CN105648793B - A kind of high chlorine-resistant print paste and preparation method and application - Google Patents

A kind of high chlorine-resistant print paste and preparation method and application Download PDF

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Publication number
CN105648793B
CN105648793B CN201610206844.0A CN201610206844A CN105648793B CN 105648793 B CN105648793 B CN 105648793B CN 201610206844 A CN201610206844 A CN 201610206844A CN 105648793 B CN105648793 B CN 105648793B
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chlorine
agent
resistant
bright
print paste
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CN105648793A (en
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罗灯洪
袁东
邓燕
张继斌
朱立太
王亚静
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Beijing Chemical Co Ltd In Textile
Dongguan Zhongfang Chemical Co Ltd
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Beijing Chemical Co Ltd In Textile
Dongguan Zhongfang Chemical Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
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    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
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    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
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    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/422—Hydrazides
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
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    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6425—Compounds containing hydrazine or azo groups
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D06P1/6497—Amides of di- or polyamines; Acylated polyamines
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67366—Phosphates or polyphosphates
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/001—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8209—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide groups
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

The invention discloses a kind of high chlorine-resistant print paste and preparation method and application.In terms of weight/mass percentage composition, it is made up of following components：0.01%~3% acid dyes, 2%~6% chlorine-resistant monomer, 1%~10% thickener, 3%~5% cosolvent, 0.5%~1% chelating agent, the water of 0.5%~6% sour agent and surplus；The chlorine-resistant monomer is made up of the water of 1%~5% polyacrylate, 5%~48% hydrazide derivatives, 0.5%~6% dispersant and surplus.The present invention is not under conditions of the existing machinery equipment of factory and production technology is changed, bright and beautiful spandex swimming suit PRINTED FABRIC stamp coloring site and the overall color fastness to chlorine at white background position are effectively increased, fabric discoloration is small, good hand touch, chlorine fastness is high, and wash durability is good.

Description

A kind of high chlorine-resistant print paste and preparation method and application
Technical field
The present invention relates to a kind of high chlorine-resistant print paste and preparation method and application, belongs to printing in textiles technology neck Domain.
Background technology
The high susceptibility to chlorine water is often shown for the dyestuff of textile dyeing and stamp.In the presence of chlorine water, The chromophore of dye molecule or auxochrome easily occur to destroy degraded, cause its absorbent properties to light to change, and then cause The change of color.Swimming pool will add a certain amount of chlorine water and carry out sterilizing, the content of Active Chlorine be usually 0.5-3ppm or It is higher, the colour fading and discoloration of swimming suit clothes can be caused.
Swimsuit is mainly made up of bright and beautiful spandex (chinlon/spandex) elastic fabric, and spandex fibre chlorine-resistant property therein is also It is poor, used in chloride environment, its elasticity and intensity can even be lost because the etch of Active Chlorine gradually reduces, and outward appearance Can slowly it turn yellow.
Therefore, chlorine-resistant property is an important performance indexes of bright and beautiful spandex swimming suit fabric, usually requires that its color fastness to chlorine Reach more than 4 grades (5 grades of highests).In order to improve the color fastness to chlorine of bright and beautiful spandex swimming suit fabric, it is necessary to be carried out with chlorine-resistant color fixing agent Post processing.
Patent CN201420041092.3 discloses a kind of high chlorine-resistant swimsuit fabric, is designed by fabric structure, One layer of high chlorine-resistant layer being made up of more amine chlorine-resistant color fixing agent is provided with above textle layers, reaches the purpose for improving chlorine fastness. Patent CN201280054268.2 discloses a kind of method for increasing polyamide fiber material fastness to chlorine-bleaching, uses sulphur after dyeing The waterborne liquid of urea/formaldehyde/bis-phenol condensation product or thiocarbamide/isocyanate addition product handles polyamide fiber material, can increase dye The fastness to chlorine-bleaching of the polyamide fiber material of color.But do not refer to the applicability of bright and beautiful spandex PRINTED FABRIC and applied to stamp In mill base.
