CN105002755B - A kind of quick alkali-resistant penetrant and preparation method thereof - Google Patents
A kind of quick alkali-resistant penetrant and preparation method thereof Download PDFInfo
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- CN105002755B CN105002755B CN201510385393.7A CN201510385393A CN105002755B CN 105002755 B CN105002755 B CN 105002755B CN 201510385393 A CN201510385393 A CN 201510385393A CN 105002755 B CN105002755 B CN 105002755B
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Abstract
The invention discloses a kind of quick alkali-resistant penetrant and preparation method thereof, by weight percentage, the quick alkali-resistant penetrant includes following components：Octyl phosphate 10~60%, amphoteric surfactant 10~30%, alkyl sugar acid anhydride 5~20%, AEO sulfonated salts 10~30% and defoamer 0.1~0.5%.Above-mentioned each raw material is added in mixing kettle in required ratio, stirred, NaOH solution adjustment PH=7~8 is added, is finally diluted with water and quick alkali-resistant penetrant is made.Bleeding agent produced by the present invention, alkaline-resisting reachable 300g/l NaOH, there is good infiltration, emulsification, scourability under neutrality to strong alkaline condition, and is free of APEO, degradable, is suitable for each process of dyeing and printing process.
Description
Technical field
The present invention relates to a kind of quick alkali-resistant penetrant for fabric printing processing technique field and preparation method thereof.
Background technology
As its name suggests, bleeding agent has been osmosis, and with fixed hydrophilic lipophilic group, in the surface energy of solution
Align, and the material that can be remarkably decreased surface tension.The generalized concept of bleeding agent refers to that one kind can help to need to ooze
Saturating penetration to the chemicals for needing to be saturated material, it is industrial be usually the use of surfactant (can be anion
Or non-ionic) or organic or inorganic solvent.
Bleeding agent is generally divided into nonionic and the class of anion two.It is non-ionic to have JFC (AEO), JFC-
1st, JFC-2, JFC-E etc.；Anion has fast penetrant T, alkali-resistant penetrant OEP-70, alkali-resistant penetrant AEP, seeping at high temperature
Agent JFC-M etc..
Chinese patent 200910039109.5 discloses a kind of alkaline-resisting infiltration for pure-cotton woven fabric short route pre-treatment
Agent, the alkali-resistant penetrant by weight it include following components：5~20 parts of isomery AEO, isomery fatty alcohol
10~25 parts of polyoxyethylene ether phosphate, 5~25 parts of isomery fatty alcohol phosphate, 1~5 part of tributyl phosphate, Malaysia acid propylene
1~10 part of acid polymer.
Chinese patent application 201410493167.6 discloses a kind of high temperature alkali resistant bleeding agent and preparation method thereof, the high temperature
Alkali-resistant penetrant is the compound ligand of methanol polyoxyethylene ether phosphate and diisooctyl maleate sulfonate, wherein, methanol
The mass ratio of polyoxyethylene ether phosphate and diisooctyl maleate sulfonate is 5-10:1.This high temperature alkali resistant bleeding agent
It can directly merge with kiering process, shorten process route, reduce cost.
Chinese patent application 201310229554.4 discloses a kind of alkali-resistant penetrant for bafta mercerising, and it is prepared
Raw material includes following components：Fatty alcohol sulfate salt 45-50 parts；Fatty alcohol ether sulfate salt 45-50 parts；Emulsifying agent 1-5 parts.Should
Carbon and low-carbon alcohols is primary raw materials during technology uses, synthetically prepared fatty alcohol sulfate salt.
Chinese patent application 201210126006.4 discloses a kind of alkali-resistant penetrant for bafta mercerising, by weight
Number, it includes following components：Sulfamic acid 60-100, fatty alcohol 25-80, (EO：7-10) fatty alcohol ether 45-150, catalyst
2-45；Its preparation method is：Fatty alcohol, fatty alcohol ether are placed in 500ml there-necked flasks in proportion, start to stir, adds catalysis
Agent and sulfamic acid, condenser reflux is connected, be warming up to 120 DEG C of timing, be incubated 120 minutes, be slowly added to less than 100 DEG C
100 parts of soft water, pH8-8.5 is adjusted with sodium hydrate aqueous solution after stirring.
