CN107753319A - A kind of hair Cleasing compositions and preparation method thereof - Google Patents

Abstract

The present invention relates to household chemicals field, discloses a kind of hair Cleasing compositions, includes the component of following percentage by weight：1 10% water-insoluble silicone oil combination；0.1 1% naturally derived cationic polymers；0.01 10% crystallization hydroxyl stabilizer；4 20% surfactant；Lemon oil 0.1 5%；Hydrolyze lupin protein 0.1 2%；Surplus is deionization.Water by rationally the building of composition framework, the limitation of the Synergistic between raw material, raw material key parameter, has preferable improvement the invention also discloses its preparation method to the health of hair and scalp.

Description

A kind of hair Cleasing compositions and preparation method thereof

Technical field

The present invention relates to household chemicals field, and in particular to a kind of hair Cleasing compositions and preparation method thereof.

Background technology

The personal care composition of combination containing a variety of detersive surfactants and hair conditioner is known, as one The method that kind can easily obtain hair-conditioning and hair cleaning performance simultaneously from single hair product, these compositions Requirement of the usage experience sense in the cognition aspect of consumer more and more higher.

The health status of pore on scalp determines the health status of hair, and the pore of many people is thick, hypersecretion Grease, excessive grease have impact on the health of scalp and hair, produces phenomena such as dandruff is excessive.

Many products carry out pore refining using natural plant composition, but most of natural plant compositions are applied to wash It is easy to run off during hair, effect is poor.

The content of the invention

The technical problems to be solved by the invention are, the defects of for prior art, there is provided a kind of hair Cleasing compositions, It is advantageous that good lasting moistening effect can be provided, possess preferable conditioning performance, while stable suspersion can be provided, allow Natural plant composition can be covered preferably with scalp and hair, making to feel greasy after user's use, harden The problem of uncomfortable；And ensureing that product high/low temperature in shelf life has good stability, said composition is reasonable by composition framework Build, the limitation of the Synergistic between raw material, raw material key parameter, can be with crystalline stability collaboration reaching good stability On the premise of cationic polymer enhancing hair conditioning, it will not cause to build up deposition.Composition components are gentle, to all kinds of hair qualitys It is applicable, significant effect, cost is cheap, and application is simple and direct.

The technical problems to be solved by the invention are achieved by the following technical programs：

A kind of hair Cleasing compositions, include the component of following percentage by weight：

1-10% water-insoluble silicone oil combination；

0.1-1% naturally derived cationic polymers；

0.01-10% crystallization hydroxyl stabilizer；

4-20% surfactant；

Lemon oil 0.1-5%；

Hydrolyze lupin protein 0.1-2%；

Surplus is deionized water.

Described naturally derived cationic polymers, it may be selected from cellulose, starch, galactomannans and be present in nature Other sources on boundary.

For the extracting method that described hydrolysis lupin protein uses for the conventional extracting method in this area, it is rich in low molecule Measure glutamine peptide and oligosaccharides, vitamin.It can promote the synthesis of epidermal protein and lipid, improve the barrier function of skin. There is preferable conditioning effect to scalp and hair-care.

Described surfactant includes laureth sulfuric ester ammonium, bay alcohol sulfuric ester ammonium, cocamidopropyl propyl amide sweet tea At least one of dish alkali.

Further, described water-insoluble silicone oil is combined as accounting for the composition weight 0.1%-9.9% poly- diformazan of preform Radical siloxane emulsion and 0.1-0.6% amido silicon oils.

