CN107898654A - Amino acid shampoo composition and preparation method thereof - Google Patents
Amino acid shampoo composition and preparation method thereof Download PDFInfo
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- CN107898654A CN107898654A CN201710992510.5A CN201710992510A CN107898654A CN 107898654 A CN107898654 A CN 107898654A CN 201710992510 A CN201710992510 A CN 201710992510A CN 107898654 A CN107898654 A CN 107898654A
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- amino acid
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- betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention belongs to cosmetic field, is related to a kind of composition for cleaning class and preparation method thereof.It is made of by weight percentage following components：Amino acid surfactant 15% 50%, alhpa olefin sodium sulfonate 10% 30%, betaines surfactant 15% 50%.The effective difficult thickening of product declared that solves the problems, such as to live as main table using amino acid surfactant of the invention, mainly thickened using anion surfactant and amphoteric surfactant compounding, using 16 alkene sulfonic acid sodiums of C14 and betaines surfactant in appropriate proportions, micella is built, thickens system.Other thickeners need not be compounded, it can be achieved that cold match somebody with somebody technique, greatly reduced the production time, and the cleaning products foaming abundancy prepared is fine and smooth, cost greatlys save, and has both solved the problems, such as that amino acid table is lived difficult thickening, also solves amino acid table and lives low bubble-related issues.
Description
Technical field
The invention belongs to cosmetic field, is related to a kind of cleaning composition of low cost thickening.
Background technology
In the market amino acid shampoo generally existing high expensive, the relatively low problem of foam.Live mainly due to amino acid table
Of high cost, generally the least expensive also wants more than 12 yuan/kilogram, expensive even nearly hundred yuan/kilogram.And the foam of amino acids table work itself
Highly more common sulfate table work is relatively low, and it is thickening hardly possible that amino acid table, which was lived in the presence of the problem of maximum, and conventional shampoo increases
Thick dose, tend not to effectively thicken, or have obvious defoaming, such as coconut oleoyl amine MEA, PEG-150 distearate, PEG-
120 methyl dioleates, acrylic acid (ester) analog copolymer, thickening effect are extremely limited.Corresponding in the market was in recent years
To solve the problems, such as difficult thickening, develop such as three isostearate of PEG-120 methyls, four stearic acid of PEG-150 pentaerythrites
The product that effectively thickening amino acid table is lived such as ester, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymers, but it is deposited
It is of high cost, defoam, need heating, complex process etc. various the problem of.
In addition, in the prior art, also have and be used to thicken the work of amino acids table, such as Lu Haiwei only with amphoteric surfactant
Amino acid pattern/amphoteric surfactant compounding is have studied, it turns out that, cocoamido betaine is to different amino acids tables
Living, thickening effect is different, has thickening power to sodium N-lauroyl sarcosinate, cocoyl Sodium L-alaninate, and to lauryl
Sodium glutamate, sodium cocoyl methyl sodium taurocholate and cocoyl Sodium Glycinate are then without effective thickening power (big amino acid in Lu sea
Type/amphoteric surfactant compounding thickened systems and rheology study [D] East China University of Science, 2013.).Therefore, both sexes table
Face activating agent is limited for the thickening that amino acids table is lived be subject to many, such as the species that amino acids table is lived, pH, and both sexes
The species that table is lived, the proportioning that table is lived etc..
The content of the invention
Present invention aims at provide a kind of combination that can effectively thicken polytype amino acid surfactant
Thing.
The present invention also aims to provide a kind of composition of inexpensive thickening amino acids surfactant.
A kind of foaming effect is good the present invention also aims to providing, the amino acids composition of durable lather.
The present invention also aims to provide a kind of composition that need not add extra thickener.
The above-mentioned purpose of the present invention is realized by following technological means：
On the one hand, the present invention provides a kind of composition, it contains following components in percentage by weight：
Amino acid surfactant 15%~50%；
Alhpa olefin sodium sulfonate 10%~30%；
Betaines surfactant 10%~50%.
As preferred embodiment, contain following components in percentage by weight：
Amino acid surfactant 20%~45%；
Alhpa olefin sodium sulfonate 10%~30%；
Betaines surfactant 15%~45%.
Wherein, the amino acid surfactant is selected from Methyl fatty acyl taurate, fatty acyl sarcosides, fat
One or more in fat acyl glutamate and fatty acyl alanine salt.
