CN109456849A - A kind of environment amenable liquid detergent - Google Patents

A kind of environment amenable liquid detergent Download PDF

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Publication number
CN109456849A
CN109456849A CN201811349232.2A CN201811349232A CN109456849A CN 109456849 A CN109456849 A CN 109456849A CN 201811349232 A CN201811349232 A CN 201811349232A CN 109456849 A CN109456849 A CN 109456849A
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CN
China
Prior art keywords
sodium
liquid detergent
methyl ester
fatty acid
kathon
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811349232.2A
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Chinese (zh)
Inventor
熊道陵
刘健聪
邱萍
王露琦
宗毅
郭彤麟
曹雪文
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Jiangxi University of Science and Technology
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Jiangxi University of Science and Technology
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Publication date
Application filed by Jiangxi University of Science and Technology filed Critical Jiangxi University of Science and Technology
Priority to CN201811349232.2A priority Critical patent/CN109456849A/en
Publication of CN109456849A publication Critical patent/CN109456849A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to the liquid detergent that one kind is newly formulated, specifically a kind of environment amenable liquid detergents.The present invention counts in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 5%-20%, alkyl glycosides 4%-8%, sodium n-alkylbenzenesulfonate 2%-10%, sodium carbonate 1%-2%, sodium metasilicate 0.5%-1%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium chloride 0.1%-0.3%, essence 0.2%-0.6%, Kathon CG 0.05%-0.2%, deionized water 57.5%-80%.Clean effect of the present invention is obvious, and under conditions of same amount, dirt-removing power is better than national standard liquid detergent, and comprehensive dirt-removing power is strong.And the biodegradability of used raw material is very high, it is non-hazardous to human body, environment.

