CN108553334A - A kind of hair care composition of the smooth not silicate-containing oil of maintenance and its application - Google Patents

Abstract

The present invention provides a kind of hair care composition of the smooth not silicate-containing oil of maintenance and its application, the composition includes 0.1 0.5% hydrolyzed wheat protein and 0.1 0.5% hydrolysed corn starch by weight percentage；The present invention is by rationally compounding hydrolyzed wheat protein and hydrolysed corn starch, blend proportion is adjusted, the two is synergistic, is added in no silicone oil shampoo, the smoothness of hair can not only be improved, and adsorbance of the guar hydroxypropyltrimonium chloride on hair can be obviously increased；Present invention process is simple, it can be achieved that industrialization large-scale production, can be that enterprise brings good economic benefit, have wide foreground.

Description

A kind of hair care composition of the smooth not silicate-containing oil of maintenance and its application

Technical field

The present invention relates to field of daily chemicals, it is related to a kind of hair care composition and its application, more particularly to a kind of The hair care composition of the smooth not silicate-containing oil of maintenance and its application.

Background technology

Currently, shampoo on the market is largely containing silicone oil.As conditioner, silicone oil component is answered in shampoo With extensive, silicone oil can make hair more smooth, be easy to comb.But highly viscous water-insoluble silicone oil is easy in hair scalp Upper generation accumulation, prevents moisture and other nursing compositions from moistening hair and scalp, and silicone oil is not degradable, can bring environment Pollution.

Therefore, the today increasingly promoted in health environment-friendly idea, not the shampoo of silicate-containing oil have become a great city Field demand and developing direction.Currently, the smoothness after the shampoo use of silicate-containing oil is not less than washing for silicate-containing oil generally in the market Shampoo, this is that no silicone oil shampoo still needs to solve the problems, such as.In addition, without the melon for usually adding high level in silicone oil shampoo Glue hydroxypropyl-trimethyl ammonium chloride or Polyquaternium-10 improve the smoothness of hair as cation opsonizing agent.Nitrogen content height, The big cation opsonizing agent of molecular weight can be obviously improved Hair setting, if deposition of the cation opsonizing agent on hair When too small, the especially dry hair-like state of cardability of hair can feel apparent coarse short-tempered.

CN106539704A discloses a kind of Haircare composition containing wheat gluten, preparation method and in hair conditioner Using including following component by weight percentage：Modified hydrolyzed wheat gluten 3-8%, silicone oil compound 2-4%, Betaine type amphoteric surfac-tant 1.5-3%, cationic surfactant 2-3%, thickener 4-8%, water 75-85%, should The invention the advantages of reparation hair of hydrolyzed wheat protein is utilized, improve the easy cardability after hair conditioning, and pass through by Hydrolyzed wheat protein modification can avoid the long-term damage of hair to avoid the raising of silane-deposited amount.CN104887578A is related to And the composition and hair conditioner with scalp care function of a kind of not silicate-containing oil, by the group for including following mass percentage content At least any four component is made in point：Hydrolysed corn starch 0.1-2%, piroctone olamine salt 0.1-2%, pyrrolidones Carboxylic acid sodium 0.1-2%, hydrolysed rice albumen 0.1-1%, polyglutamic acid sodium 0.1-1%, pipewort flower/stem extraction 0.01- 1%, raspberry juice 0.01-1%, leaf of Mentha piperita extract 0.01-1%, ginger-root extract 0.01-1% and camellia seed oil 0.01-1%.The composition and hair conditioner property of the invention are mild, non-stimulated, can be directly applied to scalp, and it is submissive to wash rear hair, And with moisturizing, nourishing, antipruritic, antibacterial effect, can mitigate head itch, dandruff problem；Silicone oil is substituted using vegetable fat, is had Effect avoids the scalp problems because caused by gathering silicone oil.CN1698574A discloses a kind of comprising natural and/or synthesized polymer Object as key component hair fixative film and be related to it is a kind of by the film apply hair on method.This film is for keeping Required hair appearance and moulding, it includes：(a) at least one hair fixative polymer, is selected from octyl acrylamide/the third Olefin(e) acid ester/methacrylic acid Butylaminoethyl ester, VA/ crotonates/neodecanoic acid vinyl ester copolymer, polystyrolsulfon acid Sodium, acrylate copolymer, polyurethane, xanthans, the starch of physical modification, the starch of chemical modification, polyquaternium- 10, polyquaternium-4, polyvinylpyrrolidone, polyvinylpyrrolidone/vinyl acetate copolymer and it Mixture；(b) it is based on hair fixative film total weight, the plasticizer of 5-30 weight %, the plasticizer is selected from the third two Alcohol, glycerine, dipropylene glycol, the wheat gluten of hydrolysis, the wheaten starch of hydrolysis, PEG-12 dimethyl siloxanes and theirs is mixed Close object；Wherein when based on hair fixative total polymer weight hair fixative polymer include at least 60% w/w day When right polymer, the amount based on natural polymer weight meter plasticizer is more than 15%, and wherein hair fixative film thickness Degree is 1-500 microns.But the problems such as above-mentioned prior art component is various, smoothness for no silicone oil shampoo and short-tempered property Technique effect is to be improved, and preparation process is complicated, is an impediment to marketing and application.

