CN109172409B - Thickener aiming at amino acid surfactant, application thereof and shampoo - Google Patents
Thickener aiming at amino acid surfactant, application thereof and shampoo Download PDFInfo
- Publication number
- CN109172409B CN109172409B CN201811099311.2A CN201811099311A CN109172409B CN 109172409 B CN109172409 B CN 109172409B CN 201811099311 A CN201811099311 A CN 201811099311A CN 109172409 B CN109172409 B CN 109172409B
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- Prior art keywords
- amino acid
- polyethylene glycol
- methyl glucoside
- shampoo
- acid surfactant
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- 239000004094 surface-active agent Substances 0.000 title claims abstract description 51
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 40
- 239000002562 thickening agent Substances 0.000 title claims abstract description 29
- 239000002453 shampoo Substances 0.000 title claims abstract description 27
- -1 polyethylene Polymers 0.000 claims abstract description 64
- 239000004698 Polyethylene Substances 0.000 claims abstract description 50
- 229920000573 polyethylene Polymers 0.000 claims abstract description 50
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 claims description 5
- QNAYBMKLOCPYGJ-UHFFFAOYSA-M alaninate Chemical compound CC(N)C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-M 0.000 claims description 5
- 229940065856 cocoyl glycinate Drugs 0.000 claims description 5
- 229940071085 lauroyl glutamate Drugs 0.000 claims description 5
- 229940071145 lauroyl sarcosinate Drugs 0.000 claims description 5
- 229940071088 methyl cocoyl taurate Drugs 0.000 claims description 5
- 229940071089 sarcosinate Drugs 0.000 claims description 5
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 5
- 229940104261 taurate Drugs 0.000 claims description 5
- VGMIHYGISGNHKU-UHFFFAOYSA-N (2-aminoacetyl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC(=O)CN VGMIHYGISGNHKU-UHFFFAOYSA-N 0.000 claims description 4
- 229940071124 cocoyl glutamate Drugs 0.000 claims description 4
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 abstract description 39
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 abstract description 39
- 230000008719 thickening Effects 0.000 abstract description 27
- 230000000694 effects Effects 0.000 abstract description 19
- 238000011161 development Methods 0.000 abstract description 4
- 239000002085 irritant Substances 0.000 abstract description 4
- 231100000021 irritant Toxicity 0.000 abstract description 4
- 235000001014 amino acid Nutrition 0.000 description 32
- 238000002474 experimental method Methods 0.000 description 19
- 238000000034 method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 3
- 235000004279 alanine Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 108700004121 sarkosyl Proteins 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 3
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229940095673 shampoo product Drugs 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000009044 synergistic interaction Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a thickening agent aiming at an amino acid surfactant, which consists of polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate in a mass ratio of 1: 1-3. The mixed thickener is used for thickening a system taking an amino acid surfactant as a main surfactant, has ideal thickening effect, effectively solves the problem of difficult thickening of the existing amino acid surfactant, enables the development of mild and non-irritant products taking the amino acid surfactant as the main surfactant, especially shampoo products, and brings better stability and use feeling to the products. The mixed thickener can be used in transparent formula to develop transparent products.
Description
Technical Field
The invention relates to a thickening agent aiming at an amino acid surfactant, application thereof and shampoo containing the thickening agent, and also relates to a method for thickening the amino acid surfactant, belonging to the fields of colloid and surface chemistry and cosmetics.
Background
Personal cleansing products have been an indispensable part of life, and not only can bring clean and comfortable feelings to people, but also can bring confidence to people. Along with the improvement of living standard of people, people pay more and more attention to the quality of products in the process of personal cleaning, and the products which are free of stimulation and have the body temperature of people are more and more popular with people.
Compared with traditional surfactants such as sodium laureth sulfate, sodium laureth sulfate and the like, the amino acid surfactant is milder, has less stimulation to skin and scalp, and can bring more comfortable and healthier cleaning experience to people. Although the thickening of amino acid surfactants in other products such as face washing cream is easy to realize, the thickening in shampoo, especially transparent shampoo is a technical problem, the commonly used traditional thickening agent basically has no thickening effect, and thickening agents such as carbomer, cellulose and the like can thicken but have great negative effect on the using feeling of the product, and the thickening agent cannot be made into a transparent product. The sticky property is indispensable for good use feeling and convenience.
Therefore, it is necessary to develop a thickener which can thicken a system mainly comprising an amino acid surfactant.
Disclosure of Invention
The invention aims to provide a thickener aiming at an amino acid surfactant, application thereof and shampoo containing the thickener, and also provides a method for thickening the amino acid surfactant, which can well solve the problem that the existing amino acid surfactant is difficult to thicken, so that more products which are mild and non-irritant and mainly take the amino acid surfactant as a main surface are developed, especially shampoo products.
