CN109481352A - It is a kind of with high conditioning performance without silicone oil without sulfate shampoo and preparation method thereof - Google Patents
It is a kind of with high conditioning performance without silicone oil without sulfate shampoo and preparation method thereof Download PDFInfo
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract
This application involves a kind of with high conditioning performance without silicone oil without sulfate shampoo, which is characterized in that is counted on the basis of mass percent, the shampoo is made of following raw material components: anionic amino acid type surfactant 20-40%；Amphoteric surfactant 10-30%；Cation opsonizing agent 0.2-0.5%；Substitute silicone oil composite 0.7-1.5%；Moisturizer 0.5-1%；Thickener 1.5-5%；Chelating agent 0.01-0.1%；Preservative 0.06-0.08%；Essence 0.5-1%；PH regulator 0.1-0.5%；And the water of surplus, wherein the sum of mass percent of all raw material components is 100%.Amino acid type surfactant, the mild cleaning formula of safety are selected in shampoo of the invention；Using PCA glyceryl oleate and two section mustard seed oil of deep-sea as substitution silicone oil composite, so that hair is easy to arrange, is smooth, is soft, is glossy, solve the problems, such as that no short-tempered difficulty of silicone oil shampoo drying hair is arranged, while avoiding scalp problems caused by silicone oil accumulation.
Description
Technical field
This application involves cosmetic technical fields, and in particular to a kind of fragrant without sulfate without silicone oil with high conditioning performance
Involve preparation method.
Background technique
In recent years, people more focus on its safety and hair conditioning to shampoo other than requirement for cleaning, therefore without silicone oil without sulphur
Hydrochlorate shampoo progresses into market.90% or more shampoo currently on the market selects laureth sodium sulfovinate or laruyl alcohol poly-
Ether sulfuric ester ammonium can generate micro by-product dioxanes as primary surfactant, but when production polyether surfactant,
Enter in shampoo as impurity, and dioxanes may have carcinogenicity.Therefore, amino acid type surfactant is gradually applied to shampoo
In, to obtain the cleaning formula of milder safety.
The outermost surface of healthy healthy hair is arranged many hair scale pieces, and the rouge (fatty acid) in hair hair scale piece includes:
18 methyl arachic acids；Palmitinic acid；Oleic acid.After cleaning and boiling hot dye are handled repeatedly, healthy hair surface hair scale piece is impaired, covers hair scale piece
Sebum be constantly etched, due to the continuous loss of this hydrophobic protective layers of sebum, leading to hair increasingly becomes coarse, unglazed
Pool and be difficult to comb.And silicone oil can form uniform hydrophobic protective layers in hair surface, while can fill up hair scale piece by
The position tilted is damaged, so that hair is become smooth, improves the cardability of hair.But due to silicone oil insoluble in water, cleaning is not thorough
Accumulation can be generated, lead to problems such as hair it is greasy it is flat collapse, scalp blocking pore, therefore select and a kind of really from use feeling and make
With effect, perfect substitute is currently badly in need of all as silicone oil.
Alcohol ethers (such as PPG-3 Octyl Ether, -5 citrate of oleth), glyceride type are often used without silicone oil shampoo at present
(such as PEG-7 glyceryl cocoate, glyceryl oleate), water-soluble plant essential oil component substitute silicone oil.These silicone oil substitutes
Or composition can make wet hair comb reason make moderate progress, but drying hair combing is ineffective, and most of consumer uses at present
The main reason for short-tempered not smooth without drying hair after silicon shampoo.
