CN109908061A - A kind of fizzy dandruff control shampoo containing and preparation method thereof - Google Patents

Abstract

The invention discloses a kind of fizzy dandruff control shampoo containings; used amino acid surfactant is the compound of sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium; mass ratio is 1:3-5:10-20; it is added to pomegranate rind extract simultaneously, unexpected technical effect is achieved in terms of foaming abundancy degree；The pomegranate rind extract that specific extracting method obtains makes shampoo of the present invention have excellent anti-dandruff effect.

Description

A kind of fizzy dandruff control shampoo containing and preparation method thereof

Technical field

The present invention relates to daily cosmetics field, it is specifically related to a kind of fizzy dandruff control shampoo containing and its preparation side Method.

Background technique

Shampoo is for cleaning the grease of human secretory being attached on scalp and hair, sweat mixed with dirt, falls off on scalp thin Born of the same parents and external dust, microorganism and bad smell etc. keep scalp and hair cleaning and hair beautiful.Shampoo also known as perfume (or spice) Wave is a kind of hair washing makeup articles for washing, belongs to personal care market and develops earliest and one of most fast product.Shampoo Development have very long history, before the 1930s people using soap clean hair, later using surfactant as base-material Liquid shampoo comes out, and the hard water resistance property of product and mildness are greatly improved.It is with the improvement of living standards and scientific and technical Fast development, people are also higher and higher to the security requirement of the surfactant of shampoo.

Shampoo is broadly divided into five major class, is respectively as follows: (1) transparent shampoo, occurs earliest, formula is simple, mainly For cleaning action.(2) shampoo with pearl-radiation, shampoo with pearl-radiation add pearling agent, the product pair on the basis of transparent shampoo Transparency does not require, and adds pearling agent at present there are two types of mode, one is directly uses pearling agent, second is that using pearlite slurry.(3) Shampoo with treatment, this product are most popular a kind of shampoo at present, and familiar Two-in-one shampoo is exactly wherein one Kind, it combines hair washing and hair care is integrated, it is primary to complete.Shampoo with treatment is on the basis of common shampoo plus various tune Agent is managed, to reach the effect of desired.(4) dandruff control shampoo containing, dandruff be as caused by scalp functional disturbance, such as bacteria breed, Seborrheic dermatitis, spongiocyte paraplasm etc..And dandruff excessively can breed more bacterial fungus, cause scalp itch Etc. symptoms.Therefore the active matter that some restraining and sterilizing bacteria effects are often added in shampoo effectively to control dandruff.(5) sun-proof to wash Shampoo, after hair is exposed to the radiation of ultraviolet radiation for a long time, can generate some photochemical reactions, to the physics and chemistry of hair Performance all has a great impact, and therefore, some sun-screening agents is often added in shampoo, suitably to prevent ultraviolet light to the damage of hair Wound.

Amino acid surfactant is the mild surfactant of a protein species, has low irritant, hypotoxicity, soft With property, good biodegradability properties and to preferable compatibility of human body etc., every demand of consumer is met, people is increasingly caused Attention.At home, to the research starting of amino acid type surfactant than later and relatively backward, amino acid pattern surface is living Property agent when being applied in cleaning class product, often asked in the presence of difficult can not even thicken of thickening so as to cause be difficult to apply Topic.Therefore, utility ratio of the amino acid type surfactant at home in hair product is not also very high.Currently, all big enterprises are logical It crosses and adds various high molecular polymer type thickeners to solve, but make the foam characteristic quilt of amino acid surfactant Inhibit, to limit application of the amino acid surfactant in hair product.