In fact, for bright and beautiful spandex dyed fabric, a fabric only has single color, by locating after chlorine-resistant color fixing agent Reason is easy to control to improve chlorine fastness in production.But for PRINTED FABRIC, a dresser line loom figured is by a variety of multiple Miscellaneous color, flower pattern are formed, and each color is inconsistent to the tolerance degree of Active Chlorine, it is difficult in identical chlorine-resistant aftertreatment technology The chlorine fastness of all colours on lower raising fabric.Moreover, for the white background position of non-stamp coloring, through common chlorine-resistant fixation Its chlorine fastness can be deteriorated on the contrary after agent processing, and unqualified bright and beautiful spandex PRINTED FABRIC color fastness to chlorine is because white background portion mostly Caused by position chlorine fastness is not up to standard.Therefore, how simultaneously improve bright and beautiful spandex PRINTED FABRIC coloring site, white background position it is whole Body color fastness to chlorine, it is always the technological difficulties and important research field of the industry.
The content of the invention
It is an object of the invention to provide a kind of high chlorine-resistant print paste and preparation method and application, the print paste can carry High bright and beautiful spandex PRINTED FABRIC coloring site and the overall color fastness to chlorine at white background position.
Print paste provided by the invention, in terms of weight/mass percentage composition, it is made up of following components：0.01%~3% acid Property dyestuff, 2%~6% chlorine-resistant monomer, 1%~10% thickener, 3%~5% cosolvent, 0.5%~1% chelating agent, 0.5%~ 6% sour agent and the water of surplus；In terms of weight/mass percentage composition, the chlorine-resistant monomer is by 1%~5% polyacrylate, 5%~48% The water composition of hydrazide derivatives, 0.5%~6% dispersant and surplus.
Above-mentioned print paste, the addition of chlorine-resistant monomer can improve bright and beautiful spandex PRINTED FABRIC coloring site and white background position Overall color fastness to chlorine；The addition of the chlorine-resistant monomer can be according to the weight/mass percentage composition and dyestuff of dyestuff in mill base point The chlorine-resistant property of minor structure is adjusted flexibly, and in terms of weight/mass percentage composition, the print paste specifically can be by following 1) -6) in appoint A kind of component composition：
1) 0.15%~2.0% acid dyes, 3%~5% chlorine-resistant monomer, 2%~7% thickener, 4%~5% cosolvent, The water of 0.5%~1% chelating agent, 2%~5% sour agent and surplus；
2) 0.55%~2.0% acid dyes, 4%~5% chlorine-resistant monomer, 2%~5% thickener, 5% cosolvent, 1% chela The water of mixture, 2%~3% sour agent and surplus；
3) 0.15%~2.0% acid dyes, 3%~4% chlorine-resistant monomer, 2%~7% thickener, 4%~5% cosolvent, The water of 0.5%~1% chelating agent, 3%~5% sour agent and surplus；
4) 0.15%~0.53% acid dyes, 3% chlorine-resistant monomer, 7% thickener, 4% cosolvent, 0.5% chelating agent, 5% sour agent and the water of surplus；
5) 1.0%~1.58% acid dyes, 5% chlorine-resistant monomer, 5% thickener, 5% cosolvent, 1% chelating agent, 2% acid Agent and the water of surplus；
6) 0.55%~2.0% acid dyes, 4% chlorine-resistant monomer, 2% thickener, 5% cosolvent, 1% chelating agent, 3% acid Agent and the water of surplus.
In above-mentioned print paste, in the chlorine-resistant monomer, the polyacrylate refers to close with acrylic ester monomer Into polymer, the acrylic ester monomer includes but is not limited to methyl acrylate, ethyl acrylate, 2- methyl methacrylates Ester, ethyl 2-methacrylate, butyl acrylate, GMA etc., its molecular weight can be 2000~6000； And/or
" hydrazide derivatives " have following general structure,
Formula I
In formula I, R can be-(CH2)5-11CH3、
R1Can be-H or-CH3；
R2Can be-H ,-CH3Or-CH2CH3；
R3Can be-H ,-CH3、—CH2CH3、
Preferably, the hydrazide derivatives can be the hydrazides of suberic acid two, the hydrazides of azelaic acid two, sebacic dihydrazide, 12 The different cigarette acid hydrazide of alkane dicarboxyl acid dihydrazide, isonicotinic acid hydrazide, 1,2- bis-, 1,2- dimethyl -1,2- dibenzoyl hydrazines and isophthalic diformazan One or more in hydrazides；And/or
The dispersant includes but is not limited to：Neopelex, dodecyl Biphenyl Ether sodium disulfonate, naphthalene sulfonic acids Formaldehyde condensation products, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, benzyl naphthalene sulfonic acid-formaldehyde condensation product, dodecyl azochlorosulfonate propyl lycine, ten In dialkyl sulfonates, fatty alcohol polyoxy ether sulfate, cocoanut fatty acid diethanolamide and AEO At least one；
Preferably, the naphthalene sulfonic acid-formaldehyde condensation product can be sodium metnylene bis-naphthalene sulfonate (dispersant NNO), methyl naphthalene sulfonic acid Formaldehyde condensation products (Dispersant MF) or benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent C NF)；
Preferably, the fatty alcohol carbon number of the AEO can be 10~18, concretely 12~14, 13~15,16~18,13 or 18；
Preferably, the APEO number of the AEO can be 5~40, concretely 7,9,15,20, 30 or 40.