Anion surfactant octyl phosphate, have and synthesize simple, cheap, three-waste free discharge, under neutrallty condition
Penetration is fast.But there is also alkaline-resisting low (about 20gNaOH/l), it is restricted its application in dyeing and printing process.
Therefore, it is necessary to provide it is a kind of overcome the quick alkali-resistant penetrant of this shortcoming of octyl phosphate, while keep its fast
The performance of speed infiltration.By adding APG, amphoteric surfactant, polyoxyethylene fatty alkyl ether sulfonate phosphoric acid can be made pungent
The alkali resistance of ester brings up to 300gNaOH/l,
The content of the invention
It is an object of the invention to provide one kind the resistance to alkali ability of octyl phosphate can be overcome low while keep its rapid osmotic again
Quick alkali-resistant penetrant of performance and preparation method thereof.
On the one hand, in order to realize the purpose of the present invention, the invention provides a kind of quick alkali-resistant penetrant, by weight percentage
Than meter, the quick alkali-resistant penetrant includes following components：
The quick alkali-resistant penetrant of the present invention is by adding APG, amphoteric surfactant, aliphatic alcohol polyethenoxy
Ether sulfonic acid sodium, it can greatly improve the alkaline resistance properties of octyl phosphate, it might even be possible to bring up to 300gNaOH/l.
In the quick alkali-resistant penetrant of the present invention, amphoteric surfactant can be one in such as next group of material
Kind or more than one combination：Dodecyl dihydroxy ethyl glycine betaine, lauroylamidopropyl betaine, dodecyl dimethyl-
2- hydroxypropyl sulfonic acids glycine betaine and N- dodecyls-Beta-alanine sodium.
In the quick alkali-resistant penetrant of the present invention, defoamer does not require particularly, such as defoamer can be commercially available
Polyethers defoamer or organic silicon defoamer, it is preferred to use organic silicon defoamer.
In the quick alkali-resistant penetrant of the present invention, polyoxyethylene fatty alkyl ether sulfonate can be commercially available AES (fat
Alcohol sodium sulfonate of ethoxylated).
As the embodiment of the present invention, quick alkali-resistant penetrant of the invention can include following components：
As another embodiment of the present invention, quick alkali-resistant penetrant of the invention can include following components：
In addition, the quick alkali-resistant penetrant of the present invention can include appropriate water.
On the other hand, in order to realize the purpose of the present invention, quick alkali-resistant penetrant is prepared present invention also offers a kind of
Method, it in turn includes the following steps：
(1) following component is proportionally added into mixing kettle：
(2) material in the mixing kettle is stirred at room temperature, makes it well mixed；
(3) NaOH solution is added in mixture obtained by step (2), regulation pH is 7~8.
In the invention described above method, it can also further comprise the steps：Added in the product obtained by step (3)
The running water of softened processing.
In the invention described above method, the mixing time of step (2) will be typically controlled in 30-60 minutes, mixed to reach
Close uniform；The concentration of the NaOH solution added in step (3) is typically in 20-40%, preferably 30% or so, such as 25-35%.
The quick alkali-resistant penetrant of the present invention, in neutral, alkalescence or even strong basicity (such as in 300g/l NaOH solution)
Under conditions of, there are good infiltration, emulsification, washing, dispersive property, cost is cheap, Environmental Safety, and is free of APEO, easily drop
Solution, it is suitable for each process of dyeing and printing process.
Further illustrate the present invention with reference to embodiment；It will be appreciated that these specific implementations
Mode is only intended to the explanation present invention, rather than limitation of the present invention.One of ordinary skill in the art completely can be at this
Under the enlightenment of invention, the embodiment of the present invention is improved, or some technical characteristics are carried out with equivalent substitution, but this
Technical scheme after improvement or replacement a bit, still falls within protection scope of the present invention.
Embodiment
In each embodiment below the present invention, unless specifically stated otherwise, used percentage composition is weight percentage.
Embodiment 1
With weight percentage, weighed in following ratio：Octyl phosphate 40%, dodecyl dihydroxy ethyl glycine betaine 30%,
APG 10%, AES 20%, defoamer 0.1%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60 minutes,
It is mixed thoroughly to each raw material, adds 30% NaOH solution, adjust pH=7~8, is eventually adding softened processing oneself
Water is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant I is made, its outward appearance is colourless transparent liquid, resistance to
Alkali is up to 150g NaOH/l.
