CN103555450B - A kind of antibacterial decontamination liquid washing agent and preparation method thereof - Google Patents
A kind of antibacterial decontamination liquid washing agent and preparation method thereof Download PDFInfo
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- CN103555450B CN103555450B CN201310539568.6A CN201310539568A CN103555450B CN 103555450 B CN103555450 B CN 103555450B CN 201310539568 A CN201310539568 A CN 201310539568A CN 103555450 B CN103555450 B CN 103555450B
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- washing agent
- add
- decontamination liquid
- deionized water
- liquid washing
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- 239000007788 liquid Substances 0.000 title claims abstract description 39
- 238000005406 washing Methods 0.000 title claims abstract description 23
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- 238000005202 decontamination Methods 0.000 title claims abstract description 15
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 13
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000008367 deionised water Substances 0.000 claims abstract description 28
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 28
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- 239000011734 sodium Substances 0.000 claims abstract description 16
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 16
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 claims abstract description 14
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000004141 Sodium laurylsulphate Substances 0.000 claims abstract description 14
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims description 21
- 238000004090 dissolution Methods 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- 239000008101 lactose Substances 0.000 claims description 4
- 125000003147 glycosyl group Chemical group 0.000 claims description 3
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 2
- 150000002430 hydrocarbons Chemical group 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 2
- 238000005201 scrubbing Methods 0.000 claims 1
- 230000000249 desinfective effect Effects 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000003599 detergent Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 4
- 241000282326 Felis catus Species 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000019633 pungent taste Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
A kind of weight percent of antibacterial decontamination liquid washing agent consists of: sodium alkyl benzene sulfonate 5-10wt%, sodium lauryl sulphate 2-5wt%, fatty alcohol-polyoxyethylene ether 5-10wt%, methyl glucamine 0.5-1 wt%, glycosyl amide quaternary ammonium salt 1-2wt%, essence 0.05-0.2 wt%, deionized water surplus.The present invention has highly effective and safe, can the advantage of simultaneously disinfecting and decontaminating.
Description
Technical field
The invention belongs to articles for washing, be specifically related to a kind of can the antiseptic liquid detergent and preparation method thereof of simultaneously disinfecting and decontaminating.
Background technology
Along with relevant department uses the restriction of synthetic detergent powder, Powdered Detergent Containing Phosphate, washing composition will be withdrawn from the market.And develop the developing direction that this kind of regeneration product of without phosphorus clothes liquid detergent washs industry just, and be also Overseas Development trend, trend of the times especially.Liquid washing agent has the advantages such as save energy, easy to use, dissolving is rapid, cold washing performance is good.Meanwhile, also there is the advantages such as formula is flexible, manufacturing process is simple, facility investment is few, tooling cost is low, be more and more subject to the welcome of human consumer.Along with the development of society and the raising of the level of consumption, the demand of people to liquid washing agent is also more and more higher, except the detersive power required, also requires other functions, and such as lasting lasting, submissive, gentleness are not hindered hand, easily rinsing, protected look and sterilization etc.The articles for washing particularly with antibacterial is also more and more subject to the favor of people, makes washing composition can also kill bacteria while removal spot, and protection fabric, anti-bacteria damages skin.
In the market, also occurred that some have the washing composition of disinfecting and sterilizing functions.Mainly with the addition of some sterilizing agent and cats products etc., make washing composition have certain sterilization effect.These sterilizing agents, some is dangerous to human body, if drift does not wash clean, has certain stimulation to the skin of people.Conventional cats product sterilant has C
8-16quaternary cationics, and traditional cats product due to duration of service longer, the problem of ubiquity resistance, also exist in addition pungency comparatively strong and with the shortcoming such as the compatibility difference of anion surfactant, cause product pungency strong, to clothing and human body dangerous, service efficiency reductions etc., are difficult to the performance giving full play to antibacterial decontamination liquid washing agent.
Summary of the invention
The object of this invention is to provide a kind of highly effective and safe, can the antiseptic liquid detergent and preparation method thereof of simultaneously disinfecting and decontaminating.