Although currently there are the formula diversified shampoo product of type, the performance difference of different product Also larger, while the foaming properties of many shampoos need to be further increased.For example, prior art discloses entitled The Chinese patent application of " a kind of mild amino acid shampoo and preparation method thereof ", Publication No. CN 106176270A, the hair The amino acid shampoo of bright offer includes following component: aliphatic alcohol polyethenoxy amine, coco betaine, alkyl glycosides, amino Acid surfaces activating agent, water-soluble grease, Polyquaternium-10, coconut oleoyl amine monoethanolamine, PEG-120 methyl dioleate, Benzoic acid, salicylic acid, glycerol, essence and water.Amino acid shampoo provided by the invention has good blistering, foam stability, fits Degree cleaning washability, moisturizing effect are good；Hair after washing is bright, submissive, flexible, cardability is good；It is milder to skin, It is nontoxic non-stimulated and comfortable soft and moist.But the effect of shampoo, is single, is not obvious in terms of anti-dandruff effect, has one's hair wash simultaneously The type of amino acid surfactant in the foaming properties and raw material of water and the relationship of dosage are very big.Therefore, one kind is developed The shampoo product that anti-dandruff effect is good, spumescence is good has good market prospects.

Summary of the invention

In view of the deficienciess of the prior art, the temperature that the object of the present invention is to provide a kind of anti-dandruff effects is good, spumescence is good And shampoo.The present invention is realized particular by following technical scheme:

A kind of fizzy dandruff control shampoo containing, is made of the raw material of following weight percent: dodecyl ether sulfate ammonium 1~ 3%, coco betaine 1~4%, coco alkyl glucoside 1~5%, amino acid surfactant 2~10%, granatum Extract 1~2%, PEG-7 olive grease 1~2%, Polyquaternium-10 0.1~0.5%, coconut oleoyl amine monoethanolamine 0.2~ 1%, PEG-120 methyl dioleate 0.2~1%, benzoic acid 0.01~0.05%, salicylic acid 0.01~0.05%, sweet Oil 1~5%, essence 0.3~0.8%, surplus are water；The amino acid surfactant is sodium N-lauroyl sarcosinate, the moon The compound of osmanthus acyl sodium glutamate and myristoyl propylhomoserin sodium, mass ratio 1:3-5:10-20.

Preferably, a kind of mild amino acid shampoo, is made of the raw material of following weight percent: dodecyl alcohol ether Ammonium sulfate 2%, coco betaine 3%, coco alkyl glucoside 2%, amino acid surfactant 5%, granatum extract Object 1%, PEG-7 olive grease 2%, Polyquaternium-10 0.25%, coconut oleoyl amine monoethanolamine 0.5%, PEG-120 methyl Portugal Sugared dioleate 0.5%, benzoic acid 0.03%, salicylic acid 0.03%, glycerol 3%, essence 0.5%, surplus are water；The ammonia Base acid surfaces activating agent is the compound of sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium, matter Amount is than being 1:5:20.

Preferably, the pomegranate rind extract preparation method the following steps are included:

(1) granatum crushed material is weighed, is 1:30 by solid-to-liquid ratio g/mL, 75% ethanol solution of volumetric concentration is added, ultrasonic wave is auxiliary Extraction 50 minutes, filtering are helped, filter residue repeats to extract 1 time, and filtrate merges, and is concentrated under reduced pressure；

(2) concentrate is extracted twice with isometric ethyl acetate, and extract liquor merges, recycling ethyl acetate to half volume, after with Isometric 4% sodium hydroxide solution of mass concentration extraction；

(3) extract liquor is added the gelatin solution that mass concentration is 5%, stood overnight, filtered with dilute hydrochloric acid tune pH value to 4；It collects Precipitating filters out insoluble matter with the dissolution of 60% acetone soln, and filtrate recycles acetone；

(4) after filtrate recycling acetone, it is splined on the polyamide chromatographic column pre-processed, successively with the volume of 3-6 times of column volume Concentration 20%, 40%, 60% and anhydrous ethanol elution, and anhydrous ethanol elution liquid is collected, it is concentrated under reduced pressure, freeze-drying obtains stone Pomegranate bark extract.

A kind of preparation method of fizzy dandruff control shampoo containing of the present invention, which comprises the following steps:

(1) it adds water in reaction cylinder, dodecyl ether sulfate ammonium is added, is heated to 75~80 DEG C while stirring, completely Dissolution, obtains solution A；

(2) coco betaine and coco alkyl glucoside are added in Xiang Shangshu solution A, stirs evenly, is cooled to 70~75 DEG C, it is completely dissolved, obtains solution B；

(3) amino acid surfactant, pomegranate rind extract and Polyquaternium-10 are added in Xiang Shangshu solution B, stirs evenly, 55~65 DEG C are cooled to, glycerol is added, is stirred evenly, is completely dissolved, solution C is obtained；

(4) above-mentioned solution C is cooled to 35~45 DEG C, PEG-7 olive grease, benzoic acid, salicylic acid and essence is added, finally plus Enter coconut oleoyl amine monoethanolamine and PEG-120 methyl dioleate, be uniformly mixed, discharging to get.