Wherein, the weight ratio of alhpa olefin sodium sulfonate and betaines surfactant is 0.8~1.2:1.8~2.4.
Further, the Methyl fatty acyl taurate is selected from sodium methyl cocoyl taurate, methyl myristoyl
Base sodium taurocholate, methyl stearyl sodium taurocholate, cocounut oil acyl methyl taurine sodium taurocholate and methyl lauroyl taurine
One or more in sodium；The fatty acyl sarcosides are selected from sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, cocounut oil acyl
One or more in sodium sarcosinate and palmitoyl sarcosine sodium；The fatty acyl glutamate is selected from myristoyl glutamate
One or more in sodium, sodium cocoyl glutamate, stearoyl-glutamic acid sodium and sodium lauroyl glutamate；Third ammonia of fatty acyl
One or more of the hydrochlorate in cocoamido sodium propionate, lauroyl sodium propionate, lauroyl methylaminopropionic sodium；
As preferred embodiment, the amino acid surfactant is selected from sodium methyl cocoyl taurate.
Wherein, the alhpa olefin sodium sulfonate is selected from C12-14 alkene sulfonic acid sodiums, C14-16 alkene sulfonic acid sodiums, C14-18 alkene
One or more combinations in hydrocarbon sulfonate sodium and C16-18 alkene sulfonic acid sodiums；As preferred embodiment, the alhpa olefin
Sodium sulfonate is selected from C12-14 alkene sulfonic acid sodiums.
Wherein, the betaines surfactant is not particularly limited, as long as the surfactant of betaines,
It can play the role of thickening system of the present invention.Specifically, such as Coco-Hydroxysultaine, coco betaine, cocounut oil
Acyl/oleamide propyl betaine, Cocoamidopropyl betaine, lauryl hydroxyl sulfo betaine, lauryl betaine, bay
One or more combinations in amido propyl hydroxy sulfo lycine and lauroylamidopropyl betaine.
The composition of the present invention can be used for cleaning class product, such as shampoo, bath oil or facial cleanser etc..
As a kind of exemplary embodiment, composition of the invention is used for shampoo, except above-mentioned composition, this hair
In bright shampoo, can also contain shampoo in common component, as cation opsonizing agent, pH adjusting agent, preservative and
Common conditioning agent etc. in other shampoo.
As preferred embodiment, the cation opsonizing agent is selected from polyquaternium -6, Polyquaternium-10, poly- season
One in ammonium salt -22, polyquaternium -47, Polyquaternium-67, polyquaternium -73 and guar hydroxypropyltrimonium chloride etc.
Kind is a variety of；
As preferred embodiment, the pH adjusting agent is selected from citric acid and sodium citrate, sodium hydroxide, hydroxide
One or more in the pH adjusting agent of the routine such as potassium and triethanolamine.
As preferred embodiment, shampoo of the invention is also containing 0.01~5% moisturizer.Further, institute
One or more of the moisturizer stated in polyalcohol, glycine betaine, Sodium Hyaluronate, Anjidew NL50 and panthenol etc..
As a preferred embodiment, the shampoo of the present invention contains following components in percentage by weight：
Preferably, the composition also water containing surplus.
Alternatively, the grease type is silicone oil, PEG-7 glyceryl cocoates, sub- oleamide propyl group PG- dimethylammonium chlorides
The common conditioner for hair such as ammonium phosphate, C12-13 alcohol lactate, PPG-3 Octyl Ethers.
As preferred embodiment, it contains following components in percentage by weight：
On the other hand, present invention also offers the preparation method of above-mentioned shampoo, it includes following steps：
S1：Cation opsonizing agent is added in water, is disperseed；
S2：Betaines surfactant is added, after stirring, amino acid surfactant is added, adds alhpa olefin sulphur
Sour sodium；
Preferably, the method further includes S3：Further add moisturizer, grease type, one kind in pH preservatives or
It is a variety of, it is stirred until homogeneous.
As further alternative scheme, the described method includes：
S1：Under low temperature, suitable quantity of water is added, then adds cation opsonizing agent, it is scattered；
S2：Betaines surfactant is added, stirring adds amino acid surfactant after 1 minute, adds α alkene
Hydrocarbon sulfonate sodium (starts to start to warm up at this moment) if the raw material of heating for dissolving in need below；
S3：The raw material of surplus in formula is added, being stirred until homogeneous to discharge.
