Summary of the invention
Can't create and improve a kind of production and have the shortcoming of color change is abundant, the fashion effect is dense, style is personalized Freehandhand-drawing fabric or ready-made clothes and a kind of method for hand-painted coloration and dyeing with Freehandhand-drawing finished product of the artistic effect of being rich in is provided in order to overcome prior art Freehandhand-drawing technology.
For solving the problems of the technologies described above, technical scheme of the present invention is, a kind of method for hand-painted coloration and dyeing of textile, and it mainly may further comprise the steps:
(1) preliminary treatment;
(2) shirt that stretches tight;
(3) hand-painted coloration, wherein Freehandhand-drawing form comprise that auxiliary agent polishes, and auxiliary agent uses the Freehandhand-drawing auxiliary agent that contains color-fixing agent, and dyestuff is REACTIVE DYES in the dye composite that uses, and dyestuff content represents that with X each component and quality percentage composition thereof are in the described dye composite:
Thickener 0~12%
Dyestuff 0<X≤15%
Urea 1~15%
Sodium bicarbonate 0~8%
M-nitrobenzene sodium sulfonate 0~3%
Surfactant 0~3%
Add hydration and become 100%
(4) vapour steaming colour fixing evaporates after comprising Freehandhand-drawing; Soap washing oven dry again after soaping behind the washing removal floating color;
(5) washing back arrangement.
The preliminary treatment of described step (1) is washing or bleeding agent preliminary treatment.
The shirt that stretches tight of described step (2): the real silk top-weight fabric is evened up fabric with framework; The medium-thick type elastic fabric is fixed with pin on cystosepiment.
The thickener of step (3) hand-painted coloration is one or more in sodium alginate, etherificate seed glue, emulsion thickening, starch ether, imperial glue or the cellulose ether.
For cotton, viscose glue, part silk fabrics, dye composite each component and quality percentage composition thereof are:
Thickener 0~12%
Dyestuff 0<X≤15%
Urea 3%~15%
Sodium bicarbonate 1%~8%
M-nitrobenzene sodium sulfonate 1%~3%
Surfactant 0%~3%
The Freehandhand-drawing form also comprise adopt pen dye, brush dye, spray-painting, inscription rubbing, pin are colluded, spill dye with resist printing in one or more.
Soaping of step (4) dyeed simultaneously again.
The content of dyestuff is represented with Y, the use of soaping and dye:
Anti-fouling agent 2g/L~15g/L in vain
Detergent 2g/L~15g/L
Dyestuff 0<Y≤5g/L
Under 80 ℃~90 ℃, carried out 5~15 minutes.
The invention has the beneficial effects as follows:, create and improve a kind of production and have Freehandhand-drawing fabric or the ready-made clothes that color change is abundant, the fashion effect is dense, style is personalized by the Freehandhand-drawing finished product that improves production technology and utilize modern dyeing and finishing technique processing to have the artistic effect of being rich in.
The specific embodiment
Method for hand-painted coloration and dyeing of textile of the present invention mainly may further comprise the steps:
(1) fabric washing pre-treatment;
(2) preliminary treatment oven dry;
(3) shirt that stretches tight;
(4) hand-painted coloration;
(5) vapour steaming colour fixing;
(6) washing back arrangement.
The fabric of step (1) comprises woolens, knitting, tatting ready-made clothes or lining, and main raw material is medium-thick type fabrics such as cotton, viscose glue, silk, wool, rabbit suede, terylene.
The fabric preliminary treatment of step (2) is: press the processing mode and the lining character of ready-made clothes, divide washing and bleeding agent preliminary treatment dual mode.Washing is conventional low temperature of known technology or high temperature washing; The bleeding agent preliminary treatment: the fabric not good at water imbibition adopts penetrant treating, makes it have water imbibition, increases the wetting property of dyestuff to fabric, makes Freehandhand-drawing production be easier to carry out.Bleeding agent can be used the oxireme addition product and the low carbon fat alcohol ethylene oxide condensate of nonyl phenol and octyl phenol, fatty alcohol-polyoxyethylene ether, the ether product that oxirane, expoxy propane and higher aliphatic are made is as all kinds of bleeding agents or wetting agents such as bleeding agent JF C, penetrant ts.