In above-mentioned print paste, in terms of weight/mass percentage composition, the chlorine-resistant monomer specifically can by 2% polyacrylate, The water composition of 15% hydrazide derivatives, 2% dispersant and surplus, such as the chlorine-resistant monomer NL- of Dongguan City Zhong Fang Chemical Co., Ltd.s 52, outward appearance is the sticky dispersion liquid of milky；The particle diameter of the chlorine-resistant monomer can be 0.1~1 μm, the non-blocking screen during stamp Net.
In above-mentioned print paste, the preparation technology of the chlorine-resistant monomer can be as follows：By hydrazide derivatives, dispersant and water Mixing, after being sanded 5~48 hours with 200~2000 revs/min of speed, polyacrylate is added, is continued with 50~200 Rev/min speed stir 0.5~2 hour.
In above-mentioned print paste, the acid dyes is the water-soluble dye containing acidic-group, is included but is not limited to： One or more in highly acid dyestuff, weak acid dye and acid metal complex dye, such as fluorescein E-B, fluorescein E-8G Deng highly acid dyestuff, the acid metal complex dyes such as NHF-S is yellow, NHF-S is red, NHF-S is blue, emerald green blue A-G, gorgeous blue 6B, red B- The weak acid dyes such as 10B, blue A-R, yellow 4G, red 3B and red 3G.
In above-mentioned print paste, the thickener can be at least one of sodium alginate, guar gum or etherification starch.
In above-mentioned print paste, the cosolvent can be urea and/or diethyl ethyl glycol, can promote dye molecule Quick all dissolvings.
In above-mentioned print paste, the chelating agent can be the big sodium acetate of two adjacent phenyl of ethylenediamine, calgon and two At least one of methene phosphoric acid of ethene triamine five, play a part of chelate the aqueous solution in calcium ions and magnesium ions, prevent calcium ions and magnesium ions with Dye molecule combines to form particle not soluble in water and screen cloth is blocked during stamp.
In above-mentioned print paste, the sour agent can be ammonium sulfate and/or citric acid.
Invention further provides a kind of preparation method of above-mentioned print paste, it comprises the following steps：
(1) thickener, the sour agent are mixed with water, lasting stirring, obtains the former paste of stamp；
(2) after mixing the acid dyes, the cosolvent and the chelating agent, dissolved and filtered with water, take filtrate, Obtain dye mother solution；
(3) the former paste of step (1) stamp is mixed with step (2) described dye mother solution, adds the chlorine-resistant monomer, Stirring, obtains print paste.
In above-mentioned preparation method, in terms of weight/mass percentage composition, the proportioning of each raw material is as follows：
Acid dyes 0.01%~3%, chlorine-resistant monomer 2%~6%, thickener 1%~10%, cosolvent 3%~5%, chela Mixture 0.5%~1%, sour agent 0.5%~6%, surplus is water.
In above-mentioned preparation method, the mass ratio of the water in the step (1) and the water in the step (2) can be (1~ 4)：1, concretely 11：5 or 7：3.
In above-mentioned preparation method, in step (1), the time persistently stirred can be 1~6 hour, concretely 2~ 4 hours, 2~3 hours, 3~4 hours, 2 hours, 3 hours or 4 hours；The rotating speed of the stirring can be 100~400 revs/min, Concretely 150~250 revs/min, 150~200 revs/min, 200~250 revs/min, 150 revs/min, 200 revs/min Or 250 revs/min.
In above-mentioned preparation method, in step (2), boiling water can be specifically used to accelerate dissolving.
In above-mentioned preparation method, in step (3), time of the stirring can be 0.5~2 hour, concretely 0.5~ 1 hour, 0.5 hour or 1 hour, the speed of agitator can be 100~300 revs/min, concretely 100~150 revs/min, 100 revs/min or 150 revs/min.
In above-mentioned preparation method, the viscosity of the print paste is 4000~5000 lis Pa Secs (CPS).
