CN107898654B - Amino acid shampoo composition and preparation method thereof - Google Patents
Amino acid shampoo composition and preparation method thereof Download PDFInfo
- Publication number
- CN107898654B CN107898654B CN201710992510.5A CN201710992510A CN107898654B CN 107898654 B CN107898654 B CN 107898654B CN 201710992510 A CN201710992510 A CN 201710992510A CN 107898654 B CN107898654 B CN 107898654B
- Authority
- CN
- China
- Prior art keywords
- sodium
- surfactant
- amino acid
- composition
- betaine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention belongs to the field of cosmetics, and relates to a cleaning composition and a preparation method thereof. The composition comprises the following components in percentage by weight: 15-50% of amino acid surfactant, 10-30% of alpha olefin sodium sulfonate and 15-50% of betaine surfactant. The invention effectively solves the problem that the product is difficult to thicken and is declared to be hard to thicken by taking the amino acid surfactant as the main surfactant, mainly adopts the compounding of the anionic surfactant and the amphoteric surfactant for thickening, and utilizes the C14-16 olefin sodium sulfonate and the betaine surfactant to construct micelles according to a proper proportion so as to thicken the system. The cold preparation process can be realized without compounding other thickeners, the production time is greatly reduced, the prepared cleaning product has rich and fine foam, the cost is greatly saved, the problem of difficult thickening of the surface activity of the amino acid is solved, and the problem of low foam of the surface activity of the amino acid is also solved.
Description
Technical Field
The invention belongs to the field of cosmetics, and relates to a low-cost thickened cleaning composition.
Background
The amino acid shampoo in the market generally has the problems of high cost and low foam. Mainly because the surface activity cost of amino acid is high, the cheapest amino acid is more than 12 yuan/kg, and the expensive amino acid is even nearly hundred yuan/kg. The foam height of the amino acid surfactant is lower than that of the common sulfate surfactant, the amino acid surfactant has the biggest problem of difficult thickening, and the conventional shampoo thickener cannot thicken effectively or has obvious defoaming, such as cocamide MEA, PEG-150 distearate, PEG-120 methyl glucose dioleate and acrylic acid (ester) copolymer, and the thickening effect is very limited. In recent years, products effective in thickening amino acids have been developed such as PEG-120 methyl glucose triisostearate, PEG-150 pentaerythritol tetrastearate, and acrylic acid (ester)/C10-30 alkanol acrylate crosslinked polymers to solve the problem of difficult thickening, but they have various problems such as high cost, defoaming, necessity of heating, and complicated process.
In addition, in the prior art, only an amphoteric surfactant is used for thickening amino acid surfactant, for example, ruhaiwei studies on amino acid type/amphoteric surfactant combination, and as a result, it is found that cocoamido betaine has different thickening effects on different amino acid surfactants, and has thickening effects on sodium lauroyl sarcosinate and sodium cocoyl alaninate, but has no effective thickening effect on sodium lauryl glutamate, sodium cocoyl methyltaurate and sodium cocoyl glycinate (ruhaiwei, amino acid type/amphoteric surfactant combination thickening system and rheology research [ D ]. university of eastern science and technology, 2013.). Therefore, the thickening of the amphoteric surfactant on the amino acid surfactant is limited by the type and pH of the amino acid surfactant, the type and ratio of the amphoteric surfactant, and the like.
Disclosure of Invention
The present invention aims to provide a composition capable of effectively thickening various types of amino acid-based surfactants.
It is also an object of the present invention to provide a low cost composition for thickening amino acid based surfactants.
The invention also aims to provide an amino acid composition with good foaming effect and lasting foam.
It is also an object of the present invention to provide a composition which does not require the addition of an additional thickener.
The above object of the present invention is achieved by the following technical means:
in one aspect, the present invention provides a composition comprising the following components in weight percent:
15% -50% of amino acid surfactant;
10 to 30 percent of alpha olefin sodium sulfonate;
10 to 50 percent of betaine surfactant.
The composition comprises the following components in percentage by weight:
20-45% of amino acid surfactant;
10 to 30 percent of alpha olefin sodium sulfonate;
15 to 45 percent of betaine surfactant.
