CN109172409A - It is a kind of for the thickener of amino acid surfactant and its application and shampoo - Google Patents
It is a kind of for the thickener of amino acid surfactant and its application and shampoo Download PDFInfo
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- CN109172409A CN109172409A CN201811099311.2A CN201811099311A CN109172409A CN 109172409 A CN109172409 A CN 109172409A CN 201811099311 A CN201811099311 A CN 201811099311A CN 109172409 A CN109172409 A CN 109172409A
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- amino acid
- polyethylene glycol
- methyl
- cocounut oil
- acid surfactant
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
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- Cosmetics (AREA)
Abstract
The present invention relates to a kind of thickeners for amino acid surfactant, are made of -120 methyl glucosamine trioleate of polyethylene glycol and three isostearate of -120 methyl glucosamine of polyethylene glycol, and the mass ratio of the two is 1:1-3.It is main table system living that the mixing thickener, which is used to thicken with amino acid surfactant, thickening effect is ideal, efficiently solve the problems, such as that current amino acid surfactant thickening is difficult, make to develop non-stimulated product live with the main table of amino acid surfactant, mild, especially shampoo product is possibly realized, and brings better stability for product and using feeling.The mixing thickener can be used in clear formula, develop opaque products.
Description
Technical field
The present invention relates to a kind of thickener for amino acid surfactant and its applications and hair washing containing the thickener
Water, the invention further relates to a kind of methods for thickening amino acid surfactant, belong to colloid and surface chemistry domain and makeup
Product field.
Background technique
Personal cleansing product is always a part indispensable in living, and can not only be brought to people clean, comfortable
Feeling, confidence can also be brought to people.As the improvement of people's living standards, people during personal cleanliness increasingly
The quality for focusing on product is increasingly liked human temperature and non-stimulated product by people.
The surfactant traditional relative to laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate etc., amino acid surface
Activating agent is then more mild, smaller to the stimulation of skin and scalp, and more comfortable, more healthy clean body can be brought to people
It tests.Although amino acid surfactant thickens in the other products such as mildy wash and is relatively easy to realize, shampoo,
Thickening in especially transparent shampoo is technical problem all the time, it is common to use traditional thickener to its substantially without
Thickening effect but has very big negative shadow to the use feeling of product although the thickeners such as card wave, cellulose can be thickened
It rings, and opaque products can not be made into.And sticky character be it is good using feel and ease of use can not or
Scarce.
Therefore a kind of can make with the thickener of the main table of amino acid surfactant system retrogradation living as one kind is developed
It needs.
Summary of the invention
The object of the present invention is to provide a kind of thickener for amino acid surfactant and its application and contain the thickening
The shampoo of agent, the present invention also provides a kind of methods for thickening amino acid surfactant, can be well solved current amino
The problem of acid surfaces activating agent difficulty thickens, to make more with the main table work of amino acid surfactant, mild non-stimulated
Product, especially shampoo product are developed.
The present invention provides a kind of thickeners for amino acid surfactant, by -120 methyl glucosamine of polyethylene glycol
Trioleate and three isostearate of -120 methyl glucosamine of polyethylene glycol form, wherein -120 methyl glucosamine three of polyethylene glycol
The mass ratio of oleate and three isostearate of -120 methyl glucosamine of polyethylene glycol is 1:1-3.
One according to the present invention specific but non-limiting embodiment, the thickener is for thickening with lauroyl
Sarcosinate, cocoyl sarcosine salt, lauroyl alanine salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl paddy
Propylhomoserin salt, lauroyl glycinate, cocounut oil acyl glycinate, methyl cocoyl taurate and cocounut oil acyl methyl taurine ox
At least one of sulfonate amino acid surfactant is main table system living.
One according to the present invention specific but non-limiting embodiment, the thickener is in clear formula.
One according to the present invention specific but non-limiting embodiment, the thickener is for producing with amino acid
Surfactant is main table shampoo living.
