CN109757099A - It is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo - Google Patents
It is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo Download PDFInfo
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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Abstract
It is a kind of containing plant extracts without silicone oil shampoo, which is derived from Rhizoma Zingiberis zerumbet petal.Except containing the acceptable group of shampoo, exceptionally, also contain: (A) accounts for the lauryl sulfate of shampoo weight 8% and account for the ethoxylated dodecyl alcohol ammonium sulfate of shampoo weight 12%, and accounts for the Cocoamidopropyl betaine of shampoo weight 6%；(B) cation guar gum of shampoo weight 0.15% is accounted for；(C) the Rhizoma Zingiberis zerumbet petal extract of shampoo weight 1-15% is accounted for；(D) it accounts for the Natrulon H-10 of shampoo weight 0.1-2% and accounts for the polyglycerol ester of shampoo weight 0.05-1%.
Description
Technical field
The invention belongs to daily chemicals fields, and in particular to it is a kind of containing plant extracts without silicone oil shampoo, the plant extract
Object is derived from Rhizoma Zingiberis zerumbet petal.
Background technique
Plant or Chinese medical extract are very universal for such as shampoo of hair cleaning products.Chinese medical extract is used for head
Hair cleaning products need to consider various factors and need to be selected according to its special effect feature.Than if any plant
Extract takes the fragrance that it is naturally felt, some plant extracts can be enhanced the quality of foam and the hair conditioning of hair, have
Plant extracts takes good care of dry scalp or hair, and some plant extracts increase the even correct luminance of the plentiful degree of hair
The promotion of degree has effect etc..
Ginger be it is a kind of live closely related plant with people, the application in terms of cosmetology and personal nursing also has
Long history.The characteristic that has its intrinsic in the application aspect of ginger, every kind of ginger and for different purposes.
Ginger is a kind of herbaceos perennial, ginger (scientific name: Zingiber officinale), and is divided into various types, is had
Ginger (white ginger), yellow ginger, erythrodontia ginger, white ginger have good aromatic character, and the root of yellow ginger, ginger or erythrodontia ginger is edible
Or it is medicinal, according to " Canoe Plants of Ancient Hawai`i " (http://www.canoeplants.com/
Awapuhi.html), record, be called " Rhizoma Zingiberis zerumbet " there are one kind, be also called shampoo ginger, Rhizoma Zingiberis zerumbet can be not only used for fragrance again
It can be used for shampoo composite and play the role of cleaning and conditioning hair, the petal extract of Rhizoma Zingiberis zerumbet can be used for developing more
The shampoo naturally felt.
Rhizoma Zingiberis zerumbet be Zingiber herbaceos perennial, 0.6-2 meters of plant height；Total bennet is 10-30 centimetres long；Inflorescence strobiloid,
6-15 centimetres long, 3.5-5 centimetres wide, at florescence 7-10 month, the 7-8 month sees bract light green, gradually becomes red ball to the 9-10 month
Shape.It is similar to flourishing flame bulb, therefore named Rhizoma Zingiberis zerumbet.Originate in the provinces and regions such as Chinese Guangdong, Guangxi, Yunnan；It is born in the shady wet place of hayashishita.Asia heat
Band area blazons.Collywobbles, diarrhea are controlled in rhizome energy wind-dispelling removing toxic substances, and extractable aromatic oil is made blending flavor of raw material and used.
The information retrieval put on record at present according to non-specialization cosmetic, sold daily chemical products such as shampoo hair care category contains currently on the market
Having the product of ginger extract, there are many brands, and the ginger extract of all brand product marks is ginger or white its Latin of ginger type
Scientific name is Zingiber officinale, and ginger Zingiber officinale extract is rhizome extract, in product
In additive amount it is few and certain products also added the essence of ginger odor characteristic, in addition, not finding to indicate washing for " Rhizoma Zingiberis zerumbet "
Send out hair products, also without discovery indicate " Rhizoma Zingiberis zerumbet " without silicone oil shampoo.It is therefore desirable to study plant " Rhizoma Zingiberis zerumbet "
Characteristic carries out the exploitation without silicon shampoo.