In conclusion providing a kind of problem that the smoothness that can be improved after no silicone oil shampoo use is relatively low, can also change The hair care composition of the short-tempered problem of hair coarse after kind cation opsonizing agent use, have broad application prospects with it is huge Big market value.

Invention content

In view of the deficiencies of the prior art with actual demand, the present invention provides a kind of hair care composition and its answer With more particularly to a kind of smooth not silicate-containing oil of maintenance hair care composition and its application, by by hydrolyzed wheat protein and Hydrolysed corn starch rationally compounds, and adjusts blend proportion, the two is synergistic, is added in no silicone oil shampoo, can not only The smoothness of hair is improved, and can obviously increase the irritated coarse problem of reduction hair, has wide foreground.

To achieve the above object, the present invention provides the following technical solutions：

In a first aspect, the present invention provides a kind of hair care composition, the hair care composition is by weight percentage The hydrolysed corn starch of hydrolyzed wheat protein and 0.1-0.5% including 0.1-0.5%.

In the present invention, hydrolyzed wheat protein has splendid repair rich in the amino acid contained in a variety of hairs, to hair Effect is protected, hydrolysed corn starch, which is a kind of good skin conditioner and moisturizer, correct leatherware, good nursing efficacy, and Hair can be made to keep moist, smooth.The two is synergistic in particular range, indispensable, can significantly improve hair Smoothness, hence it is evident that increase adsorbance of the cation opsonizing agent on hair.

Preferably, the molecular weight of the hydrolyzed wheat protein is 1000-1800 dalton, such as can be 1000 dongles , 1400 dalton, 1450 dalton, 1500 dalton, 1550 dalton, 1600 dalton or 1800 dalton, preferably 1400-1600 dalton.

The present invention uses molecular weight for the hydrolyzed wheat protein of 1500 or so dalton, protein hydrolysate molecule can all or Partial penetration enters cortex or cuticula, has and repairs damaged hair bar, repairing hair scale piece and other effects；In addition, hydrolysed corn starch Molecular weight is larger, is easy to form a film on hair, and then improves smoothness, can repair hair bifurcated, moisturizing and keep hair brilliance bright Pool, the two compounding, can play superior efficacy；And the hydrolyzed wheat protein that uses of the present invention and prior art CN104887578A The effect of the effect of hydrolysed rice albumen of use is different, hydrolysed rice albumen are to resist ultraviolet light.

Preferably, the weight percent of the hydrolyzed wheat protein for example can be 0.1%, 0.2%, 0.3%, 0.4% Or 0.5%.

Preferably, the weight percent of the hydrolysed corn starch for example can be 0.1%, 0.2%, 0.3%, 0.4% Or 0.5%.

Second aspect, the present invention provide a kind of hair care composition as described in relation to the first aspect and wash shield product as preparation Purposes.

The third aspect, the present invention provide a kind of amino acid pattern shampoo of the smooth not silicate-containing oil of maintenance, the shampoo Raw material includes the hair care composition described in first aspect.

Preferably, the raw material of the shampoo further includes sodium lauroyl sarcosine, Cocoamidopropyl betaine, decyl Portugal Glucosides, coconut oleoyl amine methyl MEA and guar hydroxypropyltrimonium chloride etc..