As described in background, amino acid surfactant is difficult to thicken, and even some surfactants can be with
Amino acid surfactant is thickened, also can be excessive there are cost, defoaming, thickens the problems such as limited.Therefore, inventor is always
One kind of concentrating on studies can effectively thicken the work of amino acids table, and the shampoo system that low cost, foaming effect are good.By a large amount of
Experimental studies have found that, alhpa olefin sodium sulfonate and betaines surfactant compounding, can effectively build a variety of amino acidses and wash
The system of the viscosity to become visible, it lives for most amino acids table, there is thickening power, and cost is low, and foaming effect is good.
Under specific compound proportion, the advantage of this thickening adjustment effect is then more notable.
It should be noted that alhpa olefin sodium sulfonate is not have thickening power in itself, and itself and betaines surface-active
Agent compounds, then can reach effectively thickening amino acid surfactant, and foaming effect is good, durable lather.
Beneficial effects of the present invention：
1st, in terms of thickening effect, the amino acids surface of alhpa olefin sodium sulfonate and betaines surfactant to multiple types
Activating agent all has obvious thickening capabilities, and has obvious help to the foam height of amino acid formula.
2nd, alhpa olefin sodium sulfonate, betaines surfactant and amino acid surfactant three compounding can improve bubble
The stability of foam.
3 while in the case of ratio appropriate mix, the cost of amino acid system formula can be significantly reduced, is solved
In the market amino acid system high expensive is difficult to the problem of popularization.
The reason for amino acid system high cost, there is two, first, amino acid table is lived substantially all in 10 yuan/more than KG, methyl amimoacetic acid
Sodium is generally the least expensive, others all more than 20 yuan, and active matter content only has 30%, compared to conventional AES want expensive one times it is even several
Times, do not have that AES is good plus its foaming power, if individually lived with amino acid table, its active matter content requires higher, higher amino yet
Sour table is lived, and brings the thickening difficulty of higher, and the raw material effectively thickened, its cost far above the common CMEA of AES shampoos,
DOE120, SF-1, light thickener are required for the cost with 1-3 members.To sum up, the amino acid shampoo worked it out, even if hair conditioning
Almost, in cost all more than 12 yuan, or even 30 yuan.
The amino acid shampoo of said composition, about 7 yuan of minimum cost, far below the average level in market.
4th, said composition enables the production of shampoo is cold to match somebody with somebody, and significantly reduces man-hour, improves production capacity, energy-efficient.Often
Rule hair washing hydro-thermal is matched somebody with somebody, and 3 hours are about needed in production, using said composition, only needs a pot production, about 1 it is small when.
Embodiment
Technical scheme is further illustrated below by way of specific embodiment, and specific embodiment is not represented to this hair
The limitation of bright protection domain.Other people according to the present invention theory made some it is nonessential modification and adjustment still fall within this hair
Bright protection domain.
Viscosity determining procedure：4# rotors 12rpm below 50000 viscosity
50000 viscosity above 4# rotors 6rpm
Foam height national standard Roche foam method of testing
Embodiment 1 verifies the betaines surfactant of different weight percentage and the alhpa olefin of different weight percentage
The synergistic thickening amino acids table of sodium sulfonate is lived
In order to verify the component of different percentage by weights and different amino acid classes for blistering and thickening effect
The influence of fruit etc., inventor devise following 3 schemes.Wherein from scheme 1 to scheme 3, betaines table is lived and alhpa olefin sulfonic acid
The percentage by weight of sodium gradually increases, for each scheme, have also been devised different types of amino acids table work to blistering and
The influence of thickening effect etc..Specific scheme sees below：
The physico-chemical property of combination in 1. scheme 1 of table prepared by different amino acid surfactants
The physico-chemical property of combination in 2. scheme 2 of table prepared by different amino acid surfactants
Note：Thickener coconut oleoyl amine MEA of the sodium lauroyl glutamate formula containing two points.
The physico-chemical property of combination in 3. scheme 3 of table prepared by different amino acid surfactants
Note：Thickener coconut oleoyl amine MEA of the sodium lauroyl glutamate formula containing two points.
