CN109745254A - It is a kind of have effects that scalp care without silicone oil shampoo and preparation method thereof - Google Patents

Abstract

The invention discloses it is a kind of have effects that scalp care without silicone oil shampoo and preparation method thereof, ingredient includes laureth sodium sulphate, cocoyl glutamic acid TEA salt, acrylic acid lipin polymer, Cocoamidopropyl betaine, glycol distearate, glycerol, PEG-7 glyceryl cocoate, essence, sodium cocoamphoacetate, sodium chloride, Phenoxyethanol, methyl hydroxybenzoate, sodium hydroxide, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis-, polyquaternium -7, hexylene glycol, sodium benzoate, glycine, camellia seed oil, arginine, coconut oleoyl amine MEA, full greenery Queensland nut seed oil, extractive of flax seed, butanediol, bladder-wrack extract, Thallus Laminariae (Thallus Eckloniae) extract, serine, red sesame stem extraction, polyglutamic acid, potassium sorbate, citric acid, vitamin E, water；The present invention solves shampoo and the drawback withered, that foaming capacity is weak that knots occurs using silicone oil, only with the shampoo hair of amino acid.

Description

It is a kind of have effects that scalp care without silicone oil shampoo and preparation method thereof

Technical field

The present invention relates to shampoo fields, specifically, more particularly to a kind of having effects that washing without silicone oil for hair nursing Shampoo and preparation method thereof.

Background technique

It is at present on the market more than still to contain dimethyl silicone polymer in ninety percent shampoo component list, silicate-containing oil is not washed Flood very few, it, can be with using since silicone oil is not soluble in water although the silicone oil in shampoo can allow hair smooth Number constantly wraps hair outer layer from level to level, and long-time service will cause hair and gradually lose elasticity, and hair pore is blocked, hair The oxygen flow in hole is insufficient and then will affect scalp health；And the shampoo of the not silicate-containing oil of this only a few, it is also only that silicone oil is gone Fall, there is no the ingredients that addition can substitute silicone oil, so that hair washing back is not dry withered smooth.A few amino acids on the market at present Shampoo still has and washes the withered phenomenon of rear hair knotting, and since amino acid foaming power itself is not strong, shampoo is caused to be not easy Blistering and foam do not enrich the impression not strong to people's cleaning force, i.e. use feeling is bad, and merely using amino acid foaming agent at This is higher, so amino acid shampoo on the market all has expensive, the common drawback of use feeling at present.

Summary of the invention

The present invention propose it is a kind of have effects that hair nursing without silicone oil shampoo and preparation method thereof, to solve shampoo The drawbacks of using silicone oil, solves the drawback withered, that foaming capacity is weak that knots occur using the shampoo hair of amino acid merely.

It is a kind of have effects that scalp care without silicone oil shampoo, main component weight accounting is as follows, laureth sulphur Sour sodium is 8%-10%, cocoyl glutamic acid TEA salt is 9%-11%, acrylic acid lipin polymer is 2.3%-2.5%, coconut oleoyl amine Propyl betaine is 1.4%-1.6%, glycol distearate 1%-2%, glycerol 4%-6%, PEG-7 glyceryl cocoate are 10%-12%, essence 0.6%-0.8%, sodium cocoamphoacetate 10%-15%, sodium chloride 1%-2%, Phenoxyethanol are 0.2%-0.4%, methyl hydroxybenzoate 0.1%-0.3%, the white pond flower seed oil amide ethyl first of sodium hydroxide 0.1%-0.3%, PEG-2 bis- Base ammonium methyl sulphate is 1%-2%, polyquaternium -7 is 1%-3%, hexylene glycol 5%-10%, sodium benzoate 0.02%-0.04%, Glycine is 1%-3%, camellia seed oil 1%-2%, arginine 0.5%-1.5%, coconut oleoyl amine MEA are 0.5%-1.5%, Quan Lvye Queensland nut seed oil is 0.5%-1.5%, extractive of flax seed 0.5%-0.8%, butanediol 1%-2%, bladder-wrack extract are 1%-2%, Thallus Laminariae (Thallus Eckloniae) extract 1%-2%, serine 0.5%-1%, red sesame stem extraction be 0.5%-1%, polyglutamic acid 0.5%- 0.8%, potassium sorbate 0.003%-0.005%, citric acid 0.003%-0.005%, vitamin E 0.5%-1%, surplus are water.

