CN116322634A - Composition for cleaning keratin fibres and use thereof - Google Patents
Composition for cleaning keratin fibres and use thereof Download PDFInfo
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- CN116322634A CN116322634A CN202080105684.5A CN202080105684A CN116322634A CN 116322634 A CN116322634 A CN 116322634A CN 202080105684 A CN202080105684 A CN 202080105684A CN 116322634 A CN116322634 A CN 116322634A
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- 239000000203 mixture Substances 0.000 title claims abstract description 132
- 108010076876 Keratins Proteins 0.000 title claims abstract description 26
- 102000011782 Keratins Human genes 0.000 title claims abstract description 26
- 238000004140 cleaning Methods 0.000 title claims abstract description 19
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 25
- 229920002545 silicone oil Polymers 0.000 claims abstract description 25
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 16
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 12
- 229920006294 polydialkylsiloxane Polymers 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 7
- LWIGVRDDANOFTD-UHFFFAOYSA-N hydroxy(dimethyl)silane Chemical group C[SiH](C)O LWIGVRDDANOFTD-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 laurylmethyl isethionate Chemical compound 0.000 claims description 90
- 125000000217 alkyl group Chemical group 0.000 claims description 29
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 29
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 29
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
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- 150000001340 alkali metals Chemical class 0.000 claims description 5
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- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 5
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- 125000003545 alkoxy group Chemical group 0.000 claims description 4
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- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
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- 125000002091 cationic group Chemical group 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
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- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 4
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
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- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 2
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- 229920002472 Starch Polymers 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- IAJILQKETJEXLJ-RSJOWCBRSA-N aldehydo-D-galacturonic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-RSJOWCBRSA-N 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 235000010407 ammonium alginate Nutrition 0.000 description 1
- 239000000728 ammonium alginate Substances 0.000 description 1
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 235000010410 calcium alginate Nutrition 0.000 description 1
- 239000000648 calcium alginate Substances 0.000 description 1
- 229960002681 calcium alginate Drugs 0.000 description 1
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229960004203 carnitine Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000003659 hair regrowth Effects 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DGQPWMPZORWLTD-UHFFFAOYSA-N hexane-1,1-diol;2-methylpentane-2,4-diol Chemical compound CCCCCC(O)O.CC(O)CC(C)(C)O DGQPWMPZORWLTD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229940054190 hydroxypropyl chitosan Drugs 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 229940001447 lactate Drugs 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229920006030 multiblock copolymer Polymers 0.000 description 1
- 235000013557 nattō Nutrition 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229940057874 phenyl trimethicone Drugs 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 235000010408 potassium alginate Nutrition 0.000 description 1
- 239000000737 potassium alginate Substances 0.000 description 1
- MZYRDLHIWXQJCQ-YZOKENDUSA-L potassium alginate Chemical compound [K+].[K+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O MZYRDLHIWXQJCQ-YZOKENDUSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003658 preventing hair loss Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 229940097319 quaternium-22 Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229940007636 sodium lauroyl methyl isethionate Drugs 0.000 description 1
- HKCPSLRXMHNTBX-DKWTVANSSA-M sodium;(2s)-2,4-diamino-4-oxobutanoate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CC(N)=O HKCPSLRXMHNTBX-DKWTVANSSA-M 0.000 description 1
- NVIZQHFCDBQNPH-UHFFFAOYSA-M sodium;2-dodecanoyloxypropane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)OC(C)CS([O-])(=O)=O NVIZQHFCDBQNPH-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- AGGIJOLULBJGTQ-UHFFFAOYSA-N sulfoacetic acid Chemical compound OC(=O)CS(O)(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-N 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- DGXNWWJYEMQHED-UHFFFAOYSA-N trimethyl-(4-methyl-3-oxopent-4-enyl)azanium Chemical compound CC(=C)C(=O)CC[N+](C)(C)C DGXNWWJYEMQHED-UHFFFAOYSA-N 0.000 description 1
- VZTGWJFIMGVKSN-UHFFFAOYSA-O trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)C VZTGWJFIMGVKSN-UHFFFAOYSA-O 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a composition for cleaning keratin fibers, comprising (a) at least one surfactant comprising (a-1) at least one anionic surfactant, and/or (a-2) at least one amphoteric surfactant; (B) At least one non-volatile silicone oil selected from polydialkylsiloxanes having terminal dimethylsilanol groups having 500 or more repeating units; and (C) at least one aminosilicone, which is an amino terminal silicone.
Description
Technical Field
The present invention relates to a composition for cleansing keratin fibres, in particular the hair. The invention also relates to a method for cleansing keratin fibres, in particular the skin, scalp and/or hair, using the composition according to the invention.
Background
Keratin fibers are widely found on human surfaces, such as, in particular, hair. For a long time, many people seek to clean keratin fibres in order to feel comfortable in daily life and work. Various products have been developed to address the need for people to clean keratin fibers, many of which are used to bring about cleaning and some other effects.
Keratin fibers, particularly hair, are cleaned and treated to improve their appearance, color, style, etc. Thus, various cleansing and/or conditioning components are added directly to the shampoo. In addition, in addition to cleansing and conditioning functions, some other properties are important to appeal to consumers, such as special fragrance, good appearance, smooth feel, ease of use, etc. For example, many consumers prefer a smooth hair feel rather than tangled hair strands.
Disclosure of Invention
Accordingly, one subject of the present invention is a cleaning composition for cleaning keratin fibres, comprising:
at least one anionic surfactant and/or at least one amphoteric surfactant;
at least one non-volatile silicone oil selected from polydialkylsiloxanes containing terminal dimethylsilanol groups having 500 or more repeating units, and
at least one aminosilicone.
The compositions according to the invention are particularly useful in shampoo products.