The present invention also provides a kind of methods for thickening amino acid surfactant, comprising: with amino acid surface activity
Agent is that -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine of polyethylene glycol is added in main table system living
Three isostearates, wherein -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine three of polyethylene glycol are different hard
The mass ratio of resin acid ester is 1:1-3.
One according to the present invention specific but non-limiting embodiment, wherein amino acid surfactant is lauroyl
Sarcosinate, cocoyl sarcosine salt, lauroyl alanine salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl paddy
Propylhomoserin salt, lauroyl glycinate, cocounut oil acyl glycinate, methyl cocoyl taurate and cocounut oil acyl methyl taurine ox
At least one of sulfonate.
On the other hand, the present invention also provides an a kind of shampoos living for main table with amino acid surfactant, including
Amino acid surfactant and by -120 methyl glucosamine three of -120 methyl glucosamine trioleate of polyethylene glycol and polyethylene glycol
The mixing thickener of isostearate composition, wherein -120 methyl glucosamine trioleate of polyethylene glycol and -120 first of polyethylene glycol
The mass ratio of three isostearate of base glucoside is 1:1-3.
One according to the present invention specific but non-limiting embodiment, wherein mixing thickener adding in shampoo
Amount is the 1%-6% of shampoo gross mass.
One according to the present invention specific but non-limiting embodiment, wherein amino acid surfactant is lauroyl
Sarcosinate, cocoyl sarcosine salt, lauroyl alanine salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl paddy
Propylhomoserin salt, lauroyl glycinate, cocounut oil acyl glycinate, methyl cocoyl taurate and cocounut oil acyl methyl taurine ox
At least one of sulfonate.
One according to the present invention specific but non-limiting embodiment, the shampoo are transparent.
The beneficial effects are mainly reflected as follows:
1. -120 methyl glucosamine trioleate of polyethylene glycol of the invention and -120 methyl glucosamine three of polyethylene glycol are different
For stearate to being that main table system living thickens with amino acid surfactant, the two produces very strong synergistic work
With, unexpected good thickening effect is achieved, efficiently solves the problems, such as that current amino acid surfactant thickening is difficult,
To make to develop non-stimulated product live with the main table of amino acid surfactant, mild, especially shampoo product becomes
It may.
2. mixing thickener of the invention can be used in clear formula, make to develop opaque products, especially transparent shampoo
Product is achieved.
3. it is the hair washing living of main table that method for thickening and thickener of the invention, which are used to develop with amino acid surfactant,
Water, shampoo product obtained is mildly non-stimulated, and stability and use are felt good, and is especially suitable for preparing transparent hair washing
Water.
Specific embodiment
Provided hereinafter specific embodiments to further illustrate the present invention, but the present invention is not limited only to implementation below
Mode.
The inventor of this patent has found in R&D process, -120 methyl glucosamine trioleate of polyethylene glycol and poly- second two
Three isostearate of -120 methyl glucosamine of alcohol is used in combination, and can effectively thicken with amino acid surfactant is that main table is living
System, thickening effect is not the simple superposition of effect when the two is used alone, but the two is used in combination and produces very by force
Synergistic function, so that system viscosity is had greatly improving for highly significant, achieve unexpected, good thickening effect
Fruit.
The present invention provides a kind of thickeners for amino acid surfactant, by -120 methyl glucosamine of polyethylene glycol
Trioleate and three isostearate of -120 methyl glucosamine of polyethylene glycol form, wherein -120 methyl glucosamine three of polyethylene glycol
When the mass ratio of oleate and three isostearate of -120 methyl glucosamine of polyethylene glycol is 1:1-3, there is ideal collaboration to increase
Thick effect.
Thickener of the invention can be used for thickening with Hamposyl L salt, cocoyl sarcosine salt, the third ammonia of lauroyl
Hydrochlorate, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl glutamate, lauroyl glycinate, cocounut oil acyl glycine
At least one of salt, methyl cocoyl taurate and cocounut oil acyl methyl taurine taurate etc. amino acid surface activity
Agent is main table system living.Thickener of the invention all has good thickening to various amino acid surfactants and combinations thereof
Effect, and have no the selective thickening behavior of larger difference.
