CN103966033A - Color-protecting laundry detergent and preparation method thereof - Google Patents
Color-protecting laundry detergent and preparation method thereof Download PDFInfo
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- CN103966033A CN103966033A CN201410235531.9A CN201410235531A CN103966033A CN 103966033 A CN103966033 A CN 103966033A CN 201410235531 A CN201410235531 A CN 201410235531A CN 103966033 A CN103966033 A CN 103966033A
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- fatty alcohol
- polyoxyethylene ether
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Abstract
The invention relates to a color-protecting laundry detergent and a preparation method thereof. In order to keep the color of a textile bright in a garment washing process, empirically the color-protecting treatment needs to be carried out in advance before the washing process, so that the washing steps are tedious and inconvenient. The novel color-protecting laundry detergent is prepared by mixing fatty alcohol polyoxyethylene ether sulfate, 5%-25% of fatty alcohol polyoxyethylene ether, coconut oil diethanolamide, an organic solvent, a bacteriostat, a thickener, citric acid, a color-protecting agent and essence with water. According to the laundry detergent, a compound color-protecting agent of a novel color-fixing agent and an anti-color-crossing agent is adopted; the color-fixing agent can be bonded with dye molecules to ensure that dyes are not easily dissolved in washing liquor, so as to achieve the dye-fixing effect; the anti-color-crossing agent forms a film on the surface of the textile to reduce the loss of dye molecules and the dye adhesion quantity of the light-colored textile or wraps the dye modules in the washing liquor to ensure that the dye molecules are not easily directly adhered to the textile, so as to achieve the anti-color-crossing purpose.
Description
Technical field
the present invention designs a kind of washing liquid, is specifically related to a kind of look washing liquid and preparation method thereof that protects.
Background technology
Laundry processes often can run into that clothing fades or the phenomenon of colour contamination, allows originally the bright clothing face that becomes entirely non-, affects washing effect.How in laundry processes, to keep clothing beautiful in colour, bright clean as new, always be a very important laundry demand.Laundry is protected look aspect and has been carried out for a long time a large amount of practices, experience a large amount of practice accumulation, as first soaked with salt solution or alum, also have the immersions such as vinegar for suggestion, citric acid, tartrate before laundry, in a word, before laundry, carry out pre-treatment meeting and reach certain chromatic effect that protects.Yet these empirical methods need to be carried out pre-treatment to clothing before laundry, made the step of laundry operations become loaded down with trivial details, can not adapt to current allegro life.
Summary of the invention
The object of this invention is to provide a kind of look washing liquid and preparation method thereof that protects, can synchronously complete the operation of doing washing and protecting look, simplify laundry step.
The technical solution adopted in the present invention is:
Protect a look washing liquid, it is characterized in that:
Component by following mass percent is made:
Fatty alcohol polyoxyethylene ether sulfate 1-20%;
Fatty alcohol-polyoxyethylene ether 5-25%;
Cocounut oil diglycollic amide 1-10%;
Organic solvent 0.1-10%;
Fungistat 0.01-0.5%;
Thickening material 1-5%;
Citric acid 0.5-2%;
Colour protecting agent 0.1-2%;
Essence 0.05-0.5%;
Water surplus.
It is polyoxyethylenated alcohol sodium sulfate salt, fatty alcohol-polyoxyethylene ether sulfuric acid sylvite, the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain.
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C18, ethoxymer distribution are 7-15.
Described organic solvent is selected from ethanol, Virahol, propylene glycol.
Described fungistat is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol.
Described thickening material is selected from sodium-chlor, sodium sulfate.
Described colour protecting agent is selected from polyquart
?fDI, Tinofix CL, TexCare
?dFC, Sokalan
?hP66K.
A preparation method who protects look washing liquid, is characterized in that:
By following steps, realized:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 1-20%;
Fatty alcohol-polyoxyethylene ether 5-25%;
Cocounut oil diglycollic amide 1-10%;
Organic solvent 0.1-10%;
Fungistat 0.01-0.5%;
Thickening material 1-5%;
Citric acid 0.5-2%;
Colour protecting agent 0.1-2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 50-60 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 10-15 minute;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
It is polyoxyethylenated alcohol sodium sulfate salt, fatty alcohol-polyoxyethylene ether sulfuric acid sylvite, the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C18, ethoxymer distribution are 7-15;
Described organic solvent is selected from ethanol, Virahol, propylene glycol;
Described fungistat is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described thickening material is selected from sodium-chlor, sodium sulfate;
Described colour protecting agent is selected from polyquart
?fDI, Tinofix CL, TexCare
?dFC, Sokalan
?hP66K.
