JP6211436B2 - Rinse aid - Google Patents

Description

  The present invention relates to a rinse agent used for hair.

  Conventionally, hair rinsing agents such as hair treatment agents and hair conditioning agents have been blended with silicone oil for the purpose of enhancing the feeling of fingering of the hair and imparting smoothness.

  However, once silicone oil adheres to the hair, it tends to be poorly washed off from the hair even after shampooing. On the other hand, there are cases where problems such as adverse effects on the hair and hair with accumulated silicone oil impair foaming of the shampoo may be pointed out.

  In addition, when a composition containing silicone oil is applied to the scalp, it may be pointed out that silicone oil clogs the pores of the scalp.

  Therefore, in recent years, attempts have been made to provide a conditioning effect equivalent to or higher than that of conventional products without blending silicone oil.

  Specifically, a hair rinse composition (Patent Document 1) containing a fatty acid amidoamine, a higher alcohol, a hydrogenated polyisobutene having a specific kinematic viscosity and not containing silicones, a fatty acid amidoamine, A hair rinse composition containing a higher alcohol and a specific fatty acid ester oil and containing no silicones (Patent Document 2), containing a transesterified oil / fat of vegetable oil and hydrogenated vegetable oil / fat Hair cosmetics (Patent Document 3) and hair cosmetics containing a cationic surfactant, a higher alcohol, oil in a paste form at 25 ° C., and polyoxypropylene butyl ether, and containing substantially no silicone oil ( Patent Document 4) has been proposed.

  However, in these attempts, it is difficult to obtain an excellent conditioning effect because a specific oil agent as a conditioning component is easily washed off from the hair, and it is difficult to obtain an effect equal to or higher than that containing silicone oil. There is.

  In addition, when these treatment agents are applied to the scalp, they are easily washed away, so that there is a disadvantage that a rich moist feeling of the scalp cannot be obtained.

JP 2010-024167 A JP 2010-024169 A JP2013-103929A JP 2013-189423 A

  Accordingly, an object of the present invention is to provide a rinse agent substantially free of silicone oil, which exhibits a conditioning effect on the hair. A further object of the present invention is to provide a rinsing agent substantially free of silicone oil, which can provide not only such a conditioning effect but also a moist feeling of the scalp.

That is, the gist of the present invention is as follows.
(A) High melting point microcrystalline wax and / or high melting point polyethylene wax, (B) cationic surfactant, (C) higher alcohol, and (D) polyoxyalkylene diglyceryl ether, substantially silicone oil The present invention relates to a rinse agent characterized by not containing any of the above.

  The main effects of the rinsing agent of the present invention are as follows: (1) It can lead to smooth and smooth hair for hair and soft, moisturized hair, and (2) rich for scalp. It can moisturize and prevent the scalp from drying out.

  The present inventors unexpectedly exert the above-mentioned effects by applying the components mainly used in hairdressing agents, specifically, high melting point microcrystalline wax and / or high melting point polyethylene wax to the rinse agent. The present invention has been completed by finding out what can be done.

(A) component (A) component in this specification is a high melting point microcrystalline wax and / or a high melting point polyethylene wax. By applying the component (A) to the rinsing agent of the present invention, the finger of the hair after drying is improved, the hair after drying is softly moisturized, and the skin is richly moisturized. The effect is demonstrated.

  The component (A) may be composed of only a high melting point microcrystalline wax, may be composed only of a high melting point polyethylene wax, or both may be used in combination.

  The “high melting point” in the high melting point microcrystalline wax and the high melting point polyethylene wax means one having a melting point of 50 ° C. or higher.

  The high melting point microcrystalline wax is not particularly limited as long as the effects of the present invention are exhibited, but from the viewpoint of further enhancing the above effects, it is preferable to use a microcrystalline wax having a melting point of 72 to 104 ° C. Specific examples include microcrystalline wax having a melting point of 75 ° C., microcrystalline wax having a melting point of 88 ° C., and microcrystalline wax having a melting point of 101 ° C. One high melting point microcrystalline wax may be used alone, or two or more high melting point microcrystalline waxes may be used in appropriate combination.