Thickener of the invention can be used in clear formula, can develop opaque products.
It is main table shampoo product living that thickener of the invention, which can be used for producing with amino acid surfactant, especially
It is the transparent shampoo product of production.Shampoo product obtained is mildly non-stimulated, and stability and use are felt good.
Dosage of the mixing thickener in shampoo is the 1%-6% of shampoo gross mass.
The present invention is further elaborated combined with specific embodiments below, but the present invention is not limited to following embodiments.
Above and experimental method used in following embodiments is conventional method unless otherwise specified.
Above and the materials, reagents and the like used in the following examples, is commercially available unless otherwise specified.
Embodiment 1
Thickening properties test
Different surfactants and different dosages are selected, to the dirt-removing power of formula system, using feeling etc.
It has a certain impact, under the premise of raw material self-characteristic, the amino acid surfactant being commonly used has Hamposyl L
Sodium (30% content), cocounut oil acyl Sodium L-alaninate (30% content), sodium methyl cocoyl taurate (30% content) etc..More than now
For stating three kinds of amino acid surfactant systems, -120 methyl glucosamine trioleate of polyethylene glycol and polyethylene glycol-are tested
120 methyl glucosamine, three isostearate is added separately to and mixes influence when being added to system viscosity.Because of methyl cocoyl
Acyl taurines sodium has a certain impact to transparency, thus can not dosage it is excessive.
The amino acid surfactant system of test, component and its mass fraction:
20 parts of sodium lauroyl sarcosine,
20 parts of cocounut oil acyl Sodium L-alaninate,
10 parts of sodium methyl cocoyl taurate.
Experimental procedure: load weighted distilled water is added in beaker, adds 20 parts of sodium lauroyl sarcosine, and 20 parts
Cocounut oil acyl Sodium L-alaninate, 10 parts of sodium methyl cocoyl taurate is heated to 80-85 DEG C, and dissolution stirs evenly.According still further to
A certain amount of -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine three of polyethylene glycol is added in following experiments
Isostearate, dissolution stir evenly.Then moisturizing is to 100 parts, the viscosity (25 DEG C, 3#, 12rpm) of measurement system.In experiment
Related dosage is mass fraction.
Experiment one:
The dosage of -120 methyl glucosamine trioleate of polyethylene glycol are as follows: 0 part.
The dosage of three isostearate of -120 methyl glucosamine of polyethylene glycol be respectively as follows: 1. 1 part 2. 1.5 parts 3. 2 parts 4.
2.5 parts of 5. 4 parts 6. 6 parts.
Resulting viscosity is respectively as follows: 1. 291mPa.s, and 2. 3. 4. 909mPa.s is 5. by 689mPa.s by 506mPa.s
1691mPa.s ⑥3210mPa.s。
Experiment two:
The dosage of three isostearate of -120 methyl glucosamine of polyethylene glycol are as follows: 0 part.
The dosage of -120 methyl glucosamine trioleate of polyethylene glycol is respectively as follows: 1. 1 part of 2. 1.5 parts 3. 2 part 4. 2.5
Part 5. 4 parts 6. 6 parts.
Resulting viscosity is respectively as follows: 1. 193mPa.s, and 2. 3. 4. 808mPa.s is 5. by 500mPa.s by 400mPa.s
1295mPa.s ⑥2406mPa.s。
From experiment one and two: three isostearate of -120 methyl glucosamine of polyethylene glycol, -120 methyl of polyethylene glycol
Glucoside trioleate is individually added into the certain thickening effect of Shi Junyou, and with the increase of dosage, viscosity also can be with increase；
And the thickening effect of three isostearate of -120 methyl glucosamine of polyethylene glycol is relative to -120 methyl glucosamine three of polyethylene glycol
Oleate is preferable.
