CN112402275A - Organic zinc compound oil-control anti-dandruff shampoo and preparation method thereof - Google Patents
Organic zinc compound oil-control anti-dandruff shampoo and preparation method thereof Download PDFInfo
- Publication number
- CN112402275A CN112402275A CN202011399037.8A CN202011399037A CN112402275A CN 112402275 A CN112402275 A CN 112402275A CN 202011399037 A CN202011399037 A CN 202011399037A CN 112402275 A CN112402275 A CN 112402275A
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- zinc
- phase
- sodium
- raw materials
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- 208000001840 Dandruff Diseases 0.000 title claims abstract description 51
- 239000002453 shampoo Substances 0.000 title claims abstract description 48
- 150000003752 zinc compounds Chemical class 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000011701 zinc Substances 0.000 claims abstract description 70
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 70
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229940043810 zinc pyrithione Drugs 0.000 claims abstract description 51
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 38
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000011576 zinc lactate Substances 0.000 claims abstract description 32
- 229940050168 zinc lactate Drugs 0.000 claims abstract description 32
- 235000000193 zinc lactate Nutrition 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims description 87
- 239000002994 raw material Substances 0.000 claims description 52
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 229910001868 water Inorganic materials 0.000 claims description 37
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- -1 methyl taurate Chemical compound 0.000 claims description 19
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 14
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 14
- 229960001763 zinc sulfate Drugs 0.000 claims description 14
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 14
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims description 13
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 13
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 13
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 12
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims description 12
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 12
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 229940079779 disodium cocoyl glutamate Drugs 0.000 claims description 12
- 230000002829 reductive effect Effects 0.000 claims description 11
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 10
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 10
- 239000003093 cationic surfactant Substances 0.000 claims description 10
- 229930182478 glucoside Natural products 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229960005323 phenoxyethanol Drugs 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 235000001014 amino acid Nutrition 0.000 claims description 9
- 150000001413 amino acids Chemical class 0.000 claims description 9
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 claims description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 7
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 7
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 229940041616 menthol Drugs 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 239000004299 sodium benzoate Substances 0.000 claims description 7
- 229920002907 Guar gum Polymers 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000000665 guar gum Substances 0.000 claims description 6
- 229960002154 guar gum Drugs 0.000 claims description 6
- 235000010417 guar gum Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- XZBPBALANIOSNO-UHFFFAOYSA-N 1-hydroxybutyl dodecanoate Chemical compound C(CCCCCCCCCCC)(=O)OC(CCC)O XZBPBALANIOSNO-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 5
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 235000000380 Nyssa aquatica Nutrition 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 229950010765 pivalate Drugs 0.000 claims description 4
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 4
- 235000005074 zinc chloride Nutrition 0.000 claims description 4
- JSOVGYMVTPPEND-UHFFFAOYSA-N 16-methylheptadecyl 2,2-dimethylpropanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C(C)(C)C JSOVGYMVTPPEND-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229940082500 cetostearyl alcohol Drugs 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 2
- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 claims description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 235000004279 alanine Nutrition 0.000 claims description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 2
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 2
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 claims description 2
- GLSRFBDXBWZNLH-UHFFFAOYSA-L disodium;2-chloroacetate;2-(4,5-dihydroimidazol-1-yl)ethanol;hydroxide Chemical compound [OH-].[Na+].[Na+].[O-]C(=O)CCl.OCCN1CCN=C1 GLSRFBDXBWZNLH-UHFFFAOYSA-L 0.000 claims description 2
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 claims description 2
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 2
- 229940044591 methyl glucose dioleate Drugs 0.000 claims description 2
- 229940086539 peg-7 glyceryl cocoate Drugs 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 108700004121 sarkosyl Proteins 0.000 claims description 2
- 229940083542 sodium Drugs 0.000 claims description 2
- 229940031688 sodium c14-16 olefin sulfonate Drugs 0.000 claims description 2
- 229940096501 sodium cocoamphoacetate Drugs 0.000 claims description 2
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 2
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 2
- 229940104256 sodium taurate Drugs 0.000 claims description 2
- GWLWWNLFFNJPDP-UHFFFAOYSA-M sodium;2-aminoethanesulfonate Chemical compound [Na+].NCCS([O-])(=O)=O GWLWWNLFFNJPDP-UHFFFAOYSA-M 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 229940104261 taurate Drugs 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- RIAJTMUAPNIDSS-UHFFFAOYSA-N 3-aminopropan-1-ol;hydron;chloride Chemical compound Cl.NCCCO RIAJTMUAPNIDSS-UHFFFAOYSA-N 0.000 claims 1
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- 230000000694 effects Effects 0.000 abstract description 30
- 210000004761 scalp Anatomy 0.000 abstract description 27
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- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract description 9
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Classifications
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9728—Fungi, e.g. yeasts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/008—Preparations for oily hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention provides an organic zinc compound oil-control and anti-dandruff shampoo, which is prepared by applying three organic zinc, namely zinc lactate, zinc yeast and Zinc Pyrithione (ZPT) to shampoo, and finds that the oil-control and anti-dandruff effect is enhanced after compound. Wherein Zinc Pyrithione (ZPT) can inhibit fungi to reduce dandruff, and zinc yeast and zinc lactate increase scalp moisture retention, strengthen scalp barrier, and reduce discomfort caused by excessive scalp epithelial lipid secretion. In the preferred embodiment of the present invention, the deposition level of zinc ions on the scalp is found to be an important factor in the effectiveness of oil control and dandruff control, and the effect of different surfactant systems on the deposition of zinc ions on the scalp is different. The surfactant system provided by the invention can better deposit zinc ions and improve the utilization rate of the zinc ions.