Description

A kind of environment amenable liquid detergent
Technical field
The present invention relates to the liquid detergent that one kind is newly formulated, specifically a kind of environment amenable liquid detergents.
Background technique
Population base of China is big, and the liquid detergent market as daily life required article is huge, with people's living standard Raising, people are more eager to the pursuit of high-quality life, and the requirement to liquid detergent is higher and higher, therefore liquid detergent must have Standby good soil release performance and economy, while also to meet the characteristics such as environmental protection, safety.However hand is hurt in existing commercial laundry liquid presence Hurt clothing, endanger environment, the disadvantages of clean effect is poor.
New lover of the liquid detergent as articles for washing market, is just increasingly liked by consumer.Washing currently on the market Clothing liquid is deployed by chemical substance mostly, and use for a long time can generate injury to skin, is also unfavorable for environmental protection.According to phase Reported in literature is closed, currently, China's liquid detergent uses the sulphurs such as sodium sulfate of polyethenoxy ether of fatty alcohol AES, α-sodium olefin sulfonate AOS more Primary raw material of the hydrochlorate anionic surfactant as liquid detergent.Although this liquid detergent has preferable detergency ability, It is that raw material is difficult to natural degradation, not environmentally, and has certain stimulation to skin.Therefore environmental-friendly do not stimulate simultaneously is developed The liquid detergent for having both fine detergency ability is necessary.
Summary of the invention
The technical problem to be solved in the present invention is that provide a kind of environment amenable liquid detergent, in good same of cleaning effect When, raw material is degradable, will not be detrimental to health and environment.
Technical solution of the present invention: a kind of environment amenable liquid detergent is counted in mass ratio, including Fatty acid methyl ester ethoxy Glycolylate sodium sulfonate 5%-20%, alkyl glycosides 4%-8%, sodium n-alkylbenzenesulfonate 2%-10%, sodium carbonate 1%-2%, Sodium metasilicate 0.5%-1%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium chloride 0.1%-0.3%, essence 0.2%- 0.6%, Kathon CG 0.05%-0.2%, deionized water 57.5%-80%.
Preferentially, it counts in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 6%-18%, alkyl glycosides 5- 7%, sodium n-alkylbenzenesulfonate 4%-8%, sodium carbonate 1.2%-1.8%, sodium metasilicate 0.6%-0.9%, ethylenediamine tetra-acetic acid Disodium 0.2%-0.4%, sodium chloride 0.15%-0.25%, essence 0.3%-0.5%, Kathon CG 0.06%-0.18%, deionization Water 54.9%-80%.
Preferentially, count in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 5%-16%, alkyl glycosides 6%, Sodium n-alkylbenzenesulfonate 5%-7%, sodium carbonate 1.4%-1.6%, sodium metasilicate 0.7%-0.8%, disodium ethylene diamine tetraacetate 0.3%, sodium chloride 0.2%, essence 0.4%, Kathon CG 0.08%-0.16%, deionized water 62.97%-80%.
The present invention uses novel yin/nonionic surfactant Fatty acid methyl ester ethoxylate sodium sulfonate (abbreviation FMES) And nonionic surfactant alkyl glycosides (APG for short) is primary raw material,
The liquid detergent detergency ability obtained through compounding is excellent and raw material is degradable.It is produced by formula provided by the invention production After product, product clarification is bright, and clean effect is obvious, and under conditions of same amount, dirt-removing power is better than national standard laundry Liquid, decontamination ratio adduction (i.e. comprehensive dirt-removing power) is optimal, up to 4.45
(being shown in Table 1).And the biodegradability of used raw material is very high, it is non-hazardous to human body, environment.
Specific embodiment
Below in conjunction with example, the present invention will be further explained:
Embodiment 1
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 5%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 8%, sodium carbonate 1%, sodium metasilicate 1%, disodium ethylene diamine tetraacetate 0.5%, chlorine Change sodium 0.1%, essence 0.3%, Kathon CG 0.2%, deionized water 79.9%.Clean effect is good, can remove various on clothing It is pretty good (being shown in Table 1) to embathe effect for stain.
Embodiment 2
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 7%, Alkyl glycosides 6%, sodium n-alkylbenzenesulfonate 6%, sodium carbonate 1.5%, sodium metasilicate 0.6%, disodium ethylene diamine tetraacetate 0.2%, sodium chloride 0.2%, essence 0.2%, Kathon CG 0.2%, deionized water 78.1%.Clean effect is good.
Embodiment 3
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 8%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 5%, sodium carbonate 1.6%, sodium metasilicate 0.7%, disodium ethylene diamine tetraacetate 0.15%, sodium chloride 0.2%, essence 0.4%, Kathon CG 0.1%, deionized water 79.45%.Clean effect is good.
Embodiment 4
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 6%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 8%, sodium carbonate 1.2%, sodium metasilicate 0.6%, disodium ethylene diamine tetraacetate 0.3%, sodium chloride 0.2%, essence 0.4%, Kathon CG 0.1%, deionized water 79.2%.Clean effect is good.
Embodiment 5
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 10%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 3%, sodium carbonate 1.5%, sodium metasilicate 0.8%, disodium ethylene diamine tetraacetate 0.4%, sodium chloride 0.25%, essence 0.5%, Kathon CG 0.15%, deionized water 79.4%.Clean effect is good.
Embodiment 6
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 9%, Alkyl glycosides 5%, sodium n-alkylbenzenesulfonate 4%, sodium carbonate 1.2%, sodium metasilicate 1%, disodium ethylene diamine tetraacetate 0.3%, Sodium chloride 0.2%, essence 0.5%, Kathon CG 0.1%, deionized water surplus 78.7%.Clean effect is good.
Embodiment 7
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 10%, Alkyl glycosides 5%, sodium n-alkylbenzenesulfonate 3%, sodium carbonate 1.2%, sodium metasilicate 1%, disodium ethylene diamine tetraacetate 0.1%, Sodium chloride 0.2%, essence 0.5%, Kathon CG 0.15%, deionized water 78.85%.Clean effect is good.
Embodiment 8
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 12%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 3%, sodium carbonate 1.6%, sodium metasilicate 0.8%, disodium ethylene diamine tetraacetate 0.15%, sodium chloride 0.2%, essence 0.5%, Kathon CG 0.2%, deionized water 75.55%.Clean effect is good.
Embodiment 9
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 14%, Alkyl glycosides 8%, sodium n-alkylbenzenesulfonate 2%, sodium carbonate 1%, sodium metasilicate 0.5%, disodium ethylene diamine tetraacetate 0.3%, Sodium chloride 0.2%, essence 0.5%, Kathon CG 0.15%, deionized water 73.35%.Clean effect is good.
Embodiment 10
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 14%, Alkyl glycosides 6%, sodium n-alkylbenzenesulfonate 2%, sodium carbonate 1%, sodium metasilicate 0.5%, disodium ethylene diamine tetraacetate 0.3%, Sodium chloride 0.1%, essence 0.5%, Kathon CG 0.2%, deionized water 75.4%.Clean effect is good.
Embodiment 11
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 18%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 2%, sodium carbonate 1%, sodium metasilicate 0.5%, disodium ethylene diamine tetraacetate 0.2%, Sodium chloride 0.15%, essence 0.4%, Kathon CG 0.15%, deionized water 73.6%.Clean effect is good.
Embodiment 12
A kind of environment amenable liquid detergent, is counted in mass ratio, including Fatty acid methyl ester ethoxylate sodium sulfonate 20%, Alkyl glycosides 4%, sodium n-alkylbenzenesulfonate 2%, sodium carbonate 1%, sodium metasilicate 0.5%, disodium ethylene diamine tetraacetate 0.2%, Sodium chloride 0.15%, essence 0.2%, Kathon CG 0.1%, deionized water 71.85%.Clean effect is good, and it is pretty good to embathe effect.
It is carried out it should be noted that existing common process can be used in the method that liquid detergent is made in each component in examples detailed above Preparation.Other components need to be only dissolved in deionized water, be filtered, is then mixed according to the ratio at normal temperature, it can be with It obtains stable and uniform, clarify bright liquid detergent.
Clean effect test
The formula of embodiment 1 according to the invention is prepared liquid detergent and is compared with 5 kinds of liquid detergents salable in the market.Ginseng According to GB/T 13174-2008 " dress material detergent detergency and the measurement for recycling scourability ", preparing mass fraction respectively is The hard water solution 1L of 0.1% liquid detergent sample controls temperature at 30 DEG C, is washed in Terg-O-Tometer, rinsed, be dehydrated Step compares the dirt-removing power of 6 kinds of liquid detergents, compares the ratio P of 6 kinds of liquid detergent detergencies Yu standard liquid detergent detergency, surveys Test result is shown in Table 1.
The test of 1 liquid detergent decontamination ratio of table
Sample JB-01 JB-02 JB-04 Decontamination ratio adduction
LB- is super clean to smoke clothing perfume (or spice) liquid detergent 1.30 1.38 1.23 3.91
CN- plants extraction low foam laundry liquid 1.34 1.5 1.35 4.19
LY- deep layer cleaning and nursing liquid detergent 1.68 1.52 1.21 4.41
The net liquid detergent of the full stain of DP- 1.01 1.16 1.31 3.48
AM- deep layer cleaning liquid detergent 1.33 1.36 1.11 3.80
1 liquid detergent of embodiment 1.45 1.53 1.47 4.45
As shown in Table 1,1 liquid detergent decontamination ratio of the embodiment of the present invention adduction (i.e. comprehensive dirt-removing power) is optimal.
Biodegradability
According to national standards, should be proved being capable of natural degradation for surfactant used in Cleaning preparations, it is desirable that table The primary biodegradation degree of face activating agent is not less than 80%, and ultimate biodegradation degree is not less than 60%.The table that the present invention uses Face activating agent has FMES, APG-0814, with reference to pertinent literature fatty acid methyl ester ethoxylate (FMES) preliminary biological degradability It can reach 89%, and ultimate biodegradation degree is higher than 60%；The biodegradability of alkyl glycosides is very good, 5 day time primary Biological degradation rate is just already close to 100%, and ultimate biodegradation degree is higher than 60%, and both surfactants itself are not deposited In toxicity.Therefore the present invention meets national standard, harmless to human body, animals and plants health.