Based on the above technical solution, the present invention can also be improved as follows.

Further, main component weight accounting is as follows, laureth sodium sulphate 8%, cocoyl glutamic acid TEA salt It is 2.3% for 9%, acrylic acid lipin polymer, Cocoamidopropyl betaine 1.4%, glycol distearate 1%, sweet Oil is 4%, PEG-7 glyceryl cocoate is 10%, essence 0.6%, sodium cocoamphoacetate 10%, sodium chloride 1%, Phenoxyethanol is 0.2%, methyl hydroxybenzoate 0.1%, sodium hydroxide 0.1%, the white pond flower seed oil amide ethyl-methyl ammonium of PEG-2 bis- Methylsulfate is 1%, polyquaternium -7 is 1%, hexylene glycol 5%, sodium benzoate 0.02%, glycine 1%, camellia seed oil For 1%, arginine 0.5%, coconut oleoyl amine MEA be 0.5%, Quan Lvye Queensland nut seed oil is 0.5%, extractive of flax seed is 0.5%, butanediol 1%, bladder-wrack extract are 1%, Thallus Laminariae (Thallus Eckloniae) extract 1%, serine 0.5%, red sesame stem extraction are 0.5%, polyglutamic acid 0.5%, potassium sorbate 0.003%, citric acid 0.003%, vitamin E 0.5%, surplus are water.

Further, main component weight accounting is as follows, laureth sodium sulphate 10%, cocoyl glutamic acid TEA salt It is 2.5% for 11%, acrylic acid lipin polymer, Cocoamidopropyl betaine 1.6%, glycol distearate 2%, sweet Oil is 6%, PEG-7 glyceryl cocoate is 12%, essence 0.8%, sodium cocoamphoacetate 15%, sodium chloride 2%, Phenoxyethanol is 0.4%, methyl hydroxybenzoate 0.3%, sodium hydroxide 0.3%, the white pond flower seed oil amide ethyl-methyl ammonium of PEG-2 bis- Methylsulfate is 2%, polyquaternium -7 is 3%, hexylene glycol 10%, sodium benzoate 0.04%, glycine 3%, camellia seed oil For 2%, arginine 1.5%, coconut oleoyl amine MEA be 1.5%, Quan Lvye Queensland nut seed oil is 1.5%, extractive of flax seed is 0.8%, butanediol 2%, bladder-wrack extract are 2%, Thallus Laminariae (Thallus Eckloniae) extract 2%, serine 1%, red sesame stem extraction are 1%, Polyglutamic acid is 0.8%, potassium sorbate 0.005%, citric acid 0.005%, vitamin E 1%, and surplus is water.

Further, main component weight accounting is as follows, laureth sodium sulphate 9%, cocoyl glutamic acid TEA salt Be 2.4% for 10%, acrylic acid lipin polymer, Cocoamidopropyl betaine 1.5%, glycol distearate 1.5%, Glycerol is 5%, PEG-7 glyceryl cocoate is 11%, essence 0.7%, sodium cocoamphoacetate 12.5%, sodium chloride are 1.5%, Phenoxyethanol 0.3%, methyl hydroxybenzoate 0.2%, sodium hydroxide 0.2%, the white pond flower seed oil amide ethyl first of PEG-2 bis- Base ammonium methyl sulphate is 1.5%, polyquaternium -7 is 2%, hexylene glycol 7.5%, sodium benzoate 0.03%, glycine 2%, Camellia seed oil is 1.5%, arginine 1%, coconut oleoyl amine MEA are 1%, Quan Lvye Queensland nut seed oil is 1%, extractive of flax seed For 0.65%, butanediol 1.5%, bladder-wrack extract be 1.5%, Thallus Laminariae (Thallus Eckloniae) extract 1.5%, serine 0.75%, red sesame stem Extract is 0.75%, polyglutamic acid 0.65%, potassium sorbate 0.004%, citric acid 0.004%, vitamin E 0.75%, Surplus is water.

