CN107287934A - A kind of processing technology of the soft anti-denim that fades - Google Patents

A kind of processing technology of the soft anti-denim that fades Download PDF

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Publication number
CN107287934A
CN107287934A CN201710486971.5A CN201710486971A CN107287934A CN 107287934 A CN107287934 A CN 107287934A CN 201710486971 A CN201710486971 A CN 201710486971A CN 107287934 A CN107287934 A CN 107287934A
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denim
processing technology
dyeing
fades
soft anti
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黄崇军
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Ningbo City Haishu District Ivanka Agricultural Science And Technology Co Ltd
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Ningbo City Haishu District Ivanka Agricultural Science And Technology Co Ltd
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    • D06P1/673Inorganic compounds
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    • D06M2200/50Modified hand or grip properties; Softening compositions

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Abstract

The invention discloses a kind of processing technology of the soft anti-denim that fades, concretely comprise the following steps:Denim base fabric is put into laccase solution and handled, go out enzyme, is cleaned, drying;Base fabric after ferment treatment is put into dye liquor and impregnated, rinses, dries;Denim after dyeing is put into soap boiling in the soap boiling liquid containing soap powder and natrium carbonicum calcinatum;It is then placed in softener solution and arranges;Sizing.Have the beneficial effect that:The lignin in base fabric is can remove using laccase in the processing technology of the present invention, dyeing ability is improved, will not polluted water resources after exclusion;Dye liquor can be evenly distributed on yarn ectonexine in dyeing course, and acyclic dye phenomenon, the extension of dye liquor is big, and dyed fabric dye-uptake is high, even dyeing;Soap boiling can change distribution situation of the dyestuff on denim, can remove part loose colour, increase the brightness of denim, improve the phenomenon that fades of denim.