The invention provides a thickening agent for an amino acid surfactant, which consists of polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate, wherein the mass ratio of the polyethylene glycol-120 methyl glucoside trioleate to the polyethylene glycol-120 methyl glucoside triisostearate is 1: 1-3.
According to a particular but non-limiting embodiment of the invention, the thickener is used for thickening a system based on at least one amino acid surfactant selected from the group consisting of lauroyl sarcosinate, cocoyl sarcosinate, lauroyl alaninate, cocoyl alaninate, lauroyl glutamate, cocoyl glutamate, lauroyl glycinate, cocoyl glycinate, methyl cocoyl taurate and cocoyl methyl taurate.
According to a particular but non-limiting embodiment of the invention, said thickener is used in transparent formulations.
According to a particular but non-limiting embodiment of the invention, said thickener is used for the production of shampoos which are predominantly based on amino acid surfactants.
The invention also provides a method for thickening amino acid surfactant, which comprises the following steps: polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate are added into a system taking an amino acid surfactant as a main surfactant, wherein the mass ratio of the polyethylene glycol-120 methyl glucoside trioleate to the polyethylene glycol-120 methyl glucoside triisostearate is 1: 1-3.
According to a specific but non-limiting embodiment of the invention, wherein the amino acid surfactant is at least one of lauroyl sarcosinate, cocoyl sarcosinate, lauroyl alaninate, cocoyl alaninate, lauroyl glutamate, cocoyl glutamate, lauroyl glycinate, cocoyl glycinate, methyl cocoyl taurate and cocoyl methyl taurate.
On the other hand, the invention also provides shampoo taking an amino acid surfactant as a main component, which comprises the amino acid surfactant and a mixed thickening agent consisting of polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate, wherein the mass ratio of the polyethylene glycol-120 methyl glucoside trioleate to the polyethylene glycol-120 methyl glucoside triisostearate is 1: 1-3.
According to a particular but non-limiting embodiment of the invention, wherein the mixed thickener is added to the shampoo in an amount of 1% to 6% of the total mass of the shampoo.
According to a specific but non-limiting embodiment of the invention, wherein the amino acid surfactant is at least one of lauroyl sarcosinate, cocoyl sarcosinate, lauroyl alaninate, cocoyl alaninate, lauroyl glutamate, cocoyl glutamate, lauroyl glycinate, cocoyl glycinate, methyl cocoyl taurate and cocoyl methyl taurate.
According to a particular but non-limiting embodiment of the invention, said shampoo is transparent.
The invention has the following beneficial effects:
1. the invention uses polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate to thicken a system taking an amino acid surfactant as a main surfactant, the polyethylene glycol-120 methyl glucoside trioleate and the polyethylene glycol-120 methyl glucoside triisostearate generate strong synergistic effect, an unexpected good thickening effect is obtained, and the problem that the existing amino acid surfactant is difficult to thicken is effectively solved, so that the development of mild and non-irritant products taking the amino acid surfactant as the main surfactant, especially shampoo products, is possible.
2. The mixed thickener of the invention can be used in transparent formulations, so that development of transparent products, especially transparent shampoo products, is realized.
3. The thickening method and the thickening agent are used for developing the shampoo taking the amino acid surfactant as the main surfactant, and the prepared shampoo product is mild, has no stimulation, has good stability and use feeling, and is particularly suitable for preparing transparent shampoo.
Detailed Description
The following specific embodiments are provided to further illustrate the present invention, but the present invention is not limited to only the following embodiments.
The inventor of the patent finds that the polyethylene glycol-120-methyl glucoside trioleate and the polyethylene glycol-120-methyl glucoside triisostearate are jointly used, so that a system taking an amino acid surfactant as a main surfactant can be effectively thickened, the thickening effect is not the simple superposition of the effects when the polyethylene glycol-120-methyl glucoside trioleate and the polyethylene glycol-120-methyl glucoside triisostearate are used independently, but the combination of the polyethylene glycol-120-methyl glucoside trioleate and the polyethylene glycol-120-methyl glucoside triisostearate generates a strong synergistic effect, the viscosity of the system is remarkably and greatly improved, and an unexpected and good thickening effect is achieved.
The invention provides a thickening agent aiming at an amino acid surfactant, which consists of polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate, wherein when the mass ratio of the polyethylene glycol-120 methyl glucoside trioleate to the polyethylene glycol-120 methyl glucoside triisostearate is 1:1-3, an ideal synergistic thickening effect is achieved.
The thickener of the present invention can be used for thickening a system having as a main surfactant at least one amino acid surfactant selected from the group consisting of lauroyl sarcosinate, cocoyl sarcosinate, lauroyl alaninate, cocoyl alaninate, lauroyl glutamate, cocoyl glycinate, methyl cocoyl taurate, cocoyl methyl taurate, and the like. The thickening agent has good thickening effect on various amino acid surfactants and combinations thereof, and has no selective thickening phenomenon with large difference.
