CN107630370A - Collect multi-functional dyeing with bath degreaser - Google Patents
Collect multi-functional dyeing with bath degreaser Download PDFInfo
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- CN107630370A CN107630370A CN201710963477.3A CN201710963477A CN107630370A CN 107630370 A CN107630370 A CN 107630370A CN 201710963477 A CN201710963477 A CN 201710963477A CN 107630370 A CN107630370 A CN 107630370A
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Abstract
The present invention relates to the multi-functional dyeing of a collection with bath degreaser, it is characterised in that by mass percentage, its composition is as follows:AEO:5 20%, modified fatty amine APEO:5 20%, dispersant:2 10%, solvent:5 10%, polyether-modified silicon ether-ether:0.3 1%, water:Surplus.The multi-functional dyeing of collection of the present invention with bath with degreaser application convenient, simple operation, only plus a auxiliary agent can.In terms of effect, there is preferable disperse dyes and level dyeing effect in textile dyeing, in addition with low bubble, easy cleaning, in one-bath dyeing multi-fiber dimensional fabric, oil removing is clean, oil stain except under is scattered in dye liquor, do not return and be stained with cloth cover and dye vat inwall, so as to effectively avoid dyeing defect, color spot, dye the problems such as uneven, be more avoided that the deposition of zwitterion dyestuff, time saving power saving water-saving simultaneously, energy-saving and emission-reduction, economic benefit is effectively improved, more conform to energy-conserving and environment-protective requirement.
Description
Technical field
The present invention relates to the multi-functional dyeing of a collection with bath degreaser, for helping in slubbing blended fabric dyeing
Agent is added, such as:Dragon and phoenix, two-sided, Jin Feng etc. dyeing.
Background technology
Market change is multifarious, increasingly updates, at present slubbing market successively develop two-sided, dragon and phoenix, Jin Feng etc.,
A whole set of auxiliary agent coordinates the use of this product.According to the requirement of market and client, it is desirable to provide a to be adapted to these mixed
The auxiliary agent of the dyeing of yarn fabric, the requirement of this auxiliary agent has multifunctionality, one to settle, that is to say, that to collect oil removing, level dyeing, delay
Dye, emulsification, disperse, the multifunctional assistant that anti-zwitterion precipitation, low bubble are integrated.
These fabrics are mostly blend fabric, such as:Jin Feng fiber forms:40%, bright and beautiful 40% is washed, nitrile 20%.
It is as follows with particularity at current deficiency:
1st, these are all chemical fibre components, to add spinning oil in spinning process containing Chuck Steak, such as terylene, in weaving process
Knitting oil or spinning oil can be added, and some external greasy dirts can be infected with, these greasy dirts must remove before dyeing, otherwise
The dye defect such as dyeing defect, spot of dyeing can be caused.According to the processing technology of normal dyeing, first using oil removing(Pre-treatment)Contaminated again
The mode of color is carried out, and technological process length, water consumption is big, is not suitable for the environmentally friendly subject requirement of present energy-saving and emission-reduction.
2nd, it is well known that terylene disperse dyes, polyamide fibre acid dyes, the acrylic fibers dye of positive ion.One-bath process
In, kind of dyes is more miscellaneous, and zwitterion has conflict, easily generation precipitation, produces color dot, color spot.
3rd, the colouring of color ratio terylene is fast on polyamide fibre, robs color, and aberration is also easy to produce by final finishing, cloth covers such as fluffings again after dyeing,
Nylon fibre substantially goes up color depth.
4th, the characteristics of disperse dyes:Water is slightly soluble in, is suspended in by the effect of dispersant in dye liquor, is easily condensed during high temperature
Into bulky grain.
For above-mentioned problem and particularity, my company have developed this product.Wish to help printing and dyeing mill to realize oil removing, dyeing
Bath, the time can be effectively saved, using water wisely, save electricity and the effect of level dyeing is realized while steam energy.