Summary of the invention
It is an object of the present invention to provide a kind of containing plant extracts without silicon shampoo, which is Rhizoma Zingiberis zerumbet flower
Luxuriant extract.
The purpose of the present invention is be achieved: it is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo, except containing washing
The acceptable group of shampoo exceptionally, also contains:
(A) it accounts for the laurel alkyl ammonium sulfate of shampoo weight 8% and accounts for the lauryl alcohol polyethylene glycol oxide of shampoo weight 12%
Ether ammonium sulfate, and account for the Cocoamidopropyl betaine of shampoo weight 6%；
(B) cation guar gum of shampoo weight 0.15% is accounted for；
(C) the Rhizoma Zingiberis zerumbet petal extract of shampoo weight 1-15% is accounted for；
(D) it accounts for the Natrulon H-10 of shampoo weight 0.1-2% and accounts for the polyglycerol ester of shampoo weight 0.05-1%, and
The weight ratio of Natrulon H-10 and -6 dioleate of polyglycereol, Natrulon H-10: -6 dioleates of polyglycereol=3:1.
It is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo, component and content are as follows:
Compared with prior art, the invention has the following advantages that
The present invention contain Rhizoma Zingiberis zerumbet petal extract without silicon shampoo, there is more excellent foam volume, foaming structure
With foam tactile and good spatter property, good experience sense is such as, plentiful during good foam characteristic can enhance hair washing
The touch sense and submissive sense during rinsing etc. when can increase shampoo top of foam sense organ and cotton thin foam tactile,
And the association for showing good foam characteristic and spatter property is applied in combination in Rhizoma Zingiberis zerumbet petal extract and polyglycereol and polyglycerol ester
With effect and mildness it is good, cleaning suitable for scalp and hair.
Specific embodiment
Below with reference to embodiment, invention is further described in detail.
Surfactant: surfactant used in the present invention can be sulfated surfactant system, or
Amino acid surfactant system.
Surfactant system that amino acid surfactant system of the present invention includes and related mating raw material such as, cocounut oil acyl
Base glutamate is such as: cocoyl glutamic acid TEA salt, cocoyl potassium glutamate, sodium cocoyl glutamate；Cocoyl flesh
Propylhomoserin salt such as Sodium Coco acylsarcosinate, cocoyl sarcosine potassium and cocoyl sarcosine TEA salt.Furthermore amino acid table
Surfactant system can be configured with cosurfactant such as: C14-16 alkene sulfonic acid sodium, lauroyl are by propyl betaine, coconut palm
Oleamide methyl MEA, glycerol monolaurate, PEG-7 glyceryl cocoate and cationic polymer such as Polyquaternium-10, sun
Cosmetically acceptable carrier has been such as cationic guar etc.: essence, preservative, pigment, chelating agent.
In order to compare with commercially available product, it is preferable to use sulfate for surfactant system contained by shampoo of the present invention
Type anionic surfactant system.