Description
Technical Field
The invention relates to the technical field of the lightening industry, in particular to an organic zinc compound oil-controlling and anti-dandruff shampoo and a preparation method thereof.
Background
Similar to the skin of other parts of the human body, the scalp is also covered with an oil film, the main component of which is sebum. Sebum is composed of sebaceous glands, sweat gland secretions and keratinocyte disintegrates, and is closely related to skin moisture, pH value and skin flora. The normally secreted oil has the functions of moistening skin, resisting infection, blocking, etc. However, excessive secretion of oil causes the acid-base balance to be disrupted, and dysbacteriosis to cause many skin problems such as Seborrheic Dermatitis (SD), dandruff, alopecia, and the like. One of the causes of dandruff is hypersecretion of oil and fat, in addition to malassezia bacteria. The malassezia is fed by grease, metabolites can stimulate the scalp to generate dandruff, excessive grease can promote the growth of the malassezia and can also generate more products which stimulate the scalp, so that the problem of excessive grease of the scalp is solved, and the scalp dandruff can be greatly relieved. Statistical data show that about 50% of adults have dandruff trouble, so that the shampoo for controlling oil and removing dandruff of the scalp has great market demand.
There are many factors that affect scalp oil secretion, including: 1. androgen levels, the sebaceous gland is a target organ for androgens, testosterone increases sebaceous gland volume and secretion; 2. skin surface flora, such as malassezia can decompose triglyceride and saturated fatty acid in sebum, and also influence the oil secretion rate; 3. age, sex, season, etc.
At present, most of oil control products on the market are designed aiming at androgen, and single oil control components are mostly used, so the problems of poor oil control effect, poor effect persistence and the like exist, and the drug resistance is easy to generate.
In view of this, the invention is particularly proposed.
Disclosure of Invention
The first purpose of the invention is to provide the organic zinc compound oil-control and anti-dandruff shampoo which has a lasting oil-control and anti-dandruff effect and has the effects of moisturizing and repairing scalp barriers.
The second purpose of the invention is to provide a preparation method of the shampoo.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the invention relates to an organic zinc compound oil-controlling and anti-dandruff shampoo which comprises the following raw materials in parts by weight: 0-20 parts of anionic surfactant, 0-0.8 part of cationic surfactant, 1-8 parts of amphoteric surfactant, 1-30 parts of amino acid surfactant, 0.1-1.5 parts of pearling agent, 1-3 parts of thickening agent, 0.01-6 parts of organic zinc, 0.1-3 parts of hair conditioner, 0.01-1 part of preservative, 0.01-1 part of pH value regulator, 0.1-2 parts of spice, 0.1-0.2 part of zinc sulfate/zinc chloride, 100 parts of raw materials in total, and the balance of water.
Preferably, the anionic surfactant is selected from at least one of sodium laureth sulfate, sodium C14-16 olefin sulfonate and disodium lauryl sulfosuccinate.
Preferably, the cationic surfactant is selected from at least one of guar hydroxypropyl trimethyl ammonium chloride, polyquaternium-10 and polyquaternium-7, and preferably guar hydroxypropyl trimethyl ammonium chloride.
Preferably, the amphoteric surfactant is selected from at least one of cocamidopropyl betaine, lauramidopropyl betaine, cocamidopropyl hydroxysultaine, sodium cocoamphoacetate.
Preferably, the amino acid surfactant is selected from at least one of sodium lauroyl sarcosinate, disodium cocoyl glutamate, sodium cocoyl alanine, sodium methyl cocoyl taurate, and sodium cocoyl methyl taurate.
Preferably, the pearling agent is at least one selected from ethylene glycol distearate and ethylene glycol stearate.
Preferably, the thickener is selected from at least one of sodium chloride, cocamide MEA, PEG-120 methyl glucose dioleate, polyacrylate copolymer.
Preferably, the organic zinc contains zinc pyrithione, zinc lactate and zinc yeast, wherein the zinc yeast is 0.01-3 parts, the Zinc Pyrithione (ZPT) is 0.1-2 parts, the zinc lactate is 0.01-0.5 part, and the mass ratio of the zinc lactate, the zinc pyrithione to the zinc yeast is preferably 0.1:1: 0.5.
Preferably, the hair conditioning agent is selected from at least one of dimethicone emulsion, PEG-7 glyceryl cocoate, PPG-3 octyl ether, isostearyl alcohol pivalate.
Preferably, the flavour is a flavour and/or menthol.
Preferably, the preservative is at least one selected from the group consisting of cason, phenoxyethanol, and sodium benzoate.