Description

A kind of processing technology of the soft anti-denim that fades
Technical field
The present invention relates to garment material field, more particularly to a kind of processing technology of the soft anti-denim that fades.
Background technology
Cowboy be in addition to Western-style clothes unique prevalence a century do not wane and without it is seasonal, may span across national and race, sex Dress ornament category.Classical denim or traditional denim, refer to make warp thread with the Quality Pure Cotton Yarn Production of indigo dyeing, true qualities cotton yarn makees weft yarn, Using the thick branch twill that once twill left to right tissue is interwoven on three.Jeans are because with wear-resisting, well-pressed, comfortable and easy to wear etc. Unique charm and it is flourishing long time.Indigo cowboy can show deep mixed tone after washing, from cowboy's seventies in last century Clothes come into vogue till now, and either on popular jeans or fashionable dress issue platform, cowboy is always the prevalence member of garment sector Element, with its fashionable whole world of elegant, comfortable, bold and unconstrained, random individual style.
The processes such as the process of denim is dyed, starching, weaving, desizing, Final finishing.And the production master of denim Warp thread is dyed using traditional bipseudoindoxyl dye, indigo dye and dyeing need to be in concentrated alkali solution, will be indigo with reducing agent After the leuco compound for being reduced into solubility, absorbed by fiber, it is oxidized again after dye to be attached into insoluble indigo color lake On fiber, so as to reach the purpose of dye.Indigo is a kind of ancient reducing dye, has the advantages that economic, environmental protection, extensively should Coloring for cellulose fibre.It has than other cottons dyestuff more excellent performance, and unique color and luster and function Property.Often occur that dye-uptake is low in actual dyeing course, the phenomenon such as uneven dyeing.Such case is contaminated on dye liquor after all Speed is too fast, penetrating power difference and not abundant etc. enough the coefficient result of each side factor of reduction.Therefore suitable dye is used Color auxiliary agent can play a part of slow dye to the upper dye of bipseudoindoxyl dye and move dye, can make to contaminate uniform on dyestuff.With dyeing and printing process The progress of technology and the exploitation of New-type adjuvant, the dyeing of cowboy's warp thread have deeper into development.People are constantly to dyestuff simultaneously Reduction technique be improved, and energetically find the reducing agent being more suitable for, the staining technique of indigo dyeing has increasingly tended to It is kind.
Prior art such as Authorization Notice No. is the B of CN 102704289 Chinese invention patent, discloses a kind of batik day The color-fixing method of right vegetable indigo dye, it is the method sloughed loose colour by oxidation and be combined using compound color fixing agent fixation To realize.First by with natural plants indigo dyeing and the fibre that dries in the alkaline solution of hydrogen peroxide and detergent, Digestion is after 10~30 minutes at 95~100 DEG C, and washing is dried, and hydrogen peroxide concentration used is 0.05~0.1%, detergent alkylate Sulfonic acid na concn is 0.1~0.3%, pH10~12, bath raio 1:20.Then again by the fibre after being handled with the de- loose colour of oxidation In the solution for the compounding color fixing agent being made up of animal glue and polyquaternium, the digestion after 10~30 minutes at a temperature of 60-70 DEG C, Clean and dry, animal gum concentration is 1~2% in body lotion, polyquaternium concentration is 1~3%.String obtained by the color fixing process Product keeps vegetable indigo fragrance, bright in colour, and friction is difficult to fade, formaldehydeless, environmental protection, but the color-fixing method is not suitable for The fixation of denim, can reduce the wearability of denim.
The content of the invention
There is soft, smooth, comfortable feel it is an object of the invention to provide one kind, even dyeing is difficult Color, colour fastness to rubbing is high, the processing technology of the anti-denim that fades of the softness for being improved the added value of denim.
The present invention is directed to the problem of being mentioned in above-mentioned technology, and the technical scheme taken is:A kind of soft anti-denim that fades Processing technology, including biology enzyme pre-treatment, dye liquor preparation, dyeing, soap boiling, soft finish, sizing are concretely comprised the following steps:
Biology enzyme pre-treatment:Denim base fabric is put into the laccase solution that concentration is 2-3g/L, regulation pH value is to 4-6, in temperature Spend 55-65 DEG C, bath raio 1:60-70min is handled under conditions of 10-12, pH value is adjusted>9.5, inactivation processing 8-12min, warm water is washed Only, dry, it is standby, lignin is contained in cowboy's measuring fiber, lignin can hinder dye molecule into the inside of fiber so that fine The dyeing ability of dimension is bad, and the laccase in the step can remove the lignin in base fabric, improves dyeing ability, and enzyme washes raffinate In containing the nutriment needed for aquatic animal, plantses, after exclusion will not polluted water resources, so as to conservation of nature environment;
Dye liquor is prepared:Take parts by weight 0.1-0.2 parts of 0.7-0.8 parts of 6-7 parts of caustic soda, bleeding agent, active peptides, it is indigo 4-5 parts, 5-6 parts of sodium hydrosulfite, 80-85 parts of water, is stirred, and dye liquor is reduced into 60-70min, the amino acid of active peptides at 50-55 DEG C Sequence is HSHCFCCGAAKCYLCRVLHPGKLCVCNCSK, can change the osmotic pressure of face liber, opens fibrous inside and leads to Road, makes distribution of the dye liquor on denim and combines the penetrating power for evenly improving indigo dye liquor, improves dye-uptake, resistance to Crock fastness and dyestuff yarn cross-section EDS maps uniformity, it is and environmentally safe;