It is a kind of to have effects that the preparation method without silicone oil shampoo of scalp care, include the following steps,

Step 1: being required according to predominant quantity, successively claim to match weight accounting laureth sodium sulphate, cocoyl paddy Propylhomoserin TEA salt, acrylic acid lipin polymer, Cocoamidopropyl betaine, glycol distearate, glycerol, PEG-7 glycerol Cocounut oil acid esters, essence, sodium cocoamphoacetate, sodium chloride, Phenoxyethanol, methyl hydroxybenzoate, sodium hydroxide, PEG-2 bis- are white Pond flower seed oil amide ethyl-methyl ammonium methyl sulphate, polyquaternium -7, hexylene glycol, sodium benzoate, glycine, camellia seed oil, Arginine, coconut oleoyl amine MEA, Quan Lvye Queensland nut seed oil, extractive of flax seed, butanediol, bladder-wrack extract, kelp mention Take object, serine, red sesame stem extraction, polyglutamic acid, potassium sorbate, citric acid, vitamin E, water；

Step 2: in the 80%-90% water for the good glycerol of counterweight, methyl hydroxybenzoate, PEG-7 glyceryl cocoate being put into the total amount of water, Water is heated to 75 degrees Celsius, dissolution, which is sufficiently stirred, is dispersed in water glycerol, methyl hydroxybenzoate, PEG-7 glyceryl cocoate；

Step 3: the good laureth sodium sulphate of counterweight, cocoyl glutamic acid TEA salt, Cocoamidopropyl betaine, Sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA put into remaining water at normal temperature and moisten；

Step 4: the laureth sodium sulphate after above-mentioned moisten, cocoyl glutamic acid TEA salt, cocamidopropyl propyl amide beet Alkali, sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA are slowly put into the solution of above-mentioned steps 2；

Step 5: the good acrylic acid of counterweight (ester) analog copolymer, polyquaternium -7, sodium hydroxide slowly being put into the solution of step 4 In, it is stirred 10 minutes, then it is stirred and is cooled to 45 degrees Celsius；

Step 6: the good essence of counterweight, Phenoxyethanol, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis-, Sodium chloride, glycine, arginine, polyglutamic acid, red sesame stem extraction, camellia seed oil, extractive of flax seed, butanediol, silk ammonia Acid, bladder-wrack extract, Thallus Laminariae (Thallus Eckloniae) extract, potassium sorbate, citric acid, Quan Lvye Queensland nut seed oil, vitamin E put into step It is sufficiently mixed in 5 solution 3 minutes, then stirring is cooled to 30 degrees Celsius；

Step 7: solution obtained in step 6 being carried out to vacuumize degassing process, then to treated, solution is filtered again；

Step 8: content analyte detection being carried out to the product of step 7, carries out discharging processing after detection；

Step 9: filling and packaging being carried out to the product that step 8 discharges, finished product detection is carried out to the filling finished product with after packaging.

The invention has the advantages that using amino acid table ingredient cocoyl glutamic acid TEA salt living, and laruyl alcohol is poly- Ether sodium sulfovinate and sodium cocoamphoacetate assist cocoyl glutamic acid TEA salt to play better as foaming agent Cleaning action had not only controlled cost but also best watch box of washing can be brought to test to consumer；Service performance close to silicone oil glycerol and PEG-7 glyceryl cocoate substitutes silicone oil, and is added to glycine, arginine, polyglutamic acid, serine etc. a variety of amino acid are protected The wet nourishing factor takees good care of scalp；Mild inirritative protective system Phenoxyethanol and sodium benzoate are added, reduces scalp not Suitable sense makes pH value tend to be neutral, vast majority of people is suitble to use；By composition proportion appropriate, each component is mutually cooperateed with, not Simple raw material function superposition, in addition the preparation method of science, makes each ingredient act on having obtained good performance, and this preparation It is simple process, easy to operate, it can industrialize and large-scale production.