  Such a high melting point microcrystalline wax can be easily obtained as a commercial product. Specific examples of commercially available products include, for example, trade names: HI-MIC-2065 (melting point: 75 ° C.), HI-MIC-1090 (melting point: 88 ° C.), HI-MIC-2095 (melting point: 101 ° C.) However, the present invention is not limited to such examples.

  The high melting point polyethylene wax is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of further enhancing the above effect, it is preferable to use a polyethylene wax having a melting point of 83 to 105 ° C. Specifically, for example, polyethylene wax having a melting point of 83 to 90 ° C., polyethylene wax having a melting point of 95 to 105 ° C., and the like can be given. A high melting point polyethylene wax may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.

  Such a high melting point polyethylene wax can be easily obtained as a commercial product. Specific examples of commercially available products include, for example, trade names: PERFORMALENE PL POLYETHYLENE (melting point: 83 to 90 ° C.), PERFORMALENE 655 POLYETHYLENE (melting point: 95 to 105 ° C.) (both manufactured by New Phase Technologies), etc. The invention is not limited to such examples.

  The content of the component (A) in the rinsing agent of the present invention is not limited as long as the desired effect is exhibited, but it improves the fingering of the hair after drying and softly moisturizes the hair after drying. From the viewpoint of giving a feeling and imparting moisture to the scalp, 0.5 to 5% by mass is preferable, and 1 to 3% by mass is more preferable.

  In addition, the ratio of both when the high melting point microcrystalline wax and the high melting point polyethylene wax are used together as the component (A) is not limited as long as the predetermined effect is exhibited, but with respect to 1 part by mass of the high melting point microcrystalline wax. The high melting point polyethylene wax is preferably 0.1 to 10 parts by mass, and more preferably 0.5 to 5 parts by mass.

(B) component (B) component in this specification is a cationic surfactant. By applying the component (B) to the rinsing agent of the present invention, the effect of imparting smoothness during washing is exhibited.

  The cationic surfactant is not particularly limited as long as the effect of the present invention is exhibited. For example, a monoalkyl type quaternary ammonium salt, a dialkyl type quaternary ammonium salt, a trialkyl type quaternary ammonium salt, a monoalkyl ether type Quaternary ammonium salts, alkylamines, fatty acid amidoamines and the like can be mentioned. A cationic surfactant may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate. As a suitable cationic surfactant, it is preferable to use a monoalkyl type quaternary ammonium salt and / or a fatty acid amidoamine from the above viewpoint. Such component (B) can be easily obtained as a commercial product.

  Specific examples of the monoalkyl type quaternary ammonium salt include, for example, lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethyl chloride. Examples include ammonium, alkyl (20-22) trimethylammonium chloride, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri (polyoxyethylene) stearylammonium chloride, di (polyoxyethylene) oleylmethylammonium chloride, and the like. A monoalkyl type quaternary ammonium salt may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate.

  Specific examples of fatty acid amidoamines include, for example, myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, myristic acid diethylaminoethylamide, myristic acid diethylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, Palmitic acid diethylaminoethylamide, palmitic acid diethylaminopropylamide, stearic acid dimethylaminoethylamide, stearic acid dimethylaminopropylamide, stearic acid diethylaminoethylamide, stearic acid diethylaminopropylamide, stearic acid dipropylaminoethylamide, stearic acid dipropyl Aminopropylamide, behenic acid dimethylaminoethylamide, beheny Acid dimethyl aminopropyl amide, behenic acid diethylaminoethyl amide, behenic acid diethylaminopropylamide. One type of fatty acid amidoamine may be used alone, or two or more types may be used in appropriate combination.

  In the present invention, the fatty acid amidoamine is used as a salt with an organic acid or an inorganic acid. Examples of the organic acid used include lactic acid, malic acid, citric acid, tartaric acid, and acetic acid, and examples of the inorganic acid include phosphoric acid, hydrochloric acid, sulfuric acid, and the like, and lactic acid is preferably used. The content of the organic acid or inorganic acid is not particularly limited as long as it can neutralize the fatty acid amidoamine to be blended.

  Although content of (B) component in the rinse agent of this invention is not limited as long as a desired effect is exhibited, 1-5 mass% is preferable from a viewpoint which provides the smoothness at the time of flushing, 1-4 mass%. Is more preferable.