Another development trend of no silicone oil is that grease is added, and such as further adjusts vegetable fat as silicone oil substitute
Manage hair.The Chinese invention patent of entitled " a kind of composition and hair conditioner with scalp care function of not silicate-containing oil "
CN104887578B disclosure substitutes silicone oil with camellia seed oil.Entitled " a kind of's have effects that scalp care without silicone oil shampoo "
Chinese invention patent application CN106265378A, which is disclosed, compounds oil of badian by camellia seed oil to substitute silicone oil.Entitled " one
Kind with vegetable fat substitution silicone oil children without silicone oil shampoo " Chinese invention patent application CN106420407A disclose utilize
One or both of Butyrospermum parkii fruit fatty oil, olive oil, Queensland nut seed oil, sunflower oil, PPG-3 Octyl Ether are replaced
For silicone oil.Impaired hair surface hydrophilic is disadvantageous in that using vegetable oil substitution silicone oil, is unfavorable for sprawling for vegetable fat,
The utilization rate and effect of vegetable fat can be reduced, therefore in order to guarantee that the grease of sufficient amount is uniformly spread on impaired hair, is needed
Improve hair surface hydrophobic.And joined non-volatile conditioning agent in patent of invention CN107468531A, it can using flocculation
To play certain conditioning effect, but not as good as the function of vegetable fat in terms of the cardability of drying hair, smoothness, glossiness, flexibility
Effect.
In order to further improve no silicone oil shampoo whole hair conditioning especially drying hair cardability and smoothness, need extensive
The hydrophobicity in silk table face is recurred, and smooths the lipid layer of hair scale piece at one layer of hair surface spreading.Therefore, this field needs to develop
It is a kind of with high conditioning performance without silicone oil without sulfate shampoo and preparation method thereof.
Summary of the invention
The application be designed to provide it is a kind of with high conditioning performance without silicone oil without sulfate shampoo, thus on solving
The technical issues of stating in the prior art.The application provide it is a kind of with high hair conditioning without the sulfate-free shampoo of silicone oil, select
Amino acid type surfactant sodium lauroyl sarcosine, it is mild safe and non-stimulating.PCA glyceryl oleate and vegetable fat is selected to make
For substitution silicone oil composite, the problem of no short-tempered difficulty of silicone oil shampoo drying hair is arranged can be efficiently solved, hair is made to be easy to arrange,
It is smooth, soft, glossy, avoid silicone oil accumulation bring scalp problems.
The purpose of the application, which also resides in, provides a kind of preparation side without silicone oil without sulfate shampoo with high conditioning performance
Method.
To achieve the goals above, the application provides following technical proposals.
In the first aspect, the application provide it is a kind of with high conditioning performance without silicone oil without sulfate shampoo, feature
It is, is counted on the basis of mass percent, the shampoo is made of following raw material components:
The water of surplus, wherein the sum of mass percent of all raw material components is 100%.
In a kind of embodiment of first aspect, the anionic amino acid type surfactant includes lauroyl flesh ammonia
One or more of sour sodium, cocounut oil acyl methyl taurine sodium or sodium cocoyl glutamate.
In a kind of embodiment of first aspect, the amphoteric surfactant include Cocoamidopropyl betaine,
One or more of lauroylamidopropyl betaine, sodium cocoamphoacetate or Sodium Lauroamphoacetate.
In a kind of embodiment of first aspect, the cation opsonizing agent includes polyquaternium -7, polyquaternium -
10, one in polyquaternium -52, guar hydroxypropyltrimonium ammonium chloride or hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chloride
Kind is several.
In a kind of embodiment of first aspect, the pH adjusting agent is citric acid.
In a kind of embodiment of first aspect, the substitution silicone oil composite includes to account for all raw material components gross masses
Following mass percent component: the PCA glyceryl oleate of 0.5-1% and the vegetable fat of 0.2-0.5%.
In a kind of embodiment of first aspect, the vegetable fat is two section mustard seed oil of deep-sea.
In a kind of embodiment of first aspect, the moisturizer is xylitol glucoside, anhydro xylitol and wood
The mixture of sugar alcohol.
In a kind of embodiment of first aspect, the thickener includes the following matter for accounting for all raw material components gross masses
Measure the component of degree: the glycerol monolaurate of 0.5-2% and the coconut oleoyl amine methyl monoethanolamine of 1-3%.