Specific embodiment

Detailed description of the preferred embodiments below, it should be appreciated that described herein specific Embodiment is merely to illustrate and explain the present invention, and protection scope of the present invention is not limited to following specific embodiments.

It is a kind of have effects that scalp care without silicone oil shampoo, main component weight accounting is as follows, laureth sulphur Sour sodium is 8%-10%, cocoyl glutamic acid TEA salt is 9%-11%, acrylic acid lipin polymer is 2.3%-2.5%, coconut oleoyl amine Propyl betaine is 1.4%-1.6%, glycol distearate 1%-2%, glycerol 4%-6%, PEG-7 glyceryl cocoate are 10%-12%, essence 0.6%-0.8%, sodium cocoamphoacetate 10%-15%, sodium chloride 1%-2%, Phenoxyethanol are 0.2%-0.4%, methyl hydroxybenzoate 0.1%-0.3%, the white pond flower seed oil amide ethyl first of sodium hydroxide 0.1%-0.3%, PEG-2 bis- Base ammonium methyl sulphate is 1%-2%, polyquaternium -7 is 1%-3%, hexylene glycol 5%-10%, sodium benzoate 0.02%-0.04%, Glycine is 1%-3%, camellia seed oil 1%-2%, arginine 0.5%-1.5%, coconut oleoyl amine MEA are 0.5%-1.5%, Quan Lvye Queensland nut seed oil is 0.5%-1.5%, extractive of flax seed 0.5%-0.8%, butanediol 1%-2%, bladder-wrack extract are 1%-2%, Thallus Laminariae (Thallus Eckloniae) extract 1%-2%, serine 0.5%-1%, red sesame stem extraction be 0.5%-1%, polyglutamic acid 0.5%- 0.8%, potassium sorbate 0.003%-0.005%, citric acid 0.003%-0.005%, vitamin E 0.5%-1%, surplus are water.

Using amino acid table ingredient cocoyl glutamic acid TEA salt living, and laureth sodium sulfovinate and cocounut oil acyl Both sexes guanidine-acetic acid sodium assists cocoyl glutamic acid TEA salt to play better cleaning action, both controls into as foaming agent This can bring best watch box of washing to test to consumer again；The glycerol and PEG-7 glyceryl cocoate of service performance close to silicone oil replace For silicone oil, and a variety of amino acid moisturizing and nourishing factors care scalps such as be added to glycine, arginine, polyglutamic acid, serine； Mild inirritative protective system Phenoxyethanol and sodium benzoate are added, the sense of discomfort of scalp is reduced, pH value is made to tend to be neutral, It is suitble to vast majority of people to use.

Embodiment 1:

Main component weight accounting is as follows, and laureth sodium sulphate 8%, cocoyl glutamic acid TEA salt is 9%, acrylic acid Lipin polymer is 2.3%, Cocoamidopropyl betaine 1.4%, glycol distearate 1%, glycerol 4%, PEG-7 Glyceryl cocoate is 10%, essence 0.6%, sodium cocoamphoacetate 10%, sodium chloride 1%, Phenoxyethanol are 0.2%, methyl hydroxybenzoate 0.1%, sodium hydroxide 0.1%, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis- It is 1% for 1%, polyquaternium -7, hexylene glycol 5%, sodium benzoate 0.02%, glycine 1%, camellia seed oil 1%, arginine It is 0.5% for 0.5%, coconut oleoyl amine MEA, Quan Lvye Queensland nut seed oil is 0.5%, extractive of flax seed 0.5%, butanediol are 1%, bladder-wrack extract is 1%, Thallus Laminariae (Thallus Eckloniae) extract 1%, serine 0.5%, red sesame stem extraction are 0.5%, polyglutamic acid is 0.5%, potassium sorbate 0.003%, citric acid 0.003%, vitamin E 0.5%, surplus are water.