The shirt that stretches tight of step (3): have any different for real silk top-weight fabric and medium-thick type elastic fabric in this step, the real silk top-weight fabric is evened up fabric with framework, because this kind fabric is lighter, the centre is unsettled can not to drop; If fabric is a medium-thick type elasticity ready-made clothes fabric, the method for fabric being evened up with framework can make unsettled fabric tenesmus and influence the carrying out and Freehandhand-drawing artistic effect that its Freehandhand-drawing is produced; As the platen mode that adopts the ready-made clothes stamp to use, because the used major part of Freehandhand-drawing is dye liquor, easily stains platen and influence use, so mode of selecting for use unique cystosepiment to fix with pin, both made fabric for convenience detach, the contamination after washing is easy, and can repeatedly reuse.
The hand-painted coloration of step (4): the dyestuff of its use adopts dyestuff kinds such as REACTIVE DYES, acidity, neutrality, dispersion, as Reactive Brilliant Blue KN-R, reactive brilliant red x-3b, active green KE-4B, and bisazo type navy ACID DYES, neutral pink BL106; Disperse lemon yellow 302 etc., the prescription of dye composite is as follows, and wherein dyestuff content is represented with X, and percentage is quality percentage composition (Hereinafter the same):
Thickener 0~12%
Dyestuff 0<X≤15%
Urea 1~15%
Sodium bicarbonate 0~8%
M-nitrobenzene sodium sulfonate 0~3%
Surfactant 0~3%
Add hydration and become 100%
Thickener can be used sodium alginate, etherificate seed glue, emulsion thickening, starch ether, imperial glue, cellulose ether etc.The addition of thickener requires to decide with effect on Freehandhand-drawing, and consumption is preferably between 0~6%.
Surfactant is the additive when various waterproof cloth cover Freehandhand-drawing, or picture adds need special effect occur the time.Surfactant is a kind of in CATION, nonionic, anion and the amphion of prior art or several, as the fatty alcohol ethylene oxide condensate.Whether the difference that the dyestuff kind is looked in the interpolation of other various auxiliary agents decides it to add and addition.
For cotton, viscose glue, part silk fabrics, be suitable for REACTIVE DYES, its formula optimization is:
Dyestuff 0<X≤15% (deciding) according to the coloured light requirement
Urea 3%~15%
Sodium bicarbonate 1%~8%
M-nitrobenzene sodium sulfonate 1%~3%
Surfactant 0%~3%
Thickener 0~12%
Surfactant herein can use the fatty alcohol ethylene oxide condensate.
Thickener can be sodium alginate, emulsion thickening etc.
For fabrics such as wool, cashmere, rabbit suede, silks, be suitable for acidity, faintly acid, neutral class dyestuff, its optimization formula is:
Dyestuff 0<X≤15%
Urea 3%~15%
Surfactant 0%~3%
Thickener 0~12%
Wherein, can add an amount of as required as 0~3% printing and dyeing acid.
Surfactant herein can use the fatty alcohol ethylene oxide condensate.
For dacron etc., be suitable for and disperse the class dyestuff, its optimization formula is:
Dyestuff 0<X≤15%
Urea 2%~15%
Surfactant 0%~3%
Thickener 0~12%
Wherein, can add an amount of as required as 0~3% printing and dyeing acid.
Surfactant herein can use the fatty alcohol ethylene oxide condensate.
In this step, Freehandhand-drawing adopt pen dye, brush dye, spray-painting, inscription rubbing, pin are colluded, spill dye, auxiliary agent is polished, resist printing.
Wherein pen dyes, brushes and dye for directly dye liquor being painted on fabric or the ready-made clothes according to design flower type with all kinds of pen-type tool such as writing brush, spread pen, hairbrush.
Spray-painting is sprayed on dye liquor on the fabric for using watering can or spray gun.
Pin colludes to using needle tubing that dye liquor slurry etc. is colluded on fabric or ready-made clothes by design flower type.
Auxiliary agent is polished: by design flower type the Freehandhand-drawing auxiliary agent of various different-styles and effect is polished drip picture or pen dyes or silk screen is stenciled etc. or two or more at least arbitrarily mode Freehandhand-drawing on fabric or ready-made clothes.
Resist printing: utilize pin to collude or the method for brush brushes resist agent at cloth cover earlier with resist agent, Freehandhand-drawing again under wet or the state done, oven dry, steam wash after, have the cloth cover of resist agent white or light decorative pattern can occur.Resist agent is different with the resist printing in the stamp, if the main medium-thick type fabric of producing adopts dye liquor to carry out Freehandhand-drawing, if use the resist agent in the stamp, its resist printing poor effect so adopt the resist agent of high molecular surfactant, is strengthened its resist printing effect.
Steam after step (5) Freehandhand-drawing and wash the technological process of dying and be: evaporate after the Freehandhand-drawing; Washing (loose colour is cleaned); Oven dry at last.