Experiment three:
Three isostearate of -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine of polyethylene glycol
Dosage is identical, adds up to dosage are as follows: 1. 2 parts of 2. 3 parts of 3. 4 parts of 4. 5 parts 5. 6 parts.
Resulting viscosity is respectively as follows: 1. 980mPa.s, and 2. 3. 4. 3405mPa.s is 5. by 2593mPa.s by 1813mPa.s
3750mPa.s。
Binding experiment one, two, from experiment three: -120 methyl glucosamine trioleate of polyethylene glycol and polyethylene glycol -
When 120 methyl glucosamine, three isostearate is added simultaneously, resulting viscosity both is not only apparently higher than when being added separately to
Viscosity (see 2 parts in experiment one and two, 4 parts, 6 parts of viscosity respectively with 2 parts in experiment three, 4 parts, 6 parts of viscosity carries out pair
Than), and the simple numerical value for both being significantly higher than gained viscosity when being individually added into be added (see 1 part in experiment one and two, 1.5 parts,
2 parts, 2.5 parts of resulting viscosity be added, respectively with 2 parts in experiment three, 3 parts, 4 parts, 5 parts of resulting viscosity compare).
It can be seen that -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine three of polyethylene glycol are different hard
Thickening effect when resin acid ester uses simultaneously is not the simple superposition of effect when the two is used alone, but has very strong collaboration
Synergistic effect makes system viscosity have greatly improving for highly significant, achieves unexpected, good thickening effect.
Embodiment 2
Influence of the different ratio to thickening effect
The amino acid surfactant system of test is with embodiment 1, according to the experimental procedure of embodiment 1, respectively by such as
- 120 methyl glucosamine trioleate of polyethylene glycol and three isostearate of -120 methyl glucosamine of polyethylene glycol is added in lower ratio,
The viscosity (25 DEG C, 3#, 12rpm) of test system.Dosage involved in experiment is mass fraction.
- 120 methyl glucosamine trioleate of polyethylene glycol and three isostearate of -120 methyl glucosamine of polyethylene glycol add
Amount totally 4 parts, ratio are respectively as follows: 1. 2:1 2. 1:1 3. 1:2 4. 1:3 5. 1:4.
Gained viscosity is respectively as follows: 1. 1769mPa.s, and 2. 3. 4. 2602mPa.s is 5. by 2796mPa.s by 2593mPa.s
1838mPa.s。
From above-mentioned experiment: -120 methyl glucosamine trioleate of polyethylene glycol and -120 methyl glucosamine of polyethylene glycol
For the quality proportioning of three isostearates probably in 1:2 or so, the thickening effect of collaboration is ideal.In combination with experiment one,
Viscosity when being individually added into 4 parts both in two is respectively 1295mPa.s and 1691mPa.s, it is seen that in ratio is 1:1 to 1:
Ideal synergistic thickening effect is all had when between 3, system viscosity is obviously improved.
Therefore, in actual use, using -120 methyl glucosamine trioleate of polyethylene glycol and polyethylene glycol -
The form of two kinds of 120 methyl glucosamine, three isostearate compoundings, thickening effect are more preferable；The quality proportioning of the two is probably in 1:1
To best between 1:3, can while reaching set viscosity, using less raw material, not only save the cost again reduction to product
The influence of use feeling.
The above is only specific application examples of the invention, are not limited in any way to protection scope of the present invention.All uses
Equivalent transformation or equivalent replacement and the technical solution formed, all fall within rights protection scope of the present invention.
Claims (10)
1. a kind of thickener for amino acid surfactant, by -120 methyl glucosamine trioleate of polyethylene glycol and poly- second
Three isostearate of -120 methyl glucosamine of glycol forms, wherein -120 methyl glucosamine trioleate of polyethylene glycol and poly- second two
The mass ratio of three isostearate of -120 methyl glucosamine of alcohol is 1:1-3.