Above-mentioned print paste is following 1) -4) at least one of in application, also within the scope of the present invention：
1) application in printing in textiles；
2) application in bright and beautiful spandex PRINTED FABRIC is prepared；
3) application in the color fastness to chlorine for improving bright and beautiful spandex PRINTED FABRIC；
4) answering in bright and beautiful spandex PRINTED FABRIC coloring site and the overall color fastness to chlorine at white background position is improved at the same time With.
Invention further provides the method for preparing bright and beautiful spandex PRINTED FABRIC using above-mentioned print paste, including following step Suddenly：
(1) bright and beautiful spandex fabric is subjected to oil removing, then padded and pre-setting processing；The working solution padded is anti- The agent of high temperature xanthochromia and/or the aqueous solution of fluorescent whitening agent；
(2) print paste is printed on the fabric handled through the pre-setting, and baked, decatize and water Wash；
(3) PRINTED FABRIC after the washing is padded and heat treatment, you can obtain the bright and beautiful spandex stamp Fabric；The working solution padded is the aqueous solution of high temperature yellow stain resistant agent.
In above-mentioned method, in step (1), the high temperature yellow stain resistant agent can prevent bright and beautiful spandex fabric from meeting in pre-setting High temperature turns yellow, while the chlorine fastness to lifting white background has positive role；The fluorescent whitening agent can be according to calico bottom The appropriate addition of color whiteness requirement；Described to pad in step, described to pad in working solution, the concentration of the high temperature yellow stain resistant agent is 10 ~40g/L, concretely 20g/L；The concentration of the fluorescent whitening agent is 0~2g/L, concretely 2g/L；The high temperature resistance is yellow Become agent as hydrazides class antioxidant and fatty alcohol polyethenoxy ether class surfactant blend, in the compound, the acyl The mass ratio of hydrazine antioxidant and the fatty alcohol polyethenoxy ether class surfactant is 4：(1~10), the high temperature resistance Xanthochromia agent concretely AH and AEO-9 compounds (mass ratio 4：3), resisting such as Dongguan City Zhong Fang Chemical Co., Ltd.s High temperature xanthochromia agent FK-161；And/or
It is described to pad in step in step (3), in the aqueous solution of the high temperature yellow stain resistant agent, the high temperature yellow stain resistant agent Concentration be 5~10g/L, concretely 5~8g/L, 8~10g/L, 5g/L, 8g/L or 10g/L；The high temperature yellow stain resistant agent is Hinered phenols antioxidant and hydrazides class antioxidant compound, in the compound, the Hinered phenols antioxidant and the acyl The mass ratio of hydrazine antioxidant is 1：(5~10), the high temperature yellow stain resistant agent concretely double [β-(uncle 3- of triethylene-glycol Butyl -4- hydroxy-5-methyl bases phenyl) propionic ester] (antioxidant 245) and isobutyrate hydrazide compound (mass ratio 1：9), such as east The high temperature yellow stain resistant agent FK-161D of Zhong Fang Chemical Co., Ltd.s of tabernaemontanus bulrush city, it is new generation of environment protection product, does not adsorb free first Aldehyde.
In above-mentioned method, in step (1), in the deoiling step, the concentration of degreaser used can be 2~5g/L, Concretely 2~4g/L, 2g/L or 4g/L；The degreaser can be isomeric alcohol polyethenoxy ether surfactant blend, tool Body can be the compound of isomerous tridecanol polyoxyethylene ether 1303,1305,1307 and 1309, as spun the limited public affairs of chemical industry in Dongguan City The degreaser FK-9507N of department；The temperature of the oil removing can be 80~85 DEG C, concretely 80 DEG C or 85 DEG C, the time can be 15~ 30 minutes, concretely 15~20 minutes, 15 minutes or 20 minutes；The oil removing is carried out on overflow machine or Full-width rinsing machine； In the pre-setting processing step, the temperature of the pre-setting can be 190~195 DEG C, concretely 190 DEG C or 195 DEG C, the time Can be 30~60 seconds, concretely 30~50 seconds, 30 seconds or 50 seconds；Described pad is carried out with the pre-setting in forming machine.