(C) component (C) component in this specification is a higher alcohol. By applying the component (C) to the rinse agent of the present invention, the effect of improving the fingering of the hair after drying and softening the hair after drying is exhibited.

  As the higher alcohol, those having 12 to 22 carbon atoms are preferable, and those having 16 to 20 carbon atoms are more preferable. Such component (C) can be easily obtained as a commercial product.

  Specific examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and behenyl alcohol. A higher alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate. From the above viewpoint, cetyl alcohol, stearyl alcohol, and behenyl alcohol are preferably used as suitable higher alcohols.

  Although content of (C) component in the rinse agent of this invention is not limited as long as a desired effect is exhibited, it makes the hair of the hair after drying favorable and softens the hair after drying. From a viewpoint, 2-10 mass% is preferable and 4-8 mass% is more preferable.

  In the present invention, as described above from the viewpoint of making the smoothness at the time of washing better, further improving the fingering of the hair after drying, and imparting excellent softness to the hair after drying (B) The content of the cationic surfactant that is the component and the content of the higher alcohol that is the component (C) described above as a mass content ratio (B: C), B: C = 1: 1 to 1: 4. It is preferable to use in the range of B: C = 1: 2 to 1: 3.

(D) component (D) component in this specification is polyoxyalkylene diglyceryl ether. By applying the component (D) to the rinsing agent of the present invention, the effect of giving a soft moist feeling to the hair after drying and moisturizing the scalp is exhibited.

  Preferable examples of the component (D) include polyoxyalkylene diglyceryl ethers having 2 to 3 carbon atoms in the alkylene group such as polyoxyethylene diglyceryl ether and polyoxypropylene diglyceryl ether. Further, the number of moles of ethylene oxide added or the number of moles of propylene oxide added is not limited as long as the desired effect is exhibited, but is preferably 5 to 20, and preferably 8 to 15. More preferred. Polyoxyalkylene diglyceryl ether may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate. From the above viewpoint, it is preferable to use polyoxypropylene diglyceryl ether as a suitable polyoxyalkylene diglyceryl ether.

  Such component (D) can be easily obtained as a commercial product. Specific examples of commercially available products include, for example, trade names: SY-DP9 (addition mole number 9), SY-DP14T (addition mole number 14) (all manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.), Unilube DGP-950 (addition mole number). 14) (manufactured by NOF Corporation) and the like, but the present invention is not limited only to such examples.

  Although content of (D) component in the rinse agent of this invention is not limited as long as a desired effect is exhibited, the viewpoint which gives a soft moist feeling to the hair after drying, and gives moisture to a scalp. Therefore, 0.1 to 2 mass% is preferable, and 0.3 to 1.3 mass% is more preferable.

Other Components In the present specification, for example, the following components that can be blended in cosmetics can be added to the rinse agent of the present invention as necessary. For example, water, anionic surfactants, nonionic surfactants, oils and fats, hydrocarbon oils other than the above component (A), waxes, higher fatty acids, fatty acid ester oils, lower alcohols, polyhydric alcohols, sterols, moisturizing agents Agents, inorganic pigments, dyes, antioxidants, ultraviolet absorbers, vitamins, astringents, whitening agents, animal and plant extracts, sequestering agents, and the like. In addition to the above-described components, components usually used in cosmetics can be arbitrarily arbitrarily blended.

  The amount of water in the rinse agent of the present invention is not particularly limited. For example, it preferably occupies 60 to 95% by mass of the rinse agent, and more preferably 70 to 90% by mass.

Rinse Agent of the Present Invention One feature of the rinse agent of the present invention is that it contains substantially no silicone oil. That is, according to the composition of the present invention, a predetermined effect can be exhibited even when substantially no silicone oil is contained. In the present invention, “substantially does not contain silicone oil” means “not to contain silicone oil separately” and includes silicone oil contained in each compounding raw material constituting the rinse agent. It is not excluded. For example, preferable examples include a case in which no silicone oil is contained in the rinse agent, or a case in which 0.2% by mass or less is contained in the rinse agent.

  Although pH of the rinse agent of this invention is not specifically limited, From a viewpoint of the influence on a human body, 3-7 are preferable at 25 degreeC, for example, and 4-6.5 are more preferable. The pH of the rinse agent can be adjusted by appropriately adding an acid or an alkali.