Preferably, the pH adjusting agent is citric acid and/or sodium hydroxide.
Preferably, the shampoo takes a sulfate surfactant as a main surfactant and comprises the following raw materials in parts by weight: 12-20 parts of sodium laureth sulfate, 1-5 parts of sodium laureth sulfate, 3-10 parts of cocamidopropyl betaine, 0-5 parts of alkyl glucoside, 0-5 parts of disodium cocoyl glutamate, 0.5-3.0 parts of cocamide MEA, 0.5-2 parts of ethylene glycol distearate, 0.1-0.5 part of cetostearyl alcohol, 1-3 parts of polyacrylic acid (ester) copolymer, 0.5-1 part of Zinc Pyrithione (ZPT), 0.05-0.5 part of zinc lactate, 0.01-1 part of yeast zinc, 0.5-4 parts of polydimethylsiloxane emulsion, 0.05-0.2 part of zinc sulfate, 0.5-1.5 parts of essence, 0.1-0.5 part of menthol, 0.01-0.1 part of kason, 0.1-0.6 part of ethanoloxyphenoxy, 0-0.8 part of guar hydroxypropyltrimethyl ammonium chloride, 0.01-1 part of citric acid, 0.01-1 part of sodium chloride, the total amount is 100 parts, and the balance is water.
The invention also relates to a preparation method of the shampoo, which comprises the following steps:
(1) taking 50-70 parts of water, sodium laureth sulfate and sodium laureth sulfate as phase A for later use;
cocamide MEA, ethylene glycol distearate, cetearyl alcohol, cocamidopropyl betaine, alkyl glucoside and disodium cocoyl glutamate as phase B;
taking 3-5 parts of water and guar gum hydroxypropyl trimethyl ammonium chloride as a C phase for later use;
3-6 parts of water, zinc sulfate, zinc lactate, zinc pyrithione and zinc yeast are taken as a phase D for standby;
taking polydimethylsiloxane emulsion, essence, menthol, kasong and phenoxyethanol as an E phase for standby;
1-3 parts of water and acrylic acid (ester) copolymer are used as an F phase for standby;
taking 1-2 parts of water, citric acid and sodium chloride as a G phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) adding the raw materials in phase B into the main stirring pot one by one, keeping the temperature for 30-40min, and stirring until the raw materials are completely dissolved;
(4) cooling, adding phase C when the temperature is reduced to 60 deg.C, and stirring for 20-30 min;
(5) continuously cooling to 40-45 deg.C, dissolving the raw materials in phase D with water, adding into main stirring pan, and stirring;
(6) continuously cooling to normal temperature, adding the E-phase raw material, and uniformly stirring;
(7) uniformly stirring the phase F, and then adding the phase F into a main stirring pot to be uniformly stirred;
(8) adding the raw material of the G phase, specifically, adding citric acid to adjust the pH value to 5.5-6.5, adding sodium chloride to adjust the viscosity to 5000-30000 mPa.s, uniformly stirring and discharging.
Preferably, the shampoo takes an amino acid surfactant as a main surfactant and comprises the following raw materials in parts by weight:
15-30 parts of cocoyl disodium glutamate, 10-25 parts of cocamidopropyl betaine, 1-5 parts of alkyl glucoside, 1-5 parts of methyl cocoyl sodium taurate, 0.5-2 parts of ethylene glycol distearate, 0.1-0.5 part of guar hydroxypropyl trimethyl ammonium chloride, 1-3 parts of polyacrylate copolymer(s), 0.3-1.5 parts of glycerol laurate, 0-1.0 part of butanediol laurate, 0.5-3 parts of cocamidomethyl MEA (methyl MEA), 0.5-1.5 parts of PPG-3 octyl ether, 0.1-1.5 parts of isostearyl pivalate, 0.05-0.5 part of zinc lactate, 0.01-1 part of yeast zinc, 1-2 parts of Zinc Pyrithione (ZPT), 0.1-1 part of phenoxyethanol, 0.1-0.5 part of sodium benzoate, 0.05-0.2 part of zinc sulfate, 0.2 part of essence, 0.2-1.0 part of essence, 0.01-1 part of citric acid, 100 parts in total, and the balance of water.
The invention also relates to a preparation method of the shampoo, which comprises the following steps:
(1) taking 3-6 parts of water and guar gum hydroxypropyl trimethyl ammonium chloride as a phase A for later use;
taking 30-50 parts of water, disodium cocoyl glutamate, cocamidopropyl betaine, alkyl glucoside and sodium methyl cocoyl taurate as a B phase for later use;
taking ethylene glycol distearate, glycerol laurate, butanediol laurate, cocamidomethyl MEA, PPG-3 octyl ether and isostearyl alcohol pivalate as a C phase for later use;
3-6 parts of water, zinc sulfate, zinc lactate, zinc pyrithione and zinc yeast are taken as a phase D for standby;
taking essence, phenoxyethanol and sodium benzoate as an E phase for later use;
taking 1-2 parts of citric acid and water as an F phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) respectively adding the raw materials in the phase B into a main stirring pot, and stirring until the raw materials are completely dissolved;
(4) keeping the temperature to 75-80 ℃, respectively adding the raw materials in the phase C into the main stirring pot, stirring until the raw materials are completely dissolved, and then continuously stirring for 30-40 min;
(5) cooling, when the temperature is reduced to 40-45 ℃, uniformly stirring all the raw materials in the phase D, adding the mixture into a main stirring pot, and stirring for 20-30min until the mixture is uniformly mixed;
(6) respectively adding the raw materials in the phase E into a main stirring pot, and uniformly stirring;
(7) and (3) uniformly mixing the raw materials of the F phase, adding the mixture into a main stirring pot, adjusting the pH value to 5.5-6.5, uniformly stirring, and discharging.