In the prior art, silicone oil adhesive ability is strong, and especially highly viscous water-insoluble silicone oil is easy on hair scalp Accumulation is generated, prevents moisture and other nursing compositions from moistening hair and scalp.Higher contain usually is added in no silicone oil shampoo The guar hydroxypropyltrimonium chloride or Polyquaternium-10 of amount improve the smoothness of hair as cation opsonizing agent, If deposition of the cation opsonizing agent on hair is too small, the especially dry hair-like state of cardability of hair can feel apparent coarse It is short-tempered；The present invention is applied in shampoo by rationally compounding the hydrolyzed wheat protein of small-molecular-weight and hydrolysed corn starch, The smoothness of hair can significantly be improved, hence it is evident that increase cation opsonizing agent, especially melon glue Hydroxyproyl Trimethyl chlorination Adsorbance of the ammonium on hair.

Preferably, weight percent of the sodium lauroyl sarcosine in the shampoo is 20-30%, such as can be with It is 20%, 22%, 24%, 26%, 28% or 30%.

Preferably, weight percent of the Cocoamidopropyl betaine in the shampoo is 6-15%, such as Can be 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14% or 15%.

Preferably, weight percent of the Plantacare 818 in the shampoo is 1-3%, such as can be 1%, 2% or 3%.

Preferably, weight percent of the coconut oleoyl amine methyl MEA in the shampoo is 1-2%, such as can be with It is 1%, 1.5% or 2%.

Preferably, weight percent of the guar hydroxypropyltrimonium chloride in the no silicone oil shampoo is 0.3-0.4%, such as can be 0.3%, 0.35% or 0.4%.

Preferably, the shampoo includes the water of the hydrolyzed wheat protein of 0.1-0.5%, 0.1-0.5% in parts by weight Solve the decyl glucose of cornstarch, the sodium lauroyl sarcosine of 20-30%, the Cocoamidopropyl betaine of 6-15%, 1-3% Glycosides, 1-2% coconut oleoyl amine methyl MEA and 0.3-0.4% guar hydroxypropyltrimonium chloride.

Preferably, the raw material of the shampoo further includes preservative, complexing agent, pH adjusting agent, essence and deionized water.

Preferably, the preservative is the combination of sodium benzoate and Phenoxyethanol.

Preferably, the complexing agent is EDETATE SODIUM.

Preferably, the pH adjusting agent is the combination of citric acid and sodium citrate.

In the present invention, preservative, complexing agent, pH conditioners, essence and water additive amount made rationally according to different situations Adjustment.

Fourth aspect, the present invention provide a kind of preparation method of the amino acid pattern shampoo of the smooth not silicate-containing oil of maintenance, packet Include following steps：

(1) guar hydroxypropyltrimonium chloride is added in the retort for filling deionized water in proportion and is slowly stirred Disperseed；

(2) sodium lauroyl sarcosine, cocamidopropyl propyl amide beet are proportionally added into after heating the retort of step (1) Alkali, Plantacare 818, coconut oleoyl amine methyl MEA, sodium benzoate, EDETATE SODIUM, pH adjusting agent carry out dispersing and dissolving；

(3) Phenoxyethanol, hydrolyzed wheat protein, hydrolysed corn is proportionally added into after the retort of step (3) cooling down to form sediment Powder and essence examine lotion after stirring evenly, and obtain the no silicone oil shampoo.

Preferably, the weight percent of step (1) described guar hydroxypropyltrimonium chloride is 0.3-0.4%, example Such as can be 0.3%, 0.35% or 0.4%

Preferably, the temperature of step (2) described heating be 60-80 DEG C, such as can be 60 DEG C, 65 DEG C, 70 DEG C, 75 DEG C or 80℃。

Preferably, the weight percent of step (2) described sodium lauroyl sarcosine is 20-30%, such as can be 20%, 22%, 24%, 26%, 28% or 30%.

Preferably, the weight percent of step (2) described Cocoamidopropyl betaine is 6-15%, such as can be 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14% or 15%.

Preferably, the weight percent of step (2) described Plantacare 818 be 1-3%, such as can be 1%, 2% or 3%.

Preferably, the weight percent of step (2) the coconut oleoyl amine methyl MEA is 1-2%, such as can be 1%, 1.5% or 2%.

Preferably, the weight percent of step (2) described EDETATE SODIUM is 0.1-0.2%, such as can be 0.1%, 0.15% or 0.2%.

Preferably, the temperature of step (3) described cooling is 40-50 DEG C, for example, can be 40 DEG C, 42 DEG C, 44 DEG C, 46 DEG C, 48 DEG C or 50 DEG C.