The thickener of the invention can be used in transparent formulations, enabling the development of transparent products.
The thickener can be used for producing shampoo products which take amino acid surfactants as main components, in particular transparent shampoo products. The prepared shampoo product is mild and non-irritant, and has good stability and use feeling.
The addition amount of the mixed thickener in the shampoo is 1-6% of the total mass of the shampoo.
The present invention will be further illustrated with reference to the following specific examples, but the present invention is not limited to the following examples.
The experimental procedures used above and in the examples below are conventional unless otherwise specified.
The materials, reagents and the like used above and in the following examples are commercially available unless otherwise specified.
Example 1
Thickening Performance test
Different surfactants and different addition amounts are selected, so that the detersive power, the use feeling and the like of a formula system are influenced to a certain extent, and under the premise of the characteristics of the raw materials, the frequently used amino acid surfactants comprise sodium lauroyl sarcosinate (30 percent of content), sodium cocoyl alanine (30 percent of content), sodium methyl cocoyl taurate (30 percent of content) and the like. Now taking the three amino acid surfactant systems described above as examples, the effect of PEG-120 methyl glucoside trioleate and PEG-120 methyl glucoside triisostearate on system viscosity when added separately and mixed, respectively, was tested. The sodium methyl cocoyl taurate has a certain influence on the transparency, so the addition amount of the sodium methyl cocoyl taurate cannot be too large.
The amino acid surfactant system for testing comprises the following components in parts by mass:
20 parts of sodium lauroyl sarcosinate,
20 parts of cocoyl alanine sodium,
10 parts of sodium methyl cocoyl taurate.
The experimental steps are as follows: adding weighed distilled water into a beaker, adding 20 parts of sodium lauroyl sarcosinate, 20 parts of sodium cocoyl alanine and 10 parts of sodium methyl cocoyl taurate, heating to 80-85 ℃, and dissolving and stirring uniformly. Then, a certain amount of PEG-120-methylglucoside trioleate and PEG-120-methylglucoside triisostearate were added according to the following experiment and dissolved and stirred uniformly. Then, water was added to 100 parts, and the viscosity of the system was measured (25 ℃, 3#, 12 rpm). The addition amounts referred to in the experiments are in parts by mass.
Experiment one:
the addition amount of the polyethylene glycol-120 methyl glucoside trioleate is as follows: 0 part of (A).
The addition amounts of polyethylene glycol-120 methyl glucoside triisostearate are respectively as follows: 1 part, 1.5 parts, 2 parts, 2.5 parts, 4 parts, and 6 parts.
The viscosities obtained were respectively: 291mPa.s, 506mPa.s, 689mPa.s, 909mPa.s, 1691mPa.s, 3210 mPa.s.
Experiment two:
the addition amount of the polyethylene glycol-120-methyl glucoside triisostearate is as follows: 0 part of (A).
The addition amount of the polyethylene glycol-120 methyl glucoside trioleate is respectively as follows: 1 part, 1.5 parts, 2 parts, 2.5 parts, 4 parts, and 6 parts.
The viscosities obtained were respectively: 193mPa.s, 400mPa.s, 500mPa.s, 808mPa.s, 1295mPa.s, 2406 mPa.s.
As can be seen from experiments one and two: polyethylene glycol-120 methyl glucoside triisostearate and polyethylene glycol-120 methyl glucoside trioleate have certain thickening effect when being added independently, and the viscosity can be increased along with the increase of the adding amount; and the thickening effect of PEG-120 methyl glucoside triisostearate is better than that of PEG-120 methyl glucoside trioleate.
Experiment three:
the addition amounts of PEG-120-methylglucoside trioleate and PEG-120-methylglucoside triisostearate are the same, and the total addition amount is as follows: 6 portions of (2) to (3) to (4) to (5).
The viscosities obtained were respectively: 980mPa.s, 1813mPa.s, 2593mPa.s, 3405mPa.s, and 3750 mPa.s.
Combining the first experiment and the second experiment, the third experiment shows that: when PEG-120 methyl glucoside trioleate and PEG-120 methyl glucoside triisostearate are added simultaneously, the obtained viscosity is not only obviously higher than the viscosity when the PEG-120 methyl glucoside trioleate and the PEG-120 methyl glucoside triisostearate are added separately (see that the viscosity of 2 parts, 4 parts and 6 parts in the experiment I and II is compared with the viscosity of 2 parts, 4 parts and 6 parts in the experiment III respectively), but also is obviously higher than the simple numerical value addition of the viscosity when the PEG-120 methyl glucoside trioleate and the PEG-120 methyl glucoside triisostearate are added separately (see that the viscosity obtained by 1 part, 1.5 parts, 2 parts and 2.5 parts in the experiment I and II is compared with the viscosity obtained by 2 parts, 3 parts, 4 parts and 5 parts in the experiment III respectively).