Can be hand printing or full-automatic decorating machine stamp in the printing step in step (2)；It is described to bake step In, the temperature baked can be 110~130 DEG C, concretely 110~120 DEG C, 120~130 DEG C, 130 DEG C, 120 DEG C, 110 DEG C, the time can be 1~3 minute, concretely 1~2 minute, 2~3 minutes, 1 minute, 2 minutes or 3 minutes；The steaming step In, the temperature of the decatize can be 102~105 DEG C, and concretely 102 DEG C or 105 DEG C, the time can be 30~40 minutes, specifically It can be 35~40 minutes, 40 minutes or 35 minutes；Described dyestuff and chlorine-resistant monomer is shifted by decatize and anchors at bright and beautiful spandex On fabric；In the water-washing step, the washing working solution is the aqueous solution of anti-staining detergent and soda ash, and the anti-staining is net The concentration of lotion is 1~3g/L (such as 2g/L), and the concentration of the soda ash is 1~2g/L (such as 2g/L)；The anti-staining detergent For aliphatic amine polyoxyethylene ether class surfactant blend, concretely beef tallow amine APEO 1812,1815,1820, 1830th, 1860 compound, such as the anti-staining detergent FK-9500NY of Dongguan City Zhong Fang Chemical Co., Ltd.s；The washing Temperature can be 40~55 DEG C, specifically can be 45~55 DEG C, 45~50 DEG C, 50~55 DEG C, 45 DEG C, 50 DEG C or 55 DEG C, and the time can be 10 ~20 minutes, concretely 10 minutes；The washing is specifically carried out on scuffing of cylinder bore machine or Full-width rinsing machine, using the scuffing of cylinder bore machine When being washed successively through soaping, clear water wash, soap and washed with clear water, the washing working solution is used during soaping, it is described Full-width rinsing machine comprises at least 6 rinsing bowls, and the washing working solution is poured into the 2nd~5 rinsing bowl.
In step (3), in the heat treatment step, the temperature of the sizing can be 150~160 DEG C, concretely 160 DEG C, the time can be 30~60 seconds, concretely 30~50 seconds, 30 seconds or 50 seconds；Described pad is being shaped with the heat treatment Carried out on machine.
In above-mentioned method, the bright and beautiful spandex PRINTED FABRIC can be bright and beautiful spandex swimming suit fabric, the bright and beautiful spandex PRINTED FABRIC Spandex content can be 2~25%, concretely 8%~23%, 8%~18%, 18%~23%, 8%, 18% or 23%.
The present invention has the advantages that：
The present invention is resistance to by height provided by the invention under conditions of the existing machinery equipment of factory and production technology is not changed The preparation and application of chlorine print paste, effectively increase bright and beautiful spandex swimming suit PRINTED FABRIC stamp coloring site and white background position Overall color fastness to chlorine, fabric discoloration is small, good hand touch, and chlorine fastness is high, and wash durability is good.
Embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
Material used, reagent etc., unless otherwise specified, are commercially obtained in following embodiments.
Chlorine-resistant monomer NL-52 is purchased from Dongguan City Zhong Fang Chemical Co., Ltd.s, and degreaser FK-9507N is purchased from Dongguan City and spun Chemical Co., Ltd., high temperature yellow stain resistant agent FK-161 are purchased from Dongguan City Zhong Fang Chemical Co., Ltd.s, anti-staining detergent FK- 9500NY is purchased from Dongguan City Zhong Fang Chemical Co., Ltd.s, and high temperature yellow stain resistant agent FK-161D, which is purchased from Dongguan City, spins the limited public affairs of chemical industry Department, chlorine-resistant color fixing agent NL-50 are purchased from Dongguan City Zhong Fang Chemical Co., Ltd.s.It is adjuvant used also can by it is other have similar structure or The auxiliary agent of similar performance substitutes.
The preparation and application of embodiment 1, high chlorine-resistant print paste
First, it is formulated
In terms of weight/mass percentage composition, high chlorine-resistant print paste is made up of following components：
2nd, preparation method
High chlorine-resistant print paste is prepared in accordance with the following steps：
(1) 7 parts of guar gums, 5 parts of ammonium sulfate and 55 parts of water are weighed in beaker, it is small that 3 are persistently stirred in electric blender When (rotating speed be 200 revs/min), the former paste of stamp is made；
(2) 0.15 part of acid dyes, 5 parts of urea, 0.5 part of big sodium acetate of ethylenediamine neighbour's phenyl are weighed, is filled with 25 parts of boiling water Divide and dissolve and filter, filtrate is obtained dye mother solution；
(3) by the former paste of stamp made from step (1) pour into step (2) dye mother solution it is well mixed after, add 3 parts of chlorine-resistant Monomer, 0.5 hour (rotating speed is 150 revs/min) is persistently stirred in electric blender, stirs, high chlorine-resistant is made Print paste.Viscosity is 5000CPS.
