CN101629130A - Fabric one-bath deoiling agent - Google Patents
Fabric one-bath deoiling agent Download PDFInfo
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- CN101629130A CN101629130A CN200910112365A CN200910112365A CN101629130A CN 101629130 A CN101629130 A CN 101629130A CN 200910112365 A CN200910112365 A CN 200910112365A CN 200910112365 A CN200910112365 A CN 200910112365A CN 101629130 A CN101629130 A CN 101629130A
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Abstract
The invention relates to a fabric deoiling agent, in particular to a fabric one-bath deoiling agent not only suitable for the single deoiling treatment of fabrics, such as terylene, chinlon, cotton, and the like, but also particularly suitable for treating chemical fiber fabrics, such as the terylene, the chinlon, and the like by a deoiling dyeing one-bath method. The invention provides the fabric one-bath deoiling agent with favorable deoiling effect under acidic conditions and an application thereof. The fabric one-bath deoiling agent comprises the following ingredients in percentage by weight: 10-60 polyoxyethylene alkyl amine, 5-40 alkyl sulfonate, 10-50 sulfate surface active agent or/and phosphate salt surface active agent and the balance of water. The fabric one-bath deoiling agent can be used for treating the fabrics of the terylene, the chinlon, the cotton, and the like by the deoiling dyeing one-bath method.
Description
Technical field
The present invention relates to a kind of fabric degreaser, especially relate to a kind of independent oil removal treatment that is not only applicable to fabrics such as terylene, polyamide fibre, cotton, and be specially adapted to the fabric one-bath deoiling agent of the oil removing one-pass bath method for dyeing processing of chemical ﹠ blended fabrics such as terylene, polyamide fibre.
Background technology
Contain finishes such as dimethyl silicone oil, amino modified or polyether modified silicon oil in the fabric raw yarn, mineral wet goods finish also can be added to make smoothly in the weaving mill.Dyeing and finishing factory must remove removers before dyeing, otherwise oil mark can occur, causes substandard products.Because common degreaser competence exertion deoiling effect under alkaline condition, and coloration of textile materials such as terylene, polyamide fibre are carried out under acidic conditions, therefore if use common degreaser, must carry out in two steps: oil removing under alkaline condition earlier, under acidic conditions, dye then.Need expend a large amount of water, electricity and vapour like this, and need the long time, cause inefficiency.
Application number is 93111379.2, name is called the Chinese invention patent application of " a kind of degreaser and production method thereof ", disclose the degreaser prescription that is formed by solvent part and the packing of dispersion emulsifier part, this degreaser only is applicable to manual oil removing, is not suitable for the oil removing in the dyeing and finishing processing.
Application number is 02156629.1, name is called the Chinese invention patent application of " clothing degreaser ", the clothing degreaser prescription of being made up of Sodium dodecylbenzene sulfonate, sodium hydroxide, 6501, Sodium Benzoate, spices, salt and polyoxyethylenated alcohol sodium sulfate is disclosed, this degreaser only is applicable to the home washings oil removing, is not suitable for the oil removing in the dyeing and finishing processing.
Summary of the invention
The purpose of this invention is to provide a kind of fabric one-bath deoiling agent that under acidic conditions, also has good deoiling effect.
Another object of the present invention is to that described a kind of fabric one-bath deoiling agent is used for that fabrics such as terylene, polyamide fibre, cotton are carried out the oil removing one-pass bath method for dyeing handles, carry out with bathing to realize fabric oil removing, dyeing, reach and save a large amount of water, electricity, vapour and time, significantly improve production efficiency, the purpose that reduces production costs.
Purpose of the present invention is realized by following technical proposals.
A kind of fabric one-bath deoiling agent, by mass percentage, it is composed as follows:
Aliphatic amine polyoxyethylene ether 10%～60%
Alkylsulfonate 5%～40%
Sulfate surfactant is or/and phosphate ester salt tensio-active agent 10%～50%
Water surplus.