The invention also relates to a method for cleaning keratin fibres, in particular keratin fibres on a body surface, especially hair, using the cleaning composition according to the invention.
The present invention therefore provides the use of the composition according to the invention for cleaning keratin fibres.
Embodiments of the invention
Throughout this specification, including the claims, the term "comprising" is to be understood as synonymous with "comprising at least one", unless otherwise indicated. Furthermore, the expression "at least one" as used in the present specification is equivalent to the expression "one or more".
Throughout the specification, including the claims, embodiments defined by "comprising" and the like should be understood to include preferred embodiments defined by "consisting essentially of and preferred embodiments defined by" consisting of.
Except in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients and/or reaction conditions are to be understood as being modified in all instances by the term "about," having a meaning conventionally known in the art, such as within 10% of the indicated number (e.g., "about 10%" means 9% -11% and "about 2%" means 1.8% -2.2%).
Throughout the specification, including the claims, the "keratin fibres" according to the invention are preferably hair.
In this application, unless specifically mentioned otherwise, amounts, parts and percentages are expressed on a weight basis.
The present invention relates to a composition for cleaning keratin fibres, comprising:
(A) At least one surfactant comprising (a-1) at least one anionic surfactant, and/or (a-2) at least one amphoteric surfactant;
(B) At least one non-volatile silicone oil selected from polydialkylsiloxanes having terminal dimethylsilanol groups having 500 or more repeating units; and
(C) At least one aminosilicone.
The present invention therefore provides the use of the composition according to the invention for cleaning keratin fibres, in particular the hair, on a body surface.
The invention also provides the use of fatty acid-ester mixtures for cleaning keratin fibres, in particular hair, on body surfaces.
The invention also relates to a method for cleaning keratin fibres, in particular keratin fibres on a body surface, especially hair, using the cleaning composition according to the invention.
Other features and advantages of the present invention will become more apparent upon reading the following specification and examples.
Surfactant (A)
The composition according to the invention comprises at least one surfactant, in particular (A-1) at least one anionic surfactant, and/or (A-2) at least one amphoteric surfactant.
Anionic surfactant (A-1)
According to one embodiment of the invention, the composition according to the invention comprises at least one anionic surfactant (A-1).
The term "anionic surfactant" is understood to mean an amphiphilic compound having a hydrophobic portion and a hydrophilic portion, wherein the hydrophilic portion carries only anionic groups as ions or ionizable groups, with a cationic counterion (which is typically a metal (alkali metal, such as Na or K) or ammonium) capable of dissociating in aqueous solution to give an anion.
More particularly, the anionic groups of the anionic surfactant belong to the group selected from: c (O) OH, -C (O) O - 、-SO 3 H、-S(O) 2 O - 、-OS(O) 2 OH、-OS(O) 2 O - 、-P(O)OH 2 、-P(O) 2 O - 、-P(O)O 2 - 、-P(OH) 2 、＝P(O)OH、-P(OH)O - 、＝P(O)O - 、＝POH、＝PO - The cationic counterion is generally selected from alkali metals such as sodium, or alkaline earth metals such as magnesium, or organic cationic counterions such as ammonium salts, amine salts or amino alkoxides. Surfactants may also be present in their acid form.
As anionic surfactants, mention may be made of surfactants comprising carboxylate, sulfate, sulfonate, sulfoacetate, sulfosuccinate, phosphate, hydroxyethyl sulfonate, sarcosinate, glutamate, lactate or taurine anionic groups, salts of fatty acids, salts of galacturonic acid (galactosiduronic acid), ether carboxylate surfactants and mixtures thereof.
More particularly, the anionic surfactant according to the invention is selected from:
·(C 6 -C 30 ) Alkyl sulphates, (C) 6 -C 30 ) Alkyl ether sulphates, (C) 6 -C 30 ) Alkyl amido ether sulfate, alkylaryl polyether sulfate or monoglyceride sulfate; preferably, for this type of anionic surface activationSex agent, use (C) 6 -C 30 ) Alkyl ether sulfates, alkylaryl polyether sulfates or mixtures. Mention may be made of the sulphates of ethers of lauryl alcohol with alkylene oxides containing from 1 to 50 alkylene oxide groups.
More preferably, the anionic surfactant is selected from the group consisting of sulfates of ethers of lauryl alcohol with alkylene oxide containing from 1 to 4 alkylene oxide groups, especially ethylene oxide groups. For example, cognis (BASF) Inc. under the name
AOS 225 UP, rhodia under the name +.>
esb-70/fla3, clariant under the name +.>
Sodium lauryl polyoxyethylene ether sulfate marketed by LRO L' O and having an average of 2.2 ethyleneoxy groups, and sodium lauryl polyoxyethylene ether sulfate marketed under the name SLES (N1 EO) and having an average of 1 ethyleneoxy group, zhejiang Zanyu Technology.
·(C 6 -C 30 ) Alkyl sulfonate, (C) 6 -C 30 ) Alkyl amidosulfonate, (C) 6 -C 30 ) Alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates;
·(C 6 -C 30 ) Alkyl phosphates;
·(C 6 -C 30 ) Alkyl sulfosuccinate salt (C) 6 -C 30 ) Alkyl ether sulfosuccinates or (C) 6 -C 30 ) Alkyl amidosulfosuccinate salt;
·(C 6 -C 30 ) Alkyl sulfoacetates;
·(C 6 -C 24 ) Acyl sarcosinates;
·(C 6 -C 24 ) Acyl glutamate;
·(C 6 -C 30 ) Alkyl polyglycoside carboxylic acid ethers;
·(C 6 -C 30 ) Alkyl polyglycoside sulfosuccinate salts;
·(C 6 -C 30 ) An alkyl sulfosuccinamide salt;
·(C 6 -C 24 ) Acyl isethionates, such as sodium lauroyl methyl isethionate, sodium cocoyl isethionate; mention may be made of those sold under the trade name Innospec Active Chemicals by the company
Sodium lauroyl methyl isethionate sold by LQ-CLR-SB;
·N-[(C 6 -C 24 ) Acyl group]Taurine salts;
fatty acid salts;
·(C 8 -C 20 ) Acyl lactylates;
·(C 6 -C 30 ) Salts of alkyl-D-galacturonic acid;
·(C 6 -C 30 ) Salts of alkyl polyoxyalkylene ether carboxylic acids, (C) 6 -C 30 ) Salts of alkylaryl polyoxyalkylene ether carboxylic acids or (C) 6 -C 30 ) Salts of alkylamido polyoxyalkylene ether carboxylic acids;
and mixtures thereof.