Wherein the amino acid surfactant is selected from one or more of methyl fatty acyl taurate, fatty acyl sarcosinate, fatty acyl glutamate and fatty acyl alanate.
Wherein the weight ratio of the alpha olefin sodium sulfonate to the betaine surfactant is 0.8-1.2: 1.8-2.4.
Further, the methyl fatty acyl taurate is selected from one or more of sodium methyl cocoyl taurate, sodium methyl myristoyl taurate, sodium methyl stearyl taurate, sodium cocoyl methyl taurate and sodium methyl lauroyl taurate; the fatty acyl sarcosine salt is selected from one or more of sodium lauroyl sarcosine, sodium myristoyl sarcosine, sodium cocoyl sarcosine and sodium palmitoyl sarcosine; the fatty acyl glutamate is selected from one or more of myristoyl sodium glutamate, cocoyl sodium glutamate, stearoyl sodium glutamate and lauroyl sodium glutamate; the fatty acyl alaninate is selected from one or more of sodium cocoyl amido propionate, sodium lauroyl propionate and sodium lauroyl methyl amino propionate;
as a preferred embodiment, the amino acid surfactant is selected from sodium methylcocoyl taurate.
Wherein the sodium alpha olefin sulfonate is selected from one or more of sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate and sodium C16-18 olefin sulfonate; in a preferred embodiment, the sodium alpha olefin sulfonate is selected from the group consisting of sodium C12-14 olefin sulfonates.
The betaine surfactant is not particularly limited, and any betaine surfactant can be used to thicken the system of the present invention. Specifically, combinations such as one or more of cocohydroxy sulfobetaine, cocobetaine, cocoyl/oleamidopropyl betaine, cocamidopropyl betaine, lauryl hydroxy sulfobetaine, lauryl betaine, lauramidopropyl hydroxysulfobetaine, and lauramidopropyl betaine are all possible.
The composition of the present invention may be used in cleansing products such as shampoos, shower or face lotions and the like.
As an exemplary embodiment, the composition of the present invention is used for a shampoo, and in addition to the above-mentioned composition, the shampoo of the present invention may further contain components commonly used in shampoos, such as a cationic conditioner, a pH adjustor, a preservative, and other modifiers commonly used in shampoos, and the like.
In a preferred embodiment, the cationic conditioning agent is one or more selected from polyquaternium-6, polyquaternium-10, polyquaternium-22, polyquaternium-47, polyquaternium-67, polyquaternium-73, guar hydroxypropyl trimonium chloride, etc.;
as a preferable embodiment, the pH regulator is one or more selected from citric acid, sodium citrate, sodium hydroxide, potassium hydroxide, triethanolamine and other conventional pH regulators.
In a preferred embodiment, the shampoo of the present invention further comprises 0.01 to 5% of a humectant. Further, the humectant is selected from one or more of polyalcohol, betaine, sodium hyaluronate, sodium PCA, panthenol and the like.
As a preferred embodiment, the shampoo provided by the invention comprises the following components in percentage by weight:
preferably, the composition further comprises a balance of water.
Optionally, the oil and fat is common hair conditioner such as silicone oil, PEG-7 glyceryl cocoate, linoleamidopropyl PG-dimethyl ammonium chloride phosphate, C12-13 alcohol lactate, PPG-3 octyl ether, etc.
As a more preferred embodiment, it contains the following components in weight percent:
on the other hand, the invention also provides a preparation method of the shampoo, which comprises the following steps:
s1: adding a cationic conditioner into water, and dispersing;
s2: adding betaine surfactant, stirring, adding amino acid surfactant, and adding alpha olefin sodium sulfonate;
preferably, the method further comprises S3: further adding one or more of humectant, oil and fat, and pH antiseptic, and stirring to uniform.
As a further alternative, the method comprises:
s1: adding a proper amount of water at low temperature, adding a cationic conditioner, and dispersing well;
s2: adding betaine surfactant, stirring for 1 min, adding amino acid surfactant, and adding alpha olefin sodium sulfonate (starting to heat at the moment if there is a material to be heated and dissolved later);
s3: adding the rest raw materials in the formula, and stirring uniformly to discharge.