Preferably, the weight percent of step (3) described hydrolysed corn starch is 0.1-0.5%, such as can be 0.1%, 0.2%, 0.3%, 0.4% or 0.5%.

Preferably, the weight percent of step (3) described hydrolyzed wheat protein is 0.1-0.5%, such as can be 0.1%, 0.2%, 0.3%, 0.4% or 0.5%.

Preferably, step (3) it is described to examine the temperature of lotion be 35-40 DEG C, such as can be 35 DEG C, 36 DEG C, 37 DEG C, 38 DEG C, 39 DEG C or 40 DEG C.

As optimal technical scheme, a kind of preparation method of the amino acid pattern shampoo of the smooth not silicate-containing oil of maintenance, specifically Include the following steps：

(1) the guar hydroxypropyltrimonium chloride addition that weight percent is 0.3-0.4% is filled into deionized water Retort in be slowly stirred and disperseed；

(2) sodium lauroyl sarcosine, coconut oleoyl amine are proportionally added into after the retort of step (1) being heated to 60-80 DEG C Propyl betaine, Plantacare 818, coconut oleoyl amine methyl MEA, sodium benzoate, EDETATE SODIUM, pH adjusting agent, disperse molten Solution；

Wherein, the weight percent of sodium lauroyl sarcosine is 20-30%, the weight percent of Cocoamidopropyl betaine Than being 1-3% for the weight percent of 6-15%, the Plantacare 818, the weight percent of coconut oleoyl amine methyl MEA is 1- 2%, the weight percent of EDETATE SODIUM is 0.1-0.2%；

(3) Phenoxyethanol, hydrolyzed wheat protein, water are proportionally added into after the retort of step (3) being cooled to 40-50 DEG C Solve cornstarch and essence, wherein the weight percent of hydrolysed corn starch is 0.1-0.5%, the weight of hydrolyzed wheat protein Percentage is 0.1-0.5%, and lotion is examined after stirring evenly, and obtains the no silicone oil shampoo.

The present invention is used as soluble agent and is applied to by rationally compounding hydrolyzed wheat protein and hydrolysed corn starch Without in silicone oil shampoo, instrument is combed using hair dynamic and is measured when smearing, bath, wet comb, dry comb four-stage comb topknot Generated resistance and its integral (i.e. combing power), to illustrate the complex composition can significantly improve hair it is wet comb and do The smoothness of comb；The content that guar hydroxypropyltrimonium chloride is measured using spectrophotometry, to illustrate the compounding group Adsorbance of the guar hydroxypropyltrimonium chloride on hair can be increased by closing object.

Compared with prior art, the invention has the advantages that：

(1) hair care composition provided by the invention is by forming sediment the hydrolyzed wheat protein of small-molecular-weight and hydrolysed corn The reasonable composite usage of powder is washed hair in no silicone oil in water, and the cardability of hair can be obviously improved, and smoothness is improved significantly, solution Hair greasy flat the problems such as collapsing caused by silicone oil of having determined deposition；Guar hydroxypropyltrimonium chloride can be increased on hair Adsorbance, solve that guar hydroxypropyltrimonium chloride adsorbance on hair is smaller to influence hair smoothness, especially It is dry hair it is short-tempered, coarse the problems such as；

(2) preparation method provided by the invention is succinctly efficient, uses manpower and material resources sparingly, application easy to spread.

Specific implementation mode

Further to illustrate the technological means and its effect of the invention taken, below in conjunction with the preferred implementation of the present invention Example is come the technical solution that further illustrates the present invention, but the present invention is not limited in scope of embodiments.

Embodiment 1- embodiments 5

The formula of according to the form below 1 weighs raw material：

Table 1

Preparation method is as follows：

Suitable quantity of water is added in retort, guar hydroxypropyltrimonium chloride is added under slow stirring and is divided It dissipates, is heated to 60-80 DEG C under slow stirring, is subsequently added into sodium lauroyl sarcosine, Cocoamidopropyl betaine, decyl Portugal Glucosides, coconut oleoyl amine methyl MEA, sodium benzoate, EDETATE SODIUM, pH adjusting agent start after so that these substances is completely dispersed dissolving Phenoxyethanol, hydrolyzed wheat protein, hydrolysed corn starch, essence are added after temperature is down to 45 DEG C or less, continues to stir for cooling It mixes, it is ensured that obtain uniform mixture, lotion discharges after the assay was approved at 38 DEG C.