In second aspect, the application provide it is a kind of prepare as described in relation to the first aspect with high hair conditioning without silicone oil without
The method of sulfate shampoo, which is characterized in that the described method comprises the following steps:
(1) mixed anion amino acid type surfactant, amphoteric surfactant, chelating agent, thickener and water, obtain
First reaction mixture；
(2) the first reaction mixture is warming up to 70 DEG C -80 DEG C, uniformly mixes the first reaction mixture and cationic conditioning
Agent obtains the second reaction mixture；
(3) the second reaction mixture is cooled to 60 DEG C -50 DEG C, uniformly mixes the second reaction mixture, substitution silicone oil group
Object and moisturizer are closed, third reaction mixture is obtained；
(4) third reaction mixture is cooled to 45 DEG C hereinafter, uniformly mixing third reaction mixture, preservative, essence
With PH regulator, obtain it is described with high hair conditioning without silicone oil without sulfate shampoo.
In a kind of embodiment of second aspect, in step (2), the temperature of the first reaction mixture is warming up to 70
℃；
In step (3), the second reaction mixture is cooled to 60 DEG C.
In a kind of embodiment of second aspect, in step (1), the thickener is glycerol monolaurate and cocounut oil
The mixture of amide methyl monoethanolamine；
In step (3), substitution silicone oil composite is the mixture of two section mustard seed oil of PCA glyceryl oleate and deep-sea；
In step (3), moisturizer is the mixture of xylitol glucoside, anhydro xylitol and xylitol.
In a kind of embodiment of second aspect, described method includes following steps:
(1) water, sodium lauroyl sarcosine, Cocoamidopropyl betaine, EDETATE SODIUM, the glycerol moon are added in agitated kettle
Cinnamic acid ester, coconut oleoyl amine methyl monoethanolamine, heating stirring；
(2) when being warming up to 70 DEG C, Polyquaternium-10 is added, stops heating after mixing evenly；
(3) when being cooled to 60 DEG C, PCA glyceryl oleate, two section mustard seed oil of deep-sea, xylitol glucoside, dehydration is added
Xylitol and xylitol, stir evenly；
(4) when being cooled to 45 DEG C, preservative, essence, citric acid is added, stops stirring after mixing evenly, obtains described
With high hair conditioning without silicone oil without sulfate shampoo.
Compared with prior art, the positive effect of the present invention is to select amino acid type surfactant, and safety is mild
Cleaning formula, no dioxanes risk；Silicone oil is substituted using the composition of PCA glyceryl oleate and two section mustard seed oil of deep-sea, effectively
The hydrophobic protective layer that supplement hair hair scale piece is lost is conducive to two section mustard seed oil of vegetable fat deep-sea and stops in hair surface, makes
Hair is easy to arrange, is smooth, is soft, is glossy, solves the problems, such as that no short-tempered difficulty of silicone oil shampoo drying hair is arranged, avoids silicone oil
Scalp problems caused by accumulation.
Specific embodiment
Unless otherwise indicated, from context cues or belong to the convention of the prior art, otherwise number all in the application
It is all based on weight with percentage, and test and characterizing method used is all synchronous with the submission date of the application.It is being applicable in
In the case where, any patent, patent application or disclosure involved in the application are fully incorporated in this as reference, and its
Patent families of equal value are also introduced into as reference.If the definition of the concrete term disclosed in the prior art with it is provided herein
Any definition it is inconsistent, then be subject to term definition provided herein.
Digital scope in the application is approximation, therefore unless otherwise stated, it may include the number other than range
Value.Numberical range include with the increased all numerical value from lower limit value to upper limit value of 1 unit, condition be any lower value with
There are the intervals of at least two unit between any high value.For example, if compositional, physics or other property (such as molecules
Amount, melt index (MI) etc.) it is 100 to 1000, it is meant that clearly list all single numbers, such as 100,101,102 etc., with
And all subranges, such as 100 to 166,155 to 170,198 to 200 etc..For comprising the numerical value less than 1 or comprising big
In the range of 1 score (such as 1.1,1.5 etc.), then suitably regard 1 unit as 0.0001,0.001,0.01 or 0.1.