Compared with prior art, the beneficial effect of cosmetics of the present invention is: (1) amino acid used by shampoo of the present invention Surfactant is the compound of sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium, mass ratio For 1:3-5:10-20, while it being added to pomegranate rind extract, unexpected technology is achieved in terms of foaming abundancy degree Effect；(2) pomegranate rind extract that specific extracting method obtains makes shampoo of the present invention have excellent anti-dandruff effect.

Specific embodiment

The present invention is described in further detail below with reference to embodiment.

Embodiment 1:

A kind of fizzy dandruff control shampoo containing, is made of the raw material of following weight percent: dodecyl ether sulfate ammonium 2%, coco betaine 3%, coco alkyl glucoside 2%, amino acid surfactant 5%, pomegranate rind extract 1%, PEG-7 olive grease 2%, Polyquaternium-10 0.25%, coconut oleoyl amine monoethanolamine 0.5%, two oil of PEG-120 methyl Acid esters 0.5%, benzoic acid 0.03%, salicylic acid 0.03%, glycerol 3%, essence 0.5%, surplus are water；The amino acid table Face activating agent is the compound of sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium, and mass ratio is 1:5:20.

The preparation method of the pomegranate rind extract, comprising the following steps:

(1) granatum crushed material is weighed, is 1:30 by solid-to-liquid ratio g/mL, 75% ethanol solution of volumetric concentration is added, ultrasonic wave is auxiliary Extraction 50 minutes, filtering are helped, filter residue repeats to extract 1 time, and filtrate merges, and is concentrated under reduced pressure；

(2) concentrate is extracted twice with isometric ethyl acetate, and extract liquor merges, recycling ethyl acetate to half volume, after with Isometric 4% sodium hydroxide solution of mass concentration extraction；

(3) extract liquor is added the gelatin solution that mass concentration is 5%, stood overnight, filtered with dilute hydrochloric acid tune pH value to 4；It collects Precipitating filters out insoluble matter with the dissolution of 60% acetone soln, and filtrate recycles acetone；

(4) after filtrate recycling acetone, it is splined on the polyamide chromatographic column pre-processed, it is successively dense with the volume of 5 times of column volumes Degree 20%, 40%, 60% and anhydrous ethanol elution, and anhydrous ethanol elution liquid is collected, it is concentrated under reduced pressure, freeze-drying obtains pomegranate Bark extract.

The preparation method of the shampoo, comprising the following steps:

(1) it adds water in reaction cylinder, dodecyl ether sulfate ammonium is added, is heated to 80 DEG C while stirring, is completely dissolved, Obtain solution A；

(2) coco betaine and coco alkyl glucoside are added in Xiang Shangshu solution A, stirs evenly, is cooled to 75 DEG C, it is complete Fully dissolved obtains solution B；

(3) amino acid surfactant, pomegranate rind extract and Polyquaternium-10 are added in Xiang Shangshu solution B, stirs evenly, 55 DEG C are cooled to, glycerol is added, is stirred evenly, is completely dissolved, solution C is obtained；

(4) above-mentioned solution C is cooled to 45 DEG C, PEG-7 olive grease, benzoic acid, salicylic acid and essence is added, is eventually adding coconut palm Oleamide monoethanolamine and PEG-120 methyl dioleate, be uniformly mixed, discharging to get.

Embodiment 2:

A kind of fizzy dandruff control shampoo containing, is made of the raw material of following weight percent: dodecyl ether sulfate ammonium 1%, coco betaine 4%, coco alkyl glucoside 1%, amino acid surfactant 10%, pomegranate rind extract 1%, PEG-7 olive grease 2%, Polyquaternium-10 0.1%, coconut oleoyl amine monoethanolamine 1%, two oleic acid of PEG-120 methyl Ester 0.2%, benzoic acid 0.05%, salicylic acid 0.01%, glycerol 5%, essence 0.3%, surplus are water；The amino acid surface Activating agent be sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium compound, mass ratio 1: 3:20.