As described in the background art, amino acid surfactants are difficult to thicken, and even if some surfactants can thicken amino acid surfactants, the problems of high cost, defoaming, limited thickening and the like exist. Therefore, the inventors have intensively studied a shampoo system which can effectively thicken amino acid-based surfactant and has a low cost and a good foaming effect. A large number of experimental researches show that the alpha olefin sodium sulfonate and the betaine surfactant are compounded, so that a system with various viscosities of amino acid shampoo can be effectively constructed, the thickening effect on most amino acid surfactants is achieved, the cost is low, and the foaming effect is good. The thickening regulation effect is more remarkable under the condition of specific compounding ratio.
The alpha olefin sodium sulfonate has no thickening effect, and can effectively thicken amino acid surfactants by compounding with betaine surfactants, and has good foaming effect and lasting foam.
The invention has the beneficial effects that:
1. from the thickening effect, the alpha olefin sodium sulfonate and the betaine surfactant have obvious thickening capability on various amino acid surfactants and have obvious help on the foam height of an amino acid formula.
2. The stability of the foam can be improved by compounding the alpha olefin sodium sulfonate, the betaine surfactant and the amino acid surfactant.
3. Meanwhile, under the condition of appropriate proportion, the cost of the amino acid system formula can be greatly reduced, and the problem that the amino acid system in the market is high in cost and difficult to popularize is solved.
The high cost of the amino acid system is caused by two reasons, namely that the surface activity of the amino acid is basically over 10 yuan/KG, sodium sarcosine is the cheapest, the other amino acid is over 20 yuan, the content of active substances is only 30 percent, and the active substances are one time or several times more expensive than the conventional AES, the foaming power of the AES is not good, if the amino acid is used alone, the content of the active substances is higher, the higher surface activity of the amino acid brings higher thickening difficulty, the cost of the raw materials for effective thickening is far higher than that of CMEA, DOE120 and SF-1 which are commonly used in AES shampoo, and the cost of the optical thickening agent is 1-3 yuan. In conclusion, the prepared amino acid shampoo has the cost of more than 12 yuan, even 30 yuan even if the conditioning is poor.
The lowest cost of the amino acid shampoo of the composition is about 7 yuan, which is far lower than the average level of the market.
4. The composition can be used for cold blending in shampoo production, greatly reduces working hours, improves productivity, and is efficient and energy-saving. The conventional shampoo is prepared by water, the production time is about 3 hours, and the composition is applied by only one pot for production for about 1 hour.
Detailed Description
The technical solutions of the present invention are further illustrated by the following specific examples, which do not represent limitations to the scope of the present invention. Insubstantial modifications and adaptations of the present invention by others of the concepts fall within the scope of the invention.
Viscosity test method: 12rpm of 4# rotor below 50000 viscosity
6rpm of 4# rotor above 50000 viscosity
Foam height national standard Roche foam test method
Example 1 verification of the synergistic thickening amino acid-based surfactant of different weight percentages of betaine surfactant with different weight percentages of sodium alpha olefin sulfonate
In order to verify the effect of different weight percentages of components and different amino acid types on foaming and thickening effects, etc., the inventors designed the following 3 protocols. From scheme 1 to scheme 3, the weight percentages of betaine surfactant and alpha olefin sodium sulfonate are gradually increased, and for each scheme, the influence of different kinds of amino acid surfactant on foaming, thickening effect and the like is also designed. The specific scheme is as follows:
TABLE 1 physicochemical Properties of combinations prepared with different amino acid surfactants in scheme 1
TABLE 2 physicochemical Properties of combinations prepared with different amino acid surfactants in scheme 2
Note: the sodium lauroyl glutamate formulation contains two points of thickener, cocamide MEA.
TABLE 3 physicochemical Properties of combinations prepared with different amino acid surfactants in scheme 3
Note: the sodium lauroyl glutamate formulation contains two points of thickener, cocamide MEA.