Further, described naturally derived cationic polymers are cationic guar derivative, are using institute of the present invention The cationic guar derivative stated, and in optimization system of the present invention of arranging in pairs or groups, it dilutes flocculation and mutually shown well Wrap up effective particulate matter in ground（Insoluble silicone）Effect, while its water content for flocculating phase reaches perfect condition, therefore has There is the effect of the wet hair frictional force of good reduction.After added with cationic guar derivative of the present invention, and locate In the composition framework that the present invention finally protects, its pure water dilution range is between 5 times -20 times（This extension rate is simulation Hair washing process hair care composition is diluted with water the dilution ratio that bath washes away）There are can carry active principle can See solid flocculation phase, and it can be seen that effective particulate matter of hair-washing composition addition such as hydrolyzes lupin protein, insoluble silicon Oxygen alkane, which can be flocculated, mutually to be wrapped up or adsorbs.

Further, described crystallization hydroxyl stabilizer include 12- hydroxy stearic acids, DHSA, The hard ester essence of three -9,10- dihydroxystearic acids glyceride, three -12- hydroxystearins, trihydroxy.

Further, this hair Cleasing compositions also include the carbonic acid dioctyl ester for accounting for gross weight 1-10%, and it has preferable The effect of scalp is moistened, reduces excitant of the composition to scalp, improves user's impression, and have preferably to this composition system Compatibility.

A kind of described hair Cleasing compositions, comprise the following steps：

A. polyalcohol is put into cylinder is synthesized, opens steam heating, main mixing speed is set as 25 revs/min, is warming up to 68 DEG C ± 3 DEG C, input crystallizes hydroxyl stabilizer, at this temperature stir-activating 20 minutes；

B. it is further continued for being warming up to 80 ± 3 DEG C, observes situation in cylinder, if finds crystallization hydroxyl stabilizer whole active dissolution to saturating Bright is to activate completely, and at 20 revs/min, cooling rate is controlled at 1.5 DEG C/min for mixing speed control；When temperature is down to 68 ℃±3℃；

C. surfactant, lemon oil, hydrolysis lupin protein are put into, then mixing speed is adjusted to 15 revs/min, stirs 30- 60 minutes；To this step, natural component cross-linked network stable with the formation such as hydroxyl stabilizer are crystallized.

D. remaining raw material is put into, mixing speed is adjusted to 10 revs/min, stirs 60-120 minutes, regulation viscosity to 1100- 13000cps obtains finished product.

The present invention has the advantages that：

1st, the present composition contains lemon oil and hydrolysis lupin protein, has preferable contraction to the pore of scalp, subtracts Few fat secretion, alleviate scalp and hair-care health problem, collocation crystallization hydroxyl stabilizer and naturally derived cationic polymers so that The natural component stably can be attached on scalp and hair in hair washing.

2nd, the storage performance of the present composition is stable, and the composition internal stress under long-time storage is stable, has good Lipidosis, be unlikely to deteriorate.

3rd, the present composition can carry conditioning working substance and effectively be deposited on damaged hair, and reuse will not be excessive Deposition, makes hair is flat to collapse, hardens.

4th, the present composition has significantly lasting moisture retention.

5th, the present composition rinses in wet hair feels that beneficial effect is especially pronounced, and dry hair shows as relaxed and comfortable, non-greasy.

Embodiment

With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, It is not limitation of the invention.

Table 1 below is 7 preferred embodiments of the invention, and the raw material of use is commercially available conventional products.

Table 1：

The preparation method of embodiment and comparative example is as follows：

A. polyalcohol is put into cylinder is synthesized, opens steam heating, main mixing speed is set as 25 revs/min, is warming up to 68 DEG C ± 3 DEG C, input crystallizes hydroxyl stabilizer, at this temperature stir-activating 20 minutes；

B. it is further continued for being warming up to 80 ± 3 DEG C, observes situation in cylinder, if finds crystallization hydroxyl stabilizer whole active dissolution to saturating Bright is to activate completely, and at 20 revs/min, cooling rate is controlled at 1.5 DEG C/min for mixing speed control；When temperature is down to 68 ℃±3℃；

C. put into surfactant, lemon oil and, hydrolysis lupin protein, then mixing speed is adjusted to 15 revs/min, stirring 30-60 minutes；To this step, natural component cross-linked network stable with the formation such as hydroxyl stabilizer are crystallized.