From three experimental programs above, it can be deduced that to draw a conclusion
1st, with the increase of both sexes glycine betaine table work amount and alhpa olefin sodium sulfonate amount, except sodium lauroyl glutamate, other bodies
The viscosity of system is all significantly improved, especially sodium methyl cocoyl taurate, in relatively low both sexes glycine betaine table work amount and α
Under alkene sulfonic acid sodium additive amount, you can reach highly viscous system.And sodium lauroyl glutamate system, even improve both sexes sweet tea
Dish alkali table work amount and alhpa olefin sodium sulfonate amount, in the case of containing the combination, are simply added into the coconut oleoyl amine methyl MEA of two points,
Also 2000 to 32000 viscosity easily can be brought up to from 0 viscosity.And if lived only with betaines table, and it is not added with alhpa olefin sulphur
Sour sodium, even adds substantial amounts of thickener coconut oleoyl amine MEA, can not also thicken sodium lauroyl glutamate system again.Demonstrate α alkene
Hydrocarbon sulfonate sodium is in the case of rational collocation with both sexes glycine betaine table work being capable of significantly synergistic thickening amino acid surface work
Property agent system.
2nd, contrasted from scheme 1 and scheme 2, draw the increase with both sexes glycine betaine table work amount and alhpa olefin sodium sulfonate amount, remove
Sodium methyl cocoyl taurate, the foam height of other systems are all improved, and more stable.
3rd, contrast, drawn with the reduction of amino acid surfactant dosage, the viscosity energy of system from scheme 2 and scheme 3
It is significantly improved.It is that the work of amino acid table can be thickened effectively further to verify the combination.
4th, system of the invention can be thickened effectively for Sodium Glycinate class surfactant, but foaming effect is general,
Therefore, for the shampoo for needing largely to blister, Sodium Glycinate class surfactant is not suitable as shampoo amino acid
Main table, which is lived, to be used.
Embodiment 2 verifies that different amounts of both sexes glycine betaine table is lived, and lives with the ratio of alhpa olefin sodium sulfonate for amino acids table
The influence of thickening effect, and influences of the pH to system viscosity
Table 4.
There is viscosity with alhpa olefin sodium sulfonate and both ratio changes of amino acids table work in the thickening capabilities of composition
Change, grope the experience with inventor by experiment, when the weight ratio of alhpa olefin sodium sulfonate and betaines surfactant is
0.8~1.2:1.8~2.4, be formulated has higher viscosity at this time.In addition, from upper table as it can be seen that the change of pH is to influence viscosity
's.The main table of different amino acid is lived, its most highly viscous point be it is different, the highest viscosity of sodium sarcosinate class 6.0 or so, with
PH is different and parabola occurs, and specific peak value can change with the difference of formula.
Generally, the viscosity of composition can be improved by suitably reducing pH, such as be formulated D, because pH value is also higher, but it is viscous
Degree does not include height, continues to increase citric acid, can reduce pH value, improves viscosity.But when alhpa olefin sodium sulfonate and betaines table
The weight ratio of face activating agent in the range of the selection of the present invention, does not reduce pH even, does not have improvement result for viscosity,
Such as it is formulated E, formula F.
The preparation and test of 4 some amino acid shampoos of embodiment
Formula according to table 5, table 6, table 7 prepares some shampoo.
Preparation method：S1：Under low temperature, suitable quantity of water is added, then adds cation opsonizing agent, it is scattered；
S2：Betaines surfactant is added, stirring adds amino acid surfactant after 1 minute, adds α alkene
Hydrocarbon sulfonate sodium；
S3：The raw material of surplus in formula is added, being stirred until homogeneous to discharge.
5. coconut oleoyl amine sodium taurocholate shampoo of table
6. sodium glutamate shampoo of table
7. sodium sarcosinate shampoo of table
The performance of the different amino acid shampoo of table 8
| Viscosity mPAs | Foam height mm | Effect | |
| Shampoo in table 5 | 15000 | 150 | It is a softer and smoother touch |
| Shampoo in table 6 | 4500 | 140 | Merrily and lightheartedly, wet comb effect is good |
| Shampoo in table 7 | 6000 | 140 | Soft, dry hair effect is good |
It is at least 4500 with amino acid shampoo viscosity representative in table 5-7, especially containing methyl cocoyl ox
The shampoo of sodium sulfonate.The height of three is not much different, and reaches 140mm.
Embodiment 5
Formula in scheme 1, appropriate addition macromolecular cation opsonizing agent, being can be in the case where low table lives content
Thickened formula.
