with the mixture obtained from step a).
The present composition and the evaluation of Comparative composition
The present composition 1 and the stability of Comparative composition 1 and 2, foaming effect and dry carding effect are evaluated.
Stability
The stability of the present composition 1 and Comparative composition 1 and 2 is by by compositions mentioned above indwelling 2 at 45 DEG C
Within individual month, it is evaluated.
Result
Observe that As time goes on Comparative composition 1 is unstable, it may be assumed that it have separated problem and the most non-all
Even.But compared with Comparative composition 1, As time goes on the present composition 1 and Comparative composition 2 are stable.
Foaming effect
The foaming effect of described compositions foaming based on described compositions abundance and expansion rate are evaluated.
For the purposes of the present invention, expansion rate refers to the foam volume produced in 120 seconds.
The present composition 1 is evaluated according to below step with the foaming abundance of Comparative composition 1 and 2:
The model of the present composition 1 and Comparative composition 1 and 2 to Philips production that weigh 4 g respectively is referenced as HR2004
Culinary whisk in.
With the water of the compositions volume of 20 times, the present composition 1 and Comparative composition 1 and 2 are diluted respectively；
The compositions of dilution is mixed 1 minute with speed 1；
At once foam and the liquid of generation are transferred in graduated cylinder；
Measure cumulative volume.
Expansion rate according to following steps evaluation compositions:
Weigh the embodiment of the present invention 1 and the comparative example 1 and 2 of 20 g respectively, and they are respectively put into what Philips produced
Model is referenced as in the culinary whisk of HR2004；
The present composition 1 and Comparative composition 1 and 2 is diluted respectively with the water of 1.25 times of compositions volumes；
Device Teclis FOAMSCAN is used to continue to evaluate for 200 seconds the foaming speed of the compositions diluted under air-flow 15 ml/min
Degree.
Result
The result of the foaming effect of described compositions shows as follows:
| The present composition 1 | Comparative composition 1 | Comparative composition 2 | |
| Foaming abundance (ml) | 410 | 370 | 380 |
| Expansion rate (ml) | 82 | 81 | 80 |
Compared with Comparative composition 1 and 2, the present composition demonstrates analogous speed and the foaming of improvement of foaming effect
Abundance.
It is dried carding effect
Respectively the present composition 1 of 0.4 g is applied to Comparative composition 1 and 2 Chinese's hair of the natural black of 6 g
With impaired Chinese's hair.Then described compositions is made to be retained in described hair upper 5 minute.The most described hair warm water rushes
Wash 10 seconds, and at room temperature stay it to be dried overnight.After the applying using method described herein to repeat for 5 times, by JAU
Combing between measurement device hair stress and the comb of the named Combing Tester JC45A-001 that CHUNG sells
Power.The reduction of carding force measures the sodium laureth sulfate aqueous solution of 9% (comparison be) based on following formula:
Wherein:
Reduce the reduction that (%) is carding force；
FComparisonIt it is the carding force of reference composition；
FCompositionsIt is the carding force of the present composition and Comparative composition respectively.
Result
The result of conditioning effect, the reduction of the carding force of the dry hair of the most described compositions shows as follows:
| Attribute | The present composition 1 | Comparative composition 1 | Comparative composition 2 |
| The carding force being dried hair reduces (%) | 88% | 84% | 80% |
As shown in Table, compared with Comparative composition 1 or 2, the conditioning effect of the dry hair of the present composition 1, especially
Carding effect is much better.So present invention has the conditioning effect of improvement, especially on dry hair.
Claims (16)
1. a compositions, is included in aqueous phase:
A) at least one cyclodextrin or derivatives thereof；
B) at least one anion surfactant；With
C) polyalkylene glycol ethers of the alcohol of at least one formula (II),
CH3(CH2)a(OR)bOH (II)
Wherein:
A is the integer of 4-14；
B is the integer of 2-30；With
R is alkylidene.
2. the compositions described in claim 1, wherein said aqueous phase exist amount based on the gross weight of described compositions
In the range of 45 weight %-85 weight %, especially 50 weight %-75 weight % and more particularly 55 weight %-65 weight %.
3. the compositions described in claim 1 or 2, wherein said cyclodextrin or derivatives thereof selected from alpha-cyclodextrin, beta-schardinger dextrin-,
Gamma-cyclodextrin, its methyl-derivatives or its mixture, the most described cyclodextrin is selected from beta-schardinger dextrin-.
Compositions according to any one of the most aforementioned claim 1-3, the amount that wherein said cyclodextrin exists is relative to described group
The gross weight meter of compound in 0.5 weight %-15 weight %, preferably 1 weight %-10 weight %, more preferably 1 weight %-5 weight %, and very
To more preferably 1 weight %-2.5 weight %.