The content of the invention
Present invention aims at according to above-mentioned requirements, there is provided a suitable blending slubbing(Jin Feng)The auxiliary agent of dyeing,
The requirement of this auxiliary agent has multifunctionality, one to settle, that is to say, that to collect oil removing, level dyeing, slow dye, emulsification, scattered, anti-negative and positive from
The multifunctional assistant that son precipitation, low bubble are integrated.
The present invention technical solution be:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
AEO:5-20%
Modified fatty amine APEO:5-20%
Dispersant:2-10%
Solvent:5-10%
Polyether-modified silicon ether-ether:0.3-1%
Water:Surplus.
Described AEO can preferentially select Brij 35, tridecyl alcohol polyoxy second
Alkene ether.AEO is nonionic surfactant, and itself has stronger emulsifying ability, dispersion force and washing force,
Scattered to dyestuff have preferable effect, while the removal to greasy dirt has certain effect.
Described modified fatty amine APEO is that aliphatic amine polyoxyethylene ether is modified by sulfamic acid, mol ratio 1:
1~1.2 general structure is:
Wherein, the direct-connected alkyl of R=18 carbon, can be saturated alkyl, or unsaturated alkyl;X+Y=5-8.
Described dispersant sells glycerine oleic acid ester, AEO by the market(80EO).To dyestuff, it is particularly
Disperse dyes play scattered, high temperature level dyeing.
Described solvent is ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, ethanol, isopropanol, two
Glycol etc., play a part of to adjust product viscosity and appearance stablity, there is syneryistic effect.Foam is reduced when applying simultaneously, is had
Dissolving dye is imitated, increases the dispersiveness of dyeing.In the application, by AEO, modified fatty amine APEO
And dispersant(Glycerine oleic acid ester or AEO)Mixing so that the product integrates multi-functional,
But in mixed process, after concentrating material mixing, mutual incompatible, product easily muddy retrogradation, it is impossible to store, can not
Follow-up normal use, the solvent that the application uses, can eliminate this adverse effect.Especially with diethylene glycol monobutyl ether effect most
It is good.
The polyether-modified silicon ether-ether is organic silicon modified by polyether emulsion, has antifoam performance, suppresses bubble in dye bath
The generation of foam, and have splendid stability at high temperature, silicon spot will not be produced.
A kind of multi-functional dyeing of described collection is applied to pure chemical fiber fabric such as terylene or containing chemical fibre with bath with degreaser
Blend fabric such as polyester-cotton blend, wash brocade, wash nitrile, wash nitrile brocade, hair washs the blend fabric such as nitrile, particularly wash nitrile brocade, hair washs the blending such as nitrile and knit
Co-bathing dyeing on thing, advantage are more prominent.
Compared with prior art, the beneficial effect of the application is:
The application degreaser be suitable for such as polyester-cotton blend of the blend fabric containing chemical fibre, wash brocade, wash nitrile, wash nitrile brocade, hair washs the blending such as nitrile and knits
Thing, it can meet that oil removing with dyeing while carrying out, has following features:1st, in temperature-rise period is dyed and whole soak
Cheng Zhong, oil removing is clean, emulsifies the oil dispersed got off in water, cooling with discharge opeing when can anti-non-return be stained with cloth cover.2nd, auxiliary agent has
There is the function of preventing that zwitterion from precipitating, suitable for terylene(Use disperse dyes), polyamide fibre(Use acid dyes), acrylic fibers(With sun from
Sub- dyestuff)Etc. different use environments.3rd, the colouring of color ratio terylene is fast on polyamide fibre, robs color, and our auxiliary agent makes to delay dye on polyamide fibre, with washing
Synthetic fibre colouring is consistent.4th, auxiliary agent has the performance of high temperature levelling agent, suitable for hot environment.
The multi-functional dyeing of collection of the present invention with bath with degreaser application convenient, simple operation, it is only plus a
Auxiliary agent can.In terms of effect, there is preferable disperse dyes and level dyeing effect in textile dyeing, in addition with low bubble
Property, easy cleaning, in one-bath dyeing multi-fiber dimensional fabric, oil removing is clean, and the oil stain except under is scattered in dye liquor, does not return and is stained with cloth
Face and dye vat inwall, so as to effectively avoid dyeing defect, color spot, dye the problems such as uneven, more it is avoided that zwitterion dyestuff
Deposition, while time saving power saving water-saving, energy-saving and emission-reduction, effectively improve economic benefit, more conform to energy-conserving and environment-protective requirement.