The invention has the beneficial effects that:
the invention provides an organic zinc compound oil-control and anti-dandruff shampoo, which is prepared by applying three organic zinc, namely zinc lactate, zinc yeast and Zinc Pyrithione (ZPT) to shampoo, and finds that the oil-control and anti-dandruff effect is enhanced after compound. Wherein Zinc Pyrithione (ZPT) can inhibit fungi to reduce dandruff, and zinc yeast and zinc lactate increase scalp moisture retention, strengthen scalp barrier, and reduce discomfort caused by excessive scalp epithelial lipid secretion.
In the preferred embodiment of the present invention, the deposition level of zinc ions on the scalp is found to be an important factor in the effectiveness of oil control and dandruff control, and the effect of different surfactant systems on the deposition of zinc ions on the scalp is different. The surfactant system provided by the invention can better deposit zinc ions and improve the utilization rate of the zinc ions.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
Aiming at the problems that the oil control product on the market at present mostly uses a single oil control component, the oil control effect is poor, the effect persistence is poor and the like, the shampoo disclosed by the invention is compounded with three oil control functional components, including zinc lactate, zinc yeast and Zinc Pyrithione (ZPT), and researches show that the zinc has a good oil control effect. The oil control mechanism of zinc includes: 1) inhibiting 5 alpha-reductase which converts testosterone to dihydrotestosterone, thereby reducing stimulation of sebaceous gland production by dihydrotestosterone; 2) inhibiting bacterial lipase on the skin, thereby inhibiting the bacteria from catalyzing the breakdown of triglycerides in sebum into free fatty acids.
The zinc added into the cosmetic can be divided into organic zinc and inorganic zinc (such as zinc sulfate and zinc chloride), and the inorganic zinc has abundant resources and lower price than the organic zinc. But the organic zinc has less irritation, high chemical stability and high bioavailability compared with inorganic zinc, and can be absorbed and utilized by cells of a human body more.
The zinc lactate, the yeast zinc and the ZPT all belong to organic zinc. Besides providing zinc ions, ZPT is commonly used in washing and caring products, is low in price but limited in bioavailability, so that yeast zinc and zinc lactate with high bioavailability are compounded on the basis of selecting ZPT, and the oil control effect is enhanced after compounding. Zinc Pyrithione (ZPT) can also inhibit malassezia so as to achieve the function of removing dandruff, so that the compounded active substance has the efficacy of controlling oil and removing dandruff. The yeast zinc and the zinc lactate contain yeast extract and lactic acid, and can play a role in moisturizing and repairing scalp barriers and relieve discomfort caused by excessive scalp grease secretion. The following are details of the three raw materials:
zinc lactate under the trade namePurchased from Corbion corporation. Has effects in controlling oil, relieving itching, and inhibiting bacteria. In addition to providing zinc, lactic acid is also an important component of natural skin moisturizing factor (NMF), and can provide additional moisturizing effects.
Yeast zinc, available under the trade name Yeast essence Z20, was purchased from Angel Yeast Inc. The Angel zinc-rich yeast extract is obtained by enriching inorganic zinc element with yeast, and combining zinc with protein and amino acid in yeast, so that it has the following advantages: the combined form of zinc and small molecule polypeptide is easier to be absorbed through skin; the product is mild, and the irritation of inorganic zinc to the skin is reduced; the yeast fermentation metabolite also has good repairing effect on skin.
Zinc Pyrithione (ZPT), marketed as Zinc OmadineTM by Lonza, FDA's validation record (1991) allows ZPT to be used in the treatment of dandruff and seborrheic dermatitis. Dandruff occurs for three reasons: the first is malassezia, the second is grease secretion, and the third is individual susceptibility. ZPT has good antibacterial effect, and can inhibit growth of malassezia, an important fungus in dandruff occurrence.
By compounding the three zinc-rich organic active substances, the grease secretion can be more effectively inhibited compared with the single component, and the compounding and synergism effects are achieved. And ZPT can inhibit malassezia so as to inhibit dandruff, and in addition, three compounded components can synthesize other beneficial effects of a single component on skin, so that the oil control and dandruff removal effects are achieved, and the skin is more friendly. According to the experimental result, if too much compound zinc component is added, the oil control and anti-dandruff effect is rather reduced, so the selected oil control components are added with 0.01-3 parts of yeast zinc, 0.1-2 parts of Zinc Pyrithione (ZPT) and 0.01-0.5 part of zinc lactate. The purpose of adding zinc sulfate/zinc chloride on the basis is to prevent the ZPT from meeting trace iron ions in water to change the material body into grey or grey purple to influence the appearance of the product.