In sulfated surfactant system the performance and dosage of each surfactant as follows such as, containing accounting for no silicon hair washing
The lauryl sulfate of water weight 5-40% and the composition of ethoxylated dodecyl alcohol ammonium sulfate, the lauryl sulfate with
The ratio of ethoxylated dodecyl alcohol ammonium sulfate is 1:2-2:1.The lauryl sulfate abbreviation K12A or SLSA, structural formula
Are as follows: ROSO3NH4 +, R=C12-C18Alkyl, the commercially available preferred active matter content of ammonium alkyl sulfate be 70%, appearance be white or
Pale yellow paste, it is good detergency that the lauryl sulfate has, hard water resistance property, lower irritation, higher
Foaming power and excellent compatibility.The fatty alcohol polyoxyethylene ether ammonium sulfate abbreviation AESA, structural formula RO
(CH2CH2O)nSO3NH4 +, R=C12-C18Alkyl, n 2-4, preferably averagely ethoxyquin degree is n=3, the laruyl alcohol polyoxy
The active matter content of ethylene ether ammonium sulfate commercial product has 25% and 70% two kind, the laruyl alcohol polyoxy second of 25% active matter content
Alkene ether ammonium sulfate is colorless and transparent thick liquid, and the ethoxylated dodecyl alcohol ammonium sulfate of 70% active matter content is white or light
The ethoxylated dodecyl alcohol ammonium sulfate that yellow paste, preferably active matter content are 70%.The ethoxylated dodecyl alcohol
Ammonium sulfate also has the characteristic of nonionic surfactant, still has preferable dirt-removing power in hard water.The laruyl alcohol sulphur
Being used in compounding for sour ammonium and laruyl alcohol polyoxy ether ammonium sulfate, can produce good synergistic effect, such as: having fine and close and enriches
Foam, extremely mild feeling, outstanding thickening properties etc..
In the present invention, lauryl sulfate accounts for shampoo weight percent 8% of the present invention, ethoxylated dodecyl alcohol sulfuric acid
Ammonium accounts for shampoo weight percent 12% of the present invention.
In addition, the also cocounut oil both sexes comprising accounting for no silicon shampoo weight 1.0% to 10.0% in sulfate type table living body system
Sodium acetate or Cocoamidopropyl betaine, the cocoyl both sexes sodium acetate are colourless to yellowish clear viscous liquids,
The active matter content of commercial product is 30%, under the conditions of 25 DEG C, viscosity 5000-10000, sodium chloride content less than 9.0%,
The pH of 1% aqueous solution is 6.0-8.0, and structural formula is RN (CH2COONa), and the irritation of the cocoyl both sexes sodium acetate is low,
It is especially mild to skin, eyes, it can significantly reduce its irritation with anionic surfactant matching, and there is good foaming
Power, foaming abundancy is fine and closely woven, and skin sense is good, can significantly improve the foam state of formula system.The Cocoamidopropyl betaine is
Yellowish transparency liquid, the active matter content of commercial product are 30%, and for sodium chloride content less than 6.0%, free amine content is small
It is 5.0-7.0 in the pH value of 0.10%, 1% aqueous solution, structural formula is RCONH (CH2)3N+(CH3)2CH2COO-.The coconut palm
Oleamide propyl betaine has excellent compatibility, and has excellent foaminess and significant thickening property, has good
Hard water resistance property, antistatic property and biological degradability, the preferred Cocoamidopropyl betaine of the present invention, the present invention in coconut oleoyl amine third
Base glycine betaine accounts for the weight percent 6% of shampoo of the present invention.
Cationic polymer: in shampoo composite of the invention containing account for composition weight 0.05% to 3.0% sun from
Sub- polymer, the cationic polymer are selected from: at least one in cationic cellulose polymer, cationic melon rubber polymer
Kind.The cationic cellulose polymer is the copolymer of hydroxyethyl cellulose and alkyl trimethyl ammonium chloride, according to cation
The difference of degree of substitution can be divided into: high-cation degree of substitution JR, middle degree ofacationic substitution LR and tri- kinds of types of low degree ofacationic substitution LK
Number, the preferably cationic cellulose polymer of high-cation degree of substitution, i.e. Polyquaternium-10 are other suitable for of the invention
There are also hydroxyethyl celluloses and the copolymer of dialkyl dimethyl ammonium chloride etc. for cationic cellulose polymer；The cation melon
Youngster's glue is the product for obtaining melon rubber after quaternized, and main component is melon rubber hydroxypropyltrimonium chloride, according to substitution
A series of cationic melon rubber product can be obtained in the difference of degree, and preferably degree of substitution is 0.1 to 0.2, for sun of the invention from
For sub- melon rubber under the conditions of 25 DEG C, the viscosity of 1% aqueous solution is 2000mPa.s to 4000mPa.s.Preferred cationic of the present invention
Guar polymer, subject cationic guar polymer account for shampoo weight percent 0.15% of the present invention.