Dyeing:Base fabric after cellulase treatment is put into dye liquor, is 1 in bath raio:25-30, temperature are dipping at 50-55 DEG C 10-15min, is then dried with padding machine, and then pick-up control thoroughly rushed after oxidation 70-75s with water in atmosphere in 75-80% Wash, dry naturally, standby, yarn ectonexine dye distribution is substantially uniform in the dyeing course, acyclic dye phenomenon, the diffusion of dye liquor Power is big, and dyed fabric dye-uptake is high, even dyeing;
Soap boiling:Denim after dyeing is put into the soap boiling liquid containing soap powder 0.8-1.2g/L and natrium carbonicum calcinatum 2-2.5g/L In, bath raio is 1:25-30, in soap boiling 10-15min at 95-100 DEG C, dries, standby, soap after taking-up clear water cleaning down The distribution situation that can change dyestuff on denim is boiled, part loose colour can be removed, increases the brightness of denim, improves denim Fade phenomenon;
Soft finish:Denim after soap boiling is placed with 15-30min in the cylinder of softening agent, the ratio of softening agent and water is 1:80- 100, softening agent be ester based quaternary ammonium salt softening agent, fatty acid ester type softening agent, right wax pattern softening agent or polyethylene softening agent, In process, feel can become coarse after jean warp is repeatedly handled, in order that fabric has soft, smooth, comfortable hand Sense, it is necessary to it is arranged with softening agent;
Sizing:By the denim feeding shaping baking oven sizing after soft finish, setting temperature is 150-200 DEG C, until moisture content To be taken out after 3-5%, cooling, cropping produce the soft anti-denim that fades, and the cowboy has soft, smooth, comfortable feel, contaminated Color is uniform, is difficult to fade, and colour fastness to rubbing is high, is improved the added value of denim.
Compared with prior art, the advantage of the invention is that:1)The denim fabric of the present invention has soft, smooth, comfortable Feel, even dyeing is difficult to fade, and colour fastness to rubbing is high, is improved the added value of denim;2)Present invention process Middle utilization laccase can remove the lignin in base fabric, improve dyeing ability, and enzyme is washed in raffinate containing needed for aquatic animal, plantses Nutriment, after exclusion will not polluted water resources, so as to conservation of nature environment;3)Dye liquor in present invention process is in dyeing During can be evenly distributed on yarn ectonexine, acyclic dye phenomenon, the extension of dye liquor is big, and dyed fabric dye-uptake is high, dyeing Uniformly;4)Soap boiling in present invention process can change distribution situation of the dyestuff on denim, can remove part loose colour, increase ox The brightness of young cloth, improves the phenomenon that fades of denim.
Embodiment
The present invention program is described further below by embodiment:
Embodiment 1:
A kind of processing technology of the soft anti-denim that fades, including biology enzyme pre-treatment, dye liquor preparations, dyeing, soap boiling, softness are whole Reason, sizing, are concretely comprised the following steps:
Biology enzyme pre-treatment:Denim base fabric is put into the laccase solution that concentration is 2.1g/L, regulation pH value is to 5, in temperature 60 DEG C, bath raio 1:70min is handled under conditions of 11, pH value is adjusted>9.5, inactivation processing 10min, warm water cleaning, drying is standby, Contain lignin in cowboy's measuring fiber, lignin can hinder dye molecule into the inside of fiber so that the dyeing ability of fiber Bad, the laccase in the step can remove the lignin in base fabric, improve dyeing ability, and enzyme is washed in raffinate containing aquatic Nutriment needed for animal and plant, after exclusion will not polluted water resources, so as to conservation of nature environment;
Dye liquor is prepared:Take 0.14 part of 0.7 part of 6.5 parts of caustic soda, bleeding agent, active peptides, indigo 5 parts, the sodium hydrosulfite 5.5 of parts by weight Part, 80 parts of water stirs, and dye liquor is reduced into 65min at 50 DEG C, the amino acid sequence of active peptides is HSHCFCCGAAKCYLCRVLHPGKLCVCNCSK, can change the osmotic pressure of face liber, open fibrous inside passage, make dye Distribution and combination of the liquid on denim evenly, improve the penetrating power of indigo dye liquor, improve dye-uptake, fastness to rubbing With dyestuff yarn cross-section EDS maps uniformity, it is and environmentally safe;
Dyeing:Base fabric after cellulase treatment is put into dye liquor, is 1 in bath raio:30th, temperature is impregnates 12min at 50 DEG C, so Dried afterwards with padding machine, then pick-up control used water cleaning down after oxidation 70s in atmosphere, dried naturally 78%, standby, Yarn ectonexine dye distribution is substantially uniform in the dyeing course, acyclic dye phenomenon, and the extension of dye liquor is big, is contaminated on dyed fabric Rate is high, even dyeing;
Soap boiling:Denim after dyeing is put into the soap boiling liquid containing soap powder 1g/L and natrium carbonicum calcinatum 2.2g/L, bath raio is 1:30, in soap boiling 12min at 95-100 DEG C, dried after taking-up clear water cleaning down, standby, soap boiling can change dyestuff in ox Distribution situation on young cloth, can remove part loose colour, increase the brightness of denim, improve the phenomenon that fades of denim;
Soft finish:Denim after soap boiling is placed with 20min in the cylinder of softening agent, the ratio of softening agent and water is 1:80- 100, softening agent be ester based quaternary ammonium salt softening agent, fatty acid ester type softening agent, right wax pattern softening agent or polyethylene softening agent, In process, feel can become coarse after jean warp is repeatedly handled, in order that fabric has soft, smooth, comfortable hand Sense, it is necessary to it is arranged with softening agent;