Fuller's skill condition is 102~190 ℃ of decatizes (or baking) 2~60 minutes after the Freehandhand-drawing, and washing gets final product with prior art.For cotton, viscose glue, part silk fabrics, steam and washed 4~30 minutes; For wool, cashmere, rabbit suede, silk etc., steam and washed 40~60 minutes; For dacron etc., steam and washed 40~60 minutes.The technology of evaporating of REACTIVE DYES is: 102~105 ℃ of decatizes 2~30 minutes, or the method for baking is 150 ℃ and baked 3~5 minutes; The technology of evaporating acid, neutral dye is: 102~105 ℃ of decatizes 40~60 minutes; Disperse the technology of evaporating of class dyestuff to be: 1.47 * 10
5~1.76 * 10
5Pa, 128~130 ℃, 20~30 minutes, or 175~185 ℃, 6~10 minutes.
If use neutral dye in the Freehandhand-drawing process, adopt low temperature (as the 50 ℃) washing (removal floating color) of prior art; If use DISPERSE DYES in the Freehandhand-drawing process, get final product in 80 ℃ of washings (removal floating color).If use REACTIVE DYES in the Freehandhand-drawing process, also can behind the washing removal floating color, further soap.
If also used the Freehandhand-drawing auxiliary agent that contains the color-fixing agent class, can directly soap need not to dye again and forms finished product in the Freehandhand-drawing, also can dye simultaneously soaping again.At this moment, Freehandhand-drawing clothes background color is based on middle light color.
When dyeing simultaneously when soaping, washing removal floating color and local dyeing are carried out simultaneously again.This kind method and Freehandhand-drawing are adjuvant used relevant in producing.
The content of dyestuff is represented with Y, the use of soaping and dye:
Anti-fouling agent 2g/L~15g/L in vain
Detergent 2g/L~15g/L
Dyestuff 0<Y≤5g/L
Under 80 ℃~90 ℃, carried out 5~15 minutes.
Because color-fixing agent is a cationic, with anionic dye strong adsorptivity is arranged, therefore in high temperature was soaped process, cloth cover did not have the part of color-fixing agent because the effect of anti-fouling agent in vain, dyestuff does not dye on not understanding, but dyes owing to the strong adsorption effect of color-fixing agent makes on the dyestuff at the position that color-fixing agent is arranged.Freehandhand-drawing clothes background color must be good with middle light color, otherwise because the dyestuff lower and DeGrain of dye-uptake once more.
Effect: because cloth cover coloured light difference everywhere after the Freehandhand-drawing, after using this kind method that it is dyed on again, though the dyestuff that adds is a kind of pure color light, because the difference of background color and can piecing together dyes now various coloured light when being different from Freehandhand-drawing, greatly enriched the color of cloth cover, made its level abundanter.
Dye dosage is unsuitable too high in soaping and dyeing, otherwise clothes integral body is cut marks.
Example one
This example is that example is specifically set forth with the hand-painted coloration of the thick type ready-made clothes of white cotton.
Step (1) is with this cotton ready-made clothes washing; Step (2) adopts penetrating agent JFC to handle oven dry, makes it have water imbibition, increases the wetting property of dyestuff to fabric, makes Freehandhand-drawing production be easier to carry out; Step (3) selects for use cystosepiment with the fixing cotton ready-made clothes of the fixing mode of pin.
Step (4) is used reactive red K-2BP, active reddish brown K-B 3R isoreactivity dyestuff according to design flower type, and preparation multicolour aqueous dye solutions as prescription is:
Reactive red K-2BP 0.4%
Activity red engleri K-B 3 R 0.3%
Urea 3%
Sodium bicarbonate 2%
M-nitrobenzene sodium sulfonate 1%
Utilize the whole bag of tricks of Freehandhand-drawing dye liquor to be painted on the cloth cover, after the Freehandhand-drawing, carry out the Freehandhand-drawing auxiliary agent again and polish by design flower type, as color-fixing agent and bleeding agent, after Freehandhand-drawing flower type is finished, oven dry.102 ℃ of decatizes 10 minutes, cold water is soaped and is dyeed after cleaning loose colour, uses anti-fouling agent 8g/L in vain, detergent 10g/L, the green KE-4B of dye activity is 1g/L, carries out under 85 ℃ 10 minutes.The clean oven dry of cold water again after soaping and dyeing.
Effect: because cloth cover coloured light difference everywhere after the Freehandhand-drawing, after dying on steaming is washed again, though the dyestuff that adds is a kind of pure color light, because the difference of background color and can piecing together dyes now various coloured light when being different from Freehandhand-drawing, greatly enriched the color of cloth cover, made its level abundanter.