The present invention has the following advantages:
1. provided by the inventionly protect colour protecting agent in look washing liquid and adopt the composite of novel laking agent and anti-colour contamination agent.Laking agent can be combined with dye molecule, makes dyestuff be difficult for being dissolved in the object that reaches firm dyestuff in washing lotion, makes clothing be difficult for fading; Anti-colour contamination agent, by forming film at fabric face, reduces the loss of dye molecule on colored fabric and the amount that light fabric attaches dyestuff, or in washing lotion, dye molecule is wrapped up, and makes dye molecule be difficult for directly sticking on fabric, reaches the object of anti-colour contamination.The look washing liquid that protects that protects at present the use of look washing liquid product or bibliographical information only has fixation or anti-colour contamination single performance, composite washing liquid fixation and the dual chromatic effect that protects of anti-colour contamination given for the first time of novel laking agent and anti-colour contamination agent.
2. the look washing liquid that protects provided by the invention is compared and is had neutral mild formulation with traditional washing liquid, does not hinder clothing, in laundry processes, make clothing clean, protect that look disposable to be completed.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail.
A kind of preparation method who protects look washing liquid involved in the present invention, is realized by following steps:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 1-20%;
Fatty alcohol-polyoxyethylene ether 5-25%;
Cocounut oil diglycollic amide 1-10%;
Organic solvent 0.1-10%;
Fungistat 0.01-0.5%;
Thickening material 1-5%;
Citric acid 0.5-2%;
Colour protecting agent 0.1-2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 50-60 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 10-15 minute;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
Wherein:
It is polyoxyethylenated alcohol sodium sulfate salt, fatty alcohol-polyoxyethylene ether sulfuric acid sylvite, the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C18, ethoxymer distribution are 7-15;
Described organic solvent is selected from ethanol, Virahol, propylene glycol;
Described fungistat is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described thickening material is selected from sodium-chlor, sodium sulfate;
Described colour protecting agent is selected from polyquart
?fDI, Tinofix CL, TexCare
?dFC, Sokalan
?hP66K.
Embodiment 1:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 1%;
Fatty alcohol-polyoxyethylene ether 5%;
Cocounut oil diglycollic amide 1%;
Organic solvent 0.1%;
Fungistat 0.01%;
Thickening material 1%;
Citric acid 0.5%;
Colour protecting agent 0.1%;
Essence 0.05%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 50 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 10 minutes;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
Wherein:
It is the polyoxyethylenated alcohol sodium sulfate salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C12, ethoxymer distribution are 7-9;
Described organic solvent is chosen ethanol;
Described fungistat is chosen triclosan;
Described thickening material is chosen sodium-chlor;
Described colour protecting agent is chosen polyquart
?fDI and Sokalan
?hP66K, blending ratio 5:3.
Embodiment 2:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 10%;
Fatty alcohol-polyoxyethylene ether 15%;
Cocounut oil diglycollic amide 5%;
Organic solvent 5%;
Fungistat 0.25%;
Thickening material 2.5%;
Citric acid 1%;
Colour protecting agent 1%;
Essence 0.2%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 55 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 12 minutes;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
Wherein:
It is the fatty alcohol-polyoxyethylene ether sulfuric acid sylvite that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 13-C15, ethoxymer distribution are 10-12;
Described organic solvent is chosen Virahol;
Described fungistat is chosen triclocarban;
Described thickening material is chosen sodium-chlor;
Described colour protecting agent is chosen TexCare
?dFC and Sokalan
?hP66K, blending ratio is 2:1.
Embodiment 3:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 20%;
Fatty alcohol-polyoxyethylene ether 25%;
Cocounut oil diglycollic amide 10%;
Organic solvent 10%;
Fungistat 0.5%;
Thickening material 5%;
Citric acid 2%;
Colour protecting agent 2%;
Essence 0.5%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 60 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 15 minutes;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
Wherein:
It is the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 16-C18, ethoxymer distribution are 13-15;
Described organic solvent is chosen propylene glycol;
Described fungistat is chosen parachlormetaxylenol or orthoxenol;
Described thickening material is chosen sodium sulfate;
Described colour protecting agent is chosen Tinofix CL and TexCare
?dFC, blending ratio is 1:2.
Protect chromatic effect evaluation method:
Fixation testing method: use and add and the method for not adding the washing liquid of laking agent by contrast, utilize the rear aberration of painting cloth washing to evaluate laking agent colour fixation.By contrast the present invention protect the washing of look washing liquid and competing product afterwards aberration judge and protect look washing liquid colour fixation.