For the range comprising the units less than 10 (such as 1 to 5), usually regard 1 unit as 0.1.These are only intended to table
The specific example of the content reached, and all possible combination of the numerical value between cited minimum and peak is all recognized
In this application for clear record.It is also pointed out that term " first " herein, " second " etc. do not limit sequencing, only
In order to distinguish the substance of different structure.
About chemical compound in use, unless explicitly stated otherwise, otherwise odd number includes all isomeric forms, otherwise also
So (for example, whole isomers that " hexane " either individually or collectively includes hexane).In addition, unless explicitly stated otherwise, otherwise using
"one", the noun that "an" or "the" are described also includes its plural form.
Term "comprising", " comprising ", " having " and their derivative are not excluded for any other component, step or mistake
The presence of journey, and whether disclose in this application with these other components, step or process unrelated.To eliminate any query,
Unless expressly stated, otherwise in the application it is all use term "comprising"s, " comprising ", or " having " composition may include appoint
What additional additive, auxiliary material or compound.On the contrary, in addition to necessary to operating characteristics those, term " substantially by ...
Composition " excludes any other component, step or process except the hereinafter described range of any term.Term " by ...
Composition " does not include any component, step or the process for not specifically describing or listing.Unless expressly stated, otherwise term "or" refers to
Separate member listed or any combination thereof.
Hair can be damaged in daily cleaning and boiling hot dye processing rear surface, 18 methyl 20 of hydrophobicity protective film of extexine
Alkanoic acid can fall off, and expose negatively charged group.PCA glyceryl oleate by by natural Monoolein emulsifier with
The 2-pyrrolidone-5-carboxylic acid in natural glutamate source combines to obtain, and the positive charge that it is provided can have good hydrophobic work with hair
With effective hydrophobic protective layer for supplementing hair hair scale piece and being lost restores the hydrophobic layer on hair surface, is conducive to vegetable fat
It stops, better cardability can be shown while reducing vegetable fat additive amount.
Two section mustard seed oil of deep-sea also known as crambe abyssinica seed oil, Crambe abyssinica are 1 year raw herbaceous plant, can grow to 60-90 centimeters
Height left and right grows very small white flower, once having arrived mature harvest time, the seed of harvest contains the grease of 26-35%.It is deep
Omega 3 is rich in extra large two section mustard seed oils, the fatty acid docosenoic acid of Omega 6 and long-chain make it have brilliant day
Right stability, without greasy feeling after the slim and graceful use of quality, this will be attributed to the fact that itself unique nutrition of lipids composition.Since it is high steady
It is qualitative, so that it becomes the natural substitute of ideal of silicone oil.It has the function of nourishing hair follicle, also will form very thin protection
Film, protection scalp from surfactant or dyeing and perm etc. injury, while can spread over hair surface supplement lipid layer to
Hair scale piece is smoothed, hair is made to be easy to arrange, in addition, it can assign the soft and moist effect of the natural gloss of hair and hair care.
Xylitol is a kind of polyalcohol, frequently as moisturizer, there is moisturizing, repair skin and other effects, it can be used as cosmetics
The wet regulator of class uses, and has no stimulation to human skin.Xylitol glucoside, anhydro xylitol and xylitol this three
The mixture of kind efficient moisture-retention agent is the glycan moisturizer extracted in the novel plant of one kind, and GAGs can be promoted (transparent
Matter acid and chondroitin sulfate) content increase, improves transepidermal water content；Promote ceramide synthesis, reinforce skin barrier effect,
Reduce water loss.Possess 3D hydration moisturizing, from inside to outside water follow it is bad, enhancing skin and hair barrier-protection effect.