Embodiment 6

Compared with Example 5, other than guar hydroxypropyltrimonium chloride is changed to Polyquaternium-10, other Condition is same as Example 5.

Comparative example 1-5

The formula of according to the form below 2 weighs raw material：

Table 2

Preparation method is the same as embodiment 5.

Comparative example 6

Compared with Example 5, in addition to use molecular weight for the hydrolyzed wheat protein of 2500 dalton other than, other conditions and reality It is identical to apply example 5.

Test example efficacy assessments compare

The effect of for comparative example and embodiment evaluation method be divided into sensory evaluation method, cardability test and melon glue hydroxypropyl Base trimethyl ammonia chloride ammonium adsorp tion capacity tests three parts；

The sensory evaluation method is：Comparative example 1-6 and embodiment 1-6 will be prepared, 60 tester's comparisons are respectively issued to It uses, washes hair in the same manner when tester is using hair washing water sample, each shampoo respectively uses 2 times；Tester's root According to oneself feel score, wherein smooth effect is scored according to the hand touch perception of dry hair and wet hair, scoring mark Standard is using 5 points of systems, and 1 point worst, and 5 points best, and score more high effect is better, then averages to trier's scoring, Suo Youxi Shampoo using effect evaluation result is listed in table 3；

3 shampoo using effect of table is evaluated

According to the sensory test of consumer, it is apparent that not adding hydrolysed corn starch and water simultaneously in comparative example 1 When solving wheat gluten, the comfort level of scalp obviously weakens, and the smoothness of wet hair and dry hair is also poor.It is single in comparative example 2-5 Variable increase hydrolyzed wheat protein or hydrolysed corn starch, which can improve scalp comfort level, wet hair smoothness and do, to be sent out smooth Degree, but volunteer's scoring is general, does not reach ideal hair washing and requires, the molecular weight of the hydrolyzed wheat protein of comparative example 6 It is exceeded, ideal effect is also not achieved；Embodiment 1-5 increases hydrolyzed wheat protein and hydrolysed corn starch simultaneously in the reasonable scope Content, scored and found according to volunteer, reasonable compound of hydrolyzed wheat protein and hydrolysed corn starch can significantly improve head Skin comfort level improves the smoothness of hair, and is had obvious synergistic function relative to comparative example 1-6.

Comparative example 1-6 and embodiment 1-6 will be prepared and carried out the test of dynamic carding force, wetting is being smeared respectively, washing by water, wet Hair, dry five phase measurings of hair comb generated resistance when topknot (and its integral, i.e. combing power), to which comparative sample is correct The submissive moisturizing effect of hair；For convenience of unified standard, a kind of silicate-containing oil shampoo product of fast sale on the market is used in test As reference, the combing power measured value of reference sample is set to 1, and calculate the relative data of each sample based on this.If The numerical value is less than 1, that is, shows that sample makes topknot only need lower combing power when combing, then sample is more excellent compared with reference to product；Conversely, Numerical value shows that sample is poor compared with reference to product more than 1, the results are shown in Table 4；

4 shampoo cardability test result of table

According to hair dynamic comb instrument test result can be seen that in comparative example 1 and meanwhile do not add hydrolysed corn starch with When hydrolyzed wheat protein, shampoo is smeared, is all bad in the state of wet comb and dry comb, and smoothness is poor.It is single in comparative example 2-5 One variable increases hydrolyzed wheat protein or hydrolysed corn starch for improving under hair rinse stage smoothness and dry hair-like state Smoothness has certain positive effect, but overall effect is still general, does not reach ideal hair care of washing and requires, comparative example 6 Hydrolyzed wheat protein molecular weight it is exceeded, ideal effect is also not achieved；Embodiment 1-5 increases hydrolysis simultaneously in the reasonable scope When the content of wheat gluten and hydrolysed corn starch, is tested and found according to cardability, hydrolyzed wheat protein and hydrolysed corn starch Reasonable compounding can be obviously improved the state that shampoo smears the stage, improve smooth under wet hair rinse stage and dry hair-like state Property, and had obvious synergistic function relative to comparative example 1-6, embodiment 6 replaces the same energy of other cation opsonizing agents Realize similar effects.