The present invention adopts novel glycosyl amide quaternary surfactant as sterilant, the mildness of glycosyl surfactant active and the high efficiency of quaternary ammonium salt cationic surfactant combine by this type of tensio-active agent, non-stimulated to skin, bactericidal properties is strong, biological degradability good and and the compatibility of anion surfactant strong.Methyl glucamine is applied in detergent formulation by the present invention simultaneously, it is not only a kind of desirable thickening material (thickening effectiveness is better than 6501), and methyl glucamine also to have foaming properties good, soil removability is strong, the feature that compatibility is good, and there is frank comfortable use sense.
The weight percent of antibacterial decontamination liquid washing agent of the present invention consists of:
Sodium alkyl benzene sulfonate 5-10 wt%
Sodium lauryl sulphate 2-5 wt%
Fatty alcohol-polyoxyethylene ether 5-10 wt%
Methyl glucamine 0.5-1 wt%
Glycosyl amide quaternary ammonium salt 1-2 wt%
Essence 0.05-0.2 wt%
Deionized water surplus
Sodium alkyl benzene sulfonate as above is C
12-14linear alkylbenzene sulphonic acid.
Fatty alcohol-polyoxyethylene ether carbon chain lengths as above is C
12-14, EO number is 5-15.
The structural formula of methyl glucamine as above is as follows:
Wherein: n is 10-18.
The structural formula of glycosyl amide quaternary ammonium salt as above is as follows:
Wherein: R is C
10-C
18long chain hydrocarbon groups, glycosyl is glucosyl group or lactose base.
The present invention is realized by following technology of preparing:
(1) A liquid preparation: add batching kettle by the 30-40 wt% of deionized water total amount and be heated to 80-90 DEG C, then add sodium alkyl benzene sulfonate successively, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent;
(2) B liquid preparation: add batching kettle by the 30-40 wt% of deionized water total amount and be heated to 60-70 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent;
(3) mixed by A and B, add essence, supply remaining deionized water, add acid or alkali adjust ph to 6.0-8.0, stir 0.5-2 hour, to homogeneous transparent liquid, discharging, namely obtains antibacterial decontamination liquid washing agent.
Acid as above is as citric acid or hydrochloric acid.
Alkali as above is NaOH or KOH.
The present invention compared with prior art tool has the following advantages:
1. the present invention adopts novel glycosyl amide quaternary surfactant as sterilant, such that washing composition is little to skin irritation, germ resistance is strong, particularly have good antibacterial ability to intestinal bacteria and staphylococcus glucose coccus.
2. the present invention adopts methyl glucamine as scrubbed component, and it is not only a kind of desirable thickening material, and it is good self also to have foaming properties, and soil removability is strong, the feature that compatibility is good, and has frank comfortable use sense.
3. not phosphorous in washings, in can not feeding water, coenocorrelation pollutes.
Embodiment:
Below in conjunction with embodiment, the present invention is described further, and embodiment is only not used in for explaining the present invention and limits the scope of the invention.
Embodiment 1:
Sodium alkyl benzene sulfonate 10 wt%
Sodium lauryl sulphate 2 wt %
C
12-14fatty alcohol-polyoxyethylene ether (EO=9) 5 wt%
C
10methyl glucamine 0.5 wt%
C
10glucosyl group amidoquat salt 2 wt%
Essence 0.05 wt%
Deionized water surplus
Preparation process:
A liquid is prepared: 40 wt% of deionized water total amount are added batching kettle and is heated to 80 DEG C, then add sodium alkyl benzene sulfonate successively, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent.
B liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 70 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent.
A and B is mixed, adds essence 0.05 wt%, supply the deionized water of residue 30 wt%, add citric acid adjust ph to 6.0, stir 0.5 hour, to homogeneous transparent liquid, discharging.