In addition, the invention achieves the purpose of enhancing the deposition of three zinc-rich organic active substances by compounding the anion and cation surfactants. Specifically, the sulfate shampoo is compounded with sodium laureth sulfate and disodium cocoyl glutamate with a dicarboxy end, so that the flocculation effect of the shampoo and a cationic polymer is enhanced, more oil control active ingredients are wrapped, and a more lasting oil control effect is achieved. In the case of the amino acid shampoo, the adopted main surfactant is disodium cocoyl glutamate, and the substance can increase the flocculation effect by itself.
Preparation of sulfate type shampoo
Example 1
(1) Taking 54.04 parts of water, 15 parts of sodium laureth sulfate and 2 parts of sodium laureth sulfate as a phase A for later use;
taking 1 part of cocamide MEA, 1 part of ethylene glycol distearate, 0.3 part of cetostearyl alcohol, 4 parts of cocamidopropyl betaine, 1 part of alkyl glucoside and 4 parts of disodium cocoyl glutamate as a phase B for standby;
4 parts of water and 0.3 part of guar gum hydroxypropyl trimethyl ammonium chloride are used as a C phase for later use;
taking 4 parts of water, 0.1 part of zinc sulfate, 0 part of zinc lactate, 0 part of zinc pyrithione and 0 part of yeast zinc as a phase D for later use;
taking 2.5 parts of polydimethylsiloxane emulsion, 0.5 part of essence, 0.1 part of menthol, 0.06 part of cason and 0.6 part of phenoxyethanol as an E phase for later use;
taking 2 parts of water and 1.5 parts of acrylic acid (ester) copolymer as an F phase for standby;
taking 2 parts of water, 0.5 part of citric acid, 0.5 part of sodium hydroxide and 1 part of sodium chloride as a G phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) adding the raw materials in phase B into the main stirring pot one by one, keeping the temperature for 30min, and stirring until the raw materials are completely dissolved;
(4) cooling, adding phase C when the temperature is reduced to 60 deg.C, and stirring for 20 min;
(5) continuously cooling to 40-45 deg.C, dissolving the raw materials in phase D with water, adding into main stirring pan, and stirring;
(6) continuously cooling to normal temperature, adding the E-phase raw material, and uniformly stirring;
(7) uniformly stirring the phase F, and then adding the phase F into a main stirring pot to be uniformly stirred;
(8) adding the G-phase raw material, specifically, adding citric acid to adjust the pH value to 6.0, adding sodium chloride to adjust the viscosity to 10000 mPa.s, uniformly stirring and discharging.
Examples 2-9 the experimental parameters were varied and the other procedures and tests were performed as in example 1, in the specific setup shown in table 1.
TABLE 1
Oil control capability test of shampoo
90 volunteers were recruited as subjects between the ages of 20 and 40. All volunteers were divided into 9 groups of 10 persons each, and the shampoos prepared in examples 1-9 were used for each group. Subjects did not wash their hair 24 hours prior to testing and baseline values were tested. After shampooing with the shampoo according to each example on site, the scalp (head top) oil value was measured at T0 instant, T2h, T4h, T6h, T8h, T20h, T24h and T26h, respectively, and then the oil control time of each group of subjects was averaged to obtain the oil control time for each example.
The oil control efficiency of the product is evaluated by comparing the change of indexes before and after use by adopting random and parallel control research, measuring the scalp oil content through an instrument Meibometer MB560 and evaluating a method of a researcher. The oil control time is the time for recovering the oil value of the scalp of a subject before hair washing, and the longer the oil control time is, the better the oil control effect of the product is.
Dandruff control test for shampoo
In addition, 90 volunteers with obvious dandruff were recruited as subjects, and all volunteers were divided into 9 groups of 10 persons each, and the shampoos prepared in examples 1 to 9 were used for each group. The head of all the subjects has excessive compound dandruff such as flaky white scale. All shampoo, hair care and daily chemical products with the anti-dandruff effect are stopped for the first two weeks. The subjects used the shampoo prepared in the above examples at least 3 times per week, and evaluated by a professional qualified dermatologist. Dandruff status was assessed prior to shampoo use and at 28 days of use, and the dandruff scores for each group of subjects were averaged to give a dandruff score for each example.
The clinical evaluation method comprises the following steps: the method adopts a ten-grade grading method of adhesive scurf, namely, grade 0 indicates no scurf, grade 1-2 indicates small powdery grey coarse scale, grade 3-4 indicates small to medium-sized chips, grade 5-6 indicates large and thin chips loosely connected with the scalp, grade 7-8 indicates large adhesive chips, and grade 9-10 indicates white to yellow thicker scales tightly attached to the scalp.
The results of the tests for oil control and anti-dandruff ability of the shampoo are shown in table 1.
Among them, example 1 is a blank control group without the tri-zinc oil control active ingredient, and it can be seen that the oil control time is shortest and the dandruff score is highest.
Example 2 the tri-zinc active ingredient was added in the optimum ratio, which has the best oil control and anti-dandruff effect.