Scheme 1 adds macromolecular cation opsonizing agent
The physico-chemical property of combination in 9. scheme 1 of table prepared by different amino acid surfactants
Compared to scheme 1, which has added cation opsonizing agent, compared to the physicochemical property of scheme 1 in table 1,
After adding a small amount of cation opsonizing agent, the combination viscosity of the amino acid of all kinds is significantly lifted, most of without viscous
The combination of degree reaches viscosity more than 1000, and then height somewhat decreases foam.
Claims (10)
1. a kind of composition, it is characterised in that contain following components in percentage by weight：
Amino acid surfactant 15%~50%；
Alhpa olefin sodium sulfonate 10%~30%；
Betaines surfactant 10%~50%；
Wherein, the amino acid surfactant is selected from Methyl fatty acyl taurate, fatty acyl sarcosides, fatty acyl
One or more in glutamate and fatty acyl alanine salt；
Preferably, the weight ratio of alhpa olefin sodium sulfonate and betaines surfactant is 0.8~1.2:1.8~2.4.
2. composition according to claim 1, it is characterised in that contain following components in percentage by weight：
Amino acid surfactant 20%~45%；
Alhpa olefin sodium sulfonate 10%~30%；
Betaines surfactant 15%~45%.
3. composition according to claim 1, it is characterised in that the Methyl fatty acyl taurate is selected from methyl cocoyl
Acyl taurines sodium, methyl myristoyl sodium taurocholate, methyl stearyl sodium taurocholate, cocounut oil acyl methyl taurine ox sulphur
One or more in sour sodium and methyl lauroyl sodium taurocholate；
Preferably, the fatty acyl sarcosides are selected from sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, cocoyl sarcosine
One or more in sodium and palmitoyl sarcosine sodium；
Preferably, the fatty acyl glutamate is selected from myristoyl glutamate sodium, sodium cocoyl glutamate, stearoyl-glutamic acid
One or more in sodium and sodium lauroyl glutamate；
Preferably, the fatty acyl alanine salt is selected from cocoamido sodium propionate, lauroyl sodium propionate, lauroyl first
One or more in base alanine sodium；
It is highly preferred that the amino acid surfactant is selected from sodium methyl cocoyl taurate.
4. composition according to claim 1, it is characterised in that the alhpa olefin sodium sulfonate is selected from C12-14 alkene sulphurs
One or more combinations in sour sodium, C14-16 alkene sulfonic acid sodiums, C14-18 alkene sulfonic acid sodiums and C16-18 alkene sulfonic acid sodiums；
Preferably, the alhpa olefin sodium sulfonate is selected from C14-16 alkene sulfonic acid sodiums.
5. composition according to claim 1, it is characterised in that the betaines surfactant is selected from cocoyl
Hydroxyl sulfo betaine, coco betaine, cocounut oil acyl/oleamide propyl betaine, Cocoamidopropyl betaine, lauryl
In hydroxyl sulfo betaine, lauryl betaine, dodecanamide propyl hydroxy sulfo lycine and lauroylamidopropyl betaine
One or more combinations.
6. according to any compositions of claim 1-5, it is characterised in that the composition is used to clean class product；
Preferably, the cleaning class product is selected from shampoo, bath oil or facial cleanser.
7. composition according to claim 6, it is characterised in that the cleaning class product is shampoo；Described washes
Become visible also containing the one or more in cation opsonizing agent, pH adjusting agent, preservative；
Preferably, the cation opsonizing agent be selected from polyquaternium -6, Polyquaternium-10, Merquat 280, polyquaternium -
47th, the one or more in Polyquaternium-67, polyquaternium -73 and guar hydroxypropyltrimonium ammonium chloride；
Preferably, the pH adjusting agent is in citric acid and sodium citrate, sodium hydroxide, potassium hydroxide and triethanolamine
It is one or more of.
8. composition according to claim 7, it is characterised in that the shampoo also contains moisturizer, the guarantor
One or more of the humectant in polyalcohol, glycine betaine, Sodium Hyaluronate, Anjidew NL50 and panthenol.
9. composition according to claim 8, it is characterised in that the component containing following total score percentage：
Preferably, the composition also water containing surplus；
Preferably, the grease type is selected from silicone oil, PEG-7 glyceryl cocoates, sub- oleamide propyl group pg dimonium chloride
Phosphate, C12-13 alcohol lactate and PPG-3 Octyl Ethers are one or more of.
Preferably, containing following components in percentage by weight：
Preferably, the grease type is selected from silicone oil, PEG-7 glyceryl cocoates, sub- oleamide propyl group pg dimonium chloride
One or more in phosphate, C12-13 alcohol lactate and PPG-3 Octyl Ethers.