Sizing:By the denim feeding shaping baking oven sizing after soft finish, setting temperature is 180 DEG C, until moisture content is 5% After take out, cooling, cropping produce the soft anti-denim that fades, and the cowboy has soft, smooth, comfortable feel, and dyeing is equal It is even, it is difficult to fade, colour fastness to rubbing is high, is improved the added value of denim.
Embodiment 2:
A kind of processing technology of the soft anti-denim that fades, is concretely comprised the following steps:
1)Denim base fabric is put into the laccase solution that concentration is 3g/L, regulation pH value is to 4.8, in temperature 60 C, bath raio 1: 65min is handled under conditions of 12, pH value is adjusted>9.5, inactivation processing 11min, warm water cleaning, drying, standby, cowboy's measuring fiber In contain lignin, lignin can hinder dye molecule to enter the inside of fiber so that the dyeing ability of fiber is bad, the step In laccase can remove the lignin in base fabric, improve dyeing ability, and enzyme is washed in raffinate containing needed for aquatic animal, plantses Nutriment, after exclusion will not polluted water resources, so as to conservation of nature environment;
2)Take 0.15 part of 0.72 part of 7 parts of caustic soda, bleeding agent, active peptides, indigo 4.3 parts, 5.8 parts of the sodium hydrosulfite, water of parts by weight 85 parts, stir, dye liquor is reduced into 68min at 52 DEG C, the amino acid sequence of active peptides is HSHCFCCGAAKCYLCRVLHPGKLCVCNCSK, can change the osmotic pressure of face liber, open fibrous inside passage, make dye Distribution and combination of the liquid on denim evenly, improve the penetrating power of indigo dye liquor, improve dye-uptake, fastness to rubbing With dyestuff yarn cross-section EDS maps uniformity, it is and environmentally safe;
3)Base fabric after cellulase treatment is put into dye liquor, is 1 in bath raio:26th, temperature is impregnates 15min at 52 DEG C, then Dried with padding machine, then pick-up control used water cleaning down after oxidation 70s in atmosphere, dried naturally 78%, standby, should Yarn ectonexine dye distribution is substantially uniform in dyeing course, acyclic dye phenomenon, and the extension of dye liquor is big, dyed fabric dye-uptake High, even dyeing;
4)Denim after dyeing is put into the soap boiling liquid containing soap powder 1g/L and natrium carbonicum calcinatum 2g/L, bath raio is 1:28, In soap boiling 10min at 100 DEG C, dried after taking-up clear water cleaning down, standby, soap boiling can change dyestuff on denim Distribution situation, can remove part loose colour, increase the brightness of denim, improve the phenomenon that fades of denim;
5)Denim after soap boiling is placed with 18min in the cylinder of softening agent, the ratio of softening agent and water is 1:100, softening agent is Ester based quaternary ammonium salt softening agent, fatty acid ester type softening agent, right wax pattern softening agent or polyethylene softening agent, in process, Feel can become coarse after jean warp is repeatedly handled, in order that fabric has soft, smooth, comfortable feel, it is necessary to right With softening agent, it is arranged;
6)By the denim feeding shaping baking oven sizing after soft finish, setting temperature is 180 DEG C, is taken after moisture content is % Go out, cooling, cropping, produce the soft anti-denim that fades, the cowboy has a soft, smooth, comfortable feel, even dyeing, no Easily fade, colour fastness to rubbing is high, is improved the added value of denim.
Embodiment 3:
A kind of processing technology of the soft anti-denim that fades, is concretely comprised the following steps:Denim base fabric is put into the paint that concentration is 3g/L In enzyme solutions, regulation pH value is to 5.5, in 65 DEG C of temperature, bath raio 1:60min is handled under conditions of 12, go out enzyme;Take the burning of parts by weight 7 parts of alkali, 0.8 part of bleeding agent, 0.15 part of active peptides, indigo 5 parts, 5.5 parts of sodium hydrosulfite, 85 parts of water stir, at 52 DEG C 70min is reduced, dye liquor is produced;Base fabric after cellulase treatment is put into dye liquor, is 1 in bath raio:28th, temperature is at 525 DEG C 15min is impregnated, is then dried with padding machine, then water cleaning down is used after oxidation 70s in atmosphere, dries naturally, it is standby;Will dye Denim after color is put into the soap boiling liquid containing soap powder 1.2g/L and natrium carbonicum calcinatum 2.2g/L, and bath raio is 1:30, at 98 DEG C Under dried after soap boiling 10min, taking-up clear water cleaning down;Denim after soap boiling is placed with 18min in the cylinder of softening agent, The ratio of softening agent and water is 1:90;By the denim feeding shaping baking oven sizing after soft finish, setting temperature is 170 DEG C, Until moisture content is taking-up after 4%, cooling, cropping produce the soft anti-denim that fades, the cowboy has soft, smooth, comfortable Feel, even dyeing is difficult to fade, and colour fastness to rubbing is high, is improved the added value of denim.
Routine operation in the operating procedure of the present invention is well known to those skilled in the art, herein without repeating.
Technical scheme is described in detail embodiment described above, it should be understood that it is described above only For the specific embodiment of the present invention, it is not intended to limit the invention, all any modifications made in the spirit of the present invention, Supplement or similar fashion replacement etc., should be included in the scope of the protection.
SEQUENCE LISTING
<110>Ningbo City Haishu District Yi Wanka agricultural science and technologys Co., Ltd
<120>A kind of processing technology of the soft anti-denim that fades
<130> 1
<160> 1
<170> PatentIn version 3.5
<210> 1
<211> 30
<212> PRT
<213>It is artificial synthesized
<400> 1
His Ser His Cys Phe Cys Cys Gly Ala Ala Lys Cys Tyr Leu Cys Arg
1 5 10 15
Val Leu His Pro Gly Lys Leu Cys Val Cys Asn Cys Ser Lys
20 25 30