Embodiment 2:

Main component weight accounting is as follows, and laureth sodium sulphate 10%, cocoyl glutamic acid TEA salt is 11%, propylene Acid esters analog copolymer is 2.5%, Cocoamidopropyl betaine 1.6%, glycol distearate 2%, glycerol 6%, PEG-7 glyceryl cocoate is 12%, essence 0.8%, sodium cocoamphoacetate 15%, sodium chloride 2%, Phenoxyethanol For 0.4%, methyl hydroxybenzoate 0.3%, sodium hydroxide 0.3%, the white pond flower seed oil amide ethyl-methyl ammonium methylsulfuric acid of PEG-2 bis- Salt is 2%, polyquaternium -7 is 3%, hexylene glycol 10%, sodium benzoate 0.04%, glycine 3%, camellia seed oil 2%, essence Propylhomoserin is 1.5%, coconut oleoyl amine MEA is 1.5%, Quan Lvye Queensland nut seed oil is 1.5%, extractive of flax seed 0.8%, fourth two Alcohol is 2%, bladder-wrack extract is 2%, Thallus Laminariae (Thallus Eckloniae) extract 2%, serine 1%, red sesame stem extraction are 1%, polyglutamic acid is 0.8%, potassium sorbate 0.005%, citric acid 0.005%, vitamin E 1%, surplus are water.

Embodiment 3:

Main component weight accounting is as follows, and laureth sodium sulphate 9%, cocoyl glutamic acid TEA salt is 10%, acrylic acid Lipin polymer is 2.4%, Cocoamidopropyl betaine 1.5%, glycol distearate 1.5%, glycerol 5%, PEG-7 glyceryl cocoate is 11%, essence 0.7%, sodium cocoamphoacetate 12.5%, sodium chloride 1.5%, benzene oxygen Ethyl alcohol is 0.3%, methyl hydroxybenzoate 0.2%, sodium hydroxide 0.2%, the white pond flower seed oil amide ethyl-methyl ammonium methyl of PEG-2 bis- Sulfate is 1.5%, polyquaternium -7 is 2%, hexylene glycol 7.5%, sodium benzoate 0.03%, glycine 2%, camellia seed oil For 1.5%, arginine 1%, coconut oleoyl amine MEA be 1%, Quan Lvye Queensland nut seed oil is 1%, extractive of flax seed 0.65%, Butanediol is 1.5%, bladder-wrack extract is 1.5%, Thallus Laminariae (Thallus Eckloniae) extract 1.5%, serine 0.75%, red sesame stem extraction are 0.75%, polyglutamic acid 0.65%, potassium sorbate 0.004%, citric acid 0.004%, vitamin E 0.75%, surplus are Water.

It is a kind of to have effects that the preparation method without silicone oil shampoo of scalp care, include the following steps,

Step 1: being required according to predominant quantity, successively claim to match weight accounting laureth sodium sulphate, cocoyl paddy Propylhomoserin TEA salt, acrylic acid lipin polymer, Cocoamidopropyl betaine, glycol distearate, glycerol, PEG-7 glycerol Cocounut oil acid esters, essence, sodium cocoamphoacetate, sodium chloride, Phenoxyethanol, methyl hydroxybenzoate, sodium hydroxide, PEG-2 bis- are white Pond flower seed oil amide ethyl-methyl ammonium methyl sulphate, polyquaternium -7, hexylene glycol, sodium benzoate, glycine, camellia seed oil, Arginine, coconut oleoyl amine MEA, Quan Lvye Queensland nut seed oil, extractive of flax seed, butanediol, bladder-wrack extract, kelp mention Take object, serine, red sesame stem extraction, polyglutamic acid, potassium sorbate, citric acid, vitamin E, water；

Step 2: in the 80%-90% water for the good glycerol of counterweight, methyl hydroxybenzoate, PEG-7 glyceryl cocoate being put into the total amount of water, Water is heated to 75 degrees Celsius, dissolution, which is sufficiently stirred, is dispersed in water glycerol, methyl hydroxybenzoate, PEG-7 glyceryl cocoate；

Step 3: the good laureth sodium sulphate of counterweight, cocoyl glutamic acid TEA salt, Cocoamidopropyl betaine, Sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA put into remaining water at normal temperature and moisten；