From the above three experimental protocols, the following conclusions can be drawn
1. With the increase of the surface activity of the amphoteric betaine and the amount of the alpha olefin sodium sulfonate, the viscosity of other systems except sodium lauroyl glutamate is obviously improved, and particularly, the high-viscosity system can be achieved under the condition of lower surface activity of the amphoteric betaine and the addition amount of the alpha olefin sodium sulfonate. While the sodium lauroyl glutamate system, even if increasing the amphoteric betaine surfactant level and the sodium alpha olefin sulfonate level, with this combination, can easily increase from 0 viscosity to 2000 to 32000 viscosity with only two points of cocoamide methyl MEA addition. And if only the betaine surfactant is adopted and the alpha olefin sodium sulfonate is not added, even if a large amount of thickener cocamide MEA is added, the sodium lauroyl glutamate system cannot be thickened. The sodium alpha olefin sulfonate and the amphoteric betaine are proved to be capable of obviously and synergistically thickening the amino acid surfactant system under the condition of reasonable collocation.
2. From a comparison of scheme 1 and scheme 2, it is concluded that with increasing amounts of amphoteric betaine surfactant and alpha olefin sodium sulfonate, the foam height of the other systems, except for sodium methylcocoyltaurate, is increased and more stable.
3. From the comparison of scheme 2 and scheme 3, it is concluded that the viscosity of the system can be significantly increased with decreasing amount of amino acid surfactant. It was further verified that the combination was effective in thickening amino acid surface activity.
4. The system of the invention can effectively thicken the sodium glycinate surfactant, but has a common foaming effect, so that the sodium glycinate surfactant is not suitable for being used as the main surface of amino acid of shampoo for shampoo requiring large foaming.
Example 2 demonstrates the effect of varying amounts of amphoteric betaine surfactant, the ratio to sodium alpha olefin sulfonate on the thickening effect of amino acid surfactant, and the effect of pH on system viscosity
Table 4.
The thickening capacity of the composition changes with the change of the ratio of the alpha olefin sodium sulfonate to the amino acid surfactant, and through experimental investigation and experience of an inventor, when the weight ratio of the alpha olefin sodium sulfonate to the betaine surfactant is 0.8-1.2: 1.8-2.4, the formula has higher viscosity. In addition, as can be seen from the above table, changes in pH affect the viscosity. The highest viscosity of sodium sarcosinate is about 6.0, and parabola appears according to different pH values, and the specific peak value can be changed according to different formulas.
In general, lowering the pH appropriately increases the viscosity of the composition, such as formula D, since the pH is still relatively high, but the viscosity is not as high, and continuing to increase citric acid decreases the pH and increases the viscosity. However, when the weight ratio of the sodium alpha olefin sulfonate to the betaine surfactant is outside the selected range of the present invention, there is no effect of improving viscosity even if the pH is lowered, such as formula E, formula F.
EXAMPLE 4 preparation and testing of several amino acid shampoos
Several shampoos were prepared according to the formulations of table 5, table 6, table 7.
The preparation method comprises the following steps: s1: adding a proper amount of water at low temperature, adding a cationic conditioner, and dispersing well;
s2: adding betaine surfactant, stirring for 1 min, adding amino acid surfactant, and adding alpha olefin sodium sulfonate;
s3: adding the rest raw materials in the formula, and stirring uniformly to discharge.
TABLE 5 Cocoamide sodium taurate shampoo
TABLE 6 monosodium glutamate shampoo
TABLE 7 sarcosine sodium shampoo
TABLE 8 Properties of different amino acid shampoos
| Viscosity mPA. s | Height mm of foam | Effect | |
| Shampoo of Table 5 | 15000 | 150 | Is soft and smooth |
| Shampoo of Table 6 | 4500 | 140 | Light and wet comb |
| Shampoo of Table 7 | 6000 | 140 | Good effect of softening and drying hair |
The amino acid shampoos represented in tables 5-7 have a viscosity of at least 4500, especially the shampoo containing sodium methylcocoyl taurate. The heights of the three parts are not greatly different and all reach 140 mm.
Example 5
The formulation of scheme 1, with the appropriate addition of a macromolecular cationic conditioning agent, allows the formulation to be thickened at low surfactant levels.
Scheme 1 addition of macromolecular cationic conditioner
TABLE 9 physicochemical Properties of combinations prepared with different amino acid surfactants in scheme 1
Compared with scheme 1, the embodiment adds the cationic conditioner, compared with the physicochemical property of scheme 1 in the table 1, after a small amount of cationic conditioner is added, the combined viscosity of all kinds of amino acids is greatly improved, most of the combinations without viscosity reach the viscosity of more than 1000, and the height of the foam is slightly reduced.