Embodiment 2
With weight percentage, weighed in following ratio：Octyl phosphate 40%, lauroylamidopropyl betaine 30%, alkyl
Glucosides 10%, AES 20%, defoamer 0.1%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60 minutes, to each
Raw material is mixed thoroughly, and adds 30% NaOH solution, adjusts pH=7~8, is eventually adding the running water of softened processing
Be diluted to solid content be 50% the aqueous solution, that is, be made quick alkali-resistant penetrant II, its outward appearance is colourless transparent liquid, it is alkaline-resisting can
Up to 180g NaOH/l.
Embodiment 3
With weight percentage, weighed in following ratio：Octyl phosphate 40%, dodecyl dimethyl -2- hydroxypropyl sulphurs
Sour glycine betaine 30%, APG 10%, AES 20%, defoamer 0.1%；Above-mentioned raw materials are added in mixing kettle, room temperature is stirred
Mix 30~60 minutes, be mixed thoroughly to each raw material, add 30% NaOH solution, adjust pH=7~8, be eventually adding
The running water of softened processing is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant III is made, and its outward appearance is
Clear colorless liquid, alkaline-resisting reachable 200g NaOH/l.
Embodiment 4
With weight percentage, weighed in following ratio：Octyl phosphate 40%, N- dodecyls-Beta-alanine sodium
30%, APG 10%, AES 20%, defoamer 0.1%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60
Minute, it is mixed thoroughly to each raw material, adds 30% NaOH solution, is adjusted pH=7~8, be eventually adding softened place
The running water of reason is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant IV, alkaline-resisting reachable 250g is made
NaOH/l。
Embodiment 5
With weight percentage, weighed in following ratio：Octyl phosphate 40%, dodecyl dihydroxy ethyl glycine betaine 10%,
Lauroylamidopropyl betaine 10%, dodecyl dimethyl -2- hydroxypropyl sulfonic acids glycine betaine 10%, N- dodecyls -
Beta-alanine sodium 10%, APG 10%, AES 10%, defoamer 0.1%；Above-mentioned raw materials are added in mixing kettle, room
Temperature stirring 30~60 minutes, is mixed thoroughly to each raw material, adds 30% NaOH solution, adjusts pH=7~8, finally
The running water for adding softened processing is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant V is made, alkaline-resisting
Up to 300g NaOH/l.
Embodiment 6
With weight percentage, weighed in following ratio：Octyl phosphate 59.8%, dodecyl dihydroxy ethyl glycine betaine
10%, APG 20%, AES 10%, defoamer 0.2%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60
Minute, it is mixed thoroughly to each raw material, adds 30% NaOH solution, is adjusted pH=7~8, be eventually adding softened place
The running water of reason is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant is made.
Embodiment 7
With weight percentage, weighed in following ratio：Octyl phosphate 30%, lauroylamidopropyl betaine 20%, alkyl
Glucosides 20%, AES 29.7%, defoamer 0.3%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60 minutes, extremely
Each raw material is mixed thoroughly, and adds 30% NaOH solution, is adjusted pH=7~8, is eventually adding softened processing originally
Water is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant is made.
Embodiment 8
With weight percentage, weighed in following ratio：Octyl phosphate 49.5%, dodecyl dimethyl -2- hydroxypropyls
Sulphonic acid betaine 25%, APG 5%, AES 20%, defoamer 0.5%；Above-mentioned raw materials are added in mixing kettle, room temperature is stirred
Mix 30~60 minutes, be mixed thoroughly to each raw material, add 20% NaOH solution, adjust pH=7~8, be eventually adding
The running water of softened processing is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant is made.
Embodiment 9
With weight percentage, weighed in following ratio：Octyl phosphate 35%, N- dodecyls-Beta-alanine sodium
35%, APG 15%, AES 25%, defoamer 0.05%；Above-mentioned raw materials are added in mixing kettle, are stirred at room temperature 30~60
Minute, it is mixed thoroughly to each raw material, adds 35% NaOH solution, is adjusted pH=7~8, be eventually adding softened place
The running water of reason is diluted to the aqueous solution that solid content is 50%, that is, quick alkali-resistant penetrant is made.