The preparation method is the same as that of Example 1 for the preparation method of the pomegranate rind extract, shampoo.

Embodiment 3:

A kind of fizzy dandruff control shampoo containing, is made of the raw material of following weight percent: dodecyl ether sulfate ammonium 3%, coco betaine 1%, coco alkyl glucoside 5%, amino acid surfactant 2%, pomegranate rind extract 2%, PEG-7 olive grease 1%, Polyquaternium-10 0.5%, coconut oleoyl amine monoethanolamine 0.2%, two oil of PEG-120 methyl Acid esters 1%, benzoic acid 0.01%, salicylic acid 0.05%, glycerol 1%, essence 0.8%, surplus are water；The amino acid surface Activating agent be sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium compound, mass ratio 1: 5:10.

The preparation method is the same as that of Example 1 for the preparation method of the pomegranate rind extract, shampoo.

Comparative example 1:

A kind of shampoo, for raw material components compared with Example 1 unique the difference lies in that being free of pomegranate rind extract, other are same Embodiment 1.

Comparative example 2:

A kind of shampoo, raw material components compared with Example 1 unique the difference lies in that in the amino acid surfactant Sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium mass ratio be 10:3:1, other are the same as real Apply example 1.

Comparative example 3:

A kind of shampoo, raw material components compared with Example 1 unique the difference lies in that in the amino acid surfactant Sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium mass ratio be 1:1:1, other are the same as implementing Example 1.

Comparative example 4:

A kind of sunscreen spray, raw material components compared with Example 1 unique the difference lies in that the pomegranate rind extract preparation 40% ethanol eluate is collected in method and step (4), reduced pressure, is freeze-dried, is obtained pomegranate rind extract, other same embodiments 1。

One, shampoo initial foam high measure

The side according to as defined in " 6.2.6 foam (shampoo) " in GB13173-2008 " surfactant detergent test method " Method, the initial foam height of shampoo prepared by testing example 1-3, comparative example 1-4, test result are shown in Table 1.

Table 1

	Embodiment 1	Embodiment 2	Embodiment 3	Comparative example 1	Comparative example 2	Comparative example 3	Comparative example 4
								Initial foam height/mm	158	151	143	127	118	139	135

From test result as can be seen that the shampoo of 1-3 of the embodiment of the present invention has excellent initial foam height, wherein implementing Example 1 is optimal technical solution.By embodiment 1, the experimental test data of comparative example 1-4 it can be concluded that the present invention is by the moon Three kinds of osmanthus sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium raw materials obtain after compounding in specific proportions Amino acid surfactant adds pomegranate rind extract, and unexpected technology effect is achieved in terms of foaming abundancy degree Fruit.Meanwhile pomegranate rind extract must be obtained by specific preparation method, could finally obtain satisfactory abundant bubble Foam.

Two, anti-dandruff effect test

80 dandruff patients are chosen, " ten grades of point systems of tackness dandruff " is used to score every patient, 80 are suffered from Person is divided into 4 groups according to grading system, every group of 20 people, so that the dandruff severity of every group of patient does not have conspicuousness poor It is different, it is comparable.The shampoo that test group 1-4 uses embodiment 1-3, comparative example 4 to prepare respectively, every morning use one It is secondary, it is used continuously 7 days, does not wash hair within the 8-9 days, the dandruff situation of the 10th day observation in afternoon user has with complete treatment Efficiency (there is no the percentages that dandruff number accounts for this group of total number of persons after use) is assessed, and test result see the table below 2.

Table 2

	Embodiment 1	Embodiment 2	Embodiment 3	Comparative example 4
					Complete treated effect %	90%	85%	85%	45%

From test result it may be concluded that the shampoo of 1-3 of the embodiment of the present invention has excellent anti-dandruff effect.Comparative example 4 Shampoo used by pomegranate rind extract preparation method be different from embodiment 1-3, cause anti-dandruff effect to substantially reduce.