Described aliphatic amine polyoxyethylene ether is nonionogenic tensides such as coco amine Soxylat A 25-7, stearylamine Soxylat A 25-7, oil base amine Soxylat A 25-7, lauryl amine Soxylat A 25-7 or octadecylamine Soxylat A 25-7 preferably, and the general structure of aliphatic amine polyoxyethylene ether is:
R represents alkyl in the formula, and X, Y are the integer greater than 3.
Anion surfactants such as described alkylsulfonate preferred alkyl benzene sulfonate, secondary paraffin sulfonate or alkene sulfonate, described alkylbenzene sulfonate can be selected Sodium dodecylbenzene sulfonate etc. for use, and alkene sulfonate can be selected alpha-olefin sodium sulfonate etc. for use.
Described sulfate surfactant preferred fat polyoxyethylenated alcohol vitriol or sodium lauryl sulphate etc.Described phosphate ester salt tensio-active agent preferred fat polyoxyethylenated alcohol phosphate ester salts etc., aliphatic alcohol polyoxyvinethene phosphate salt can be selected aliphatic alcohol polyoxyvinethene phosphate sodium or dodecyl alcohol polyoxyethylene ether phosphate sodium etc. for use.
Described a kind of fabric one-bath deoiling agent can be used for that fabrics such as terylene, polyamide fibre, cotton are carried out the oil removing one-pass bath method for dyeing to be handled.
Compared with the prior art, fabric one-bath deoiling agent of the present invention has following outstanding advantage and beneficial effect:
In the composition of fabric one-bath deoiling agent of the present invention, because aliphatic amine polyoxyethylene ether is a nonionogenic tenside, its special aliphatic amide oleophilic group structure has stronger avidity to various finishes, greasy dirt, therefore finish, greasy dirt is shown good emulsifying, washing, decontamination and dissemination; Because it is anion surfactants such as alkylsulfonate, sulfate surfactant, phosphate ester salt tensio-active agent have good penetration, emulsification and dissemination, therefore also very strong to the removal ability of greasy dirt, solid spot.
With nonionogenic tenside and anion surfactant combination, played obvious synergistic effect in the composition of fabric one-bath deoiling agent of the present invention, be further described below:
(1) alkylsulfonate, sulfate surfactant, phosphate ester salt tensio-active agent are anion surfactant, and they and aliphatic amine polyoxyethylene ether (nonionogenic tenside) have formed mixed micelle in solution.Anion surfactant inserts in the nonionogenic tenside micella, formed mixed micelle based on nonionogenic tenside, micellar surface electric density increases, because Coulomb repulsion effect, mixed micelle is difficult for assembling, and the cloud point of nonionogenic tenside is raise, therefore in oil removing one-pass bath method for dyeing technology, at higher temperature section, nonionogenic tenside still has the outstanding functional oil that removes.
(2) the present invention adopts anion surfactant and nonionic surfactant combinations, because the hydrocarbon interchain hydrophobic interaction of two kinds of surfactant molecules, make system be easier to form micella, so micelle-forming concentration (cmc of system, be that tensio-active agent begins to assemble from individual molecule or ion, minimum concentration when forming micella) greatly descend, when dyeing and finishing factory used product of the present invention, promptly usage quantity is less also can obtain deoiling effect preferably.
(3) the present invention adopts anion surfactant and nonionic surfactant combinations, because the surface tension of solution is lower during than both independent uses, so shows higher surfactivity.
Embodiment
The present invention is further illustrated below by embodiment.