The alkyl or acyl groups of these various anionic surfactants preferably contain 12 to 20 carbon atoms.
Furthermore, the oxyalkylenated or polyoxyalkylenated anionic surfactant preferably comprises from 1 to 50 alkylene oxide groups, more preferably from 1 to 4 alkylene oxide groups, in particular ethylene oxide groups.
Advantageously, according to one embodiment, the present invention comprises at least one anionic surfactant chosen from (C) 6 -C 30 ) Alkyl sulphates, (C) 6 -C 30 ) Alkyl ether sulphates, (C) 6 -C 30 ) Alkyl amido ether sulfate, alkylaryl polyether sulfate, monoglyceride sulfate, (C) 6 -C 24 ) Acyl isethionates, or mixtures thereof.
According to one embodiment of the present invention, the anionic surfactant is preferably selected from sodium laureth sulfate, sodium laurylmethyl isethionate, sodium cocoyl isethionate or mixtures thereof.
According to one embodiment of the invention, the anionic surfactant is sodium lauryl polyoxyethylene ether sulfate containing an average of 0.8 to 2.2 ethyleneoxy groups.
According to a particular exemplary embodiment of the present invention, the composition may be free of any sulfate salt used as an anionic surfactant.
The at least one anionic surfactant (a-1) may be present in the composition according to the invention in an amount ranging from 1% to 30%, for example from 5% to 25%, or from 10% to 20% relative to the total weight of the composition.
Amphoteric surfactant (A-2)
According to one embodiment of the present invention, the composition according to the present invention comprises at least one amphoteric surfactant (a-2), which may also be referred to as zwitterionic surfactant.
The one or more amphoteric or zwitterionic surfactants useful in the present invention can be quaternized aliphatic secondary or tertiary amine derivatives which contain at least one anionic group, such as carboxylate, sulfonate, sulfate, phosphate, or phosphonate groups, and in which the aliphatic group or at least one aliphatic group is straight or branched chain containing from 8 to 22 carbon atoms.
Mention may in particular be made of (C 8 -C 20 ) Alkyl betaines, sulfobetaines, (C) 8 -C 20 Alkyl) amido (C) 2 -C 8 Alkyl) betaines and (C) 8 -C 20 Alkyl) amido (C) 2 -C 8 Alkyl) sulfobetaines.
At (C) 8 -C 20 ) Among the alkyl betaines that may be mentioned are behenyl betaine, cetyl betaine, coco betaine, decyl betaine. Among the alkyl betaines, preferred is coco betaine, for example under the trade name of Rhodia, inc
BB/FLA sales products.
Among the optionally quaternized aliphatic secondary or tertiary amine derivatives which may be used, mention may also be made of the products of the following corresponding structures (Al) and (A2):
(A1)R a -CON(Z)CH 2- (CH 2 ) m -N + (R b )(R c )(CH 2 COO - )
wherein:
R a represents an acid R derived from the acid preferably present in hydrolysed coconut oil a C of-COOH 10 -C 30 Alkyl or alkenyl, heptyl, nonyl or undecyl,
rb represents a group consisting of beta-hydroxyethyl,
R c represents carboxymethyl;
m is equal to 0, 1 or 2,
z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group;
(A2)R a’ -CON(Z)CH 2- (CH 2 ) m’ -N(B)(B′)
wherein:
b represents-CH 2 CH 2 OX ', wherein X' represents-CH 2 -COOH、CH 2 -COOZ’、-CH 2 CH 2 -COOH、-CH 2 CH 2 -COOZ' or a hydrogen atom,
b' represents- (CH) 2 ) z -Y ', wherein z=1 or 2, Y ' represents-COOH-COOZ ' -CH 2 -CHOH-SO 3 H or-CH 2 -CHOH-SO 3 Z’，
m' is equal to 0, 1 or 2,
z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group,
z' represents an ion generated from an alkali metal or alkaline earth metal such as sodium, potassium or magnesium; an ammonium ion; or ions from organic amines, in particular amino alcohols, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, 3-propanediol and tris (hydroxymethyl) aminomethane,
R a′ represents the acid R preferably present in hydrolyzed linseed oil or coconut oil a′ C of COOH 10 -C 30 Alkyl or alkenyl, alkyl, especially C 17 Alkyl groups and isomeric forms thereof, or unsaturated C 17 A group.
Compounds corresponding to formula (A1) may be preferred.
Among the compounds corresponding to formula (A1), mention may be made of cocoamidopropyl betaine, such as the product sold under the trade name Dehyton PK 45 by Cognis (BASF).