Claims (10)

1. a kind of processing technology of the soft anti-denim that fades, including biology enzyme pre-treatment, dye liquor preparation, dyeing, soap boiling, softness Arrange, shape, it is characterised in that:The composition and its parts by weight of dye liquor are during described dye liquor is prepared:6-7 parts of caustic soda, bleeding agent 0.7-0.8 parts, 0.1-0.2 parts of active peptides, indigo 4-5 parts, 5-6 parts of sodium hydrosulfite, 80-85 parts of water.
2. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described dye liquor The amino acid sequence of active peptides is HSHCFCCGAAKCYLCRVLHPGKLCVCNCSK in preparation.
3. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described dye liquor In preparation 60-70min is reduced at 50-55 DEG C.
4. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described biology The pH value that enzyme washes middle enzyme solutions is 6-6.5, and enzyme washes temperature for 75-80 DEG C, and the time is 60-80min.
5. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described biology Enzyme pre-treatment is:Denim base fabric is put into the laccase solution that concentration is 2-3g/L, regulation pH value is to 4-6, in temperature 55-65 DEG C, bath raio 1:60-70min is handled under conditions of 10-12, go out enzyme.
6. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described dyeing Middle bath raio is 1:25-30, dipping temperature is 50-55 DEG C, and the time is 10-15min.
7. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described dyeing Middle pick-up is 75-80%, aoxidizes 70-75s in air.
8. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described soap boiling For:Denim after dyeing is put into the soap boiling liquid containing soap powder 0.8-1.2g/L and natrium carbonicum calcinatum 2-2.5g/L, bath raio For 1:25-30, in soap boiling 10-15min at 95~100 DEG C.
9. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described softness Arrange and be:Denim after soap boiling is placed with 15-30min in the cylinder of softening agent, the ratio of softening agent and water is 1:80-100.
10. a kind of processing technology of soft anti-denim that fades according to claim 1, it is characterised in that:Described determines Setting temperature is 150-200 DEG C in type, and sizing to moisture content is 3-5%.
CN201710486971.5A 2017-06-23 2017-06-23 A kind of processing technology of the soft anti-denim that fades Withdrawn CN107287934A (en)

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Application publication date: 20171024