Concrete testing method:
1. directly blue (red, the purple) painting cloth (5cm*5cm) of the suitable test of cutting;
2. washing soln preparation: preparation is containing laking agent with do not contain the 0.3% washing liquid aqueous solution of laking agent respectively, and be heated to 60 ℃ standby;
3. painting cloth is placed in respectively to the washing liquid aqueous solution, same rotational speed magnetic agitation 1 hour, same operation repeats 3 times;
4. after stirring finishes, take out painting cloth, deionized water is cleaned, 55 ℃ of oven dry, observable comparing result.
Anti-colour contamination testing method:
In order with the naked eye intuitively to observe the present invention, protect the anti-colour contamination effect of look washing liquid, selected the anti-colour contamination test of dye method, the method can be used for contrast adds anti-colour contamination agent and does not add the significant difference of anti-colour contamination agent washing liquid aspect anti-colour contamination, be also applicable to the anti-colour contamination Performance Ratio of relevant competing product.
Concrete testing method is as follows:
1. the test cloth sheet of the suitable size of cutting (white towel 5cm*5cm);
2. washing soln preparation:
The preparation of 2.1 dye solutions: first prepare 0.0625% direct indigo plant, the substantive dyestuff solution such as red, dilution 500-1000 makes test dye solution after doubly;
The preparation of 2.2 washing liquid dye solutions: each 200ml of washing liquid dye solution all kinds of to be tested of preparation 0.5% is in 500ml beaker;
3. painting cloth is placed in respectively to washing liquid dye solution, same rotational speed magnetic agitation 10 minutes, changes the clean tap water rinsing of 400ml after taking-up, continues to stir rinsing 5 minutes, rinsing 2 times under same rotational speed;
After stirring finishes, take out painting cloth, can directly observe comparing result, after drying, also can observe again comparative test result.
It is cited that content of the present invention is not limited to embodiment, and the conversion of any equivalence that those of ordinary skills take technical solution of the present invention by reading specification sheets of the present invention, is claim of the present invention and contains.
Claims (9)
1. protect a look washing liquid, it is characterized in that:
Component by following mass percent is made:
Fatty alcohol polyoxyethylene ether sulfate 1-20%;
Fatty alcohol-polyoxyethylene ether 5-25%;
Cocounut oil diglycollic amide 1-10%;
Organic solvent 0.1-10%;
Fungistat 0.01-0.5%;
Thickening material 1-5%;
Citric acid 0.5-2%;
Colour protecting agent 0.1-2%;
Essence 0.05-0.5%;
Water surplus.
2. a kind of look washing liquid that protects according to claim 1, is characterized in that:
It is polyoxyethylenated alcohol sodium sulfate salt, fatty alcohol-polyoxyethylene ether sulfuric acid sylvite, the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain.
3. a kind of look washing liquid that protects according to claim 2, is characterized in that:
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C18, ethoxymer distribution are 7-15.
4. a kind of look washing liquid that protects according to claim 3, is characterized in that:
Described organic solvent is selected from ethanol, Virahol, propylene glycol.
5. a kind of look washing liquid that protects according to claim 4, is characterized in that:
Described fungistat is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol.
6. a kind of look washing liquid that protects according to claim 5, is characterized in that:
Described thickening material is selected from sodium-chlor, sodium sulfate.
7. a kind of look washing liquid that protects according to claim 6, is characterized in that:
Described colour protecting agent is selected from polyquart
?fDI, Tinofix CL, TexCare
?dFC, Sokalan
?hP66K.
8. a preparation method who protects look washing liquid, is characterized in that:
By following steps, realized:
Step 1: each component is got the raw materials ready by following formula:
Fatty alcohol polyoxyethylene ether sulfate 1-20%;
Fatty alcohol-polyoxyethylene ether 5-25%;
Cocounut oil diglycollic amide 1-10%;
Organic solvent 0.1-10%;
Fungistat 0.01-0.5%;
Thickening material 1-5%;
Citric acid 0.5-2%;
Colour protecting agent 0.1-2%;
Essence 0.05-0.5%;
Water surplus;
Step 2: add water and organic solvent in batch tank, and heat, temperature is controlled to 50-60 ℃, then adds fatty alcohol polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether and cocounut oil diglycollic amide, is stirred to completely and dissolves;
Step 3: in the situation that stirring, add fungistat, thickening material and citric acid, until dissolve completely;
Step 4: stop heating, add colour protecting agent, stir 10-15 minute;
Step 5: in the situation that continue stirring, add essence a little;
Step 6: work in-process carry out ripening;
Step 7: sampling Detection, finished product packing.