Compounds of formula (A3) may also be used:
(A3)R a” -NH-CH(Y”)-(CH 2 )n-C(O)-NH-(CH 2 )n’-N(R d )(R e )
wherein:
-R a” represents the acid R preferably present in hydrolyzed linseed oil or coconut oil a” C of-C (O) OH 10 -C 30 Alkyl or alkenyl;
y 'represents a group-C (O) OH, -C (O) OZ', -CH 2 -CH(OH)-SO 3 H or a group-CH 2 -CH(OH)-SO 3 -Z ", wherein Z" represents a cationic counter ion generated from an alkali metal or alkaline earth metal such as sodium, an ammonium ion or an ion generated from an organic amine;
-R d and R is e Independently of each other, represent C 1 -C 4 Alkyl or hydroxyalkyl; and
-n and n' independently of each other represent an integer from 1 to 3.
Among the compounds corresponding to formula (A3), mention may in particular be made of the compounds classified under the name diethylaminopropyl coco asparagine sodium in the CTFA dictionary, for example the compounds sold under the name Chimexane HB by Chimex company.
Preferably, the amphoteric surfactant may be selected from (C 8 -C 20 ) Alkyl betaines, (C) 8 -C 20 ) Alkylamido (C) 1 -C 6 ) Alkyl betaines, and mixtures thereof.
More preferably, the amphoteric or zwitterionic surfactant may be selected from cocoamidopropyl betaine, coco betaine or mixtures thereof.
The at least one amphoteric surfactant (a-2) may be present in the composition in an amount ranging from 0.5% to 20%, for example from 0.5% to 10%, or from 1% to 6% relative to the total weight of the composition, including all ranges and subranges therebetween.
According to one embodiment of the present invention, the surfactant may preferably comprise a combination of an anionic surfactant (A-1) and an amphoteric surfactant (A-2). More preferably, the surfactant of the present invention comprises a combination of sulfate anionic surfactant and betaine surfactant, such as a combination of sodium laureth sulfate and cocoamidopropyl betaine. Without being bound by any known theory, it is believed that such a combination may be particularly beneficial for the cleansing ability of the shampoo.
According to one embodiment of the invention, the combination of anionic surfactant (a-1) and amphoteric surfactant (a-2) may preferably be present in the composition according to the invention in an amount ranging from 1% to 40%, for example from 5% to 30%, or from 10% to 20%, relative to the total weight of the composition.
Silicone oil (B)
The composition of the invention may optionally comprise at least one silicone oil. For the purposes of the present invention, the term "silicone oil" is intended to mean an oil comprising at least one silicon atom, in particular at least one Si-O group. For the purposes of the present invention, the term "silicone oil" is interchangeable with the terms "polysiloxane" and "polysiloxane oil". For the purposes of the present invention, "aminosilicone" is not considered to be a "silicone oil". Instead, aminosilicones form an independent class of components that may optionally be included in the hair treatment composition. More detailed definitions and non-limiting examples of aminosilicones are provided later under the heading "aminosilicone".
Of course, the composition according to the invention or the composition considered according to the method of the invention may contain a mixture of silicone oils consisting only in part of such oils.
The silicone oils which can be used in the composition according to the invention are preferably nonvolatile.
Non-volatile silicone oil
The composition of the present invention may optionally comprise at least one non-volatile silicone oil to be used as silicone oil (B).
The non-volatile silicone oils useful in the present invention may be selected from the group consisting of silicone oils having a viscosity of greater than or equal to 9 centistokes (cSt) (9 x 10) -6 m 2 S) and less than 800000cSt, preferably 50-600000cSt, preferably 100-500000 cSt. The viscosity of such silicones can be measured according to standard ASTM D-445.
Examples of non-volatile silicone oils according to one embodiment of the invention may be the family of polydialkylsiloxanes having terminal trimethylsilyl groups, for example having a viscosity of 0.2m at 25 ℃C 2 /s-2.5m 2 Oils of/s, such as DC200 series from DOW CORNING, particularly oils having a viscosity of 60,000cst, oils from SILIBIONE 70047 series, more particularly 70,047V 500,000 oils supplied by RHODIA CHIMIE, suppliers, polydialkylsiloxanes having terminal dimethylsilanol groups, such as polydimethylsiloxane alcohols, such as 48 series oils from Rhodia, inc., or polyalkylarylsiloxanes, such as SILIBIONE 70641V 200 oils supplied by RHODIA CHIMIE, suppliers.
The silicone oil (B) may be present in the composition according to the invention in an amount of from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, more particularly from 0.5 to 3% by weight, relative to the total weight of the composition.
Aminosilicone (C)
The term "aminosilicone" is intended to mean any silicone comprising at least one primary, secondary or tertiary amine or quaternary ammonium group (i.e., quaternized group). For the purposes of the present invention, "aminosilicone" is not a "silicone oil". In contrast, aminosilicones are components other than silicone oils in the hair treatment compositions of the present invention. More detailed definitions and non-limiting examples of silicone oils are provided above under the heading "silicone oils".
Silicones can bear amine groups on the main chain of the molecule, known as amino-terminal silicones, or amine groups on the side chains, known as amino-grafted silicones.
Aminosilicones are described, for example, in US2011/0155163 and US2011/155164, both of which are incorporated herein by reference.
Non-limiting examples include amino terminal polydimethylsiloxane, silicone quaternary ammonium salt-22 (silicone quaternium-22), trimethylsilyl amino terminal polydimethylsiloxane, bis-isobutyl/PEG/PPG-20/35/amino terminal polydimethylsiloxane copolymer, bis-cetylstearyl amino terminal polydimethylsiloxane, bis-aminoppeg/PPG-41/3 aminoethylpg-propylpolydimethylsiloxane, PEG-40/PPG-8 methylaminopropylhydroxypropyl polydimethylsiloxane copolymer, bis-isobutyl/PEG/PPG-20/35/amino terminal polydimethylsiloxane copolymer, quaternary ammonium salt-80, methoxy PEG/PPG-7/3 aminopropylpolydimethylsiloxane, silicone quaternary ammonium salt-22, bis (C13-15 alkoxy) PG-amino terminal polydimethylsiloxane, bis-hydroxy/methoxy amino terminal polydimethylsiloxane, aminopropyl phenyl trimethicone, aminopropyl polydimethylsiloxane, bis-aminopropyl polydimethylsiloxane, PEG-7 amino terminal polydimethylsiloxane, quaternary ammonium salt-8, PPG-7/35/amino terminal polydimethylsiloxane copolymer, quaternary ammonium salt-80, methoxy PEG/PPG-7/3 aminopropyl polydimethylsiloxane, silicone quaternary ammonium salt-18, bis (C13-15 alkoxy) PG-amino terminal polydimethylsiloxane, bis-hydroxy/methoxy terminal polydimethylsiloxane, and mixtures thereof.