Polyglycereol and its esters conditioner: hair conditioner composition of the present invention is such as poly- except conventional use of cationic polymer
Outside quaternary ammonium salt -10 and cation guar gum, polyglycereol and polyglycereol esters, dimethyl silica alkanes, fatty alcohols can be used
And its mixture；Shampoo of the present invention is no silicone oil shampoo, and therefore, conditioner preferably glycerine esters of the present invention are suitable for this
The polyglycereol and glyceride type of invention are selected from: polyglycereol -2, Natrulon H-10, Polyaldo DGDO(10-10-0), gathers polyglycereol -6
- 6 distearate of glycerol, -6 oleate of polyglycereol, -6 dioleate of polyglycereol, six oleate of glycerol -6, Natrulon H-10 are stearic
Acid esters and its mixture.By optimization, the polyglycereol that the present invention selects is Natrulon H-10, the polyglycereol conditioning that the present invention selects
Its HLB value of agent is between 7-10, therefore preferred -6 monoleate of polyglycereol of polyglycereol conditioner of the present invention or polyglycereol -6 two
Oleate, the polyglycereol conditioner of optimal selection of the present invention are -6 dioleate of polyglycereol, thus hair conditioner of the present invention at
Part in addition to conventional use of cationic polymer such as Polyquaternium-10 and cation guar gum, further preferably Natrulon H-10 and poly-
- 6 dioleate of glycerol.
Natrulon H-10: Natrulon H-10 appearance is yellow or light yellow clear liquid, and (25 DEG C) of density are 0.910-
1.180, CAS NO.9041-07-0., Natrulon H-10, ten glycerol ring poly structure and form the effect of cage water lock, then plus
Upper hydrogen bond association, moisture retention effect are obvious and lasting.Further, since bull's eye poly structure and cage water lock effect, hydrophobicity point
Son, which enters in cage, to be locked such that form the effect of grease general character, and the effect of this grease general character enables Natrulon H-10 in skin
On skin and hair continuous film forming and have the silty sense of touch similar with silicone oil elastomer, therefore, Natrulon H-10 fills in the present invention
When the effect of moisturizing and conditioning.
- 6 dioleate of polyglycereol: -6 dioleate alias of polyglycereol: the double oil of two oleic acid, six polyglycerol ester, polyglycereol -6-
Acid esters, CAS:76009-37-5, acid value (mg KOH/g)≤2.0, saponification number (mg KOH/g) 150-180, iodine number: (g I2/
100g) 340.HLB value about 8.0；- 6 dioleate of polyglycereol is light yellow to yellowish clear oil liquid.Free from admixture, it is odorless
It is tasteless, it is dissolved in ether, chloroform and carbon tetrachloride, is slightly soluble in ethyl alcohol.- 6 dioleate of polyglycereol is practically insoluble in water in the present invention,
It is dispersed in water.
- 6 dioleate of Natrulon H-10 and polyglycereol of the present invention forms the network structure of macromolecular, except playing scalp and head
Outside the moisturizing and opsonic action of hair, Natrulon H-10 and -6 dioleate of polyglycereol and Rhizoma Zingiberis zerumbet petal extract of the present invention can also
Play the role of stable foam and promoted foam quality (improving foaming structure and elasticity), is had to the spatter property of shampoo certain
Synergy and reduce the irritation of surfactant.
The weight ratio of Natrulon H-10 of the present invention and -6 dioleate of polyglycereol are as follows: Natrulon H-10: two oleic acid of polyglycereol -6
Ester=3:1
It is 0.1-4% that wherein Natrulon H-10, which accounts for shampoo weight percent of the present invention, is advanced optimized as 0.2-2%；It is poly-
It is 0.05-1% that -6 dioleate of glycerol, which accounts for shampoo weight percent of the present invention, is advanced optimized as 0.07-0.67%.