Claims (23)
1. The composition is characterized by comprising the following components in percentage by weight:
15% -50% of amino acid surfactant;
10% -30% of alpha olefin sodium sulfonate;
10% -50% of betaine surfactant;
wherein the amino acid surfactant is selected from one or more of methyl fatty acyl taurate, fatty acyl sarcosinate, fatty acyl glutamate and fatty acyl alanate;
the weight ratio of the alpha olefin sodium sulfonate to the betaine surfactant is 0.8-1.2: 1.8-2.4;
the alpha olefin sodium sulfonate is selected from one or more of C12-18 olefin sodium sulfonate;
the composition is free of a thickener.
2. The composition according to claim 1, characterized by comprising the following components in percentage by weight:
20% -45% of amino acid surfactant;
10% -30% of alpha olefin sodium sulfonate;
15% -45% of betaine surfactant.
3. The composition according to claim 1, wherein the methyl fatty acyl taurate is selected from one or more of sodium methyl cocoyl taurate, sodium methyl myristoyl taurate, sodium methyl stearyl taurate, sodium cocoyl methyl taurate and sodium methyl lauroyl taurate.
4. The composition according to claim 1, wherein the fatty acyl sarcosine salt is selected from one or more of sodium lauroyl sarcosine, sodium myristoyl sarcosine, sodium cocoyl sarcosine and sodium palmitoyl sarcosine.
5. The composition according to claim 1, wherein the fatty acyl glutamate is selected from one or more of sodium myristoyl glutamate, sodium cocoyl glutamate, sodium stearoyl glutamate and sodium lauroyl glutamate.
6. The composition according to claim 1, wherein the fatty acyl alaninate is selected from one or more of sodium cocamidopropionate, sodium lauroyl propionate, and sodium lauroyl methylaminopropionate.
7. The composition of claim 1 wherein said amino acid based surfactant is selected from the group consisting of sodium methylcocoyl taurate.
8. The composition of claim 1, wherein the sodium alpha olefin sulfonate is selected from the group consisting of sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, and sodium C16-18 olefin sulfonate.
9. The composition of claim 1, wherein said sodium alpha olefin sulfonate is selected from the group consisting of sodium C14-16 olefin sulfonates.
10. The composition of claim 1, wherein the betaine surfactant is selected from the group consisting of cocohydroxy sulfobetaine, cocobetaine, cocoacyl/oleamidopropyl betaine, cocamidopropyl betaine, lauryl hydroxy sulfobetaine, lauryl betaine, lauramidopropyl hydroxysulfobetaine, and lauramidopropyl betaine.
11. The composition according to any one of claims 1 to 10, wherein said composition is used in a cleaning product.
12. The composition of claim 11, wherein the cleansing product is selected from the group consisting of a shampoo, a shower gel, and a facial cleanser.
13. The composition of claim 11, wherein the cleansing product is a shampoo; the shampoo also contains one or more of cationic conditioner, pH regulator and antiseptic.
14. The composition of claim 13 wherein the cationic conditioning agent is selected from the group consisting of one or more of polyquaternium-6, polyquaternium-10, polyquaternium-22, polyquaternium-47, polyquaternium-67, polyquaternium-73, and guar hydroxypropyltrimonium chloride.
15. The composition of claim 13, wherein the pH adjusting agent is selected from the group consisting of citric acid and one or more of sodium citrate, sodium hydroxide, potassium hydroxide and triethanolamine.
16. The composition of claim 13, wherein said shampoo further comprises a moisturizer selected from the group consisting of one or more of a polyol, betaine, sodium hyaluronate, sodium PCA and panthenol.
17. The composition according to claim 16, comprising the following components in total percentage by weight:
15-50% of amino acid surfactant
10-30% of alpha olefin sodium sulfonate
10-50% of betaine surfactant
0.01 to 5 percent of cationic conditioner
0.01 to 5 percent of humectant
0.01 to 5 percent of oil and fat
0.01 to 5 percent of pH regulator
Proper amount of preservative.