Embodiment:
With reference to example, the present invention will be further described.
Case study on implementation 1:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
Brij 35:15%
Sulfamic acid modified fatty amine APEO: 10%
Glycerine oleic acid ester:10%
Diethylene glycol monobutyl ether:5%
Polyether-modified silicon ether-ether:0.3%
Water:Surplus
Preparation method is as follows:Weigh above-mentioned article respectively by mass percentage, then put into reactor, add water, heating
To 50 DEG C -60 DEG C, stir, produce the multi-functional dyeing of collection with bath degreaser.
Case study on implementation 2:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
Tridecyl alcohol APEO(8EO):15%
Sulfamic acid modified fatty amine APEO: 10%
Glycerine oleic acid ester:5%
AEO(80EO)5%
Ethylene glycol monobutyl ether:5%
Polyether-modified silicon ether-ether:0.3%
Water:Surplus
Preparation method is the same as case study on implementation 1.
Case study on implementation 3:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
Tridecyl alcohol APEO(10EO):15%
Sulfamic acid modified fatty amine APEO: 10%
Glycerine oleic acid ester:5%
AEO(80EO)5%
Ethylene glycol monobutyl ether:5%
Polyether-modified silicon ether-ether:0.3%
Water:Surplus
Preparation method is the same as case study on implementation 1.
Case study on implementation 4:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
Tridecyl alcohol APEO(8EO):15%
Sulfamic acid modified fatty amine APEO: 10%
Glycerine oleic acid ester:5%
AEO(80EO)5%
Ethylene glycol monobutyl ether:10%
Polyether-modified silicon ether-ether:0.3%
Water:Surplus
Preparation method is the same as case study on implementation 1.
Case study on implementation 5:
The multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
Brij 35:15%
Sulfamic acid modified fatty amine APEO: 10%
Glycerine oleic acid ester:10%
Diethylene glycol monobutyl ether:5%
Polyether-modified silicon ether-ether:0.3%
Water:Surplus
Application note:
Application note:Suitable for pure chemical fiber fabric such as terylene or such as polyester-cotton blend of the blend fabric containing chemical fibre, wash brocade, wash nitrile, wash nitrile brocade,
Hair washs the blend fabric such as nitrile, particularly washs nitrile brocade, hair washs the blend fabric such as nitrile.Environment protection type dye is with dispersant dosage with bath
0.5-2%(o.w.f)(Relative to the gross mass of pending fabric).Processing temperature is ordinary temperature(98℃-130℃), add
It is the normal dyeing time between man-hour(50-60min), processing temperature and process time are selected depending on fabric species.
Application effect:
Application example 1:Referring to table 1, table 1 gives case study on implementation 1, case study on implementation 2, case study on implementation 3, case study on implementation 4 gained
Product, case study on implementation 5, the comparing result applied to co-bathing dyeing.The technique that table 1 is applied is impregnation technology, and that is applied knits
Thing is washs nitrile brocade blend fabric, and dyeing temperature is 120 DEG C, and dyeing time is 60 minutes, and heating rate is 2 DEG C/min, just dye temperature
Spend for 40 DEG C.
The impregnation technology comparing result of table 1
Relevant explanation in table 1 given below:
Color yield test instrument in table 1 is spectrophotometer.
Color yield method of testing is in table 1:
At room temperature, by the dyeing residual liquid dilution 10% after be unstained dye liquor and each dyeing, extinction is tested respectively on spectrophotometer
Degree.Dye liquor absorbance of being unstained is x, and dyeing residual liquid absorbance is y.