Cosmetically acceptable carrier
Remaining cosmetically acceptable carrier of the invention can contain pearlite slurry, the main active substances in the pearlite slurry
For ethylene glycol monostearate and ethylene glycol double stearate.The addition of the pearlite slurry can assign shampoo beautiful pearly-lustre
Effect.
The present invention can also include other optional components, including viscosity-controlling agent, chelating agent, pH adjusting agent, preservative, color
Element and fragrance etc..The viscosity-controlling agent accounts for the 0.1% to 5.0% of composition weight, the viscosity-controlling agent it is non-limiting
Example has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, cellulose derivative, acrylic copolymer etc..The chelating agent accounts for
The non-limiting example of the 0.01% to 0.30% of composition weight, the chelating agent has: ethylenediamine tetra-acetic acid, ethylenediamine tetrem
Acid disodium, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferably disodium ethylene diamine tetraacetate；The pH tune
The non-limiting example of section agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system is 4.0 to 6.0, preferably 4.5
To 5.5；The selection of the preservative, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material.
In shampoo composite of the invention, exceptionally in addition to the above group, mended with water to aequum.
Rhizoma Zingiberis zerumbet shampoo of the present invention includes following main component composition (it is as follows to account for shampoo weight percent of the present invention)
A) Rhizoma Zingiberis zerumbet extract accounts for shampoo weight 0.5-20% of the present invention, advanced optimizes as 1-15%；
B) surfactant accounts for shampoo weight 5-40% of the present invention, advanced optimizes the lauryl sulfate for 8%,
12% laureth ammonium sulfate, 6% Cocoamidopropyl betaine；
C) cationic polymer accounts for shampoo weight 0.05-3% of the present invention, and advanced optimizing is 0.15%；
D) polyglycereol and its esters conditioner account for shampoo weight 0.15-5% of the present invention, advanced optimize as polyglycereol-
10 be 0.2-2.0%, and -6 dioleate of polyglycereol is 0.07-0.67%, and the weight of Natrulon H-10 and -6 dioleate of polyglycereol
Amount is than being 3:1.
And the water of surplus e).
Rhizoma Zingiberis zerumbet petal extract: weight percent is 0.5-20% to Rhizoma Zingiberis zerumbet petal extract in the present invention, into one
Step is optimized for 1-15%.
The preparation method of Rhizoma Zingiberis zerumbet petal extract:
1, petal is picked: when Rhizoma Zingiberis zerumbet florescence 9-10 month, the inflorescence of strobiloid becomes red, represents Rhizoma Zingiberis zerumbet
It is mature.Acquire its petal at this time, petal away from luxuriant 2 centimeters of stem bottom from cutting off and be put into 4 degrees Celsius of containers store.
2, it squeezes: the petal of acquisition is put into squeezer (squeezing about 1 ton of weight) squeezing, then collect mucus, in mucus
Bract containing about 2 cm diameters is with some particles.
3, it filters: the above Rhizoma Zingiberis zerumbet petal mucus being sieved with 10 mesh stainless steels and is filtered, bract and tiny solid are removed
Particle becomes Rhizoma Zingiberis zerumbet petal first squeezing mucus.
4, preservative treatment: the above first squeezing mucus is subjected to preservative treatment, first squeezing mucus is added to the benzene oxygen second of weight 0.5%
Alcohol, is added the Bis(hydroxymethyl)imidazolidinyl urea of weight 0.6% and the EDTA-2 sodium of weight 0.1%, is mixed later straight
To dispersion and dissolution.
5, the first squeezing mucus after preservative treatment centrifugal filtration: is placed in the centrifuge for being equipped with 60 mesh filter screen, centrifugation speed
Degree is 10000-15000 revs/min, and the finely ground particles that particle is greater than 60 mesh are separated.
6, refined filtration: by above-mentioned steps 5) filtered fluid is placed in the centrifuge for being equipped with 100 mesh filter screen, and centrifugal speed is
10000-15000 revs/min, the finely ground particles that particle is greater than 100 mesh are separated and finally obtain Rhizoma Zingiberis zerumbet petal extract.
