CN102080295A - Cotton-diacetate cellulose fiber jacquard fabric and processing method thereof - Google Patents

Cotton-diacetate cellulose fiber jacquard fabric and processing method thereof Download PDF

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CN102080295A
CN102080295A CN201110026113.5A CN201110026113A CN102080295A CN 102080295 A CN102080295 A CN 102080295A CN 201110026113 A CN201110026113 A CN 201110026113A CN 102080295 A CN102080295 A CN 102080295A
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dyeing
cellulose fiber
dye liquor
fabric
cotton
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CN102080295B (en
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陈红霞
王石磊
丁可敬
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Jiangsu Goldsun Textile Science and Technology Co Ltd
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GOLDSUN HOLDING GROUP CO Ltd
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Abstract

The invention discloses a cotton-diacetate cellulose fiber jacquard fabric and a processing method thereof. Cotton yarns used as warp yarns and diacetate cellulose fiber filaments used as weft yarns are woven according to a jacquard texture process to obtain a gray fabric; after the gray fabric is preprocessed, the gray fabric is dyed with a dispersive/active two-bath method; finally, the gray fabric is subjected to fabric finishing process to obtain a flexible dyed splendor fabric. Because the structural formula of the diacetate cellulose fiber filaments contains an amido bond, the diacetate cellulose fiber filaments can be dyed by adopting a low-temperature dispersed dyeing method and cotton yarns are dyed with active dye to finish the dyeing of the whole batch of fabrics so as to obtain the fabric with flexible hand feeling, bright color and the color fastness reaching more than four grades. Meanwhile, the strong and smooth hand feeling and soft gloss of diacetate fibers are not influenced by dyeing.