Above-described embodiment is only currently preferred case study on implementation, cannot limit present invention model claimed with this Enclose, any unsubstantiality that those skilled in the art is done on the basis of the present invention and replacement belong to the present invention claims The range of protection.

Claims (4)

1. a kind of fizzy dandruff control shampoo containing, which is characterized in that be made of the raw material of following weight percent: dodecyl Ether sulfate ammonium 1~3%, coco betaine 1~4%, coco alkyl glucoside 1~5%, amino acid surfactant 2 ~10%, pomegranate rind extract 1~2%, PEG-7 olive grease 1~2%, Polyquaternium-10 0.1~0.5%, coconut oleoyl amine Monoethanolamine 0.2~1%, PEG-120 methyl dioleate 0.2~1%, benzoic acid 0.01~0.05%, salicylic acid 0.01~0.05%, glycerol 1~5%, essence 0.3~0.8%, surplus are water；The amino acid surfactant is laurel The compound of sarcosinate, sodium lauroyl glutamate and myristoyl propylhomoserin sodium, mass ratio 1:3-5:10-20.

2. a kind of fizzy dandruff control shampoo containing according to claim 1, which is characterized in that by following weight percent Raw material be made: dodecyl ether sulfate ammonium 2%, coco betaine 3%, coco alkyl glucoside 2%, amino acid table Face activating agent 5%, pomegranate rind extract 1%, PEG-7 olive grease 2%, Polyquaternium-10 0.25%, coconut oleoyl amine list second Hydramine 0.5%, PEG-120 methyl dioleate 0.5%, benzoic acid 0.03%, salicylic acid 0.03%, glycerol 3%, essence 0.5%, surplus is water；The amino acid surfactant is sodium N-lauroyl sarcosinate, sodium lauroyl glutamate and Pork and beans The compound of cool acyl group propylhomoserin sodium, mass ratio 1:5:20.

3. a kind of fizzy dandruff control shampoo containing according to claim 1 or 2, which is characterized in that the granatum mentions Take the preparation method of object the following steps are included:

(1) granatum crushed material is weighed, is 1:30 by solid-to-liquid ratio g/mL, 75% ethanol solution of volumetric concentration is added, ultrasonic wave is auxiliary Extraction 50 minutes, filtering are helped, filter residue repeats to extract 1 time, and filtrate merges, and is concentrated under reduced pressure；

(2) concentrate is extracted twice with isometric ethyl acetate, and extract liquor merges, recycling ethyl acetate to half volume, after with Isometric 4% sodium hydroxide solution of mass concentration extraction；

(3) extract liquor is added the gelatin solution that mass concentration is 5%, stood overnight, filtered with dilute hydrochloric acid tune pH value to 4；It collects Precipitating filters out insoluble matter with the dissolution of 60% acetone soln, and filtrate recycles acetone；

(4) after filtrate recycling acetone, it is splined on the polyamide chromatographic column pre-processed, successively with the volume of 3-6 times of column volume Concentration 20%, 40%, 60% and anhydrous ethanol elution, and anhydrous ethanol elution liquid is collected, it is concentrated under reduced pressure, freeze-drying obtains stone Pomegranate bark extract.

4. a kind of preparation method of fizzy dandruff control shampoo containing according to claim 1 or 2, which is characterized in that packet Include following steps:

(1) it adds water in reaction cylinder, dodecyl ether sulfate ammonium is added, is heated to 75~80 DEG C while stirring, completely Dissolution, obtains solution A；

(2) coco betaine and coco alkyl glucoside are added in Xiang Shangshu solution A, stirs evenly, is cooled to 70~75 DEG C, it is completely dissolved, obtains solution B；

(3) amino acid surfactant, pomegranate rind extract and Polyquaternium-10 are added in Xiang Shangshu solution B, stirs evenly, 55~65 DEG C are cooled to, glycerol is added, is stirred evenly, is completely dissolved, solution C is obtained；

(4) above-mentioned solution C is cooled to 35~45 DEG C, PEG-7 olive grease, benzoic acid, salicylic acid and essence is added, finally plus Enter coconut oleoyl amine monoethanolamine and PEG-120 methyl dioleate, be uniformly mixed, discharging to get.