According to one embodiment of the invention, the aminosilicone is preferably an amino terminal silicone.
Thus, another group of preferred aminosilicones according to the invention may include: amino dipropyl polydimethylsiloxane; aminopropyl polydimethylsiloxane; amino terminal polydimethylsiloxane; bis-aminopropyl polydimethylsiloxane; bis-aminopropyl/ethoxyaminopropyl polydimethylsiloxane; bis-butoxyamino-terminated polydimethylsiloxane/PEG-60 copolymer; bis-isobutyl PEG-14/amino terminal polydimethylsiloxane copolymer; di-isobutyl PEG-15/amino terminal polydimethylsiloxane copolymer.
Without being bound by any known theory, it is believed that the use of a bis-amino terminal silicone, i.e., an aminosilicone having two amino terminal groups, is preferred. For the purposes of the present invention, such a bisaminoterminal silicone is referred to as a bisaminosilicone unless specifically indicated otherwise. Wherein, bis-aminopropyl polydimethylsiloxane; bis-aminopropyl/ethoxyaminopropyl polydimethylsiloxane, bis-isobutyl/PEG/PPG-20/35/amino-terminated polydimethylsiloxane copolymer, bis-cetylstearyl amino-terminated polydimethylsiloxane, bis-aminoppeg/PPG-41/3 aminoethylpg-propylpolydimethylsiloxane, bis (C13-15 alkoxy) PG-amino-terminated polydimethylsiloxane, bis-hydroxy/methoxy amino-terminated polydimethylsiloxane may be preferred.
The aminosilicone (C) may be present in the composition according to the invention in an amount of from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, more particularly from 0.4 to 2% by weight, relative to the total weight of the composition.
Thickening agent (D)
As a shampoo, it is preferred that the compositions of the present invention be easily and uniformly distributed on the hair, or on the hair along with the scalp. Thus, a thickener may optionally be incorporated into the composition according to the present invention to adjust the viscosity of the resulting product and promote the formation of a lamellar distribution or uniform film of the composition on the hair, or on the hair together with the scalp.
Thickeners include those that increase the viscosity of the composition without significantly altering the effectiveness of one or more active ingredients in the composition. Thickeners may also increase the compositional stability of the composition.
Non-limiting examples of thickeners include carboxylic acid polymers, crosslinked polyacrylate polymers, polyacrylamide polymers, polysaccharides, and gums.
Examples of carboxylic acid polymers include crosslinked compounds containing one or more monomers derived from acrylic acid, substituted acrylic acids, and salts and esters of these acrylic acids and substituted acrylic acids, wherein the crosslinking agent contains two or more carbon-carbon double bonds, derived from a polyol. Examples of commercially available carboxylic acid polymers include carbomers, which are homopolymers of acrylic acid crosslinked with allyl ethers of sucrose or pentaerythritol (e.g., carbopol 900 series from b.f. goodrich).
Non-limiting examples of polyacrylamide polymers include nonionic polyacrylamide polymers, including substituted branched or unbranched polymers, including polyacrylamide, isoparaffin, and laureth (7) ether acrylamide. And substituted multiblock copolymers of acrylamide with acrylic acid and substituted acrylic acids.
Non-limiting examples of polysaccharides include cellulose, carboxymethyl hydroxyethyl cellulose, cellulose acetate propionate, hydroxyethyl cellulose, hydroxyethyl ethyl cellulose, hydroxypropyl methyl cellulose, methyl hydroxyethyl cellulose, microcrystalline cellulose, sodium cellulose sulfate, and mixtures thereof. Another example is alkyl substituted cellulose wherein the hydroxyl groups of the cellulose polymer are hydroxyalkylated (preferably hydroxyethylated or hydroxypropylated) to form hydroxyalkylated cellulose, followed by C 10 -C 30 The linear or branched alkyl groups further modify the hydroxyalkylated cellulose via ether linkages. These polymers are typically C 10 -C 30 Ethers of straight or branched chain alcohols with hydroxyalkyl celluloses. Other useful polysaccharides include linear scleroglucans containing (1-3) linked glucose units, with each of the three units having (1-6) linked glucose.
Non-limiting examples of gums include acacia, agar, algin, alginic acid, ammonium alginate, pullulan, calcium alginate, calcium carrageenan, carnitine, carrageenan, dextrin, gelatin, guar gum, guar hydroxypropyl trimethyl ammonium chloride, hectorite, hyaluronic acid, hydrated silica, hydroxypropyl chitosan, hydroxypropyl guar gum, karaya gum, seaweed, locust bean gum, natto gum, potassium alginate, potassium carrageenan, propylene glycol alginate, sclerotium gum, sodium carboxymethyl dextran, sodium carrageenan, tragacanth gum, xanthan gum, and mixtures thereof.
If present, the thickener may be present in the composition according to the present invention in an amount of 0.01 to 5 wt%, preferably 0.05 to 3 wt%, or preferably 0.1 to 1 wt%, relative to the total weight of the composition.
Cationic polymer (E)
The composition according to the invention may optionally comprise at least one cationic polymer.