  The rinse agent of this invention can be manufactured by a conventional method. For example, the above-mentioned constituent components are mixed and a known method, specifically, a method of stirring with a homomixer or the like can be mentioned. Although it does not specifically limit as a dosage form of the rinse agent of this invention, For example, a gel, emulsion, cream, etc. are mentioned.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified. Moreover, all the compounding components were converted into pure components.

(Sample preparation)
According to the composition described in Tables 1-2, the rinse agent of Examples 1-11 and Comparative Examples 1-11 was prepared, and it used for the following evaluation test. The results are shown in Tables 1 and 2, respectively. In addition, pH of the rinse agent of these Examples and Comparative Examples was in the range of 4 to 6.5.

(Preparation of standard test hair bundle)
3g of GB perfect clear shampoo (trade name, manufactured by Mandom) was applied to a test straight hair bundle (length 30cm, weight 10g) that was left overnight at 23 ° C and 60% humidity. After soaking, the hair bundle for standard test was washed with warm water of about 40 ° C. for 1 minute.

(Test Example 1: Evaluation of smoothness during washing)
5 g of the sample obtained in Example 1 was uniformly applied to the standard test hair bundle. Next, after 2 minutes, it was thoroughly conditioned and washed with warm water at about 40 ° C. for 1 minute. The same operations were performed for the remaining examples and comparative examples.
Moreover, what was washed off with warm water of about 40 ° C. for 1 minute without applying anything to the standard test hair bundle was used as a comparative hair bundle.

  The evaluation was performed by 10 sensory evaluation panels according to the following evaluation criteria for the smoothness of the hair bundle at the time of washing, and the average score was calculated and evaluated.

(Evaluation criteria for smoothness during washing)
Score 3: Inferior smoothness compared to comparison hair bundle Score 4: Have smoothness equivalent to comparison hair bundle Score 5: Smoothness slightly better than comparison hair bundle Score 6: The smoothness is clearly better than the comparison hair bundle. Score 7: The smoothness is much better than the comparison hair bundle.

<Evaluation>
◎ (Very good): Score average value is larger than 6 and 7 or less ○ (Good): Score average value is larger than 5 and 6 or less △ (Inadequate): Score average value is larger than 4 and 5 or less × (Poor): Score average is 4 or less

(Test Example 2: Evaluation of finger feeling after drying and soft moist feeling)
After the evaluation of Test Example 1, the hair bundle was sufficiently wiped away by towel drying.
Next, the same 10 evaluation panels as in Test Example 1 scored each finger bundle after drying the hair bundle and the soft moist feeling according to the following evaluation criteria, and the average score was calculated and evaluated.

(Evaluation criteria as per finger after drying)
Score 3: inferior to fingers according to comparison hair bundle Score 4: having finger passages equivalent to comparison hair bundle Score 5: finger passage slightly better than comparison hair bundle Score 6: comparison object Score 7 is clearly superior to the hair bundle Score 7: The finger passage is significantly superior to the comparison hair bundle

<Evaluation>
◎ (Very good): Score average value is larger than 6 and 7 or less ○ (Good): Score average value is larger than 5 and 6 or less △ (Inadequate): Score average value is larger than 4 and 5 or less × (Poor): Score average is 4 or less

(Evaluation criteria for soft moist feeling after drying)
Score 3: Compared with the comparison hair bundle, inferior to the soft moist feeling Score 4: Have a soft moist feeling equivalent to the comparison hair bundle, Score 5: Slightly moist feeling compared with the comparison hair bundle Score 6: The soft moist feeling is clearly superior to the comparative hair bundle Score 7: The soft moist feeling is significantly superior compared to the comparative hair bundle

<Evaluation>
◎ (Very good): Score average value is larger than 6 and 7 or less ○ (Good): Score average value is larger than 5 and 6 or less △ (Inadequate): Score average value is larger than 4 and 5 or less × (Poor): Score average is 4 or less

(Test Example 3: Evaluation of scalp moisture)
Ten panelists of sensory evaluation performed shampoo treatment of the panel's own hair using 5 g of GB perfect clear shampoo (mandom), and washed it off with warm water of about 40 ° C. for 1 minute.

