CN108685736A - A kind of detergent composition and its application - Google Patents
A kind of detergent composition and its application Download PDFInfo
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- CN108685736A CN108685736A CN201810833173.XA CN201810833173A CN108685736A CN 108685736 A CN108685736 A CN 108685736A CN 201810833173 A CN201810833173 A CN 201810833173A CN 108685736 A CN108685736 A CN 108685736A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of detergent composition and its applications, including following component:0-90%(A)N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt;5-40%(B)N- long-chain fatty acyl group N-methyltaurines and/or its salt;0.5-2%(C)PPG-2 hydroxyethyl cocamides and/or olive oil PEG-7 esters and/or PEG-7 glyceryl cocoates;0.1%-3.5%(D)Oil components and/or essence.The present invention passes through in the N- acyl amino acid type surfactants of N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt; and on the basis of adding a large amount of essence or oil components, by the component for adding specific compounding ratio(B)And component(C)It is compounded, the detergent composition being prepared remains as transparent appearance, and has viscosity appropriate and foam volume, and good fragrant atmosphere experience or moisture feeling can be brought while using, can be widely used in the cosmetics such as cleaning products or hair washing product.
Description
Technical field
The present invention relates to biotechnology, more particularly to a kind of detergent composition and its application.
Background technology
Fine smell can not only allow people to be in a cheerful frame of mind, and also bring along unexpected temptation effect.Fragrant atmosphere bathing is general
Just much more popular market is read, fragrant extraction of the atmosphere from plants and flowers keeps permanent fragrant breath, pleasant mental and body after with.
In fact, skin is also to have temper, and busy especially in city life brings heavy pressure and influence instantly for skin, beautiful
Wonderful fragrant atmosphere product, had both brought carefree atmosphere, more can advanced optimize skin state.
Oil components, such as vitamin E, vegetable fat or animal fat etc. can provide moist and opsonic action for skin.
However, the conventional anions such as laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and C14-16 alkene sulfonic acid sodiums
The formula that table is lived still can guarantee the formula transparency in the case that oil components and/or a large amount of essence is added, but its irritation compared with
It is high.Simultaneously because its residual on human body is higher, continues wiping after crossing water frequent occurrence and the case where foam occur, thus into
One step provides residue for stimulation.
Amino acid table, which is lived, has irritation low, safe to use, nontoxic, the preferable feature of biological degradability.
But amino acid table can lead to muddiness in living in the case where adding oil components and/or a large amount of essence, put for a long time
It sets and will appear the case where oil-phase component floats on the surface, to which stability is poor.Traditional solubilization method is using such as TWEEN Series
With the solubilizer of PEG-40/60 rilanit specials, but its solubilising power is limited, while it has reduces dispensing viscosity and foam uses
The characteristics of sense.Meanwhile in the case where adding a large amount of essence, viscosity is substantially reduced.It has been recognized that the formula that viscosity is high
Active matter content is high, and higher viscosity will not cause detergent from spill and leakage on hand, have good performance.
Invention content
In order to solve the above technical problems, the primary purpose of the present invention is that provide a kind of detergent composition, it is big in addition
While measuring essence or oil components, the composition is still transparent appearance, and has viscosity appropriate and foam volume, is being used
While good fragrant atmosphere can be brought to give sympathetic consideration to and moisture feeling.
The technical solution adopted by the present invention is as follows:
A kind of detergent composition, by weight percentage, including following component:
(A)N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt 0-90%;
(B)N- long-chain fatty acyl group N-methyltaurines and/or its salt 5-40%;
(C)PPG-2 hydroxyethyl cocamides and/or olive oil PEG-7 esters and/or PEG-7 glyceryl cocoates 0.5-2%;
(D)Oil components and/or essence 0.1%-3.5%.
Wherein, the component(B):Component(C)Compounding weight ratio be(5-40):(0.5-2.0).