Use the normal undamaged hair quality of comparative example 1-6 and 12 beam of embodiment 1-6 shampoos sample clean respectively, then as Then the solution of hair washing is placed in oscillation (200r/min) in constant temperature oscillation case, is taken out after 20min molten by ventilation naturally dry Liquid, the content of guar hydroxypropyltrimonium chloride is measured using spectrophotometry, and then calculates its suction on hair Attached amount, the results are shown in Table 5；

Guar hydroxypropyltrimonium chloride deposition test result on 5 hair of table

It can be seen that in comparative example 1 according to the test result of guar hydroxypropyltrimonium chloride deposition while not When adding hydrolysed corn starch and hydrolyzed wheat protein, deposition is very low；In comparative example 2-5, unitary variant increases hydrolyzed wheat Albumen or hydrolysed corn starch are for can improve guar hydroxypropyltrimonium chloride deposition, but deposition effect still one As, the molecular weight of the hydrolyzed wheat protein of comparative example 6 is exceeded, and ideal effect is also not achieved, and embodiment 1-5 is same in the reasonable scope It when the content of Shi Zengjia hydrolyzed wheat proteins and hydrolysed corn starch, finds after tested, hydrolyzed wheat protein and hydrolysed corn form sediment The reasonable compounding of powder can significantly improve guar hydroxypropyltrimonium chloride deposition, and have relative to comparative example 1-6 Apparent synergistic function, embodiment 6, which replaces other cation opsonizing agents, can equally realize similar effects.

In conclusion the hydrolyzed wheat protein and hydrolysed corn starch in hair care composition provided by the invention are at this Invention can play synergistic function in the range of providing, and effectively improve the smoothness of the wet comb of hair and dry comb and increase melon Adsorbance of the glue hydroxypropyl-trimethyl ammonium chloride on hair has broad application prospects and huge market value.

Applicant states that the present invention illustrates the method detailed of the present invention, but the present invention not office by above-described embodiment It is limited to above-mentioned method detailed, that is, does not mean that the present invention has to rely on above-mentioned method detailed and could implement.Technical field Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention Addition, the selection etc. of concrete mode, all fall within protection scope of the present invention and the open scope.

Claims (10)

1. a kind of hair care composition, which is characterized in that the composition includes the hydrolysis of 0.1-0.5% by weight percentage The hydrolysed corn starch of wheat gluten and 0.1-0.5%.

2. composition according to claim 1, which is characterized in that the molecular weight of the hydrolyzed wheat protein is 1000- 1800 dalton, preferably 1400-1600 dalton.

3. a kind of hair care composition as claimed in claim 1 or 2 is used as preparing the purposes for washing shield product.

4. a kind of amino acid pattern shampoo of the smooth not silicate-containing oil of maintenance, which is characterized in that the raw material of the shampoo includes power Profit requires the hair care composition described in 1 or 2.

5. shampoo according to claim 4, which is characterized in that the raw material of the shampoo further includes Hamposyl L Sodium, Cocoamidopropyl betaine, Plantacare 818, coconut oleoyl amine methyl MEA and guar hydroxypropyltrimonium chloride.

6. shampoo according to claim 5, which is characterized in that the sodium lauroyl sarcosine is in the shampoo Weight percent is 20-30%；

Preferably, weight percent of the Cocoamidopropyl betaine in the shampoo is 6-15%.

7. shampoo according to claim 5 or 6, which is characterized in that the Plantacare 818 is in the shampoo Weight percent is 1-3%；

Preferably, weight percent of the coconut oleoyl amine methyl MEA in the shampoo is 1-2%；

Preferably, weight percent of the guar hydroxypropyltrimonium chloride in the shampoo is 0.3-0.4%.

8. according to the shampoo described in any one of claim 5-7, which is characterized in that the shampoo includes in parts by weight The hydrolyzed wheat protein of 0.1-0.5%, the hydrolysed corn starch of 0.1-0.5%, the sodium lauroyl sarcosine of 20-30%, 6- Coconut oleoyl amine the methyl MEA and 0.3-0.4% of 15% Cocoamidopropyl betaine, the Plantacare 818 of 1-3%, 1-2% Guar hydroxypropyltrimonium chloride.

9. the shampoo described in any one of 5-8 according to claim, which is characterized in that the raw material of the shampoo is also Including preservative, complexing agent, pH adjusting agent, essence and deionized water.

10. shampoo according to claim 9, which is characterized in that the preservative is sodium benzoate and Phenoxyethanol Combination；

Preferably, the complexing agent is EDETATE SODIUM；

Preferably, the pH adjusting agent is the combination of citric acid and sodium citrate.