  Next, 5 g of the sample obtained in Example 1 was applied to the entire scalp of the right half of the head so that the scalp was massaged for 2 minutes. The scalp on the left half of the head was massaged so that the scalp was swallowed for 2 minutes without applying anything.

  Next, after washing the entire head with warm water of about 40 ° C. for 1 minute, the hair and scalp were thoroughly dried using a towel and a dryer, and the moisture of the scalp after drying was evaluated according to the following evaluation criteria. .

  About each of the remaining Examples and Comparative Examples, the same operation was performed and evaluated according to the following evaluation criteria.

<Evaluation criteria for scalp moisture>
◎ (very good): 8 or more of 10 respondents said that the scalp in the right half of the head is moist compared to the scalp in the left half of the head ○ (Good): 6 to 10 in 10 7 responded that the scalp in the right half of the head was moist compared to the scalp in the left half of the head. △ (Inadequate): 4 to 5 out of 10 scalp in the left half of the head Answer that the scalp in the right half of the head is moist compared to the head × (bad): 3 out of 10 people have a scalp in the right half of the head compared to the scalp in the left half of the head Answer that there is more moisture

(Results and discussion)
The results are shown in Tables 1 and 2 below.

The detail of each raw material in a table | surface and the formulation example is as follows.
Microcrystalline wax * 1 (Nippon Seiwa Co., Ltd., trade name: HI-MIC-2065, melting point 75 ° C.)
Microcrystalline wax * 2 (Nippon Seiwa Co., Ltd., trade name: HI-MIC-1090, melting point 88 ° C.)
Microcrystalline wax * 3 (Nippon Seiwa Co., Ltd., trade name: HI-MIC-2095, melting point 101 ° C.)
Polyethylene wax * 4 (manufactured by New Phase Technologies, trade name: PERFORMOLENE PL POLYETHLENE, melting point 83-90 ° C.)
Polyethylene wax * 5 (manufactured by New Phase Technologies, trade name: PERFORMOLENE 655 POLYETHYLENE, melting point 95-105 ° C.)

Carnauba wax * 6 (manufactured by Toa Kasei Co., Ltd., trade name: TOWAX-1F8, melting point 80-86 ° C.)
Candelilla wax * 7 (obtained from Mitsuba Trading Co., Ltd., trade name: refined candelilla wax R-2CGM, melting point 68-72 ° C.)
Liquid isoparaffin (manufactured by NOF Corporation, trade name: Pearl Ream EX)
Vaseline (Sonborn, trade name: WHITE PROTOPET 1S)
Beeswax * 8 (Miki Chemical Industry Co., Ltd., trade name: Kosan Dash Beeswax, melting point 60-67 ° C)
Alkyl chloride (20-22) trimethylammonium (manufactured by Clariant, trade name: GENAMIN KDMP-J)
Polyoxypropylene (14) diglyceryl ether (manufactured by Sakamoto Pharmaceutical Co., Ltd., trade name: SY-DP14T)
Liquid paraffin (Sonborn, trade name: CARNATION)

  From the results shown in the above table, the rinsing agent of the present invention has smoothness at the time of washing, fingering after drying, soft moist feeling after drying, and moisturization of the scalp even without adding silicone oil. And found to be very good or good.

  On the other hand, the composition lacking any of the component (A), the component (B), the component (C), and the component (D) is poor in terms of a soft moist feeling after drying and moisturizing the scalp (comparison). Examples 1 and 4), or all components were separated without dissolving, and the dosage form as a rinse agent could not be maintained (Comparative Examples 2 and 3).

  Furthermore, a composition (Comparative Examples 5, 6 and 9) using waxes (carnauba wax, candelilla wax and beeswax) used similarly to high melting point microcrystalline wax and high melting point polyethylene wax in the field of hairdressing agents, In the composition (Comparative Examples 7, 8, 10 and 11) using oily components (liquid isoparaffin, petrolatum, cetyl 2-ethylhexanoate and glyceryl tri-2-ethylhexanoate) widely used in the field of hairdressing agents, Any of the above four types of evaluation items was insufficient or poor.