Embodiment 2:
Sodium alkyl benzene sulfonate 8 wt%
Sodium lauryl sulphate 3 wt%
C
12-14fatty alcohol-polyoxyethylene ether (EO=7) 8 wt%
C
12methyl glucamine 0.7 wt%
C
18glucosyl group amidoquat salt 1.8 wt%
Essence 0.1 wt%
Deionized water surplus
Preparation process:
A liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 90 DEG C, then add sodium alkyl benzene sulfonate successively in above-mentioned raw materials ratio, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent.
B liquid is prepared: 40 wt% of deionized water total amount are added batching kettle and is heated to 60 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent.
A and B is mixed, adds essence 0.1 wt%, supply the deionized water of residue 30 wt%, add salt acid for adjusting pH value to 7.0, stir 1 hour, to homogeneous transparent liquid, discharging.
Embodiment 3:
Sodium alkyl benzene sulfonate 7 wt%
Sodium lauryl sulphate 4 wt%
C
12-14fatty alcohol-polyoxyethylene ether (EO=5) 7 wt%
C
18methyl glucamine 0.8 wt%
C
12glucosyl group amidoquat salt 1.5 wt%
Essence 0.15 wt%
Deionized water surplus
Preparation process:
A liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 90 DEG C, then add sodium alkyl benzene sulfonate successively in above-mentioned raw materials ratio, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent.
B liquid is prepared: 40 wt% of deionized water total amount are added batching kettle and is heated to 70 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent.
A and B mixes, and adds essence 0.15 wt%, supplies the deionized water of residue 30 wt%, add NaOH adjust ph to 7.0, stir 1.5 hours, to homogeneous transparent liquid, and discharging.
Embodiment 4:
Sodium alkyl benzene sulfonate 5 wt%
Sodium lauryl sulphate 5 wt%
C
12-14fatty alcohol-polyoxyethylene ether (EO=15) 10 wt%
C
12methyl glucamine 1 wt%
C
12lactose base amidoquat salt 1 wt%
Essence 2 wt%
Deionized water surplus
Preparation process:
A liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 85 DEG C, then add sodium alkyl benzene sulfonate successively in above-mentioned raw materials ratio, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent.
B liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 65 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent.
A and B mixes, and adds essence 2 wt%, supplies the deionized water of residue 40 wt%, add NaOH adjust ph to 8.0, stir 1.5 hours, to homogeneous transparent liquid, and discharging.
Embodiment 5:
Sodium alkyl benzene sulfonate 10 wt%
Sodium lauryl sulphate 5 wt%
C
12-14fatty alcohol-polyoxyethylene ether (EO=9) 6 wt%
C
14methyl glucamine 1 wt%
C
14lactose base amidoquat salt 1.5 wt%
Essence 1 wt%
Deionized water surplus
Preparation process:
A liquid is prepared: 30 wt% of deionized water total amount are added batching kettle and is heated to 80 DEG C, then add sodium alkyl benzene sulfonate successively in above-mentioned raw materials ratio, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent.
B liquid is prepared: 40 wt% of deionized water total amount are added batching kettle and is heated to 70 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent.
A and B mixes, and adds essence 1 wt%, supplies the deionized water of residue 30 wt%, add KOH adjust ph to 7.0, stir 1 hour, to homogeneous transparent liquid, and discharging.
Above-described embodiment prepares the performance test results of sample as following table:
1. draw above decontamination result according to the People's Republic of China's evaluation method of light industry standard QB1224-1991 to detersive power performance, wherein require that decontamination index >=1 is for qualified.Therefore, as can be seen from the experimental result of upper table, the sample that embodiment obtains can reach the requirement of standard.