The other raw materials of example 3 were the same as those of example 2 except that guar hydroxypropyltrimonium chloride was replaced with polyquaternium-10, which shows a great decrease in oil-controlling and anti-dandruff abilities, indicating that guar hydroxypropyltrimonium chloride is preferable as the cationic surfactant.
Example 4 without any cationic surfactant, the oil-controlling and anti-dandruff ability is further reduced compared with example 3, which shows that the selection of proper cationic surfactant contributes to the oil-controlling and anti-dandruff effect of the shampoo besides the organic zinc oil-controlling active ingredient.
Example 5 did not add yeast zinc compared to example 2, example 6 did not add zinc lactate compared to example 2, and example 7 did not add zinc pyrithione compared to example 2. Wherein the oil control time of examples 5 and 6 decreased greatly, and the dandruff score of example 7 increased greatly, indicating that yeast zinc and zinc lactate have a greater effect on scalp oil control, while zinc pyrithione contributed greatly to dandruff control.
Example 8 has higher concentration of tri-zinc than example 2, and example 9 has lower concentration of tri-zinc than example 2, and the oil control and anti-dandruff capability of the composition is reduced. The adding amount of the three-zinc oil control active ingredients is controlled within a proper range, so that better effects can be exerted.
Orthogonal experiment of sulfate shampoo
Examples 1-1 to 1-9 were designed by changing the amounts of yeast zinc, zinc lactate and zinc pyrithione in shampoo, while keeping other materials unchanged based on example 1, in order to design an orthogonal experiment to obtain the optimum amount of tri-zinc oil-control active ingredients. 80 volunteers were randomly divided into 8 groups, and oil control ability test was performed by the same test method as in the sulfate type shampoo, and the oil control time of examples 1-1 to 1-9 was recorded. The specific setup is shown in table 2, and the results of the orthogonal experiments are shown in table 3.
TABLE 2
TABLE 3
Zinc pyrithione | Yeast zinc | Zinc lactate | |
k1 | 13.80 | 16.73 | 17.80 |
k2 | 13.60 | 12.27 | 11.20 |
k3 | 11.87 | 10.27 | 10.27 |
K1 | 41.4 | 50.2 | 53.4 |
K2 | 40.8 | 36.8 | 33.6 |
K3 | 35.6 | 30.8 | 30.8 |
R (great difference) | 5.80 | 19.40 | 22.60 |
In Table 3, K1 is taken as an example of 13.80, which represents the average value of the oil control time when the amount of zinc pyrithione is 0.1, and K1 is the sum of the oil control time; taking k2 as an example of 13.60, the value represents the average value of the oil time when the zinc pyrithione addition amount is 1, and so on. The R (range) value is the sum of the maximum oil control time minus the minimum oil control time of the corresponding influence factors, and the larger the R value is, the larger the influence factor has larger influence on the oil control time.
From the oil-controlling time of Table 2, it is understood that the oil-controlling time is the maximum when the amount ratio of zinc pyrithione, zinc yeast and zinc lactate is 0.1:0.5: 0.1. From the R value, it can be seen that the effect of zinc lactate and zinc yeast on oil control time was greater than that of zinc pyrithione in the above test.
Preparation of amino acid type shampoo
Example 1'
(1) Taking 5 parts of water and 0.32 part of guar gum hydroxypropyl trimethyl ammonium chloride as a phase A for later use;
taking 34.48 parts of water, 20 parts of disodium cocoyl glutamate, 16 parts of cocamidopropyl betaine, 5 parts of alkyl glucoside and 5 parts of sodium methyl cocoyl taurate as a phase B for later use;
taking 1 part of ethylene glycol distearate, 0.4 part of glycerol laurate, 0.5 part of butanediol laurate, 1.5 parts of cocamidomethyl MEA, 0.5 part of PPG-3 octyl ether and 0.4 part of isostearyl pivalate as a C phase for standby;
taking 5 parts of water, 0.1 part of zinc sulfate, 0 part of zinc lactate, 0 part of zinc pyrithione and 0 part of zinc yeast as a phase D for later use;
taking 0.6 part of essence, 0.8 part of phenoxyethanol and 0.4 part of sodium benzoate as an E phase for later use;
taking 1 part of citric acid and 1 part of water as an F phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) respectively adding the raw materials in the phase B into a main stirring pot, and stirring until the raw materials are completely dissolved;
(4) keeping the temperature to 75-80 ℃, respectively adding the raw materials in the phase C into the main stirring pot, stirring until the raw materials are completely dissolved, and then continuously stirring for 30 min;
(5) cooling, when the temperature is reduced to 40-45 ℃, uniformly stirring all the raw materials in the phase D, adding the mixture into a main stirring pot, and stirring for 20min until the mixture is uniformly mixed;
(6) respectively adding the raw materials in the phase E into a main stirring pot, and uniformly stirring;
(7) and (3) uniformly mixing the raw materials of the F phase, adding the mixture into a main stirring pot, adjusting the pH value to 6.0, uniformly stirring, and discharging.
Example 2 ' -9 ' one experimental parameter was changed, and other operation steps and test procedures were the same as in example 1 ', and the specific setup was shown in table 4.