Step 4: the laureth sodium sulphate after above-mentioned moisten, cocoyl glutamic acid TEA salt, cocamidopropyl propyl amide beet Alkali, sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA are slowly put into the solution of above-mentioned steps 2；

Step 5: the good acrylic acid of counterweight (ester) analog copolymer, polyquaternium -7, sodium hydroxide slowly being put into the solution of step 4 In, it is stirred 10 minutes, then it is stirred and is cooled to 45 degrees Celsius；

Step 6: the good essence of counterweight, Phenoxyethanol, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis-, Sodium chloride, glycine, arginine, polyglutamic acid, red sesame stem extraction, camellia seed oil, extractive of flax seed, butanediol, silk ammonia Acid, bladder-wrack extract, Thallus Laminariae (Thallus Eckloniae) extract, potassium sorbate, citric acid, Quan Lvye Queensland nut seed oil, vitamin E put into step It is sufficiently mixed in 5 solution 3 minutes, then stirring is cooled to 30 degrees Celsius；

Step 7: solution obtained in step 6 being carried out to vacuumize degassing process, then to treated, solution is filtered again；

Step 8: content analyte detection being carried out to the product of step 7, carries out discharging processing after detection；

Step 9: filling and packaging being carried out to the product that step 8 discharges, finished product detection is carried out to the filling finished product with after packaging.

By composition proportion appropriate, each component is mutually cooperateed with, not simple raw material function superposition, in addition the system of science Preparation Method makes each ingredient act on having obtained good performance, and this preparation process is simple and convenient to operate, and can be industrialized and be advised Modelling production.

Embodiment 1,2,3 is prepared using above-mentioned preparation method, obtained shampoo carries out drug effect comparison respectively, The obtained effect of embodiment 3 is more excellent as the result is shown.

Based on the product obtained with embodiment 3 and above-mentioned preparation method as scheme 1；On the basis of embodiment 3, Without using laureth sodium sulphate, the product obtained only with above-mentioned preparation method is as scheme 2；In the base of embodiment 3 On plinth, cocoyl glutamic acid TEA salt is not only used, the product obtained using above-mentioned preparation method is as scheme 3；By this three Kind scheme, i.e. scheme 1, scheme 2, scheme 3, the different shampoo of core component are respectively acting on 20 experiments of scalp health Person, three kinds of schemes are used continuously one month respectively, and feedback is as shown in table 1 below.

The experimenter of 1 three kinds of different schemes of table uses contrast table

In above-mentioned table 1, use feeling refers to well: foam exquisiteness is abundant, and cleaning force is moderate, and Yi Chongxi is not stimulated, and does not dry up；It uses Sense generally refers to: foam is general, and cleaning force is general, somewhat dry；Use feeling difference refers to: foam is seldom, and cleaning force is poor, beats after washing Knot.

The resultant effect that can be seen that scheme 1 from 1 effect of table is best, merely using amino acid foaming agent due to gas itself Bubble ability not enough causes user to generate the not strong illusion of cleaning force, instead because its expensive cost causes to waste.If only made It will cause irritation again with laureth sodium sulfovinate, foam is not fine and smooth etc..And it can be brought well in conjunction with two kinds of uses Effect, but because the amino acid factor being added in shampoo, plays the role of good maintenance and nursing to hair quality.

Although the embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not These embodiments can be carried out with a variety of variations, modification, replacement and deformation in the case where being detached from the principle of the present invention and objective, this The range of invention is defined by the claims and their equivalents.

Claims (5)