Compositions according to any one of the most aforementioned claim 1-4, at least one anion surfactant wherein said selects
From carboxylate radical, sulfate radical, sulfonate radical, sulfoacetic acid root, sulfosuccinic acid group, phosphate radical, hydroxyethylsulfonic acid. root, sarcosine root,
Glutamate, lactylate or taurine root anionic group, their salt, the salt of fatty acid, galactose iduronic acid
Salt, the salt of ether carboxylic acid or its mixture.
Compositions according to any one of the most aforementioned claim 1-5, at least one anion surfactant wherein said selects
From (C6-C30) alkyl sulfate, (C6-C30) alkyl ether sulfate, (C6-C30) alkylamidoether sulfates, alkyl aryl polyether
Sulfate, monoglyceride sulfates, (C6-C30) alkylsulfonate, (C6-C30) alkylamide sulfonates, (C6-C30) alkyl virtue
Base sulfonate, alpha-alkene sulfonate, paraffin sulfonate, (C6-C30) alkylphosphonic, (C6-C30) alkyl sulfo succinate,
(C6-C30) alkyl ether sulfo succinate, (C6-C30) alkylamide sulfosuccinate, (C6-C30) alkyl sulfoacetate,
(C6-C24) acyl sarcosinates, (C6-C24) acyl glutamate, (C6-C30) APG ether carboxylic acid, (C6-C30) alkyl is many
Glucosides sulfosuccinate, (C6-C30) alkyl sulfosuccinates amide hydrochlorate, (C6-C24) acyl-hydroxyethyl sulfonate, N-[(C6-
C24) acyl group] taurate, the salt of fatty acid, (C8-C20) acyl group lactylates, (C6-C30) alkyl-D-galactose idose
The salt of aldehydic acid, (C6-C30) salt of alkyl polyoxyalkylene ether carboxylic acid, (C6-C30) alkylaryl polyoxyalkylenated ether carboxylic acid salt,
(C6-C30) salt of alkylamide polyoxyalkylenated ether carboxylic acid or its mixture.
7. the compositions according to any one of claim 1-6, wherein said anion surfactant is selected from (C6-C30) alkyl
Sulfate, (C6-C30) alkyl ether sulfate, (C6-C30) alkylamidoether sulfates, alkyl aryl polyether sulfate, mono-acid be sweet
Grease sulfate, (C6-C24) acyl-hydroxyethyl sulfonate or its mixture；Be preferably selected from sodium laureth sulfate,
Lauroyl methyl isethionate, sodium cocoyl isethionate or its mixture, the most described anion table
Face activating agent is containing average 1-4 ethylene oxide group, and the lauryl more preferably containing average 2.2 ethylene oxide groups gathers
Oxygen vinyl Ether sodium sulfate.
Compositions according to any one of the most aforementioned claim 1-7, the amount phase that wherein said anion surfactant exists
For the gross weight meter of described compositions in 1 weight %-50 weight %, preferably 5 weight %-30 weight % and more preferably 10 weight %-25
In the range of weight %.
Compositions according to any one of the most aforementioned claim 1-8, gathering of the fatty alcohol of wherein said at least one formula (II)
Alkylene glycol ether,
CH3(CH2)a(OR)bOH (II)
Wherein it is preferred to,
A be the integer of 6-12, more preferably a be 11；
B is the integer of 4-12；
R is ethylidene or propylidene, preferably ethylidene.
Compositions according to any one of the most aforementioned claim 1-9, the polyalkylene two of at least one fatty alcohol wherein said
Alcohol ether is selected from polyglycol ether or its mixture of lauryl alcohol；More preferably lauryl polyoxyethylene (12) ether, lauryl polyoxy second
Alkene (4) ether or its mixture, more preferably lauryl polyoxyethylene (12) ether.
Compositions according to any one of 11. aforementioned claim 1-10, the polyalkylene glycol ethers of wherein said fatty alcohol is deposited
Amount based on the gross weight of described compositions in 0.01 weight %-10 weight %, 0.1 weight %-5 weight %, more preferably 0.2
In the range of weight %-2.5 weight %.
Compositions according to any one of 12. aforementioned claim 1-11, it comprises at least one amophoteric surface active further
Agent or zwitterionic surfactant, it is selected from (C8-C20) alkyl betaine, sulfobetaines, (C8-C20Alkyl) amide (C2-
C8Alkyl) glycine betaine, (C8–C20Alkyl) amide (C2-C8Alkyl) sulfobetaines, or its mixture, it is preferably selected from cocos nucifera oil acyl
Amine CAB, cocoyl glycine betaine, alkali-metal N-coconut oleoyl amine carboxymethyl glycinate, the most described both sexes
Surfactant or zwitterionic surfactant are cocoyl glycine betaines.
Compositions according to any one of 13. aforementioned claim 1-12, wherein said amphoteric surfactant or amphion
The amount that surfactant exists is in 1 weight %-15 weight % based on the gross weight of described compositions, and preferably 3 weight %-12 are heavy
Amount %, in the range of more preferably 5 weight %-10 weight %.