The chemical analysis of Rhizoma Zingiberis zerumbet petal extract:
Calcium ion (milligram)/100 gram extract: 2-4
Iron ion (milligram)/100 gram extract: 0.1-0.2
Potassium ion (milligram)/100 gram extract: 15-22
Sodium ion (milligram)/100 gram extract: 18-20
Fatty (gram)/100 gram extract: 0.01-0.03
Protein (gram)/100 gram extract: 0.5-1.5
Carbohydrate (gram)/100 gram extract: 0.05-0.1
Moisture (gram)/100 gram extract: 99.
Preparation method of the invention.
Shampoo composite of the invention can be by any known or other effective suitable for providing shampoo composite
Technology preparation, the method for preparing shampoo composite of the invention includes conventional preparation and hybrid technology.
Application method
Shampoo composite of the invention is used in a manner of conventional cleaning and conditioning hair, mainly includes following step
It is rapid:
(A) hair is soaked with water；
(B) shampoo composite of a effective amount of aforementioned any one claim, the effective agent are applied on the hair
Amount is generally in the range of 1 gram to 50 grams, preferably 2 to 20 grams；A small amount of shampoo of the present invention is first taken first to wash hair skin and root of hair for the first time,
It is taken for the second time after flushing than hair washing water wash my hairs more for the first time.
These steps can according to need repeatedly, with reach sought scalp and hair cleaning, conditioning, moisten and
The effect of moisturizing.
Embodiment
Here is the non-limiting example of shampoo composite of the invention.These embodiments be only given in order to illustrate
Purpose, limitation of the invention can not be interpreted as, can be with because without departing from the spirit and scope of the present invention
Many changes are carried out to the present invention.In these embodiments, unless stated otherwise, all concentration is all weight percent.Institute
Those of optional substance is referred to term " a small amount of substance ", such as preservative, viscosity modifier, pH adjusting agent, fragrance, pigment
Deng the selection of these a small amount of substances will change with the selected physics to prepare special component of the invention and chemical characteristic
Become.
Prepare embodiment: comparison 1, comparison 2, comparison 3 and comparison 4 and embodiment I-VI
Suitable preparation embodiment comparison 1, comparison 2, comparison 3 and comparison 4 and embodiment I-VI, wherein the shampoo
The method of composition is as follows: suitable quantity of water being added in reactor tank, Natrulon H-10 and the stirring point of -6 dioleate of polyglycereol is added
It dissipates uniformly, cation guar gum is then added under slow stirring and is dispersed, is heated to 60 DEG C to 80 DEG C, is subsequently added into laurel
Alkylsurfuric acid ammonium, ethoxylated dodecyl alcohol ammonium sulfate, Cocoamidopropyl betaine, disodium ethylene diamine tetraacetate are (if made
With these substances), cool down after being completely dispersed these substances.Rhizoma Zingiberis zerumbet petal extract is added when temperature is down to 65 DEG C or so
If (using this substance), continues to stir and cool down, sodium chloride, citric acid, preservative, coloring are added when cooling to 50 DEG C
Agent (pigment), essence etc. continue to stir, it is ensured that obtain uniform mixture.After all components are added, it can add as needed
Enter viscosity modifier and pH adjusting agent, adjust the viscosity of product, pH value is adjusted to 4.5-5.5, water can finally be added and supply.
Embodiment: comparison 1, comparison 2 and embodiment I-III
Embodiment: comparison 3, comparison 4 and embodiment IV-VI
Highly preferred embodiment of the present invention is:
Each embodiment foam situation table
Comparison 1, comparison 2, the Roche foam height and foamed elastic (average value) of 4 compositions of comparison 3 and comparison are respectively less than
Embodiment I-III and embodiment IV-VI illustrate in the present invention with plant extracts Rhizoma Zingiberis zerumbet petal extract and conditioning
The addition of -6 dioleate of agent Natrulon H-10 and polyglycereol has certain effect to the promotion tool of foam quality of the present invention, and
With the increase of additive amount, the promotion effect of foam quality is better, and wherein embodiment V is best.Comparison 2 compares bubble with comparison 3
Foam Flexible change is little, and foam height value added is larger, illustrates the present invention the case where not containing Rhizoma Zingiberis zerumbet petal extract
Under, with the increase of -6 dioleate weight percent of conditioner Natrulon H-10 and polyglycereol, height (foam volume) meeting of foam
Increase therewith.