Claims (7)
1. a kind of quick alkali-resistant penetrant, by weight percentage, the quick alkali-resistant penetrant include following components：
Wherein, described amphoteric surfactant is one or more kinds of combinations in such as next group of material：12
Alkyldihydxyethyl betaines, lauroylamidopropyl betaine, dodecyl dimethyl -2- hydroxypropyl sulfonic acids glycine betaine, with
And N- dodecyls-Beta-alanine sodium.
2. quick alkali-resistant penetrant as claimed in claim 1, wherein, described defoamer is commercially available polyethers defoamer or had
Machine silicon defoaming agent.
3. quick alkali-resistant penetrant as claimed in claim 2, wherein, described defoamer is organic silicon defoamer.
4. quick alkali-resistant penetrant as claimed in claim 1, wherein, described aliphatic alcohol polyoxyethylene sulfonate is fat
Alcohol sodium sulfonate of ethoxylated, described polyoxyethylene fatty alkyl ether sulfonate are commercially available AES.
5. quick alkali-resistant penetrant as claimed in claim 1, wherein, described quick alkali-resistant penetrant includes following components：
6. a kind of method for preparing quick alkali-resistant penetrant, it in turn includes the following steps：
(1) following component is proportionally added into mixing kettle：
(2) material in the mixing kettle is stirred at room temperature, makes it well mixed；
(3) NaOH solution is added in mixture obtained by step (2), regulation pH is 7~8；
Wherein, described amphoteric surfactant is one or more kinds of combinations in such as next group of material：12
Alkyldihydxyethyl betaines, lauroylamidopropyl betaine, dodecyl dimethyl -2- hydroxypropyl sulfonic acids glycine betaine, with
And N- dodecyls-Beta-alanine sodium.
7. method as claimed in claim 6, wherein, this method further comprises：Warp is added in the product obtained by step (3)
The running water of sofening treatment.
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| CN105671946A (en) * | 2016-02-26 | 2016-06-15 | 苏州三和开泰花线织造有限公司 | Efficient environment-friendly penetrant for fabric pretreatment and preparation method thereof |
| CN106120319A (en) * | 2016-07-01 | 2016-11-16 | 潘明华 | A kind of silkete penetrating agent and preparation method thereof |
| CN106368009A (en) * | 2016-08-31 | 2017-02-01 | 浙江皇马科技股份有限公司 | Rapid alkali-resistant penetration agent and compounding method thereof |
| CN106368011A (en) * | 2016-10-13 | 2017-02-01 | 无锡市华诚印染剂厂 | High temperature resistance penetrant for fabric |
| CN106368010A (en) * | 2016-10-13 | 2017-02-01 | 无锡市华诚印染剂厂 | Easily degradable and highly efficient penetrant used for fabric |
| CN106521995A (en) * | 2016-10-13 | 2017-03-22 | 无锡市华诚印染剂厂 | Fabric penetrating agent facilitating even dyeing |
| CN106801333A (en) * | 2017-01-23 | 2017-06-06 | 济宁锦祥化工科技有限公司 | A kind of textile printing and dyeing preparation method of green strong high-temperature alkali-resistant penetrant |
| CN108221385A (en) * | 2017-04-06 | 2018-06-29 | 上海天坛助剂有限公司 | A kind of environment-friendly type silkete penetrating agent and its production method |
| CN107938396A (en) * | 2017-10-20 | 2018-04-20 | 江苏新瑞贝科技股份有限公司 | A kind of environmental protection bleeding agent and preparation method thereof |
| CN107829320A (en) * | 2017-10-20 | 2018-03-23 | 江苏新瑞贝科技股份有限公司 | A kind of dye penetrant and preparation method thereof |
| CN107829321A (en) * | 2017-10-20 | 2018-03-23 | 江苏新瑞贝科技股份有限公司 | A kind of alkali-resistant penetrant and preparation method thereof |
| CN111972416A (en) * | 2020-07-31 | 2020-11-24 | 常州润源新材料科技有限责任公司 | All-round penetration spreading agent |
| CN115584646B (en) * | 2022-10-18 | 2024-03-19 | 英德市东鸿化工科技有限公司 | Penetrant produced by utilizing industrial side ester |
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| CN101725042B (en) * | 2009-12-08 | 2011-11-23 | 山东金鲁化工有限公司 | Alkali proof scouring penetrant and method for preparing same |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
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