TABLE 4
180 volunteers were randomly divided into 18 groups, and oil control ability test and dandruff removing ability test were performed by the same test method as in the sulfate type shampoo. The test results are shown in Table 4.
Among them, example 1' is a blank control group without the tri-zinc oil control active ingredient, and it can be seen that the oil control time is the shortest and the dandruff score is the highest.
Example 2' the tri-zinc active ingredient was added in the optimum ratio, which has the best oil control and anti-dandruff effect.
The other raw materials of example 3' are the same as those of example 2 except that guar hydroxypropyltrimonium chloride is replaced with polyquaternium-10, which shows a great decrease in oil-controlling and anti-dandruff abilities, indicating that guar hydroxypropyltrimonium chloride is preferable as the cationic surfactant.
Example 4 'without any cationic surfactant, the oil-controlling and anti-dandruff ability is further reduced compared with example 3', which shows that the selection of proper cationic surfactant contributes to the oil-controlling and anti-dandruff effect of the shampoo besides the organic zinc and oil-controlling active ingredients.
Example 5 'did not add yeast zinc compared to example 2', example 6 'did not add zinc lactate compared to example 2', and example 7 'did not add zinc pyrithione compared to example 2'. Wherein the oil control time of examples 5 ' and 6 ' decreased more and the dandruff score of example 7 ' increased more, indicating that yeast zinc and zinc lactate had a greater effect on scalp oil control and zinc pyrithione contributed more to dandruff control.
Example 8 'increased the concentration of tri-zinc compared to example 2' and example 9 'decreased the concentration of tri-zinc compared to example 2', both of which decreased the oil control and anti-dandruff ability. The adding amount of the three-zinc oil control active ingredients is controlled within a proper range, so that better effects can be exerted.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. The organic zinc compound oil-control anti-dandruff shampoo is characterized by comprising the following raw materials in parts by weight: 0-20 parts of anionic surfactant, 0-0.8 part of cationic surfactant, 1-8 parts of amphoteric surfactant, 1-30 parts of amino acid surfactant, 0.1-1.5 parts of pearling agent, 1-3 parts of thickening agent, 0.01-6 parts of organic zinc, 0.1-3 parts of hair conditioner, 0.01-1 part of preservative, 0.01-1 part of pH value regulator, 0.1-2 parts of spice, 0.1-0.2 part of zinc sulfate/zinc chloride, 100 parts in total and the balance of water.
2. The shampoo according to claim 1, wherein the organozinc comprises zinc pyrithione, zinc lactate, and zinc yeast.
3. The shampoo according to claim 2, characterized in that the yeast zinc is 0.01-3 parts, the zinc pyrithione is 0.1-2 parts, and the zinc lactate is 0.01-0.5 part.
4. The shampoo according to any one of claims 1 to 3, wherein the anionic surfactant is selected from at least one of sodium laureth sulfate, sodium C14-16 olefin sulfonate, disodium lauryl sulfosuccinate;
and/or the cationic surfactant is selected from at least one of guar hydroxypropyl trimethyl ammonium chloride, polyquaternium-10 and polyquaternium-7, preferably guar hydroxypropyl trimethyl ammonium chloride.
5. Shampoo according to any of claims 1 to 3 characterised in that the amphoteric surfactant is selected from at least one of cocamidopropyl betaine, lauramidopropyl betaine, cocamidopropyl hydroxysultaine, sodium cocoamphoacetate;
and/or the amino acid surfactant is selected from at least one of sodium lauroyl sarcosinate, disodium cocoyl glutamate, sodium cocoyl alanine, sodium methyl cocoyl taurate and sodium cocoyl methyl taurate.
6. The shampoo according to any one of claims 1 to 3, wherein the pearlizing agent is selected from at least one of ethylene glycol distearate and ethylene glycol stearate;
and/or, the thickener is selected from at least one of sodium chloride, cocamide MEA, PEG-120 methyl glucose dioleate, polyacrylate copolymer;
and/or, the hair conditioner is selected from at least one of polydimethylsiloxane emulsion, PEG-7 glyceryl cocoate, PPG-3 octyl ether and isostearyl alcohol pivalate;
and/or the perfume is essence and/or menthol;
and/or the preservative is at least one selected from the group consisting of cason, phenoxyethanol, and sodium benzoate;
and/or the pH value regulator is citric acid and/or sodium hydroxide.
7. The shampoo according to claim 1, wherein the shampoo takes a sulfate surfactant as a main surfactant, and comprises the following raw materials in parts by weight: 12-20 parts of sodium laureth sulfate, 1-5 parts of sodium laureth sulfate, 3-10 parts of cocamidopropyl betaine, 0-5 parts of alkyl glucoside, 0-5 parts of disodium cocoyl glutamate, 0.5-3.0 parts of cocamide MEA, 0.5-2 parts of ethylene glycol distearate, 0.1-0.5 part of cetostearyl alcohol, 1-3 parts of polyacrylic acid (ester) copolymer, 0.5-1 part of zinc pyrithione, 0.05-0.5 part of zinc lactate, 0.01-1 part of zinc yeast, 0.5-4 parts of polydimethylsiloxane emulsion, 0.05-0.2 part of zinc sulfate, 0.5-1.5 parts of essence, 0.1-0.5 part of menthol, 0.01-0.1 part of kason, 0.1-0.6 part of phenoxyethanol, 0-0.8 part of guar hydroxypropyl ammonium chloride, 0.01-1 part of citric acid and 0.01-1 part of sodium chloride, the total amount is 100 parts, and the balance is water.