Compositions according to any one of 14. aforementioned claim 1-13, it comprises and gathers selected from least one following cation
Compound:
Cation cyclic polymer cyclopolymers of alkyldiallylamine or dialkyl diallyl ammonium, containing the key component as chain
Formula (IV) or the homopolymer of unit of (V) or copolymer:
(IV),
(V),
Wherein,
D and e, identical or different, equal to 0 or 1, and d+e sum is equal to 1,
R32Represent hydrogen atom or methyl,
R30And R31Represent C independently of each other1-C8Alkyl, wherein alkyl is C1-C5Hydroxyalkyl, wherein alkyl is C1-C4Amide
Alkyl；R30And R31Heterocyclic group such as piperidyl or morpholinyl can also be represented together with being attached to their nitrogen-atoms；R30And R31
The most preferably represent C1-C4Alkyl,
Y-is organic or inorganic anion such as bromide ion, chloride ion, acetate, borate, citrate, tartrate anion, sulphuric acid
Hydrogen radical, bisulfite, sulfate radical or phosphate radical,
The most described cationic polymer is selected from dialkyl diallyl ammonium, more preferably dimethyl diallyl ammonium chloride homopolymerization
Thing.
Compositions according to any one of 15. aforementioned claim 1-14, it comprises selected from least one following adjuvant: silicon
Ketone, spice, preservative, chelating agen, thickening agent, wetting agent, dandruff removing agent or lipotropism bleeding, vitamin, sunscreen, suspending agent,
Stabilizer, such as sodium chloride, magnesium chloride or magnesium sulfate, gellant, film forming polymer or surfactant, pH adjusting agent or its
Mixture, wherein said silicone is preferably selected from nonvolatile silicone, and it is selected from the line containing hydroxydimethylsilyl end group
Type polydialkysiloxane race, more preferably polydimethylsiloxane.
16. are used for nursing keratin material, especially the method for hair, and it includes institute any one of aforementioned claim 1-15
The compositions stated is applied to the step of described keratin material, and the most described method includes foaming and the step rinsed well,
The most described method includes washing keratin material, preferably hair.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2013/089581 WO2015089716A1 (en) | 2013-12-16 | 2013-12-16 | Composition comprising cyclodextrin and its derivative, anionic surfactant and polyalkylene glycol ether of alcohol, and its use thereof |
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| CN105828801A true CN105828801A (en) | 2016-08-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380081669.1A Pending CN105828801A (en) | 2013-12-16 | 2013-12-16 | Composition comprising cyclodextrin and its derivative, anionic surfactant and polyalkylene glycol ether of alcohol, and use thereof |
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| Country | Link |
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| WO (1) | WO2015089716A1 (en) |
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| KR102251488B1 (en) | 2016-07-12 | 2021-05-17 | 로레알 | Composition of Pickering Emulsion |
| CN115141691A (en) * | 2022-06-23 | 2022-10-04 | 纳爱斯浙江科技有限公司 | Composition for reducing irritation of detergent and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1292255A (en) * | 1999-09-29 | 2001-04-25 | 欧莱雅 | Keratin material detergent composition containing washing surfactant, dialkyl diallyl ammonium homopolymer and acrylic ternary copolymer |
| CN1589767A (en) * | 2003-07-28 | 2005-03-09 | 欧莱雅 | Cosmetic composition containing a mixture of surfactants, a mixture of cationic polymers and a silicone |
| CN101431979A (en) * | 2006-04-25 | 2009-05-13 | 爱默思公司 | A mild leave-on composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2838642B1 (en) * | 2002-04-22 | 2004-07-30 | Oreal | USE OF A CYCLODEXTRIN AS A NACRANT AND PEARL COMPOSITIONS |
| US20070104669A1 (en) * | 2005-10-26 | 2007-05-10 | Rainer Muller | Cosmetic composition comprising at least one ester, at least one acrylic polymer, at least one cyclodextrin and at least one surfactant, and uses thereof |
| FR2920970B1 (en) * | 2007-09-14 | 2010-02-26 | Oreal | COSMETIC COMPOSITIONS CONTAINING CATIONIC COPOLYMER, CYCLODEXTRIN AND SURFACTANT AND USES THEREOF. |
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2013
- 2013-12-16 WO PCT/CN2013/089581 patent/WO2015089716A1/en active Application Filing
- 2013-12-16 CN CN201380081669.1A patent/CN105828801A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1292255A (en) * | 1999-09-29 | 2001-04-25 | 欧莱雅 | Keratin material detergent composition containing washing surfactant, dialkyl diallyl ammonium homopolymer and acrylic ternary copolymer |
| CN1589767A (en) * | 2003-07-28 | 2005-03-09 | 欧莱雅 | Cosmetic composition containing a mixture of surfactants, a mixture of cationic polymers and a silicone |
| CN101431979A (en) * | 2006-04-25 | 2009-05-13 | 爱默思公司 | A mild leave-on composition |
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| WO2015089716A1 (en) | 2015-06-25 |
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