1. it is a kind of have effects that scalp care without silicone oil shampoo, it is characterised in that: main component weight accounting is as follows, laurel Alcohol polyethers sodium sulphate is 8%-10%, cocoyl glutamic acid TEA salt is 9%-11%, acrylic acid lipin polymer be 2.3%-2.5%, Cocoamidopropyl betaine is 1.4%-1.6%, glycol distearate 1%-2%, glycerol 4%-6%, PEG-7 glycerol coconut palm Oleate is 10%-12%, essence 0.6%-0.8%, sodium cocoamphoacetate 10%-15%, sodium chloride 1%-2%, benzene Oxyethanol is 0.2%-0.4%, methyl hydroxybenzoate 0.1%-0.3%, the white pond flower seed oil acyl of sodium hydroxide 0.1%-0.3%, PEG-2 bis- Amine ethyl-methyl ammonium methyl sulphate is 1%-2%, polyquaternium -7 is 1%-3%, hexylene glycol 5%-10%, sodium benzoate are 0.02%-0.04%, glycine 1%-3%, camellia seed oil 1%-2%, arginine 0.5%-1.5%, coconut oleoyl amine MEA are 0.5%-1.5%, Quan Lvye Queensland nut seed oil is 0.5%-1.5%, extractive of flax seed 0.5%-0.8%, butanediol 1%- 2%, bladder-wrack extract is 1%-2%, Thallus Laminariae (Thallus Eckloniae) extract 1%-2%, serine 0.5%-1%, red sesame stem extraction are 0.5%- 1%, polyglutamic acid 0.5%-0.8%, potassium sorbate 0.003%-0.005%, citric acid 0.003%-0.005%, vitamin E For 0.5%-1%, surplus is water.

2. it is according to claim 1 it is a kind of have effects that scalp care without silicone oil shampoo, it is characterised in that: mainly at Point weight accounting is as follows, and laureth sodium sulphate 8%, cocoyl glutamic acid TEA salt is 9%, acrylic acid lipin polymer For 2.3%, Cocoamidopropyl betaine 1.4%, glycol distearate 1%, glycerol 4%, PEG-7 glycerol coconut oil Ester is 10%, essence 0.6%, sodium cocoamphoacetate 10%, sodium chloride 1%, Phenoxyethanol 0.2%, methyl hydroxybenzoate For 0.1%, sodium hydroxide 0.1%, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis- be 1%, polyquaternium- 7 be 1%, hexylene glycol 5%, sodium benzoate 0.02%, glycine 1%, camellia seed oil 1%, arginine 0.5%, cocounut oil acyl Amine MEA is 0.5%, Quan Lvye Queensland nut seed oil is 0.5%, extractive of flax seed 0.5%, butanediol 1%, bladder-wrack extraction Object is 1%, Thallus Laminariae (Thallus Eckloniae) extract 1%, serine 0.5%, red sesame stem extraction are 0.5%, polyglutamic acid 0.5%, potassium sorbate For 0.003%, citric acid 0.003%, vitamin E 0.5%, surplus is water.

3. it is according to claim 1 it is a kind of have effects that scalp care without silicone oil shampoo, it is characterised in that: mainly at Divide weight accounting as follows, laureth sodium sulphate 10%, cocoyl glutamic acid TEA salt are 11%, propylene esters of gallic acid is copolymerized Object is 2.5%, Cocoamidopropyl betaine 1.6%, glycol distearate 2%, glycerol 6%, PEG-7 glycerol cocounut oil Acid esters is 12%, essence 0.8%, sodium cocoamphoacetate 15%, sodium chloride 2%, Phenoxyethanol 0.4%, oxybenzene first Ester is 0.3%, sodium hydroxide 0.3%, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis- are 2%, polyquaternary amine Salt -7 is 3%, hexylene glycol 10%, sodium benzoate 0.04%, glycine 3%, camellia seed oil 2%, arginine 1.5%, coconut palm Oleamide MEA is 1.5%, Quan Lvye Queensland nut seed oil is 1.5%, extractive of flax seed 0.8%, butanediol 2%, bladder-wrack Extract is 2%, Thallus Laminariae (Thallus Eckloniae) extract 2%, serine 1%, red sesame stem extraction are 1%, polyglutamic acid 0.8%, potassium sorbate For 0.005%, citric acid 0.005%, vitamin E 1%, surplus is water.