18. The composition of claim 17, wherein the composition further comprises a balance of water.
19. The composition according to claim 17, wherein the fats and oils are selected from one or more of silicone oil, PEG-7 glyceryl cocoate, linoleamidopropyl PG-dimethylammonium chloride phosphate, C12-13 alcohol lactate, and PPG-3 octyl ether.
20. The composition according to claim 18, wherein the fats and oils are selected from one or more of silicone oil, PEG-7 glyceryl cocoate, linoleamidopropyl PG-dimethylammonium chloride phosphate, C12-13 alcohol lactate, and PPG-3 octyl ether.
21. The composition according to claim 16, characterized by comprising the following components in percentage by weight:
20% -45% of amino acid surfactant
10-30% of alpha olefin sodium sulfonate
15-45% of betaine surfactant
0.01-4% of cationic conditioner
0.01 to 4 percent of humectant
0.01-3% of oil and fat
0.01 to 2 percent of pH regulator
Proper amount of preservative
The balance of water.
22. The composition according to claim 21, wherein the fats and oils are selected from one or more of silicone oil, PEG-7 glyceryl cocoate, linoleamidopropyl PG-dimethylammonium chloride phosphate, C12-13 alcohol lactate, and PPG-3 octyl ether.
23. A method of preparing a composition according to any one of claims 17 to 22, comprising the steps of:
s1: adding a cationic conditioner into water, and dispersing;
s2: adding betaine surfactant, stirring, adding amino acid surfactant, and adding alpha olefin sodium sulfonate;
s3: further adding humectant, oils, pH regulator and antiseptic, and stirring to uniform.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710992510.5A CN107898654B (en) | 2017-10-23 | 2017-10-23 | Amino acid shampoo composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710992510.5A CN107898654B (en) | 2017-10-23 | 2017-10-23 | Amino acid shampoo composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107898654A CN107898654A (en) | 2018-04-13 |
| CN107898654B true CN107898654B (en) | 2021-01-15 |
Family
ID=61840660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710992510.5A Active CN107898654B (en) | 2017-10-23 | 2017-10-23 | Amino acid shampoo composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107898654B (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108524310A (en) * | 2018-05-08 | 2018-09-14 | 花安堂生物科技集团有限公司 | A kind of amino acid and modified amino acid table are lived shading composition and its application |
| CN108434079B (en) * | 2018-06-01 | 2020-06-02 | 广州澳希亚实业有限公司 | Shampoo and bath foam composition for infants and children |
| CN108685736B (en) * | 2018-07-26 | 2019-09-20 | 花安堂生物科技集团有限公司 | A kind of detergent composition and its application |
| CN108944112A (en) * | 2018-07-28 | 2018-12-07 | 黄智慧 | A kind of preparation method for exempting from alcohol fountain solution |
| CN108865165A (en) * | 2018-08-22 | 2018-11-23 | 山西华欣久泰科技有限公司 | A kind of heavy-metal contaminated soil renovation agent and preparation method thereof |
| CN108929699A (en) * | 2018-08-22 | 2018-12-04 | 山西华欣久泰科技有限公司 | A kind of soil-repairing agent and preparation method thereof for administering heavy metal pollution |
| CN109172409B (en) * | 2018-09-20 | 2021-07-27 | 洛娃日化(江苏)股份有限公司 | Thickener aiming at amino acid surfactant, application thereof and shampoo |
| CN109666549B (en) * | 2018-10-31 | 2021-04-23 | 广东头缘生物科技有限公司 | Hair soap containing soapberry extract |
| CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
| CN113395957A (en) * | 2018-12-25 | 2021-09-14 | 莱雅公司 | Composition for cleaning keratin materials |
| CN109602639B (en) * | 2019-01-31 | 2021-12-21 | 广州艾蓓生物科技有限公司 | Amino acid-washing shampoo and preparation method thereof |
| CN110721108A (en) * | 2019-09-26 | 2020-01-24 | 广州妮趣化妆品有限公司 | Thickening composition of cocoyl alanine salt and application thereof |
| CN111616972A (en) * | 2020-05-13 | 2020-09-04 | 名臣健康用品股份有限公司 | Low-cost self-thickening mild sulfate-free shampoo composition and preparation method thereof |
| CN112263499B (en) * | 2020-11-27 | 2023-05-23 | 佛山市南海东方澳龙制药有限公司 | Animal flavor wave with antibacterial function and preparation method thereof |