Only adjust component(B):Component(C)Compounding weight ratio be(5-40):(0.5-2.0), the washing that is prepared
Agent composition is still transparent appearance, and has viscosity appropriate and foam volume, and good perfume (or spice) can be brought while using
Atmosphere is given sympathetic consideration to and moisture feeling.And work as component(B):Component(C)Compounding weight ratio it is excessive(More than 40:0.5), the washing that is prepared
Agent composition is unable to reach ideal solubilizing effect, therefore is unable to reach good fragrant atmosphere and gives sympathetic consideration to or moisture feeling, and dispensing viscosity
Less than preferred proportion;And work as component(B):Component(C)Compounding weight ratio it is too small(Less than 5:2.0), the detergent that is prepared
Composition is unable to reach ideal solubilizing effect and foam volume, therefore is unable to reach good fragrant atmosphere and gives sympathetic consideration to or moisture feeling.
Preferably, the component(B):Component(C)Compounding weight ratio be(10-40):(1.0-1.8), more preferably
(15-40):1.5.
Wherein, component in the present invention(A)N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl groups are modified
Amino acid and/or its salt can be obtained by known method.For example, between amino acid and fatty acid halide
Schotten-Baumann reactions are well-known method.
Instant component(A)Amino acid, can use acidic amino acid such as glutamic acid and aspartic acid, neutral amino
Sour such as alanine and threonine and basic amino acid such as arginine, lysine and ornithine, modified propylhomoserin such as flesh ammonia
Acid and methylalanine, N-methyltaurine.These amino acid and modified amino acid can be L- isomers, D- isomers, DL- different
The mixture of structure body or the above isomers of above two.They can be used alone or two kinds and two or more aforementioned substances
It is used in mixed way.
Component(A)Fatty acyl group group, can use 8-22 carbon saturation and unsaturated fatty acid derived from branched fatty acyl
Base group, aliphatic acid example include octanoic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palmitic acid, oleic acid,
The fatty acid of linoleic acid, behenic acid, coco-nut oil fatty acid, PALM FATTY ACID, hydrogenated animal, octanoic acid, undecanoic acid, tridecanoic acid, 15
Acid, heptadecanoic acid, nonadecanoic acid, heneicosoic acid etc..They can be used alone or two kinds and two or more aforementioned substances mixing make
With.In view of excellent foaming capacity and quality, froth, particularly preferred coco-nut oil fatty acid, palm kernel fatty acid, lauric acid
And myristic acid.
Component(A)Salt be not particularly limited, example includes inorganic salts, such as alkali metal such as sodium and potassium, alkaline earth gold
Belong to calcium and magnesium, aluminum and zinc, organic salt, such as ammonia, organic amine such as monoethanolamine, diethanol amine and triethanolamine, and alkalinity
The salt of amino acid such as arginine and lysine.They can be used alone or two kinds and two or more aforementioned substances mixing make
With.In view of easily acquirement property and operability, preferred as alkali salt, organic amine salt and basic amino acid salt, and it is especially excellent
Select the salt of sodium, potassium, triethanolamine, arginine and N-methyltaurine sodium.
Preferably, the component(A)Selected from cocoamido sodium propionate, sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid
Sodium, cocoyl glutamic acid TEA salt, sodium cocoyl glutamate, cocounut oil acyl disodium glutamate, lauroyl methylaminopropionic
The mixing of one or more of sodium, lauroyl methylaminopropionic acid TEA salt and lauroyl NaAsp.
Preferably, the component(B)Selected from sodium methyl cocoyl taurate, methyl cocoyl taurine potassium, methyl
Lauroyl sodium taurocholate, sodium methyl palmitoyl taurate, methyl myristoyl sodium taurocholate, cocounut oil acyl methyl taurine
The mixing of one or more of sodium taurocholate and methyl cocoyl taurine.
Preferably, the component(D)Oil components in vitamin E, Synthetic Oil, vegetable fat, animal fat
One or more of mixing.