2. thickener as described in claim 1 is for thickening with Hamposyl L salt, cocoyl sarcosine salt, lauroyl third
Propylhomoserin salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl glutamate, lauroyl glycinate, the sweet ammonia of cocounut oil acyl
At least one of hydrochlorate, methyl cocoyl taurate and cocounut oil acyl methyl taurine taurate amino acid surface activity
Agent is main table system living.
3. thickener as described in claim 1 is in clear formula.
4. it is main table shampoo living that thickener as described in claim 1, which is used to produce with amino acid surfactant,.
5. a kind of method for thickening amino acid surfactant, comprising: be main table system living with amino acid surfactant
Middle -120 methyl glucosamine trioleate of addition polyethylene glycol and three isostearate of -120 methyl glucosamine of polyethylene glycol, wherein
- 120 methyl glucosamine trioleate of polyethylene glycol and the mass ratio of three isostearate of -120 methyl glucosamine of polyethylene glycol are
1:1-3。
6. method according to claim 5, wherein amino acid surfactant is Hamposyl L salt, cocoyl sarcosine
Salt, lauroyl alanine salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl glutamate, lauroyl glycine
At least one of salt, cocounut oil acyl glycinate, methyl cocoyl taurate and cocounut oil acyl methyl taurine taurate.
It with amino acid surfactant is main table shampoo living 7. a kind of, including amino acid surfactant and by poly- second two
The mixing thickener of -120 methyl glucosamine trioleate of alcohol and three isostearate of -120 methyl glucosamine of polyethylene glycol composition,
The wherein quality of -120 methyl glucosamine trioleate of polyethylene glycol and three isostearate of -120 methyl glucosamine of polyethylene glycol
Than for 1:1-3.
8. shampoo according to claim 7, wherein dosage of the mixing thickener in shampoo is shampoo gross mass
1%-6%.
9. wherein amino acid surfactant is Hamposyl L salt, cocounut oil acyl flesh according to the shampoo of claim 7 or 8
Propylhomoserin salt, lauroyl alanine salt, cocounut oil acyl alanine salt, lauroyl glutamate, cocounut oil acyl glutamate, the sweet ammonia of lauroyl
At least one in hydrochlorate, cocounut oil acyl glycinate, methyl cocoyl taurate and cocounut oil acyl methyl taurine taurate
Kind.
10. being transparent according to the shampoo of claim 7 or 8.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811099311.2A CN109172409B (en) | 2018-09-20 | 2018-09-20 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811099311.2A CN109172409B (en) | 2018-09-20 | 2018-09-20 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
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| CN109172409A true CN109172409A (en) | 2019-01-11 |
| CN109172409B CN109172409B (en) | 2021-07-27 |
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|---|---|---|---|---|
| US20150037393A1 (en) * | 2013-07-31 | 2015-02-05 | Peter Robert Millman | Adhesive patches for use in sunless tanning |
| CN104940042A (en) * | 2015-06-18 | 2015-09-30 | 杭州孔凤春化妆品有限公司 | Low-irritation bath product formula composition and preparation method thereof |
| CN106901998A (en) * | 2015-12-22 | 2017-06-30 | 广州市浪奇实业股份有限公司 | A kind of bath foam |
| CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
-
2018
- 2018-09-20 CN CN201811099311.2A patent/CN109172409B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150037393A1 (en) * | 2013-07-31 | 2015-02-05 | Peter Robert Millman | Adhesive patches for use in sunless tanning |
| CN104940042A (en) * | 2015-06-18 | 2015-09-30 | 杭州孔凤春化妆品有限公司 | Low-irritation bath product formula composition and preparation method thereof |
| CN106901998A (en) * | 2015-12-22 | 2017-06-30 | 广州市浪奇实业股份有限公司 | A kind of bath foam |
| CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 国产非特殊用途化妆品备案信息服务平台: "丹慕妮尔净彻润颜洁面乳", 《FTBA.NMPA.GOV.CN:8181/FTBAN/ITOWNET/HZP_BA/FW/PZ.JSP?PROCESSID=201808151359244AOR0&NID=201808151359244AOR0》 * |
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