| CN114288209B (en) * | 2021-10-25 | 2023-11-24 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
| CN114191323B (en) * | 2021-12-24 | 2024-03-26 | 岳阳科罗德联合化学工业有限公司 | Gemini glutamic acid amino acid surfactant composition, and preparation method and application thereof |
| CN114224765A (en) * | 2021-12-31 | 2022-03-25 | 上海佰太生物科技有限公司 | Amino acid shampoo and preparation method thereof |
| CN114306135A (en) * | 2022-01-06 | 2022-04-12 | 清远天赐高新材料有限公司 | Transparent thickening suspension system, preparation method and application |
| CN115975612B (en) * | 2022-06-16 | 2024-02-09 | 桂林理工大学 | Subway shield foaming agent and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60199811A (en) * | 1984-03-22 | 1985-10-09 | Lion Corp | Shampoo composition |
| FR3029778B1 (en) * | 2014-12-12 | 2018-03-02 | L'oreal | COSMETIC COMPOSITION COMPRISING LINEAR ALPHA-OLEFINE SULFONATES, ANIONIC SURFACTANTS AND NON-IONIC AND / OR AMPHO-TERES SURFACTANTS, AND COSMETIC TREATMENT METHOD |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
-
2017
- 2017-10-23 CN CN201710992510.5A patent/CN107898654B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107898654A (en) | 2018-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107898654B (en) | Amino acid shampoo composition and preparation method thereof | |
| CN109498494B (en) | Refreshing oil-control silicone-oil-free shampoo and preparation method thereof | |
| CN108078796B (en) | Silicone-oil-free moistening and smoothing hair mask and preparation method thereof | |
| CN104540551A (en) | Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamines and having improved foam quality and higher viscosity | |
| CN104940071B (en) | A kind of moderately removing dandruff shampoo and preparation method thereof | |
| CN110123721B (en) | Shampoo composition for improving oily scalp | |
| CN111643433A (en) | Oil-control anti-dandruff shampoo composition | |
| EP2436371A1 (en) | Hair cosmetic | |
| CN112402275A (en) | Organic zinc compound oil-control anti-dandruff shampoo and preparation method thereof | |
| CN108685734A (en) | A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon | |
| JP2014125435A (en) | Skin cleanser composition | |
| US11491094B2 (en) | Sulfate-free surfactant system | |
| CN108295010A (en) | A kind of yellow ginger oil-control hair-loss preventing and hair-restoring shampoo and preparation method thereof | |
| CN114306131A (en) | Washing composition based on modified corn starch and preparation method thereof | |
| CN112891252A (en) | Mild itching-relieving bath composition and preparation method thereof | |
| CN116370349A (en) | Amino acid facial cleanser, and preparation method and application thereof | |
| JP2014125434A (en) | Skin cleanser composition | |
| CN115068389A (en) | Multi-effect composition, essence cream and preparation method thereof | |
| CN114366680A (en) | Shampoo composition for maintaining scalp health, preventing alopecia and strengthening hair and preparation method thereof | |
| CN110623853B (en) | Cleaning and nursing composition and preparation method thereof | |
| EP3505218B1 (en) | A gentle detergent composition for greasy and acneic skins | |
| CN114366693A (en) | Shampoo shower gel for infants and children | |
| CN109908061B (en) | Anti-dandruff shampoo rich in foam and preparation method thereof | |
| CN107648061B (en) | Shampoo with dandruff removing, nourishing and pearly luster and preparation method thereof | |
| CN113476341A (en) | Alkaline silicone oil-free shampoo and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220809 Address after: No.23 Xianke Er Road, Huadong Town, Huadu District, Guangzhou City, Guangdong Province 510800 Patentee after: GUANGZHOU KENENG COSMETIC RESEARCH Co.,Ltd. Patentee after: GUANGDONG DANZ GROUP Co.,Ltd. Address before: No.6-1, Yongxing Industrial Zone, chentai Road, Taihe Town, Baiyun District, Guangzhou, Guangdong 510540 Patentee before: GUANGZHOU BAIYUN LIANJIA FINE CHEMICAL PLANT |
|
| TR01 | Transfer of patent right |