3rd, apply
Bright and beautiful spandex swimming suit fabric specification：The spandex of 82% polyamide fibre 18%, grammes per square metre 190g/m2。
Bright and beautiful spandex swimming suit fabric is prepared according to following processing step：
Bright and beautiful spandex fabric oil removing (degreaser FK-9507N 2g/L；80℃×20min；Overflow machine oil removing) → pre-setting is (anti- High temperature xanthochromia agent FK-161 20g/L；195 DEG C × 30sec) → stamp → bake (110 DEG C × 3min) → decatize (102 DEG C × 40min) → (scuffing of cylinder bore machine, soap (anti-staining detergent FK-9500NY 2g/L, soda ash 2g/L for washing；50 DEG C × 10min) → clear Wash → soap (anti-staining detergent FK-9500NY 2g/L, soda ash 2g/L；50 DEG C × 10min) → clear water washes) → finished product is fixed Type (high temperature yellow stain resistant agent FK-161D 5g/L；160℃×30sec).
Print paste as the comparative example of the present embodiment is made up of following substances by mass percentage：Dyestuff (dyestuff Kind and percentage composition are identical with corresponding embodiment)；Diethyl ethyl glycol 5%；Sodium alginate 5%；Ammonium sulfate 5%；More than water Amount.Its finished product setting process is chlorine-resistant color fixing agent NL-50 20g/L, 160 DEG C × 30sec.Remaining technique for applying and embodiment are complete It is exactly the same.
According to standard ISO 105-E03-1997《Textile color stability experiment E03 parts chlorine-resistant water colour fastness (swimming pool Water)》(effective chlorine 20ppm) testing example, comparative example and according to standard AATCC 61-2A-2003《Family and commercial face The washing of color is strong》The chlorine-resistant water colour fastness of embodiment and comparative example after washing 1 time, and to stamp coloring site and white background portion Position is graded respectively, and test result is shown in Table 1.
The color fastness to chlorine of embodiment and comparative example when table 1, embodiment 1 are from different dyestuffs
The preparation and application of embodiment 2, high chlorine-resistant print paste
First, it is formulated
In terms of weight/mass percentage composition, high chlorine-resistant print paste is made up of following components：
2nd, preparation method
High chlorine-resistant print paste is prepared in accordance with the following steps：
(1) 7 parts of sodium alginates, 2 parts of citric acids and 55 parts of water are weighed in beaker, 2 are persistently stirred in electric blender Hour (rotating speed is 250 revs/min), the former paste of stamp is made；
(2) 0.5 part of acid dyes, 5 parts of urea, 1 part of calgon are weighed, is fully dissolved and filtered with 25 parts of boiling water, Filtrate is obtained dye mother solution；
(3) by the former paste of stamp made from step (1) pour into step (2) dye mother solution it is well mixed after, add 5 parts of chlorine-resistant Monomer, 1 hour (rotating speed is 100 revs/min) is stirred in electric blender, stirs, high chlorine-resistant stamp color is made Slurry.Viscosity is 4800CPS.
3rd, apply
Bright and beautiful spandex swimming suit fabric specification：The spandex of 92% polyamide fibre 8%, grammes per square metre 170g/m2。
Bright and beautiful spandex swimming suit fabric is prepared according to following processing step：
Bright and beautiful spandex fabric oil removing (degreaser FK-9507N 4g/L；85℃×15min；Full-width rinsing machine oil removing) → predetermined Type (high temperature yellow stain resistant agent FK-161 20g/L, fluorescent whitening agent NFW 450%2g/L；190 DEG C × 50sec) → stamp → bake (120 DEG C × 2min) → decatize (105 DEG C × 35min) → washing (6 groove Full-width rinsing machines, the anti-staining detergent FK- of 2-5 grooves 9500NY 2g/L, soda ash 2g/L；55 DEG C × 10min) → finished product sizing (high temperature yellow stain resistant agent FK-161D 8g/L；160℃× 50sec)
Print paste as the comparative example of the present embodiment is made up of following substances by mass percentage：Dyestuff (dyestuff Kind and percentage composition are with corresponding embodiment)；Urea 5%；Sodium alginate 6%；Citric acid 2%；Water surplus.Its finished product is determined Type technique is chlorine-resistant color fixing agent NL-50 20g/L, 160 DEG C × 50sec.Remaining technique for applying is identical with embodiment.