Embodiment 1
By mass percentage, fabric one-bath deoiling agent is composed as follows:
Lauryl amine Soxylat A 25-7 50%
Alpha-olefin sodium sulfonate 10%
Polyoxyethylenated alcohol sodium sulfate 10%
Aliphatic alcohol polyoxyvinethene phosphate sodium 15%
Water surplus
The preparation method of fabric one-bath deoiling agent is as follows: take by weighing lauryl amine Soxylat A 25-7, alpha-olefin sodium sulfonate, polyoxyethylenated alcohol sodium sulfate and aliphatic alcohol polyoxyvinethene phosphate sodium by mass percentage respectively, all drop into reaction vessel then, add entry, be warming up to 50 ℃, stir, promptly make fabric one-bath deoiling agent.
Embodiment 2
By mass percentage, fabric one-bath deoiling agent is composed as follows:
Oil base amine Soxylat A 25-7 60%
Sodium dodecylbenzene sulfonate 5%
Sodium alkyl sulfate 10%
Aliphatic alcohol polyoxyvinethene phosphate sodium 15%
Water surplus
The preparation method is with embodiment 1.
Embodiment 3
By mass percentage, the fabric degreaser is composed as follows:
Coco amine Soxylat A 25-7 60%
Alpha-olefin sodium sulfonate 10%
Sodium lauryl sulphate 10%
Dodecyl alcohol polyoxyethylene ether phosphate sodium 10%
Water surplus
The preparation method is with embodiment 1.
Embodiment 4
By mass percentage, fabric one-bath deoiling agent is composed as follows:
Octadecylamine Soxylat A 25-7 10%
Sodium dodecylbenzene sulfonate 30%
Polyoxyethylenated alcohol sodium sulfate 25%
Dodecyl alcohol polyoxyethylene ether phosphate sodium 25%
Water surplus
The preparation method is with embodiment 1.
Embodiment 5
By mass percentage, fabric one-bath deoiling agent is composed as follows:
Stearylamine Soxylat A 25-7 25%
Alpha-olefin sodium sulfonate 40%
Polyoxyethylenated alcohol sodium sulfate 10%
Water surplus
The preparation method is with embodiment 1.
Embodiment 6
Application note: during use, prepared fabric one-bath deoiling agent carries out the oil removing one-pass bath method for dyeing to looped fabrics such as terylene, polyamide fibre, cottons to be handled, and the fabric one-bath deoiling agent consumption is about 1% (with respect to the total mass of pending fabric) and gets final product.Other auxiliary agents and dyestuff be technology adding routinely all, and heating up also routinely, dyeing requires to get final product.
Effect (is the example explanation with embodiment 1): referring to table 1, table 1 has provided the product that uses embodiment 1 gained, is applied to oil removing one-pass bath method for dyeing technology and traditional technology result relatively.The applied textiles of table 1 is the pure looped fabric of washing of 75D.
Table 1
| Index | The present invention | Traditional technology |
| The consumption time (the every cylinder of min/) | ??120 | ??180 |
| Water consumption (ton/cloth per ton) | ??10 | ??30 |
| Power consumption (degree/cloth per ton) | ??108 | ??163 |
| Steam consumption (m 3/ cloth per ton) | ??2.6 | ??3.8 |
| Deoiling effect (level) | ??5 | ??5 |
| Colour fastness to washing (level) | ??4～5 | ??4～5 |
| Fastness to perspiration (sweat acid condition) (level) | ??4 | ??4 |
| Fastness to perspiration (sweat stain condition) (level) | ??4 | ??4 |
Below provide the relevant explanation in the table 1.
1) the consumption time is meant the time that oil removing, dyeing process (not comprising reduction clearing) consume altogether;
2) water consumption, power consumption, steam consumption are meant water, electricity, the vapour amount that oil removing, dyeing process (not comprising reduction clearing) use altogether;
3) deoiling effect, pass judgment on cloth cover greasy dirt residual quantity:
1 grade: the cloth cover greasy dirt is not removed fully;
2 grades: the cloth cover greasy dirt is removed on a small quantity;
3 grades: cloth cover greasy dirt half amount is removed;
4 grades: cloth cover greasy dirt great majority are removed;
5 grades: the cloth cover greasy dirt is removed substantially.