8. The preparation method of the shampoo as claimed in claim 7, characterized by comprising the following steps:
(1) taking 50-70 parts of water, sodium laureth sulfate and sodium laureth sulfate as phase A for later use;
cocamide MEA, ethylene glycol distearate, cetearyl alcohol, cocamidopropyl betaine, alkyl glucoside and disodium cocoyl glutamate as phase B;
taking 3-5 parts of water and guar gum hydroxypropyl trimethyl ammonium chloride as a C phase for later use;
3-6 parts of water, zinc sulfate, zinc lactate, zinc pyrithione and zinc yeast are taken as a phase D for standby;
taking polydimethylsiloxane emulsion, essence, menthol, kasong and phenoxyethanol as an E phase for standby;
1-3 parts of water and acrylic acid (ester) copolymer are used as an F phase for standby;
taking 1-2 parts of water, citric acid and sodium chloride as a G phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) adding the raw materials in phase B into the main stirring pot one by one, keeping the temperature for 30-40min, and stirring until the raw materials are completely dissolved;
(4) cooling, adding phase C when the temperature is reduced to 60 deg.C, and stirring for 20-30 min;
(5) continuously cooling to 40-45 deg.C, dissolving the raw materials in phase D with water, adding into main stirring pan, and stirring;
(6) continuously cooling to normal temperature, adding the E-phase raw material, and uniformly stirring;
(7) uniformly stirring the phase F, and then adding the phase F into a main stirring pot to be uniformly stirred;
(8) adding the raw material of the G phase, specifically, adding citric acid to adjust the pH value to 5.5-6.5, adding sodium chloride to adjust the viscosity to 5000-30000 mPa.s, uniformly stirring and discharging.
9. The shampoo according to claim 1, wherein the shampoo takes an amino acid surfactant as a main surfactant, and comprises the following raw materials in parts by weight:
15-30 parts of cocoyl disodium glutamate, 10-25 parts of cocamidopropyl betaine, 1-5 parts of alkyl glucoside, 1-5 parts of methyl cocoyl sodium taurate, 0.5-2 parts of ethylene glycol distearate, 0.1-0.5 part of guar hydroxypropyl trimethyl ammonium chloride, 1-3 parts of polyacrylate (type) copolymer, 0.3-1.5 parts of glycerol laurate, 0-1.0 part of butanediol laurate, 0.5-3 parts of cocamidomethyl MEA, 0.5-1.5 parts of PPG-3 octyl ether, 0.1-1.5 parts of isostearyl pivalate, 0.05-0.5 part of zinc lactate, 0.01-1 part of yeast zinc, 1-2 parts of zinc pyrithione, 0.1-1 part of ethanol, 0.1-0.5 part of sodium benzoate, 0.05-0.2 part of zinc sulfate, 0.2-1.0 part of essence and 0.01-1 part of citric acid, the total amount is 100 parts, and the balance is water.
10. The preparation method of the shampoo as claimed in claim 9, characterized by comprising the following steps:
(1) taking 3-6 parts of water and guar gum hydroxypropyl trimethyl ammonium chloride as a phase A for later use;
taking 30-50 parts of water, disodium cocoyl glutamate, cocamidopropyl betaine, alkyl glucoside and sodium methyl cocoyl taurate as a B phase for later use;
taking ethylene glycol distearate, glycerol laurate, butanediol laurate, cocamidomethyl MEA, PPG-3 octyl ether and isostearyl alcohol pivalate as a C phase for later use;
3-6 parts of water, zinc sulfate, zinc lactate, zinc pyrithione and zinc yeast are taken as a phase D for standby;
taking essence, phenoxyethanol and sodium benzoate as an E phase for later use;
taking 1-2 parts of citric acid and water as an F phase for later use;
(2) cleaning the main stirring pot, starting stirring, adding the raw materials in the phase A into the main stirring pot one by one, heating to 75-80 ℃, and stirring until the phase A is completely dissolved;
(3) respectively adding the raw materials in the phase B into a main stirring pot, and stirring until the raw materials are completely dissolved;
(4) keeping the temperature to 75-80 ℃, respectively adding the raw materials in the phase C into the main stirring pot, stirring until the raw materials are completely dissolved, and then continuously stirring for 30-40 min;
(5) cooling, when the temperature is reduced to 40-45 ℃, uniformly stirring all the raw materials in the phase D, adding the mixture into a main stirring pot, and stirring for 20-30min until the mixture is uniformly mixed;
(6) respectively adding the raw materials in the phase E into a main stirring pot, and uniformly stirring;
(7) and (3) uniformly mixing the raw materials of the F phase, adding the mixture into a main stirring pot, adjusting the pH value to 5.5-6.5, uniformly stirring, and discharging.
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