The detergent composition of the present invention, can under the premise of not reducing effect of the present invention in addition to above-mentioned main component
With a variety of suitable components suitably used containing ordinary cosmetics, special cosmetics etc..More specifically, it may include oil
Agent, thickener, preservative, essence, ultra-violet absorber, wetting agent, physiologically active ingredient, antioxidant, resists surfactant
Scorching agent, antiseptic, anhidrotic, chelating agent, neutralizer, pH adjusting agent etc., and can be contained according to specific purposes and form
There are said components.Produce the detergent composition of the present invention by common method, and liquid and gel may be used etc.
Form.It is suitable as the cosmetics of skin, hair etc..
The application that the present invention also provides said detergent compositions in cosmetics.The detergent composition of the present invention
Purposes is not particularly limited, but can provide a variety of cosmetics.Its example includes:Cleaning supplies such as cleanser(Including face cleaning
Foam, liquid gel, wetting agent etc.), shampoo, makeup removing agent and detergent, substrate product such as hair treating agent(Including spraying
The product of product, gel products, other forms)And shaving cream(Shave Gel miles, shaving cream etc.), etc..In view of amino acid changes
The use scope that acidic amino acid table is lived, is preferred for cleaning products and hair washing product.
Compared with prior art, the present invention having the advantages that:
The present invention by N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its
It is special by adding in the N- acyl amino acid type surfactants of salt, and on the basis of adding a large amount of essence or oil components
Surely the component of ratio is compounded(B)And component(C)It is compounded, the detergent composition being prepared remains as transparent appearance, and has
There are viscosity appropriate and foam volume, good fragrant atmosphere can be brought to give sympathetic consideration to or moisture feeling while using, can be widely used for
In the cosmetics such as cleaning products or hair washing product.
Specific implementation mode
It is further illustrated the present invention below by specific implementation mode, but embodiments of the present invention are not by following realities
Apply the limitation of example.
Raw material used in the embodiment of the present invention and comparative example derives from purchased in market.
The test method or evaluation method of each performance indicator:
The test method of the transparency of detergent composition:Sample is placed in 100ml Clear glass bottles and jars, in room temperature and non-sunlight
Direct projection visual observations(Transparent effect:Tou Ming >Meng Long >Hun Zhuo >Gonorrhoea).
The test method of the viscosity of detergent composition:Brookfiled DV-C digital display viscosimeters, No. 63 rotors, rotating speed
20rpm expects temperature:25 DEG C, the reading duration:It is read at 1 minute after startup.
The test method of the foam height of detergent composition:According to"GB/T 29679-2013 shampoos, hair cream"
Middle method is detected.
The fragrant atmosphere of detergent composition gives sympathetic consideration to evaluation method:Tested number:13 people;Position on probation:Body;Application method:
Clean body is carried out using detergent composition;Then to aromaticity and lasting persistence(After 12 hours)It is tested, is tried out
After fill in questionnaire(It is 0-5 points, weak-strong), then statistical average score, the results are shown in Table 1.
The evaluation method of the moist degree of detergent composition:Tested number:13 people;Position on probation:Arm;Application method:
It is cleaned using detergent composition;Questionnaire is filled in after on probation(It is 0-5 points, dry-to moisten), then statistical average obtains
Point, the results are shown in Table 1.
Embodiment 1-7 and comparative example 1-6:
By shown in table 1 be formulated, according to table 1 proportioning by water,(A)N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chains
Fatty acyl group modified amino acid and/or its salt,(B)N- long-chain fatty acyl group N-methyltaurines and/or its salt stir evenly, and are heated to
Set point of temperature, is added glycerol monolaurate, and stirring and dissolving will after being cooled to set point of temperature(C)PPG-2 hydroxyethyl cocamides
And/or olive oil PEG-7 esters and/or PEG-7 glyceryl cocoates and(D)Oil components and/or essence premix dissolving,
Then it is added and stirs evenly, be added surplus material after cooling, the 100% of moisturizing to formula ratio, it stirs evenly and adjusts pH to providing
To get detergent composition after range, the results are shown in Table 1 for test performance.