In a specific embodiment, the application provide it is a kind of with high hair conditioning without silicone oil without sulfate shampoo,
It is characterized in that, being made of the component for including following mass percentage content: sodium lauroyl sarcosine 20-40%, coconut oleoyl amine
Propyl betaine 10-30%, Polyquaternium-10 0.2-0.5% substitute silicone oil composite 0.7-1.5%, moisturizer 0.5-
1%, thickener 1.5-5%, chelating agent 0.01-0.1%, preservative 0.06-0.08%, essence 0.5-1%, citric acid 0.1-
0.5% and excess water.
In a specific embodiment, the substitution silicone oil composite includes the component of following mass percentage content:
PCA glyceryl oleate 0.5-1%, vegetable fat 0.2-0.5%.
In a specific embodiment, the vegetable fat is preferably two section mustard seed oil of deep-sea.
In a specific embodiment, the moisturizer is preferably xylitol glucoside/anhydro xylitol and xylose
The moisturizing agent composition of alcohol.
In a specific embodiment, the thickener includes the component of following mass percentage content: glycerol laurel
Acid esters 0.5-2%, coconut oleoyl amine methyl monoethanolamine 1-3%.
In a specific embodiment, the application provide it is a kind of with high hair conditioning without silicone oil without sulfate shampoo
Preparation method, which comprises the steps of:
(1) water, sodium lauroyl sarcosine, Cocoamidopropyl betaine, EDETATE SODIUM, the glycerol moon are added in agitated kettle
Cinnamic acid ester, coconut oleoyl amine methyl monoethanolamine, heating stirring；
(2) when being warming up to 70 DEG C, Polyquaternium-10 is added, stops heating after mixing evenly；
(3) when being cooled to 60 DEG C, PCA glyceryl oleate, two section mustard seed oil of deep-sea, xylitol glucoside, dehydration is added
Xylitol and xylitol, stir evenly；
(4) when being cooled to 45 DEG C, preservative, essence, citric acid is added, stops stirring after mixing evenly to get described
With high hair conditioning without silicone oil without sulfate shampoo.
Embodiment
Below in conjunction with embodiments herein, clear and complete description is carried out to the technical solution of the application.Such as nothing
It illustrates, reagent used and raw material can all be bought by commercial sources.Actual conditions are not specified in the following example
Experimental method according to conventional methods and conditions, or is selected according to product manual.
Sodium lauroyl sarcosine is purchased from Guangzhou Tianci Advanced Materials Co., Ltd, mass concentration 30%.
Cocoamidopropyl betaine is purchased from Evonik Degussa (China) Co., Ltd. Shanghai branch company, and quality is dense
Degree is 30%.
Polyquaternium-10 is purchased from Dow Chemical.
PCA glyceryl oleate is purchased from IOI grease Co., Ltd.
Two section mustard seed oil of deep-sea is purchased from Co., Ltd in Clariant chemical industry.
Xylitol glucoside, anhydro xylitol and xylitol are purchased from match BIC Corp, France.
Glycerol monolaurate is purchased from Belgium Ou Lian (OLEON) company.
Coconut oleoyl amine methyl monoethanolamine is purchased from flower king (China) joint-stock company.
Chelating agent EDETATE SODIUM is purchased from Akzo Nobel's chemicals (Ningbo) Co., Ltd.
Essence is purchased from IFF International Flavors & Fragrances Inc..
Preservative Microcare CM is purchased from Bristol specialty chemicals (Shanghai) Co., Ltd..
Citric acid is purchased from Weifang Ensign Industry Co., Ltd,.