Efficacy test
Properties of product test (foam characteristic)
(a) shampoo (shampoo of the extract of petal containing Rhizoma Zingiberis zerumbet/said without silicone oil-with embodiment V of the present invention
It is bright, the same below)
(b) compare shampoo (without containing any extract/without silicone oil-with compare 3 examples be illustrated, it is the same below)
(c) commercial shampoos (containing Ginger P.E/be illustrated with commercially available certain brand A without silicon shampoo without silicone oil-,
It is the same below)
It is tested using the test method of Roche (Ross--Mi les) foamer meter, it is high to test initial foam respectively
Degree, foam height and foam height after five minutes, are then averaged and (are shown in Table 1) after 1 minute
Table 1
Foam value is bigger, and the foam performance for illustrating shampoo is better.It can be seen that by the above numerical value and compare hair washing
Water is compared with commercial shampoos, and the foaming properties for the shampoo that the present invention contains Rhizoma Zingiberis zerumbet petal extract are superior to comparison hair washing
Water and commercial shampoos.
Foaming structure research
Above (a) (b) (c) shampoo is configured to the aqueous solution of volume ratio 2% such as, 2% shampoo (a)+98% go from
Sub- water；+ 98% deionized water of 2% shampoo (b)；+ 98% deionized water of 2% shampoo (c) stirs evenly spare.
Respectively by above 150 milliliters spare of (a) aqueous solution shampoo, (b) aqueous solution shampoo and the shampoo of (c) aqueous solution are set
Enter to have the high cylinder flask of agitating paddle, then quickly stirs 20 seconds, then take 1 gram of foam to be put into the center of paper handkerchief, after ten minutes
The distance that observation water infiltrates outward, the distance that water infiltrates outward is shorter, and the density and thickness of foam are bigger, conversely, foam is diluter
It is thin.Use high-speed stirred in this experiment and generate foam imitate during practical hair washing caused by foam.It the results are shown in Table 2,
Table 2
As the result is shown compared with control shampoo and commercial shampoos, the present invention contains the hair washing of Rhizoma Zingiberis zerumbet petal extract
The total infiltration distance of water is less than reference substance and commercial shampoos, illustrates that shampoo of the present invention has denseer foaming structure.
Foam feels sensory evaluation
The structure and elasticity of foam can make one to generate the quality of foam different feelings.
This experiment is manually evaluated using the foam that foaming structure experimental method obtains.
(1) foaming structure sensory evaluation, score value are divided into 1-5 point, and 1 point represents loose foam, 5 points represent it is tiny and highly dense
The foam of degree.
(2) foamed elastic sensory evaluation method are as follows:, score value is divided into 1-5 point, and 1 point represents foam and is easy to touch deformation, and 5 points
It is good to represent foamed elastic, after touching, foam is easy to restore its shape.
No matter above evaluation (1) or (2) numerical value is bigger represents consumer and more likes.It is shown in Table 3 and table 4 respectively.(the bubble of table 3
Foam structure sensory evaluation)
As the result is shown compared with control shampoo and commercial shampoos, the present invention contains the hair washing of Rhizoma Zingiberis zerumbet petal extract
The total infiltration distance of water is less than reference substance and commercial shampoos, illustrates that shampoo of the present invention has denseer foaming structure.