Color yield computational methods are formula 1 in table 1:
Color yield(%)=[(x-y)/x]×100%
As it can be seen from table 1 the present invention be applied to pure chemical fiber fabric such as terylene or such as polyester-cotton blend of the blend fabric containing chemical fibre, wash brocade,
Wash nitrile, wash nitrile brocade, hair wash the blend fabric such as nitrile, particularly wash nitrile brocade, hair wash the blend fabric such as nitrile.It is relative with conventional dispersant
Than, according to environment protection type dye produced by the present invention with bath with dispersant have color depth the characteristics of, can effectively save dyestuff, meet
Market use demand.
Application example 2:Referring to table 2, table 2 gives case study on implementation 1, case study on implementation 2, case study on implementation 3, the institute of case study on implementation 4
The product obtained, applied to co-bathing dyeing and the comparing result of traditional handicraft.The technique that table 2 is applied is impregnation technology, is applied
Fabric to wash nitrile brocade blend fabric, dyeing temperature is 120 DEG C, and dyeing time is 60 minutes, and heating rate is 2 DEG C/min, just
It is 40 DEG C to contaminate temperature.
The One Bath Dyeing of table 2
Relevant explanation in table 2 given below:
(1)The tester of color yield, method of testing and computational methods are the same as table 1 in table 2.
From table 2 it can be seen that being compared with common process, divided using being used according to environment protection type dye produced by the present invention with bath
Color yield approaches with traditional handicraft when powder dyes, and meets the market demand, while can effectively shorten dyeing time and number, reduces
Washing times after dyeing, mitigate the pressure to sewage disposal, water and electric saving, effectively improve economic benefits, meet energy-saving and emission-reduction
It is required that.
(Degreaser performance)
Application example 3:Referring to table 3, table 3 gives case study on implementation 1, case study on implementation 2, case study on implementation 3, case study on implementation 4 gained
Product, the comparing result applied to oil removing process.The technique that table 3 is applied is impregnation technology, and the fabric applied is bright and beautiful to wash nitrile
Blend fabric, except oil temperature is 120 DEG C, the oil removing time is 30 minutes, and working solution pH is 4-5.
The process ration of the deoiling effect of table 3
Relevant explanation in table 3 given below:
(1)The preparation of soiled cotton in table 3:It is clean that the extraction of nitrile brocade blend fabric chloroform will first be washed, then pad by white oil, machine oil,
The mixing greasy dirt that petroleum ether, solvent blue are formulated by a certain percentage, two leachings two are rolled rear room temperature and dried.
(2)The fabric of each sample will be separated and washed in table 3, using distillation washing during washing, washed and must fully be taken off
Water, 80 DEG C of drying cloth specimens.
(3)The determining instrument of oil removal rate is the quick withdrawal device of fiber grease in table 3.
(4)Oil removal rate computational methods are formula 2 in table 3:
Cloth specimen after the soiled cotton of the identical grams of accurate clip and oil removing, the finish amount for extracting and being calculated respectively, soiled cotton oil
Dosage is m0, the cloth specimen finish amount after oil removing is m1.
Oil removal rate computational methods are formula 2 in table 3:
Oil removal rate(%)=[(m0-m1)/m0]*100%
From table 3 it can be seen that being compared with conventional degreaser, dyed using according to produced by the present invention with bath degreaser oil removing
Rate is higher, disclosure satisfy that the market demand.
Claims (6)
1. the multi-functional dyeing of one kind collection is the same as bath degreaser, it is characterised in that by mass percentage, its composition is as follows:
AEO:5-20%
Sulfamic acid modified fatty amine APEO:5-20%
Dispersant:2-10%
Solvent:5-10%
Polyether-modified silicon ether-ether:0.3-1%
Water:Surplus.
2. the multi-functional dyeing of collection according to claim 1 is the same as bath degreaser, it is characterised in that:Described poly alkyl alcohol
Oxygen vinethene selects Brij 35 or tridecyl alcohol APEO.
3. the multi-functional dyeing of collection according to claim 1 is the same as bath degreaser, it is characterised in that:Described modified fat
Amine APEO is that aliphatic amine polyoxyethylene ether is modified by sulfamic acid, mol ratio 1:1~1.2, general structure is:
Wherein, the direct-connected alkyl of R=18 carbon, can be saturated alkyl, or unsaturated alkyl;X+Y=5-8.