4) colour fastness to washing is carried out the GB/T3921.3-2008 standard;
5) fastness to perspiration is carried out the GB/T3922-1997 standard.
As can be seen from Table 1, use the present invention when textiles that oil removing one-pass bath method for dyeing technology is produced, the time that every cylinder consumes can reduce 60min, and cloth per ton can 20 tons of the amounts of conserving water, power consumption 55 degree, steam consumption 1.2m
3, energy conservation and consumption reduction effects is obvious.
Claims (9)
1, a kind of fabric one-bath deoiling agent is characterized in that by mass percentage, it is composed as follows:
Aliphatic amine polyoxyethylene ether 10%～60%
Alkylsulfonate 5%～40%
Sulfate surfactant and/or phosphate ester salt tensio-active agent 10%～50%
Water surplus.
2, described a kind of fabric one-bath deoiling agent as claimed in claim 1 is characterized in that the general structure of described aliphatic amine polyoxyethylene ether is:
R represents alkyl in the formula, and X, Y are the integer greater than 3.
3, described a kind of fabric one-bath deoiling agent as claimed in claim 1 or 2 is characterized in that described aliphatic amine polyoxyethylene ether is coco amine Soxylat A 25-7, stearylamine Soxylat A 25-7, oil base amine Soxylat A 25-7, lauryl amine Soxylat A 25-7 or octadecylamine Soxylat A 25-7.
4, described a kind of fabric one-bath deoiling agent as claimed in claim 1 is characterized in that described alkylsulfonate is alkylbenzene sulfonate, secondary paraffin sulfonate or alkene sulfonate.
5, described a kind of fabric one-bath deoiling agent as claimed in claim 4 is characterized in that described alkylsulfonate selects alpha-olefin sodium sulfonate or Sodium dodecylbenzene sulfonate for use.
6, described a kind of fabric one-bath deoiling agent as claimed in claim 1 is characterized in that described sulfate surfactant is fatty alcohol polyoxyethylene ether sulfate or sodium lauryl sulphate.
7, described a kind of fabric one-bath deoiling agent as claimed in claim 1 is characterized in that described phosphate ester salt tensio-active agent is an aliphatic alcohol polyoxyvinethene phosphate salt.
8, described a kind of fabric one-bath deoiling agent as claimed in claim 7 is characterized in that described aliphatic alcohol polyoxyvinethene phosphate salt is aliphatic alcohol polyoxyvinethene phosphate sodium or dodecyl alcohol polyoxyethylene ether phosphate sodium.
9, a kind of fabric one-bath deoiling agent as claimed in claim 1, the application in fabrics such as terylene, polyamide fibre, cotton being carried out the processing of oil removing one-pass bath method for dyeing.
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| CN2009101123652A CN101629130B (en) | 2009-08-14 | 2009-08-14 | Fabric one-bath deoiling agent |
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| CN101984175A (en) * | 2010-11-12 | 2011-03-09 | 常熟市群英针织制造有限责任公司 | Method for processing three-dimensional mesh fabric |
| CN102444033A (en) * | 2011-09-20 | 2012-05-09 | 杭州天宇印染有限公司 | Dyeing and finishing method of brocade/rayon/spandex knitted fabric |
| CN102995468A (en) * | 2012-11-26 | 2013-03-27 | 浙江安诺其助剂有限公司 | Polyester fabric dyeing degreaser and preparation method thereof |
| CN103174019A (en) * | 2011-12-23 | 2013-06-26 | 广东德美精细化工股份有限公司 | Multifunctional chemical system used for scouring and bleaching cotton-polyester blended fabrics and dyeing polyester components in one bath |
| CN103174004A (en) * | 2011-12-23 | 2013-06-26 | 广东德美精细化工股份有限公司 | Multifunctional chemical system used for scouring and dyeing cotton knitted fabrics in one bath |
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