The term "cationic polymer" is intended to mean any polymer comprising cationic groups and/or groups that can be ionized into cationic groups. Preferably, the cationic polymer is hydrophilic or amphiphilic. Preferred cationic polymers are selected from those containing units comprising primary, secondary, tertiary and/or quaternary amine groups, which groups may form part of the polymer backbone or may be carried by pendant substituents directly attached thereto. Preferably, the composition of the invention may comprise cationic polysaccharides, in particular cationic celluloses and cationic galactomannans gums. For the purposes of the present invention, the composition according to the invention may preferably comprise cationic cellulose and cationic galactomannan gum.
Among the cationic celluloses, the compositions of the invention comprise cationic cellulose copolymers or cellulose derivatives grafted with water-soluble quaternary ammonium monomers, as described for example in us patent 4131576, and hydroxyalkyl celluloses, such as hydroxymethyl, hydroxyethyl or hydroxypropyl celluloses, can be mentioned, which are grafted in particular with methacryloylethyl trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyldiallylammonium or hydroxypropyltrialkylammonium salts, such as 2-hydroxypropyl trimethylammonium chloride. More particularly, the commercial products meeting this definition are those sold under the name National Starch company
L200 and->
H100, polyquaternium-10 (hydroxyethyl cellulose-2-hydroxypropyl trimethyl ammonium chloride ether), for example by KCI under the name +.>
The product sold by 400KC, polyquaternium-6 (polydiallyl dimethyl ammonium chloride), e.g. by Nalco under the name Merquat TM 100 Polymer sales products. Among them, particular preference is given to polyquaternium polymers, such as polyquaternium-7, 11, 15, 16, 22, 39, 47, 55And 67 and 76.
Cationic galactomannan gums are described, for example, in US3589578 and US4031307, and guar gums containing cationic trialkylammonium groups may be mentioned. For example, guar modified with 2, 3-epoxypropyltrimethylammonium salt (e.g., chloride) is used. Such products are sold, inter alia, by Rhodia company under the names JAGUAR C13S, JAGUAR C15, JAGUAR C17 or JAGUAR C162 (INCI: hydroxypropyl guar hydroxypropyl trimethylammonium chloride).
The cationic polymer (E) may be present in the composition according to the invention in an amount of from 0.01 to 5% by weight, preferably from 0.05 to 1% by weight, or preferably from 0.1 to 0.6% by weight, relative to the total weight of the composition, of one or more cationic polymers.
Solvent(s)
The composition according to the invention may advantageously comprise one or more solvents, for example water and/or organic solvents.
Water and its preparation method
The composition according to the invention may advantageously comprise various amounts of water. For example, water is used in a content of greater than or equal to 40% by weight relative to the total weight of the composition. The water content in the low viscosity composition according to the invention is preferably 40 to 90 wt%, more preferably 50 to 85 wt%, or 60 to 80 wt%, relative to the total weight of the composition.
Organic solvents
The composition according to the invention may also comprise one or more organic solvents, preferably water-soluble organic solvents (water solubility greater than or equal to 5% at 25 ℃ and at atmospheric pressure).
Examples of organic solvents which may be mentioned include straight-chain or branched and preferably saturated monohydric alcohols or diols containing from 2 to 10 carbon atoms, such as ethanol, isopropanol, hexanediol (2-methyl-2, 4-pentanediol), neopentyl glycol and 3-methyl-1, 5-pentanediol, butanediol, dipropylene glycol and propylene glycol; aromatic alcohols such as phenethyl alcohol; polyols containing more than two hydroxyl functions, such as glycerol; polyol ethers, e.g. ethylene glycol monomethylMonoethyl and monobutyl ethers, propylene glycol or ethers thereof, such as propylene glycol monomethyl ether; and diethylene glycol alkyl ethers, especially C 1 -C 4 Alkyl ethers, such as diethylene glycol monoethyl ether or monobutyl ether, alone or as a mixture.
When present, the organic solvent may constitute from 0% to 20% by weight, and preferably from 0.1% to 15% by weight, or from 0.3% to 5% by weight, relative to the total weight of the composition according to the invention. According to one embodiment of the present invention, no alcohol, in particular a polyol, is deliberately added as an organic solvent to the composition of the present invention. For example, the composition according to the invention may be free of any polyols.
Additional additives
According to various embodiments, the compositions of the present invention are provided for application to keratin fibers, such as skin or hair. According to these embodiments, the compositions of the present invention may comprise various ingredients conventionally used in compositions for cleansing keratin fibers, such as active ingredients, moisturizers, fatty substances, antidandruff agents, anti-seborrheic agents, agents for preventing hair loss and/or promoting hair regrowth, vitamins and provitamins (including panthenol), sunscreens, chelators, plasticizers, acidulants, opacifiers, pearlescers (pearlescent or nacreous agents), antioxidants, hydroxy acids, fragrances and preservatives.
A non-exhaustive list of such ingredients can be found in U.S. patent application publication 2004/0170586 (the entire contents of which are incorporated herein by reference). Still further examples of these additional ingredients can be found in International Cosmetic Ingredient Dictionary and Handbook (International cosmetic raw materials dictionary and handbook) (9 th edition, 2002).
The person skilled in the art will take care to choose the optional additional additives and/or the amounts thereof such that the envisaged addition does not or substantially not adversely affect the advantageous properties of the composition according to the invention.
These additives can be variously selected by those skilled in the art to prepare compositions having desired properties (e.g., consistency or texture). In particular, the additives (if used) and their amounts are determined in particular according to the particular product/its application (e.g., lotion, leave-on conditioner, shampoo, cream, rinse-off conditioner, emulsion, etc.).