Embodiment 1-3 and comparative example 1-3
Embodiment 1-3 without silicone oil without sulfate shampoo the preparation method is as follows:
(1) water, sodium lauroyl sarcosine, Cocoamidopropyl betaine, EDETATE SODIUM, the glycerol moon are added in agitated kettle
Cinnamic acid ester, coconut oleoyl amine methyl monoethanolamine, heating stirring；
(2) when being warming up to 70 DEG C, Polyquaternium-10 is added, stops heating after mixing evenly；
(3) when being cooled to 60 DEG C, PCA glyceryl oleate, two section mustard seed oil of deep-sea, xylitol glucoside, dehydration is added
Xylitol and xylitol, stirring；
(4) when being cooled to 45 DEG C, preservative, essence, citric acid is added, stops stirring after mixing evenly to get described
With high hair conditioning without silicone oil without sulfate shampoo.
The formula composition of embodiment 1-3 and comparative example 1-3 are as shown in table 1.
The formula composition of table 1. embodiment 1-3 and comparative example 1-3
Comparative example 1-3
The shampoo preparation method of comparative example 1-3 and embodiment 2 it is identical, but be formulated it is different, in preparation process also correspondingly
Do not add the raw material components lacked in formula.Specifically, PCA glyceryl oleate and deep-sea is not added in the formula of embodiment 2
The substitution silicone oil composite of two section mustard seed oils obtains comparative example 1.Substitution silicone oil composite in the formula of embodiment 2 is sweet with PCA
Oily oleate individually substitutes, and obtains comparative example 2.By the substitution silicone oil composite in the formula of embodiment 2 with two section mustard seed oil of deep-sea
Individually substitution, obtains comparative example 3.
4 Hair setting performance test of embodiment evaluation:
Experiment equipment: INSTRON static state combs instrument
Test method:
First use the cleaning of comparative example 1 to non-foam all natural untreated Asia topknots to be measured, in INSTRON static state
It carries out wet combing test dry on combing instrument.Then it is surveyed respectively with carrying out wet comb after embodiment 1-3 and comparative example 2-3 shampoo cleans
Examination；To topknot under conditions of 25 DEG C of room temperature, humidity 60% after natural drying, carry out dry cardability test.According to each topknot
The dry and wet of front and back twice sends out combing power, and dry and wet hair comb rationality enhancing rate is calculated.
Table 2 lists the Hair setting power test data of the shampoo of embodiment 1-3, comparative example 1-3 and the sale of a market.
This commercially available shampoo is the Head&Shoulders anti-dandruff shampoo of silicate-containing oil.
2. Hair setting example test data of table
Data show that the wet hair carding property and commercially available silicate-containing oil of the embodiment 1-3 containing silicone oil substitute composition is had one's hair wash
It shows one's true colours and works as, drying hair carding property enhancing rate is slightly above siliceous oil product.Embodiment 2, Dan Jia PCA containing silicone oil substitute composition
The comparative example 2 of glyceryl oleate, single comparative example 3 for deepening extra large two section mustard seed oils are compared, and the dry and wet hair comb rationality of embodiment 2 improves
Rate is higher than the summation of the increase rate of comparative example 2 and 3, illustrates two when PCA glyceryl oleate and two section mustard seed oil of deep-sea are used in compounding
The synergistic function of person makes final product have high conditioning performance.
The improvement of wet hair comb reason be because PCA glyceryl oleate has repaired the surface hydrophobic of impaired hair, in rubbing and
Rinse stage can make hair more soft and smooth.It is because PCA glyceryl oleate can help that dry cardability, which obtains improving,
Two section mustard seed oil sprawling on hair of vegetable fat deep-sea.PCA glyceryl oleate is after improving hair hydrophobicity, hydrophobic hair
Silk table face is more conducive to sprawling for vegetable fat, the vegetable oil of sufficient amount spread over can just be brought on hair the smooth of drying hair and
Soft feeling.Therefore, PCA glyceryl oleate is compounded to meet simultaneously with two section mustard seed oil of deep-sea and repairs hair surface hydrophobicity
Property, and the requirement of the lipid layer of hair scale piece is smoothed at one layer of hair surface spreading, so as to improve the entirety conditioning of no silicone oil shampoo
Property, solve the problems, such as that no short-tempered difficulty of silicone oil shampoo drying hair is arranged.