According to standard ISO 105-E03-1997《Textile color stability experiment E03 parts chlorine-resistant water colour fastness (swimming pool Water)》(effective chlorine 50ppm) testing example, comparative example and according to standard AATCC 61-2A-2003《Family and commercial face The washing of color is strong》The chlorine-resistant water colour fastness of embodiment and comparative example after washing 1 time, and to stamp coloring site and white background portion Position is graded respectively, and test result is shown in Table 2.
The color fastness to chlorine of embodiment and comparative example when the embodiment 2 of table 2 is from different dyestuffs
The preparation and application of embodiment 3, high chlorine-resistant print paste
First, it is formulated
In terms of weight/mass percentage composition, high chlorine-resistant print paste is made up of following components：
2nd, preparation method
High chlorine-resistant print paste is prepared in accordance with the following steps：
(1) 2 parts of etherification starch, 3 parts of ammonium sulfate and 64 parts of water are weighed in beaker, 4 are persistently stirred in electric blender Hour (rotating speed is 150 revs/min), the former paste of stamp is made；
(2) 0.15 part of acid dyes, 5 parts of urea, 1 part of sodium tripolyphosphate are weighed, is fully dissolved and filtered with 25 parts of boiling water, Filtrate is obtained dye mother solution；
(3) by the former paste of stamp made from step (1) pour into step (2) dye mother solution it is well mixed after, add 3 parts of chlorine-resistant Monomer, 0.5 hour (rotating speed is 150 revs/min) is stirred in electric blender, stirs, high chlorine-resistant stamp is made Mill base.Viscosity is 4500CPS.
3rd, apply
Bright and beautiful spandex swimming suit fabric specification：The spandex of 77% polyamide fibre 23%, grammes per square metre 150g/m2。
Bright and beautiful spandex swimming suit fabric is prepared according to following processing step：
Bright and beautiful spandex fabric oil removing (degreaser FK-9507N 2g/L；80℃×20min；Overflow machine oil removing) → pre-setting is (anti- High temperature xanthochromia agent FK-161 20g/L, fluorescent whitening agent NFW 450%2g/L；195 DEG C × 30sec) → stamp → bake (130 DEG C × 1min) → decatize (105 DEG C × 40min) → washing (6 groove Full-width rinsing machines, the anti-staining detergent FK-9500NY of 2-5 grooves 2g/L, soda ash 2g/L；45 DEG C × 10min) → finished product sizing (high temperature yellow stain resistant agent FK-161D 10g/L；160℃×30sec)
Print paste as the comparative example of the present embodiment is made up of following substances by mass percentage：Dyestuff (dyestuff Kind and percentage composition are identical with corresponding embodiment)；Urea 5%；Etherification starch 5%；Ammonium sulfate 5%；Water surplus.Its finished product Setting process is chlorine-resistant color fixing agent NL-50 20g/L, 160 DEG C × 30sec.Remaining technique for applying is identical with embodiment.
According to standard ISO 105-E03-1997《Textile color stability experiment E03 parts chlorine-resistant water colour fastness (swimming pool Water)》(effective chlorine 50ppm) testing example, comparative example and according to standard AATCC 61-2A-2003《Family and commercial face The washing of color is strong》The chlorine-resistant water colour fastness of embodiment and comparative example after washing 1 time, and to stamp coloring site and white background portion Position is graded respectively, and test result is shown in Table 3.
The color fastness to chlorine of embodiment and comparative example when the embodiment 3 of table 3 is from different dyestuffs
From table 1, table 2 and table 3 as can be seen that embodiment is suitable with comparative example in the color fastness to chlorine of stamp coloring site, And the color fastness to chlorine at white background position is high more than 1 grade compared to comparative example.High chlorine-resistant print paste provided by the invention and its system Preparation Method and technique for applying, can solve existing sizing and use chlorine-resistant color fixing agent technique PRINTED FABRIC white background color fastness to chlorine difference Problem, the overall color fastness to chlorine of PRINTED FABRIC is set to reach more than 4 grades, and discoloration is small, good hand touch, and washability is good, by AATCC Standard still has considerable color fastness to chlorine after washing 1 time.