Claims (5)
1. an antibacterial decontamination liquid washing agent, is characterized in that the weight percent of antibacterial decontamination liquid scrubbing consists of:
The structural formula of described methyl glucamine is as follows:
Wherein: n is 10-18;
The structural formula of described glycosyl amide quaternary ammonium salt is as follows:
Wherein: R is C
10-C
18long chain hydrocarbon groups, glycosyl is glucosyl group or lactose base;
And prepared by following steps:
(1) A liquid preparation: add batching kettle by the 30-40wt% of deionized water total amount and be heated to 80-90 DEG C, then add sodium alkyl benzene sulfonate successively, sodium lauryl sulphate, methyl glucamine, continue stirring until dissolution homogeneity transparent;
(2) B liquid preparation: add batching kettle by the 30-40wt% of deionized water total amount and be heated to 60-70 DEG C, then add fatty alcohol-polyoxyethylene ether successively, glycosyl amide quaternary ammonium salt, continues stirring until dissolution homogeneity transparent;
(3) mixed by A and B, add essence, supply remaining deionized water, add acid or alkali adjust ph to 6.0-8.0, stir 0.5-2 hour, to homogeneous transparent liquid, discharging, namely obtains antibacterial decontamination liquid washing agent.
2. a kind of antibacterial decontamination liquid washing agent as claimed in claim 1, is characterized in that described sodium alkyl benzene sulfonate is C
12-14linear alkylbenzene sulphonic acid.
3. a kind of antibacterial decontamination liquid washing agent as claimed in claim 1, is characterized in that the length of described fatty alcohol-polyoxyethylene ether carbochain is C
12-14, EO number is 5-15.
4. a kind of antibacterial decontamination liquid washing agent as claimed in claim 1, is characterized in that described acid is citric acid or hydrochloric acid.
5. a kind of antibacterial decontamination liquid washing agent as claimed in claim 1, is characterized in that described alkali is NaOH or KOH.
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| CN201310539568.6A CN103555450B (en) | 2013-11-05 | 2013-11-05 | A kind of antibacterial decontamination liquid washing agent and preparation method thereof |
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| CN201310539568.6A CN103555450B (en) | 2013-11-05 | 2013-11-05 | A kind of antibacterial decontamination liquid washing agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105794778A (en) * | 2014-12-30 | 2016-07-27 | 3M创新有限公司 | Antibacterial composition, and preparation method and application thereof |
| CN108179073B (en) * | 2018-01-12 | 2020-05-15 | 张潇瀚 | Mild bactericidal laundry detergent and preparation method thereof |
| CN110881463B (en) * | 2018-09-07 | 2021-12-03 | 中国科学院武汉植物园 | Method for preventing and treating fungal infection in haematococcus culture by using surfactant |
| CN113549500A (en) * | 2021-07-23 | 2021-10-26 | 河南省科学院化学研究所有限公司 | Fatty alcohol-polyoxyethylene ether-based detergent and preparation method and application thereof |
| CN114181781B (en) * | 2021-12-24 | 2024-03-26 | 山东富斯特油脂科技有限公司 | Detergent and bactericide, preparation method and application thereof |
| CN114230481B (en) * | 2021-12-29 | 2023-09-22 | 太原科技大学 | Low-toxicity sterilizing glycosylamide ionic liquid and preparation method and application thereof |
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| CN1513438A (en) * | 2003-08-08 | 2004-07-21 | 新疆奥斯曼生物科技有限公司 | Qiamuwuer shower cream, and its prepn. method |
| CN100575471C (en) * | 2005-08-23 | 2009-12-30 | 穆世民 | A kind of environmental protection multifunctional deoiling decontaminant |
| CN101255381B (en) * | 2007-02-27 | 2012-03-21 | 3M创新有限公司 | Cleaning method and combination |
| CN101649258A (en) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | Tableware detergent with enzyme and preparation method thereof |
| CN102764609B (en) * | 2012-07-26 | 2014-06-25 | 合肥工业大学 | Glucose ester group quaternary ammonium salt cationic surfactant and synthesizing method thereof |
| CN102960379A (en) * | 2012-11-26 | 2013-03-13 | 大连创达技术交易市场有限公司 | Technology for producing fruit and vegetable bactericide containing Chinese medicinal herb components |
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Effective date of registration: 20191122 Address after: 450000 Suzhuang Village, Yingyang Town, Xiangcheng County, Xuchang City, Henan Province Patentee after: Li Shuangfeng Address before: 030001 Yingze City, Taiyuan province Wen Xiang lane, No. Patentee before: Chinese Daily Use Chemical Industry Research Inst. |