D. put into remaining raw material, mixing speed is adjusted to 10 revs/min, stirs 60-120 minutes, regulation viscosity to 11000-13000cps obtains finished product.

The stability of above-mentioned 7 compositions is tested, effect carries out instrument efficacy assessment, human body evaluates two kinds Method carries out efficacy assessment, stability result result as shown in table 2；Arbitrarily select 32 volunteers more than use 7 groups respectively Sensory experience assessment is carried out after compound, full marks 10 divide, and finally draw average result as shown in table 3.

Table 2：12 peripheral stability test results

The above results are shown, the hydroxyl-stabilizing agent containing crystallization, provide stress stability in the composition, can be passed through 12 weeks - 15 DEG C of low temperature, the cold and hot stability test of 48 DEG C of high temperature.

Table 3

From above test data, embodiment 1 reaches effect stable and that pore shrinkage is good；Comparative example 1 lacks naturally Source cationic polymer, hair conditioning is poor, and stability is also bad；Comparative example 2 is because of stabilizer of the hydroxyl without crystallization etc., hair Hole shrinkage is poor；Comparative example 3 is because poor without lemon oil and hydrolysis lupin protein, pore shrinkage；Comparative example 4 is because without lemon Lemon oil, pore shrinkage are poor；Comparative example 5 is poor without hydrolysis lupin protein, pore shrinkage；Comparative example 6 is free of emollient Carbonic acid dioctyl ester, usage experience are poor.

Claims (7)

1. a kind of hair Cleasing compositions, it is characterised in that include the component of following percentage by weight：

1-10% water-insoluble silicone oil combination；

0.1-1% naturally derived cationic polymers；

0.01-10% crystallization hydroxyl stabilizer；

4-20% surfactant；

0.1-5% lemon oil；

0.1-2% hydrolysis lupin protein；

Surplus is deionized water.

2. hair Cleasing compositions according to claim 1, it is characterised in that described water-insoluble silicone oil is combined as accounting for Composition weight 0.1%-9.9% preform aqueous emulsion of dimethyl polysiloxane fluid and 0.1-0.6% amido silicon oils.

3. hair Cleasing compositions according to claim 1, it is characterised in that described naturally derived cationic polymers are Cationic guar derivative.

4. hair Cleasing compositions according to claim 1, it is characterised in that described crystallization hydroxyl stabilizer includes 12- hydroxy stearic acids, 9,10- dihydroxystearic acids, three -9,10- dihydroxystearic acids glyceride, three -12- hydroxy stearic acids are sweet The hard ester essence of grease, trihydroxy.

5. hair Cleasing compositions according to claim 1, it is characterised in that described surfactant includes anion Surfactant and nonionic surfactant.

6. hair Cleasing compositions according to claim 1, it is characterised in that described hair Cleasing compositions also include Account for total weight percent 1-10% carbonic acid dioctyl ester.

7. the hair Cleasing compositions described in a kind of claim 1-6 any one, it is characterised in that comprise the following steps：

A. polyalcohol is put into cylinder is synthesized, opens steam heating, main mixing speed is set as 25 revs/min, is warming up to 68 DEG C ± 3 DEG C, input crystallizes hydroxyl stabilizer, at this temperature stir-activating 20 minutes；

B. it is further continued for being warming up to 80 ± 3 DEG C, observes situation in cylinder, if finds crystallization hydroxyl stabilizer whole active dissolution to saturating Bright is to activate completely, and at 20 revs/min, cooling rate is controlled at 1.5 DEG C/min for mixing speed control；When temperature is down to 68 ℃±3℃；

C. surfactant, lemon oil, hydrolysis lupin protein are put into, then mixing speed is adjusted to 15 revs/min, stirs 30- 60 minutes；

D. remaining raw material is put into, mixing speed is adjusted to 10 revs/min, stirs 60-120 minutes, regulation viscosity to 11000- 13000cps obtains finished product.