Therefore, the thickening effect of the polyethylene glycol-120-methyl glucoside trioleate and the polyethylene glycol-120-methyl glucoside triisostearate when used simultaneously is not the simple superposition of the effects when the polyethylene glycol-120-methyl glucoside trioleate and the polyethylene glycol-120-methyl glucoside triisostearate are used independently, but has strong synergistic interaction, so that the viscosity of a system is remarkably and greatly improved, and an unexpected and good thickening effect is obtained.
Example 2
Influence of different proportions on thickening effect
Amino acid surfactant systems for testing the viscosity of the system (25 ℃, 3#, 12rpm) were tested by adding polyethylene glycol-120-methylglucoside trioleate and polyethylene glycol-120-methylglucoside triisostearate, respectively, in the same proportions as in example 1, following the experimental procedure of example 1. The addition amounts referred to in the experiments are in parts by mass.
4 parts of polyethylene glycol-120 methyl glucoside trioleate and polyethylene glycol-120 methyl glucoside triisostearate in proportion: and (2): 1 and 2, 1:1- (1): 2, 1: 3, 1: 4.
the viscosities obtained were respectively: 1769mPa.s, 2593mPa.s, 2796mPa.s, 2602mPa.s, 1838 mPa.s.
From the above experiments it can be seen that: the mass ratio of the polyethylene glycol-120-methyl glucoside trioleate to the polyethylene glycol-120-methyl glucoside triisostearate is approximately 1: about 2, the synergistic thickening effect is most desirable. Meanwhile, the viscosity of the mixture is 1295mPa.s and 1691mPa.s when 4 parts of the mixture is independently added in the first experiment and the second experiment, and the mixture ratio is 1:1 to 1: 3, the synergistic thickening effect is ideal, and the system viscosity is obviously improved.
Therefore, in the actual use process, the thickening effect is better by adopting two compounding forms of polyethylene glycol-120-methyl glucoside trioleate and polyethylene glycol-120-methyl glucoside triisostearate; the mass ratio of the two is approximately 1:1 to 1: 3, the viscosity can be set, and simultaneously, less raw materials are used, so that the cost is saved and the influence on the use feeling of the product is reduced.
The above is only a specific application example of the present invention, and the protection scope of the present invention is not limited in any way. All the technical solutions formed by equivalent transformation or equivalent replacement fall within the protection scope of the present invention.
Claims (3)
1. A shampoo taking an amino acid surfactant as a main surfactant comprises the amino acid surfactant and a mixed thickening agent consisting of polyethylene glycol-120-methyl glucoside trioleate and polyethylene glycol-120-methyl glucoside triisostearate, wherein the mass ratio of the polyethylene glycol-120-methyl glucoside trioleate to the polyethylene glycol-120-methyl glucoside triisostearate is 1:1-3, and the shampoo is transparent.
2. The shampoo according to claim 1, wherein the amount of the mixed thickener added to the shampoo is 1% to 6% of the total mass of the shampoo.
3. A shampoo according to claim 1 or 2 wherein the amino acid surfactant is at least one of lauroyl sarcosinate, cocoyl sarcosinate, lauroyl alaninate, cocoyl alaninate, lauroyl glutamate, cocoyl glutamate, lauroyl glycinate, cocoyl glycinate, methyl cocoyl taurate and cocoyl methyl taurate.
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| CN201811099311.2A CN109172409B (en) | 2018-09-20 | 2018-09-20 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
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| CN201811099311.2A CN109172409B (en) | 2018-09-20 | 2018-09-20 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
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| CN109172409B true CN109172409B (en) | 2021-07-27 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104940042A (en) * | 2015-06-18 | 2015-09-30 | 杭州孔凤春化妆品有限公司 | Low-irritation bath product formula composition and preparation method thereof |
| CN106901998A (en) * | 2015-12-22 | 2017-06-30 | 广州市浪奇实业股份有限公司 | A kind of bath foam |
| CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20150037393A1 (en) * | 2013-07-31 | 2015-02-05 | Peter Robert Millman | Adhesive patches for use in sunless tanning |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104940042A (en) * | 2015-06-18 | 2015-09-30 | 杭州孔凤春化妆品有限公司 | Low-irritation bath product formula composition and preparation method thereof |
| CN106901998A (en) * | 2015-12-22 | 2017-06-30 | 广州市浪奇实业股份有限公司 | A kind of bath foam |
| CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 丹慕妮尔净彻润颜洁面乳;国产非特殊用途化妆品备案信息服务平台;《ftba.nmpa.gov.cn:8181/ftban/itownet/hzp_ba/fw/pz.jsp?processid=201808151359244aor0&nid=201808151359244aor0》;20180823;第1-2页 * |
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