4. it is according to claim 1 it is a kind of have effects that scalp care without silicone oil shampoo, it is characterised in that: mainly at Point weight accounting is as follows, and laureth sodium sulphate 9%, cocoyl glutamic acid TEA salt is 10%, acrylic acid lipin polymer For 2.4%, Cocoamidopropyl betaine 1.5%, glycol distearate 1.5%, glycerol 5%, PEG-7 glycerol cocounut oil Acid esters is 11%, essence 0.7%, sodium cocoamphoacetate 12.5%, sodium chloride 1.5%, Phenoxyethanol 0.3%, hydroxyl Benzene methyl is 0.2%, sodium hydroxide 0.2%, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis- are 1.5%, Polyquaternium -7 is 2%, hexylene glycol 7.5%, sodium benzoate 0.03%, glycine 2%, camellia seed oil 1.5%, arginine Be 1% for 1%, coconut oleoyl amine MEA, Quan Lvye Queensland nut seed oil is 1%, extractive of flax seed 0.65%, butanediol 1.5%, Bladder-wrack extract is 1.5%, Thallus Laminariae (Thallus Eckloniae) extract 1.5%, serine 0.75%, red sesame stem extraction are 0.75%, polyglutamic Acid is 0.65%, potassium sorbate 0.004%, citric acid 0.004%, vitamin E 0.75%, and surplus is water.

5. a kind of a kind of as described in claim 1-4 is any has effects that the preparation side without silicone oil shampoo of scalp care Method, it is characterised in that: include the following steps,

Step 1: being required according to predominant quantity, successively claim to match weight accounting laureth sodium sulphate, cocoyl paddy Propylhomoserin TEA salt, acrylic acid lipin polymer, Cocoamidopropyl betaine, glycol distearate, glycerol, PEG-7 glycerol Cocounut oil acid esters, essence, sodium cocoamphoacetate, sodium chloride, Phenoxyethanol, methyl hydroxybenzoate, sodium hydroxide, PEG-2 bis- are white Pond flower seed oil amide ethyl-methyl ammonium methyl sulphate, polyquaternium -7, hexylene glycol, sodium benzoate, glycine, camellia seed oil, Arginine, coconut oleoyl amine MEA, Quan Lvye Queensland nut seed oil, extractive of flax seed, butanediol, bladder-wrack extract, kelp mention Take object, serine, red sesame stem extraction, polyglutamic acid, potassium sorbate, citric acid, vitamin E, water；

Step 2: in the 80%-90% water for the good glycerol of counterweight, methyl hydroxybenzoate, PEG-7 glyceryl cocoate being put into the total amount of water, Water is heated to 75 degrees Celsius, dissolution, which is sufficiently stirred, is dispersed in water glycerol, methyl hydroxybenzoate, PEG-7 glyceryl cocoate；

Step 3: the good laureth sodium sulphate of counterweight, cocoyl glutamic acid TEA salt, Cocoamidopropyl betaine, Sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA put into remaining water at normal temperature and moisten；

Step 4: the laureth sodium sulphate after above-mentioned moisten, cocoyl glutamic acid TEA salt, cocamidopropyl propyl amide beet Alkali, sodium cocoamphoacetate, glycol distearate, coconut oleoyl amine MEA are slowly put into the solution of above-mentioned steps 2；

Step 5: the good acrylic acid of counterweight (ester) analog copolymer, polyquaternium -7, sodium hydroxide slowly being put into the solution of step 4 In, it is stirred 10 minutes, then it is stirred and is cooled to 45 degrees Celsius；

Step 6: the good essence of counterweight, Phenoxyethanol, the white pond flower seed oil amide ethyl-methyl ammonium methyl sulphate of PEG-2 bis-, Sodium chloride, glycine, arginine, polyglutamic acid, red sesame stem extraction, camellia seed oil, extractive of flax seed, butanediol, silk ammonia Acid, bladder-wrack extract, Thallus Laminariae (Thallus Eckloniae) extract, potassium sorbate, citric acid, Quan Lvye Queensland nut seed oil, vitamin E put into step It is sufficiently mixed in 5 solution 3 minutes, then stirring is cooled to 30 degrees Celsius；

Step 7: solution obtained in step 6 being carried out to vacuumize degassing process, then to treated, solution is filtered again；

Step 8: content analyte detection being carried out to the product of step 7, carries out discharging processing after detection；

Step 9: filling and packaging being carried out to the product that step 8 discharges, finished product detection is carried out to the filling finished product with after packaging.