The each component weight percent of 1 embodiment and comparative example of table when each the performance test results
Note:Component D is essence, tests fragrant atmosphere and gives sympathetic consideration to;Component D is vitamin E, tests and moistens degree.
The present invention is by N- long-chain fatty acyl group amino acid and/or its salt it can be seen from the embodiment and comparative example of table 1
And/or in the N- acyl amino acid type surfactants of N- long-chain fatty acyl group modified amino acids and/or its salt, and it is a large amount of in addition
On the basis of essence or oil components, by the component for adding specific compounding ratio(B)And component(C)It is compounded, is prepared
Detergent composition remain as transparent appearance, and there is viscosity appropriate and foam volume, can be brought while using
Good perfume atmosphere is given sympathetic consideration to or moisture feeling, can be widely used in the cosmetics such as cleaning products or hair washing product.
Claims (7)
1. a kind of detergent composition, which is characterized in that by weight percentage, including following component:
(A)N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt 0-90%;
(B)N- long-chain fatty acyl group N-methyltaurines and/or its salt 5-40%;
(C)PPG-2 hydroxyethyl cocamides and/or olive oil PEG-7 esters and/or PEG-7 glyceryl cocoates 0.5-2%;
(D)Oil components and/or essence 0.1%-3.5%.
2. detergent composition according to claim 1, which is characterized in that the component(B):Component(C)Compounding weight
Measuring ratio is(5-40):(0.5-2.0), preferably(10-40):(1.0-1.8), more preferably(15-40):1.5.
3. detergent composition according to claim 1, which is characterized in that the component(A)Selected from cocoamido third
Sour sodium, sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, cocoyl glutamic acid TEA salt, sodium cocoyl glutamate, coconut palm
Oleoyl disodium glutamate, lauroyl methylaminopropionic sodium, lauroyl methylaminopropionic acid TEA salt and lauroyl asparagus fern ammonia
One or more of mixing of sour sodium.
4. detergent composition according to claim 1, which is characterized in that the component(B)Selected from methyl cocoyl
Sodium taurocholate, methyl cocoyl taurine potassium, methyl lauroyl sodium taurocholate, sodium methyl palmitoyl taurate, methyl
One or more of myristoyl sodium taurocholate, cocounut oil acyl methyl taurine sodium taurocholate and methyl cocoyl taurine
Mixing.
5. detergent composition according to claim 1, which is characterized in that the component(D)Oil components be selected from dimension
The mixing of one or more of raw element E, Synthetic Oil, vegetable fat, animal fat.
6. application of the claim 1-5 any one of them detergent compositions in cosmetics.
7. application according to claim 6, which is characterized in that the cosmetics are cleaning products or hair washing product.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102199498A (en) * | 2004-09-13 | 2011-09-28 | 味之素株式会社 | Detergent composition |
CN107157847A (en) * | 2017-06-19 | 2017-09-15 | 宁波上山打老虎日化有限公司 | Improve a kind of Chinese medicine preparation composition of hair healthy and preparation method thereof |
CN107349135A (en) * | 2017-07-11 | 2017-11-17 | 上海韵宜生物科技有限公司 | A kind of transparent cleansing composition and preparation method thereof |
CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
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2018
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102199498A (en) * | 2004-09-13 | 2011-09-28 | 味之素株式会社 | Detergent composition |
CN107157847A (en) * | 2017-06-19 | 2017-09-15 | 宁波上山打老虎日化有限公司 | Improve a kind of Chinese medicine preparation composition of hair healthy and preparation method thereof |
CN107349135A (en) * | 2017-07-11 | 2017-11-17 | 上海韵宜生物科技有限公司 | A kind of transparent cleansing composition and preparation method thereof |
CN107898654A (en) * | 2017-10-23 | 2018-04-13 | 广州市白云联佳精细化工厂 | Amino acid shampoo composition and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109288719A (en) * | 2018-11-23 | 2019-02-01 | 广州市科能化妆品科研有限公司 | A kind of mild shampoo composition and preparation method thereof |
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