4. the multi-functional dyeing of collection according to claim 1 is the same as bath degreaser, it is characterised in that:Described dispersant is
Glycerine oleic acid ester or AEO.
5. the multi-functional dyeing of collection according to claim 1 is the same as bath degreaser, it is characterised in that:Described solvent is selected from
Ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol butyl ether, ethanol, isopropanol, the one or more in diethylene glycol (DEG).
6. the multi-functional dyeing of collection according to claim 1 is the same as bath degreaser, it is characterised in that:The polyether-modified silicon
Ether-ether is organic silicon modified by polyether emulsion.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108570360A (en) * | 2018-04-26 | 2018-09-25 | 浙江汉邦化工有限公司 | A kind of guarantor's color vividization unclogging agent |
CN109898344A (en) * | 2019-01-11 | 2019-06-18 | 杭州航民达美染整有限公司 | It is a kind of to wash the colouring method and scouring and dyeing emulsifier that are knitted fabric suitable for containing |
CN111206442A (en) * | 2020-02-28 | 2020-05-29 | 纳派化学(上海)有限公司 | Nylon-spandex blended fabric deoiling leveling agent and preparation method thereof |
CN111749034A (en) * | 2020-07-03 | 2020-10-09 | 绍兴海成化工有限公司 | Multifunctional emulsifier and application thereof |
CN112553907A (en) * | 2020-12-30 | 2021-03-26 | 江苏尼美达科技有限公司 | Multifunctional degreasing agent for dyeing one bath and preparation method thereof |
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CN101629130A (en) * | 2009-08-14 | 2010-01-20 | 福建省晋江新德美化工有限公司 | Fabric one-bath deoiling agent |
CN103952905A (en) * | 2014-05-13 | 2014-07-30 | 浙江丝科院轻纺材料有限公司 | One-bath multifunctional treating agent and preparation method thereof |
CN104804890A (en) * | 2014-01-25 | 2015-07-29 | 无锡市拓普科技开发中心 | Decontaminating and deoiling agent for fabric dyeing |
CN106087407A (en) * | 2016-06-15 | 2016-11-09 | 晋江市南星印染材料有限公司 | A kind of textile highly effective oil remover |
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CN101629130A (en) * | 2009-08-14 | 2010-01-20 | 福建省晋江新德美化工有限公司 | Fabric one-bath deoiling agent |
CN104804890A (en) * | 2014-01-25 | 2015-07-29 | 无锡市拓普科技开发中心 | Decontaminating and deoiling agent for fabric dyeing |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108570360A (en) * | 2018-04-26 | 2018-09-25 | 浙江汉邦化工有限公司 | A kind of guarantor's color vividization unclogging agent |
CN108570360B (en) * | 2018-04-26 | 2021-12-17 | 浙江汉邦新材料股份有限公司 | Color-preserving brightening oil stain removing agent |
CN109898344A (en) * | 2019-01-11 | 2019-06-18 | 杭州航民达美染整有限公司 | It is a kind of to wash the colouring method and scouring and dyeing emulsifier that are knitted fabric suitable for containing |
CN111206442A (en) * | 2020-02-28 | 2020-05-29 | 纳派化学(上海)有限公司 | Nylon-spandex blended fabric deoiling leveling agent and preparation method thereof |
CN111206442B (en) * | 2020-02-28 | 2023-04-11 | 纳派化学(上海)有限公司 | Nylon-spandex blended fabric deoiling leveling agent and preparation method thereof |
CN111749034A (en) * | 2020-07-03 | 2020-10-09 | 绍兴海成化工有限公司 | Multifunctional emulsifier and application thereof |
CN112553907A (en) * | 2020-12-30 | 2021-03-26 | 江苏尼美达科技有限公司 | Multifunctional degreasing agent for dyeing one bath and preparation method thereof |
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Application publication date: 20180126 |