10. a kind of preparation method of composition, it is characterised in that comprise the steps of：
S1：Cation opsonizing agent is added in water, is disperseed；
S2：Betaines surfactant is added, after stirring, amino acid surfactant is added, adds alhpa olefin sulfonic acid
Sodium；
Preferably, the method further includes S3：The one or more in moisturizer, grease type, pH preservatives are further added,
It is stirred until homogeneous.
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| CN109172409A (en) * | 2018-09-20 | 2019-01-11 | 洛娃日化(江苏)股份有限公司 | It is a kind of for the thickener of amino acid surfactant and its application and shampoo |
| CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
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| CN110721108A (en) * | 2019-09-26 | 2020-01-24 | 广州妮趣化妆品有限公司 | Thickening composition of cocoyl alanine salt and application thereof |
| WO2020132861A1 (en) * | 2018-12-25 | 2020-07-02 | L'oreal | Composition for cleansing keratin materials |
| CN111616972A (en) * | 2020-05-13 | 2020-09-04 | 名臣健康用品股份有限公司 | Low-cost self-thickening mild sulfate-free shampoo composition and preparation method thereof |
| CN112263499A (en) * | 2020-11-27 | 2021-01-26 | 佛山市南海东方澳龙制药有限公司 | Animal shampoo with antibacterial function and preparation method thereof |
| CN114191323A (en) * | 2021-12-24 | 2022-03-18 | 岳阳科罗德联合化学工业有限公司 | Gemini glutamic acid amino acid surfactant composition and preparation method and application thereof |
| CN114224765A (en) * | 2021-12-31 | 2022-03-25 | 上海佰太生物科技有限公司 | Amino acid shampoo and preparation method thereof |
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
| CN114306135A (en) * | 2022-01-06 | 2022-04-12 | 清远天赐高新材料有限公司 | Transparent thickening suspension system, preparation method and application |
| CN115975612A (en) * | 2022-06-16 | 2023-04-18 | 桂林理工大学 | Subway shield foaming agent and preparation method thereof |
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| CN109172409A (en) * | 2018-09-20 | 2019-01-11 | 洛娃日化(江苏)股份有限公司 | It is a kind of for the thickener of amino acid surfactant and its application and shampoo |
| CN109172409B (en) * | 2018-09-20 | 2021-07-27 | 洛娃日化(江苏)股份有限公司 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
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| WO2020132861A1 (en) * | 2018-12-25 | 2020-07-02 | L'oreal | Composition for cleansing keratin materials |
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| CN109602639B (en) * | 2019-01-31 | 2021-12-21 | 广州艾蓓生物科技有限公司 | Amino acid-washing shampoo and preparation method thereof |
| CN110721108A (en) * | 2019-09-26 | 2020-01-24 | 广州妮趣化妆品有限公司 | Thickening composition of cocoyl alanine salt and application thereof |
| CN111616972A (en) * | 2020-05-13 | 2020-09-04 | 名臣健康用品股份有限公司 | Low-cost self-thickening mild sulfate-free shampoo composition and preparation method thereof |
| CN112263499A (en) * | 2020-11-27 | 2021-01-26 | 佛山市南海东方澳龙制药有限公司 | Animal shampoo with antibacterial function and preparation method thereof |
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
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| CN114191323A (en) * | 2021-12-24 | 2022-03-18 | 岳阳科罗德联合化学工业有限公司 | Gemini glutamic acid amino acid surfactant composition and preparation method and application thereof |
| CN114191323B (en) * | 2021-12-24 | 2024-03-26 | 岳阳科罗德联合化学工业有限公司 | Gemini glutamic acid amino acid surfactant composition, and preparation method and application thereof |
| CN114224765A (en) * | 2021-12-31 | 2022-03-25 | 上海佰太生物科技有限公司 | Amino acid shampoo and preparation method thereof |
| CN114306135A (en) * | 2022-01-06 | 2022-04-12 | 清远天赐高新材料有限公司 | Transparent thickening suspension system, preparation method and application |
| CN115975612A (en) * | 2022-06-16 | 2023-04-18 | 桂林理工大学 | Subway shield foaming agent and preparation method thereof |
| CN115975612B (en) * | 2022-06-16 | 2024-02-09 | 桂林理工大学 | Subway shield foaming agent and preparation method thereof |
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