Claims (3)

1. a kind of environment amenable liquid detergent, is counted in mass ratio, it is characterized in that: including Fatty acid methyl ester ethoxylate sulfonic acid Sodium 5%-20%, alkyl glycosides 4%-8%, sodium n-alkylbenzenesulfonate 2%-10%, sodium carbonate 1%-2%, sodium metasilicate 0.5%-1%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium chloride 0.1%-0.3%, essence 0.2%-0.6%, Kathon CG 0.05%-0.2%, deionized water 57.5%-80%.
2. a kind of environment amenable liquid detergent according to claim 1, it is characterized in that: including Fatty acid methyl ester ethyoxyl Compound sodium sulfonate 6%-18%, alkyl glycosides 5-7%, sodium n-alkylbenzenesulfonate 4%-8%, sodium carbonate 1.2%-1.8%, silicon Sour sodium 0.6%-0.9%, disodium ethylene diamine tetraacetate 0.2%-0.4%, sodium chloride 0.15%-0.25%, essence 0.3%- 0.5%, Kathon CG 0.06%-0.18%, deionized water 54.9%-80%.
3. a kind of environment amenable liquid detergent according to claim 1 or 2, it is characterized in that: including Fatty acid methyl ester second Oxygroup compound sodium sulfonate 5%-16%, alkyl glycosides 6%, sodium n-alkylbenzenesulfonate 5%-7%, sodium carbonate 1.4%-1.6%, Sodium metasilicate 0.7%-0.8%, disodium ethylene diamine tetraacetate 0.3%, sodium chloride 0.2%, essence 0.4%, Kathon CG 0.08%- 0.16%, deionized water 62.97%-80%.
CN201811349232.2A 2018-11-14 2018-11-14 A kind of environment amenable liquid detergent Pending CN109456849A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110777017A (en) * 2019-11-07 2020-02-11 江西理工大学 Environment-friendly laundry detergent and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031756A (en) * 2014-05-07 2014-09-10 拉芳家化股份有限公司 Concentrated laundry liquid suitable for machine washing, and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031756A (en) * 2014-05-07 2014-09-10 拉芳家化股份有限公司 Concentrated laundry liquid suitable for machine washing, and preparation method thereof

Non-Patent Citations (1)

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Title
徐铭勋: "脂肪酸甲酯乙氧基化物及其磺酸盐的生产技术与应用", 《化学工业》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110777017A (en) * 2019-11-07 2020-02-11 江西理工大学 Environment-friendly laundry detergent and preparation method thereof

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