9. a kind of preparation method who protects look washing liquid according to claim 8, is characterized in that:
It is polyoxyethylenated alcohol sodium sulfate salt, fatty alcohol-polyoxyethylene ether sulfuric acid sylvite, the AESA salt that C12-C18, ethoxymer distribution are 2-4 that described fatty alcohol polyoxyethylene ether sulfate is selected from fatty alcohol carbochain;
Described fatty alcohol-polyoxyethylene ether is selected from the fatty alcohol-polyoxyethylene ether that straight chain C 10-C18, ethoxymer distribution are 7-15;
Described organic solvent is selected from ethanol, Virahol, propylene glycol;
Described fungistat is selected from triclosan, triclocarban, parachlormetaxylenol, orthoxenol;
Described thickening material is selected from sodium-chlor, sodium sulfate;
Described colour protecting agent is selected from polyquart
?fDI, Tinofix CL, TexCare
?dFC, Sokalan
?hP66K.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410235531.9A CN103966033A (en) | 2014-05-30 | 2014-05-30 | Color-protecting laundry detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410235531.9A CN103966033A (en) | 2014-05-30 | 2014-05-30 | Color-protecting laundry detergent and preparation method thereof |
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| CN201410235531.9A Pending CN103966033A (en) | 2014-05-30 | 2014-05-30 | Color-protecting laundry detergent and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112174A (en) * | 2015-09-10 | 2015-12-02 | 辽宁石化职业技术学院 | Bactericidal mould-proof laundry detergent |
| CN105296191A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Efficient decontaminating and color-protecting laundry detergent and preparation method therefor |
| CN105586165A (en) * | 2016-01-29 | 2016-05-18 | 广州康钰生物科技有限公司 | Laundry sheet with color protecting function and preparation method thereof |
| CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
| CN106833932A (en) * | 2016-12-28 | 2017-06-13 | 于文 | Gym suit cleaning agent and preparation method thereof |
| CN107574032A (en) * | 2017-10-13 | 2018-01-12 | 洛娃科技实业集团有限公司 | A kind of liquid detergent and preparation method |
| CN107805553A (en) * | 2017-11-06 | 2018-03-16 | 浙江神英科技有限公司 | A kind of anti-dyeing liquid detergent containing olive oil component and preparation method thereof |
| CN108048242A (en) * | 2017-11-30 | 2018-05-18 | 广东嘉丹婷日用品有限公司 | A kind of high-efficiency antimicrobial liquid detergent and preparation method thereof |
| WO2019084976A1 (en) * | 2017-11-06 | 2019-05-09 | 广东嘉丹婷日用品有限公司 | Composition and laundry tablet for cleaning clothes and preparation method therefor |
| CN111057624A (en) * | 2019-12-19 | 2020-04-24 | 威莱(广州)日用品有限公司 | Sterilization, color protection and color cross-linking prevention concentrated laundry detergent and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112174B (en) * | 2015-09-10 | 2018-01-23 | 辽宁石化职业技术学院 | A kind of fungus and mildew resistance liquid detergent |
| CN105112174A (en) * | 2015-09-10 | 2015-12-02 | 辽宁石化职业技术学院 | Bactericidal mould-proof laundry detergent |
| CN105296191A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Efficient decontaminating and color-protecting laundry detergent and preparation method therefor |
| CN105586165A (en) * | 2016-01-29 | 2016-05-18 | 广州康钰生物科技有限公司 | Laundry sheet with color protecting function and preparation method thereof |
| CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
| CN106833932A (en) * | 2016-12-28 | 2017-06-13 | 于文 | Gym suit cleaning agent and preparation method thereof |
| CN107574032A (en) * | 2017-10-13 | 2018-01-12 | 洛娃科技实业集团有限公司 | A kind of liquid detergent and preparation method |
| CN107805553A (en) * | 2017-11-06 | 2018-03-16 | 浙江神英科技有限公司 | A kind of anti-dyeing liquid detergent containing olive oil component and preparation method thereof |
| WO2019084976A1 (en) * | 2017-11-06 | 2019-05-09 | 广东嘉丹婷日用品有限公司 | Composition and laundry tablet for cleaning clothes and preparation method therefor |
| CN108048242A (en) * | 2017-11-30 | 2018-05-18 | 广东嘉丹婷日用品有限公司 | A kind of high-efficiency antimicrobial liquid detergent and preparation method thereof |
| CN111057624A (en) * | 2019-12-19 | 2020-04-24 | 威莱(广州)日用品有限公司 | Sterilization, color protection and color cross-linking prevention concentrated laundry detergent and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
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