5 efficacy test of embodiment:
Further to compare shampoo service performance, each 30 progress Blind Test of 22-50 years old age men and women volunteer is chosen.Everyone
With 2 shampoo of embodiment and commercially available silicate-containing oil shampoo continuous hair washing 10 times respectively, washes within every two days once, then carries out questionnaire survey,
Investigation result is shown in Table 3.
3 shampoo contrast test of table
The result shows that embodiment 2 is suitable with commercially available silicate-containing oil shampoo at foam, wet cardability, smooth and soft aspect, it is wet
Commercially available siliceous shampoo is slightly excellent in terms of rushing feel, and embodiment 2 is slightly better than commercially available silicate-containing oil shampoo in terms of drying hair cardability and glossiness,
The hair conditioning having without silicone oil without sulfate shampoo and silicate-containing oil shampoo compares favourably for illustrating the present invention, efficiently solves use
The problem of short-tempered difficulty of drying hair is arranged after no silicone oil shampoo.
The above-mentioned description to embodiment is that this Shen can be understood and applied for the ease of those skilled in the art
Please.Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein
General Principle is applied in other embodiments without paying creative labor.Therefore, the application is not limited to implementation here
Example, those skilled in the art make according to herein disclosed content in the case where not departing from the application scope and spirit
It improves and modifies within all scope of the present application.
Claims (10)
1. it is a kind of with high conditioning performance without silicone oil without sulfate shampoo, which is characterized in that counted on the basis of mass percent,
The shampoo is made of following raw material components:
The water of surplus, wherein the sum of mass percent of all raw material components is 100%.
2. as described in claim 1 with high conditioning performance without silicone oil without sulfate shampoo, which is characterized in that the yin from
Sub- amino acid type surfactant includes in sodium lauroyl sarcosine, cocounut oil acyl methyl taurine sodium or sodium cocoyl glutamate
It is one or more of；
The amphoteric surfactant includes Cocoamidopropyl betaine, lauroylamidopropyl betaine, cocounut oil acyl both sexes base
One or more of sodium acetate or Sodium Lauroamphoacetate；
The cation opsonizing agent includes polyquaternium -7, Polyquaternium-10, polyquaternium -52, guar hydroxypropyltrimonium
One or more of ammonium chloride or hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chloride；
The pH adjusting agent is citric acid.
3. as claimed in claim 1 or 2 with high conditioning performance without silicone oil without sulfate shampoo, which is characterized in that it is described
Substitution silicone oil composite includes the component for accounting for the following mass percent of all raw material components gross masses: the PCA glycerol of 0.5-1%
The vegetable fat of oleate and 0.2-0.5%.
4. as claimed in claim 3 with high hair conditioning without silicone oil without sulfate shampoo, which is characterized in that the vegetable oil
Rouge is two section mustard seed oil of deep-sea.
5. as claimed in claim 1 or 2 with high hair conditioning without silicone oil without sulfate shampoo, which is characterized in that the guarantor
Humectant is the mixture of xylitol glucoside, anhydro xylitol and xylitol.
6. as claimed in claim 1 or 2 with high hair conditioning without silicone oil without sulfate shampoo, which is characterized in that the increasing
Thick dose includes the component for accounting for the following mass percentage content of all raw material components gross masses: the glycerol monolaurate of 0.5-2%
With the coconut oleoyl amine methyl monoethanolamine of 1-3%.