Claims (7)

  1. A kind of 1. print paste, it is characterised in that：In terms of weight/mass percentage composition, it is made up of following components：0.01%~3% acid Property dyestuff, 2%~6% chlorine-resistant monomer, 1%~10% thickener, 3%~5% cosolvent, 0.5%~1% chelating agent, 0.5%~ 6% sour agent and the water of surplus；In terms of weight/mass percentage composition, the chlorine-resistant monomer is chlorine-resistant monomer NL-52；The chlorine-resistant monomer Particle diameter is 0.1~1 μm；
    The thickener is at least one of sodium alginate, guar gum or etherification starch；The cosolvent is urea and/or diethyl Ethyl glycol；The chelating agent is the big sodium acetate of two adjacent phenyl of ethylenediamine, calgon and the methene phosphoric acid of diethylenetriamine five At least one of；The sour agent is ammonium sulfate and/or citric acid.
  2. 2. the preparation method of the print paste described in claim 1, comprises the following steps：
    (1) after mixing the thickener, the sour agent with water, lasting stirring, the former paste of stamp is obtained；
    (2) after mixing the acid dyes, the cosolvent and the chelating agent, dissolved and filtered with water, take filtrate, must contaminated Expect mother liquor；
    (3) the former paste of step (1) stamp is mixed with step (2) described dye mother solution, adds chlorine-resistant monomer, stir, i.e., Obtain the print paste.
  3. 3. preparation method according to claim 2, it is characterised in that：In step (1), the time persistently stirred is 1 ~6 hours, rotating speed was 100~400 revs/min；And/or
    In step (3), the time of the stirring is 0.5~2 hour, and rotating speed is 100~300 revs/min.
  4. 4. print paste described in claim 1 is following 1) -4) at least one of in application：
    1) application in printing in textiles；
    2) application in bright and beautiful spandex PRINTED FABRIC is prepared；
    3) application in the color fastness to chlorine for improving bright and beautiful spandex PRINTED FABRIC；
    4) application in bright and beautiful spandex PRINTED FABRIC coloring site and the overall color fastness to chlorine at white background position is improved at the same time.
  5. 5. the method for preparing bright and beautiful spandex PRINTED FABRIC using the print paste described in claim 1, comprises the following steps：
    (1) bright and beautiful spandex fabric is subjected to oil removing, then padded and pre-setting processing；The working solution padded is high temperature resistance Xanthochromia agent and/or the aqueous solution of fluorescent whitening agent；
    (2) print paste is printed on the fabric handled through the pre-setting, and baked, decatize and washing；
    (3) PRINTED FABRIC after the washing is padded and heat treatment, you can obtain the bright and beautiful spandex PRINTED FABRIC； The working solution padded is the aqueous solution of high temperature yellow stain resistant agent.
  6. 6. according to the method for claim 5, it is characterised in that：It is described to pad in step in step (1), it is described to pad work Make in liquid, the concentration of the high temperature yellow stain resistant agent is 10~40g/L, and the concentration of the fluorescent whitening agent is 0~2g/L；It is described anti- The agent of high temperature xanthochromia is hydrazides class antioxidant and fatty alcohol polyethenoxy ether class surfactant blend, in the compound, The mass ratio of the hydrazides class antioxidant and the fatty alcohol polyethenoxy ether class surfactant is 4：(1~10)；With/ Or,
    It is described to pad in step in step (3), in the aqueous solution of the high temperature yellow stain resistant agent, the high temperature yellow stain resistant agent it is dense Spend for 5~10g/L；The high temperature yellow stain resistant agent is Hinered phenols antioxidant and hydrazides class antioxidant compound, the compounding In thing, the mass ratio of the Hinered phenols antioxidant and the hydrazides kind antioxidant is 1：(5~10).
  7. 7. the method according to claim 5 or 6, it is characterised in that：It is used in the washing deoiling step in step (1) The concentration of degreaser be 2~5g/L；The degreaser is isomeric alcohol polyethenoxy ether surfactant blend；The washing Temperature be 80~85 DEG C, the time be 15~30 minutes；The temperature of the pre-setting is 190~195 DEG C, and the time is 30~60 Second；And/or
    In step (2), in the baking step, the temperature of the baking is 110~130 DEG C, and the time is 1~3 minute；The vapour Steam in step, the temperature of the decatize is 102~105 DEG C, and the time is 30~40 minutes；In the water-washing step, the washing Working solution is the aqueous solution of anti-staining detergent and soda ash, and the concentration of the anti-staining detergent is 1~3g/L, the soda ash Concentration is 1~2g/L；The anti-staining detergent is aliphatic amine polyoxyethylene ether class surfactant blend；The washing Temperature is 40~55 DEG C, and the time is 10~20 minutes；And/or
    In step (3), in the heat treatment step, the temperature of the sizing is 150~160 DEG C, and the time is 30~60 seconds.
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