  From these results, it is presumed that the effect of the present invention is exhibited by the following mechanism. That is, the high melting point microcrystalline wax which is the component (A) of the present invention has a higher melting point than general paraffin waxes and contains a large amount of isoparaffins and cycloparaffins. It is considered that the structure is easy to take, and as a result, the crystal structure is formed in the rinse agent. And, it is thought that fine crystals adhere to the hair to realize a feeling of softness and moistness of the scalp after passing through the fingers after drying. Ordinary ester oils do not have a fine crystal structure like high melting point microcrystalline wax, so they are not only inferior to fingering and soft moisture after drying, but also inferior to the scalp. I think.

  Hereinafter, formulation examples of the rinse agent according to the present invention will be shown. In addition, content is mass%.

(Prescription Example 1)
High melting point microcrystalline wax (melting point 88 ° C) 2.0%
Alkyl chloride (20-22) trimethylammonium solution (80%) 1.0%
Stearic acid dimethylaminopropylamide 0.8%
Polyoxypropylene (14) diglyceryl ether 0.7%
Stearyl alcohol 4.0%
Lactic acid 0.23%
Liquid paraffin 4.0%
Phytosterol 0.3%
Ubidecarenone 0.001%
l-Menthol 0.3%
Ethanol 2.0%
Concentrated glycerin 3.0%
Isopropyl methylphenol 0.1%
Preservative Appropriate amount Fragrance Appropriate amount
Purified water balance 100.0%

(Prescription example 2)
High melting point microcrystalline wax (melting point 101 ° C) 1.0%
High melting point polyethylene wax (melting point 83-90 ° C) 1.5%
Alkyl chloride (20-22) trimethylammonium solution (80%) 1.2%
Stearic acid dimethylaminoethylamide 0.8%
Polyoxypropylene (14) diglyceryl ether 0.5%
Stearyl alcohol 4.5%
Lactic acid 0.25%
Liquid paraffin 3.0%
Dipropylene glycol 3.0%
Allantoin 0.2%
Black tea extract 0.5%
Preservative Appropriate amount Fragrance Appropriate amount
Purified water balance 100.0%

(Prescription Example 3)
High melting point microcrystalline wax (melting point 75 ° C) 2.0%
Alkyl chloride (20-22) trimethylammonium solution (80%) 2.0%
Polyoxypropylene (14) diglyceryl ether 1.0%
Stearyl alcohol 1.5%
Cetyl alcohol 2.0%
Liquid paraffin 2.5%
Cholesteryl hydroxystearate 0.5%
1,3-butylene glycol 2.0%
Seaweed extract 0.5%
Licorice extract powder 0.1%
Cay skin extract 0.5%
Citric acid appropriate amount Preservative appropriate amount Fragrance appropriate amount
Purified water balance 100.0%

(Prescription Example 4)
High melting point polyethylene wax (melting point 95-105 ° C) 1.0%
Stearyltrimethylammonium chloride solution (50%) 2.0%
Stearic acid dimethylaminopropylamide 1.5%
Polyoxypropylene (14) diglyceryl ether 1.2%
Behenyl alcohol 5.0%
Lactic acid 0.46%
Liquid paraffin 4.0%
Concentrated glycerin 3.0%
Hydrolyzed hyaluronic acid 0.2%
Dipotassium glycyrrhizinate 0.1%
Preservative Appropriate amount Fragrance Appropriate amount
Purified water balance 100.0%

  The rinse agent of the present invention can be used as a scalp care agent as well as a hair rinse agent such as a hair treatment agent for hair and a hair conditioning agent.

Claims (3)

(A) melting from 72 to 104 ° C. microcrystalline wax and / or melting point 83-105 ° C. Polyethylene waxes of, (B) a cationic surfactant, (C) a higher alcohol, and (D) polyoxyalkylene glyceryl ether Contains,
The content of the component (A) is 1 to 3% by mass, the content of the component (B) is 1 to 4% by mass, the content of the component (C) is 4 to 8% by mass, and the component (D) The rinse agent characterized by containing 0.3-1.3 mass%, and containing substantially no silicone oil. The rinse agent according to claim 1, wherein the component (B) is a cationic surfactant selected from the group consisting of a monoalkyl type quaternary ammonium salt and a fatty acid amidoamine. The rinse agent according to claim 1 or 2 , wherein the component (D) is polyoxypropylene diglyceryl ether.