7. a kind of method without silicone oil without sulfate shampoo prepared as described in claim 1 with high hair conditioning, feature
It is, the described method comprises the following steps:
(1) mixed anion amino acid type surfactant, amphoteric surfactant, chelating agent, thickener and water, obtain first
Reaction mixture；
(2) the first reaction mixture is warming up to 70 DEG C -80 DEG C, uniformly mixes the first reaction mixture and cation opsonizing agent,
Obtain the second reaction mixture；
(3) the second reaction mixture is cooled to 60 DEG C -50 DEG C, uniformly mixes the second reaction mixture, substitution silicone oil composite
And moisturizer, obtain third reaction mixture；
(4) third reaction mixture is cooled to 45 DEG C hereinafter, uniformly mixing third reaction mixture, preservative, essence and PH
Regulator, obtain it is described with high hair conditioning without silicone oil without sulfate shampoo.
8. the method for claim 7, which is characterized in that in step (2), the temperature of the first reaction mixture is heated up
To 70 DEG C；
In step (3), the second reaction mixture is cooled to 60 DEG C.
9. the method for claim 7, which is characterized in that in step (1), the thickener be glycerol monolaurate and
The mixture of coconut oleoyl amine methyl monoethanolamine；
In step (3), substitution silicone oil composite is the mixture of two section mustard seed oil of PCA glyceryl oleate and deep-sea；
In step (3), moisturizer is the mixture of xylitol glucoside, anhydro xylitol and xylitol.
10. the method for claim 7, which is characterized in that described method includes following steps:
(1) water, sodium lauroyl sarcosine, Cocoamidopropyl betaine, EDETATE SODIUM, glycerol lauric acid are added in agitated kettle
Ester, coconut oleoyl amine methyl monoethanolamine, heating stirring；
(2) when being warming up to 70 DEG C, Polyquaternium-10 is added, stops heating after mixing evenly；
(3) when being cooled to 60 DEG C, PCA glyceryl oleate, two section mustard seed oil of deep-sea, xylitol glucoside, dehydration xylose is added
Alcohol and xylitol, stir evenly；
(4) when being cooled to 45 DEG C, preservative, essence, citric acid is added, stops stirring after mixing evenly, obtains described having
High hair conditioning without silicone oil without sulfate shampoo.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811502798.4A CN109481352B (en) | 2018-12-10 | 2018-12-10 | Silicone oil-free and sulfate-free shampoo with high conditioning performance and preparation method thereof |
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| CN201811502798.4A CN109481352B (en) | 2018-12-10 | 2018-12-10 | Silicone oil-free and sulfate-free shampoo with high conditioning performance and preparation method thereof |
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| CN109481352B CN109481352B (en) | 2021-07-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110623853A (en) * | 2019-07-29 | 2019-12-31 | 德亚生物科技有限公司 | Cleaning and nursing composition and preparation method thereof |
| CN113425615A (en) * | 2021-08-16 | 2021-09-24 | 中山市匠研日用化工有限公司 | Deep-care smooth shampoo without silicone oil and sulfate and preparation method thereof |
| CN113499303A (en) * | 2021-08-16 | 2021-10-15 | 中山市匠研日用化工有限公司 | Moisturizing, repairing, silicone oil-free and sulfate-free shampoo and preparation method thereof |
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| CN105213224A (en) * | 2015-09-22 | 2016-01-06 | 拉芳家化股份有限公司 | A kind of Haircare composition of moisturizing |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110623853A (en) * | 2019-07-29 | 2019-12-31 | 德亚生物科技有限公司 | Cleaning and nursing composition and preparation method thereof |
| CN110623853B (en) * | 2019-07-29 | 2022-09-09 | 德亚生物科技有限公司 | Cleaning and nursing composition and preparation method thereof |
| CN113425615A (en) * | 2021-08-16 | 2021-09-24 | 中山市匠研日用化工有限公司 | Deep-care smooth shampoo without silicone oil and sulfate and preparation method thereof |
| CN113499303A (en) * | 2021-08-16 | 2021-10-15 | 中山市匠研日用化工有限公司 | Moisturizing, repairing, silicone oil-free and sulfate-free shampoo and preparation method thereof |
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| CN109481352B (en) | 2021-07-16 |
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