These additives may be present in the composition in amounts of 0.01% to 90%, and further for example 0.1% to 50%, if present, relative to the total weight of the composition, including all ranges and subranges therebetween.
Method and use
The composition according to the invention can be prepared generally according to the general knowledge of a person skilled in the art. Nevertheless, it is understood that the skilled person may choose the preparation method based on his general knowledge, taking into account the nature of the ingredients used, such as their solubility in the carrier and the application envisaged for the composition or kit.
According to one embodiment, the composition according to the invention can be used for cleaning keratin fibres, in particular the hair, or the hair and scalp. Such use may manifest itself in a method of cleaning keratin fibres, in particular the hair, comprising the step of applying the composition of the invention to said keratin fibres.
The composition according to the invention is preferably useful for making shampoo products. The invention will be further illustrated by the following examples, which illustrate particularly advantageous embodiments.
Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements. Accordingly, the following examples are intended to illustrate the invention without limiting its scope.
Examples
The amounts/concentrations of ingredients in the following compositions/formulations are expressed in weight percent relative to the total weight of each composition/formulation.
Materials not specifically described herein are each commercially available.
Example 1
Composition a and comparative composition B as in table 1 were formulated separately:
TABLE 1
The above-listed compositions a and B were prepared according to manufacturing methods known in the art.
Compositions a and B were obtained in shampoo products according to the invention.
Example 2
Compositions a and B were evaluated. An equivalent sample of a 6 gram, 27 cm chinese hair sample was used. The same DIASTRON MTT175 device, but with different components, was used for both experiments: the TOUCHAIR test (reported in N) and DETANGLE test (reported in N) for average friction and the average disentanglement force) were followed according to routine on the device for both tests. For each test, a relatively low value represents better results. The evaluation was performed according to the following steps:
1) Washing all hair samples twice (1.6 g+1.2 g/6 g hair samples) with cleaning compositions a-B according to procedure RC-MCI-OIP-003B;
2) The friction force of all samples was then measured under wet conditions using the TOUCHAIR test;
3) Reorganizing all hair samples into groups with similar average wet friction and standard deviation thereof;
4) Samples were treated separately with all products according to standard procedures, but applied 2 times (dose: 1.6 grams +1.2 grams);
5) The friction force of all samples was then measured under wet conditions using the TOUCHAIR test;
6) The hair samples were dried naturally overnight and kept in an H & T chamber (23 ℃,50% rh);
7) The friction of all samples was then measured again under dry conditions using the TOUCHAIR test;
8) All hair samples were blown in a T & H chamber by wind (10 minutes) to create tangles;
9) Measuring the disentangling force under dry conditions with disentangling test;
10 Twisting the hair samples in a mixer with water (10 s each) to create tangles;
11 Under humid conditions, the disentanglement force was measured with a wet disentanglement test.
The results are provided in table 2 below.
TABLE 2
| Results | Composition A1 | Comparative composition B |
| Dry smoothness (N) | 2.52 | 2.32 |
| Wet smoothness (N) | 2.29 | 2.2 |
| Wet disentanglement (N) | 4.54 | 5.16 |
Example 3
The durability properties of compositions A and B were evaluated by comparison with the commercial products of ADOLPH NOURISH & REPAIR SHAMPOO, respectively.
The 6 trained panelists assessed the composition by a semi-hair trial. The evaluation was carried out 24 hours after the use of the composition, which means a dry performance check after 24 hours. Any significantly different sensations were recorded compared to the sales product, the results are provided in table 3 below:
table 3: performance compared to sales products
Note that: + represents a significantly better sensation;
o represents a similar sensation.
Example 4
Compositions a and B were evaluated. An equivalent sample of a 6 gram, 27 cm chinese hair sample was used.
Test compositions A-B (2.4 g) were applied to 6 g hair samples and rinsed off according to standard procedure RC-MCI-OIP-003B.
The hair samples were dried naturally overnight and kept in an H & T chamber (23 ℃,50% rh);
the smoothness, softness of the hair samples were evaluated by 6 trained panelists using standard poses and scores were given.
And (3) the reference: adolph Nourish and Repair shampoo comparison gives a score and is calculated as follows:
-2 represents a very significant worse;
-1 represents a significant worse;
0 represents a similar property;
+1 represents significantly better;
+2 represents very much better;
the average score of 6 experts was counted and the average calculated. The average scores are provided in table 4 below.
The spacing was greater than 0.5, considered a significant difference.
TABLE 4 Table 4
| The test method comprises the following steps: | composition A | Composition B |
| Smoothness of hair | +0.8 | +0.8 |
| Softness of hair | +0.6 | +0.2 |
Referring to Table 4, it was observed that composition A exhibited superior performance to composition B.
Claims (15)
1. A composition for cleaning keratin fibers comprising the following components:
(A) At least one surfactant comprising (a-1) at least one anionic surfactant, and/or (a-2) at least one amphoteric surfactant;
(B) At least one non-volatile silicone oil selected from polydialkylsiloxanes having terminal dimethylsilanol groups having 500 or more repeating units; and
(C) At least one aminosilicone, which is an amino terminal silicone.
2. The composition of claim 1, wherein the anionic surfactant (a-1) is selected from the group consisting of alkali metal, alkaline earth metal or ammonium salts of laureth sulfate, laurylmethyl isethionate, cocoyl isethionate, or mixtures thereof.
3. The composition according to any of the preceding claims, wherein the anionic surfactant (a-1) is present in the composition in an amount of 1% to 30%, such as 5% to 25%, or 10% to 20%, including all ranges and subranges therebetween, relative to the total weight of the composition.