Table 4 (foamed elastic sensory evaluation)
As the result is shown compared with comparison shampoo and commercial shampoos, the present invention contains the hair washing of Rhizoma Zingiberis zerumbet petal extract
Water, no matter the sensory evaluation numerical value of foaming structure sensory evaluation or foamed elastic is above reference substance and commercial shampoos, steeps
Touch sense and submissive experience sense during rinsing when the promotion of foam structure and foamed elastic is for shampoo top have very big
Help, illustrate shampoo of the present invention have more excellent foam characteristic.
Spatter property test
Above (a) (b) (c) shampoo is configured to the aqueous solution of volume ratio 2% such as, 2% shampoo (a)+98% go from
Sub- water；+ 98% deionized water of 2% shampoo (b)；+ 98% deionized water of 2% shampoo (c) stirs evenly spare.
The preparation of Synthetic Oil:
Synthetic Oil is to imitate the composition of grease in hair and be designed.
According to weight ratio, by olive oil 30%, palmitinic acid 10%, stearic acid 10%, oleic acid 10%, paraffin 10%, spiny dogfish
Alkene 15%, beeswax 15% are put together, and are heated until dissolving and being uniformly dispersed, spare.
It takes configured Synthetic Oil weight percent 5% to be added in the ethyl alcohol of weight percent 95% and is configured to 5%
Synthetic Oil solution.
Three groups every group 15 topknots are taken, the size of topknot is 10 centimetres long, and 1 centimetre wide, each topknot samples weighing simultaneously records.
It is taken out by the Synthetic Oil solution of sample topknot merging 5% and after infiltrating 1 minute, then air-dries, weigh, that is, can determine topknot sample
The weight (mg) of remaining Synthetic Oil in product.It is ready for the aqueous solution of volume ratio 2% and contains respectively containing (a) present invention
There is the shampoo of Rhizoma Zingiberis zerumbet petal extract；(b) shampoo (not containing Rhizoma Zingiberis zerumbet petal extract) and (c) commercially available hair washing are compareed
Each 500 milliliters of water (containing Ginger P.E) spare.It will be more than three groups of processed topknot immersions of Synthetic Oil solution with 5%
It is cleaned 2 minutes in three 500 milliliters of shampoo, dry 12 hours is put into drying box after being rinsed with water 1 minute, are taken out simultaneously
It weighs again, and calculates the removal amount of the residuals on hair (Synthetic Oil), finally calculate the average removal amount of topknot
It is shown in Table 5
Table 5
The above results show that shampoo of the present invention and comparison shampoo have the function of preferably removing Synthetic Oil, and
Shampoo of the present invention has stronger cleaning capacity, comparison discovery, and commercial shampoos are inferior in terms of hair cleaning capacity
Shampoo of the present invention.
Claims (2)
1. a kind of also containing except group is subjected to exceptionally containing shampoo without silicon shampoo containing Rhizoma Zingiberis zerumbet petal extract:
(A) it accounts for the laurel alkyl ammonium sulfate of shampoo weight 8% and accounts for the ethoxylated dodecyl alcohol sulphur of shampoo weight 12%
Sour ammonium, and account for the Cocoamidopropyl betaine of shampoo weight 6%；
(B) cation guar gum of shampoo weight 0.15% is accounted for；
(C) the Rhizoma Zingiberis zerumbet petal extract of shampoo weight 1-15% is accounted for；
(D) it accounts for the Natrulon H-10 of shampoo weight 0.1-2% and accounts for the polyglycerol ester of shampoo weight 0.05-1%, and gather sweet
The weight ratio of oil -10 and -6 dioleate of polyglycereol, Natrulon H-10: -6 dioleates of polyglycereol=3:1.
2. it is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo, component and content are as follows:
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| Application Number | Priority Date | Filing Date | Title |
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| PCT/CN2017/100471 WO2019047000A1 (en) | 2017-09-05 | 2017-09-05 | Silicone-free shampoo containing zingiber zerumbet flower bud extract |
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| WO (1) | WO2019047000A1 (en) |
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| CN109757099B (en) | 2021-08-10 |
| WO2019047000A1 (en) | 2019-03-14 |
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