4. The composition according to any of the preceding claims, wherein the amphoteric surfactant (a-2) is a betaine surfactant selected from (C 8 -C 20 ) Alkyl betaines, sulfobetaines, (C) 8 -C 20 Alkyl) amido (C) 2 -C 8 Alkyl) betaines and (C) 8 -C 20 Alkyl) amido (C) 2 -C 8 Alkyl) sulfobetaines; cocoamidopropyl betaine or coco betaine is preferred.
5. The composition according to any of the preceding claims, wherein the amphoteric surfactant (a-2) is present in the composition in an amount of 0.5% to 20%, such as 0.5% to 10%, or 1% to 6%, including all ranges and subranges therebetween, relative to the total weight of the composition.
6. A composition according to any preceding claim, wherein the composition comprises a combination of anionic surfactant in the form of sulphate and betaine surfactant, such as sodium laureth sulphate and cocamidopropyl betaine.
7. A composition according to any preceding claim wherein the silicone oil (B) is a polydialkylsiloxane having terminal trimethylsilyl groups, a polydialkylsiloxane having terminal dimethylsilanol groups or a polyalkylarylsiloxane.
8. A composition according to any preceding claim wherein the silicone oil (B) is a dimethiconol.
9. Composition according to any one of the preceding claims, in which the silicone oil (B) is present in the composition in an amount ranging from 0.1 to 20% by weight, preferably from 0.5 to 10% by weight, more particularly from 1 to 5% by weight, relative to the total weight of the composition, including all ranges and subranges therebetween.
10. The composition according to any one of the preceding claims, wherein the aminosilicone (C) is bis-aminopropyl polydimethylsiloxane; bis-aminopropyl/ethoxyaminopropyl polydimethylsiloxane, bis-isobutyl/PEG/PPG-20/35/amino-terminated polydimethylsiloxane copolymer, bis-cetylstearyl amino-terminated polydimethylsiloxane, bis-aminoppeg/PPG-41/3 aminoethylpg-propylpolydimethylsiloxane, bis (C13-15 alkoxy) PG-amino-terminated polydimethylsiloxane, bis-hydroxy/methoxy amino-terminated polydimethylsiloxane, and mixtures thereof.
11. Composition according to any one of the preceding claims, in which the aminosilicone (C) is present in the composition according to the invention in an amount ranging from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, more particularly from 0.4 to 2% by weight, relative to the total weight of the composition.
12. The composition of any of the preceding claims, further comprising (D) at least one thickener selected from carboxylic acid polymers, crosslinked polyacrylate polymers, polyacrylamide polymers, polysaccharides, gums, or mixtures thereof; preferably, the polysaccharide is selected from the group consisting of cellulose, carboxymethyl hydroxyethyl cellulose, cellulose acetate propionate, hydroxyethyl cellulose, hydroxyethyl ethyl cellulose, hydroxypropyl methyl cellulose, methyl hydroxyethyl cellulose, microcrystalline cellulose, sodium cellulose sulfate, and mixtures thereof; the thickener is present in the composition in an amount of 0.01 to 5 wt%, preferably 0.05 to 3 wt%, or preferably 0.1 to 1 wt%, relative to the total weight of the composition, including all ranges and subranges therebetween.
13. The composition according to any of the preceding claims, further comprising at least one cationic polymer (E) selected from the group consisting of polyquaternium-6, 7, 10, 11, 15, 16, 22, 39, 47, 55, 67 and 76.
14. A shampoo product comprising the composition according to any preceding claim.
15. Use of a composition according to any one of claims 1 to 13 for cleaning keratin fibres.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2020/119187 WO2022067612A1 (en) | 2020-09-30 | 2020-09-30 | Composition for cleansing keratin fibers and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116322634A true CN116322634A (en) | 2023-06-23 |
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| CN202080105684.5A Pending CN116322634A (en) | 2020-09-30 | 2020-09-30 | Composition for cleaning keratin fibres and use thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN116322634A (en) |
| FR (1) | FR3114505B1 (en) |
| WO (1) | WO2022067612A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3140269A1 (en) * | 2022-09-29 | 2024-04-05 | L'oreal | Cosmetic composition comprising a particular silicone emulsion, a particular cationic polymer, a particular anionic surfactant and an amphoteric surfactant |
| FR3141344A1 (en) * | 2022-10-28 | 2024-05-03 | L'oreal | Cosmetic composition comprising an anionic surfactant, an amphoteric surfactant, an alpha-omega bis-amino silicone and an amine silicone |
| FR3141343A1 (en) * | 2022-10-28 | 2024-05-03 | L'oreal | Cosmetic composition comprising an alpha-omega bis-amino silicone, an amino silicone, an anionic surfactant and an amphoteric surfactant |
| WO2024094537A1 (en) * | 2022-11-03 | 2024-05-10 | L'oreal | Composition comprising a particular silicone, a particular silicone emulsion, a particular vinylic polymer and surfactants |
| FR3143364A1 (en) * | 2022-12-19 | 2024-06-21 | L'oreal | COMPOSITION COMPRISING A PARTICULAR SILICONE, A PARTICULAR SILICONE EMULSION, A PARTICULAR VINYL POLYMER AND SURFACTANTS |
| FR3145688A1 (en) * | 2023-02-15 | 2024-08-16 | L'oreal | COMPOSITION COMPRISING A PARTICULAR SILICONE EMULSION, AN AMPHOTERIC OR CATIONIC VINYL POLYMER, SURFACTANTS AND AN ACRYLIC COPOLYMER |
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- 2020-09-30 WO PCT/CN2020/119187 patent/WO2022067612A1/en active Application Filing
- 2020-09-30 CN CN202080105684.5A patent/CN116322634A/en active Pending
- 2020-12-01 FR FR2012454A patent/FR3114505B1/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| FR3114505B1 (en) | 2024-01-19 |
| FR3114505A1 (en) | 2022-04-01 |
| WO2022067612A1 (en) | 2022-04-07 |
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