Description

Cotton-diacetate fibre cellulose fiber jacquard fabric and processing method thereof
Technical field
The present invention relates to a kind of cotton-diacetate fibre cellulose fiber lining and processing method thereof that is used for the bed necessaries lining, belong to household textiles lining field.
Background technology
Tradition bed necessaries lining is generally based on native cellulose fibre or regenerated celulose fibre, because of the cellulose family lining possesses good hygroscopicity and skin-friendly, as cotton, viscose glue, day silk and as the functional fiber lining of carrier, do bed necessaries and paste skin and use, very popular.
For making the bed necessaries fabric color rich and varied, adopt the bed necessaries lining of pure cellulose fiber weaving generally to realize, and will obtain the jacquard fabric of extraordinary splendor effect by printing and dyeing, then must knit and could realize by look, promptly first yarn dyeing is weaved cotton cloth and just can be obtained the extraordinary splendor jacquard fabric.The mode of production of extraordinary splendor jacquard fabric, determined its not only the production cycle long, delivery date is slow, change color is dumb, the more important thing is in yarn stage dyeing increases cost and energy consumption, with contemporary people energy-conservation pursuit is misfitted.
The diacetate fibre cellulose fiber is a kind of cellulose derivative of semisynthetic fibre, has the excellent specific property of the soft and synthetic fiber of natural fabric concurrently, has soft silk quality gloss simultaneously.Application in the bed necessaries field at present is in space state; one of reason is the powerful non-constant of diacetate fibre cellulose fiber; on the wide cut loom, weave and have any problem; former two is that diacetate fibre cellulose fiber alkali resistance is poor therefore; after interweaving with other celluloses; occur acetylation easily in back arrangement process, then the dyeability of diacetate fibre cellulose fiber changes, and loses original sub dued lustre simultaneously.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of cotton-diacetate fibre cellulose fiber jacquard fabric and processing method thereof is provided, its adopt cotton yarn as warp thread, diacetate fibre cellulose fiber long filament as weft yarn, according to figured texture weave technology weave obtain grey cloth after, after grey cloth was processed through pre-treatment, the dispersion/active two bath methods of employing were carried out dyeing and finishing and are got final product.Therefore, the present invention is because the structural formula of diacetate fibre cellulose fiber long filament contains amido link, dyes on can be to DISPERSE DYES under certain process conditions and REACTIVE DYES is dyed on not, thereby dyeing extraordinary splendor effect occurs.
For realizing above technical purpose, the present invention will take following technical scheme:
A kind of cotton-diacetate fibre cellulose fiber jacquard fabric, the warp thread of described jacquard fabric are adopted cotton yarn, weft yarn to adopt diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology and form.
Another technical purpose of the present invention provides the processing method of a kind of cotton-diacetate fibre cellulose fiber jacquard fabric, may further comprise the steps: (1) grey cloth is weaved warp thread and is adopted cotton yarn, weft yarn to adopt diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology; (2) the grey cloth pre-treatment with the woven grey cloth of step (1) institute successively through singing, destarch, refining, bleaching and washing process to be to carry out pre-treatment processing; (3) dyeing and finishing adopts dispersion/REACTIVE DYES two-bath dyeing method that the grey cloth through the described pre-treatment processing of step (2) is carried out dyeing and finishing, described dispersion/REACTIVE DYES two-bath dyeing method may further comprise the steps: advance cloth → disperse dyeing → discharge opeing → reduction cleaning → reactive dyeing → soap → hot water wash → cold wash → drying, described disperse dyeing process: at room temperature advance cloth, then regulate the pH value to 6.5-9.5, and adding dispersant, make that dispersant concentration is 1-1.3g/L in the dye liquor, then the heating rate with 1.5 ℃/min is warming up to 70 ℃ with dye liquor, add DISPERSE DYES, then the heating rate with 1 ℃/min is warming up to 85 ℃ with dye liquor, discharge opeing behind the insulation dyeing 60min; Described reduction cleaning technology: will be dipped in concentration through the cloth after the disperse dyeing and be in the HY01 reduction cleaning liquid of 1.5g/L, handle 20min under 80 ℃ condition, the pH value of this HY01 reduction cleaning liquid is 6.5-7.5; Described reactive dyeing technology: in initial dye liquor, add REACTIVE DYES under the room temperature, in dye liquor, add glauber salt behind the dyeing 5min, make that the concentration of glauber salt is 30g/L, speed with 1 ℃/min behind the 10min is warming up to 60 ℃ with dye liquor, in dye liquor, add glauber salt and soda ash once more, make that the concentration of soda ash is 8g/L in the dye liquor, add soda ash behind the 30min once more, the 30min that then dyes gets final product; (4) cloth of fabric post-treatment after with the dyeing and finishing concentration that places the amino silicone softener HS-01 of nonionic to form is that the dressing liquid of 15g/L floods 2min, and the pH value of dressing liquid is 6.5-9.5; Cross roll afterwards, make the cloth liquid carrying rate maintain 70%, 80 ℃ of oven dry down, bake 2min at 100 ℃ at last and get final product then.
In the described step (3), when carrying out reactive dyeing technology, glauber salt and soda ash twice is added to equivalent to be added.
According to above technical scheme, can realize following beneficial effect:
1, the present invention adopts cotton yarn and diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology and forms jacquard fabric, because the structural formula of diacetate fibre cellulose fiber long filament contains amido link, therefore, can adopt low temperature dispersion dyeing method that it is dyeed, then adopt REACTIVE DYES that cotton yarn is dyeed again, can finish the dyeing and finishing of whole cloth, soft to obtain, bright in colour, color fastness can reach the lining more than the level Four.Simultaneously, the brute force of diacetate fibre, smooth feel and soft gloss all are not subjected to the dyeing influence.In addition, DISPERSE DYES is 0 for the dye-uptake of cotton yarn, and it is to the colouring of diacetate fibre cellulose fiber long filament, and dye-uptake is at 90%-99%; And REACTIVE DYES is 0 for the dye-uptake of diacetate fibre cellulose fiber long filament, and only to the cotton yarn colouring, dye-uptake is at 60-70%, so the extraordinary splendor effect of requirement can appear in dyeing and finishing technology of the present invention.
2, warp thread of the present invention is that cotton yarn, weft yarn are diacetate fibre cellulose fiber long filament, because diacetate fibre cellulose fiber long filament gloss is better, therefore, for through the face satin weave, diacetate fibre cellulose fiber long filament uses as weft yarn and is designed to through the face satin, can make diacetate fibre cellulose fiber long filament float over fabric face, thereby obtain gloss preferably; In addition, the brute force of cotton yarn is better than diacetate fibre cellulose fiber long filament, so weaving efficiency is than higher.
The specific embodiment
Below with reference to embodiment, explain technical scheme of the present invention.
The processing method of cotton of the present invention-diacetate fibre cellulose fiber jacquard fabric may further comprise the steps: (1) grey cloth is weaved warp thread and is adopted cotton yarn, weft yarn to adopt diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology; (2) the grey cloth pre-treatment with the woven grey cloth of step (1) institute successively through singing, destarch, refining, bleaching and washing process to be to carry out pre-treatment processing; (3) dyeing and finishing adopts dispersion/REACTIVE DYES two-bath dyeing method that the grey cloth through the described pre-treatment processing of step (2) is carried out dyeing and finishing, described dispersion/REACTIVE DYES two-bath dyeing method may further comprise the steps: advance cloth → disperse dyeing → discharge opeing → reduction cleaning → reactive dyeing → soap → hot water wash → cold wash → drying, described disperse dyeing process: at room temperature advance cloth, then regulate the pH value to 6.5-9.5, and adding dispersant, make that dispersant concentration is 1-1.3g/L in the dye liquor, then the heating rate with 1.5 ℃/min is warming up to 70 ℃ with dye liquor, add DISPERSE DYES, then the heating rate with 1 ℃/min is warming up to 85 ℃ with dye liquor, discharge opeing behind the insulation dyeing 60min; Described reduction cleaning technology: will be dipped in concentration through the cloth after the disperse dyeing and be in the HY01 reduction cleaning liquid of 1.5g/L, handle 20min under 80 ℃ condition, the pH value of this HY01 reduction cleaning liquid is 6.5-7.5; Described reactive dyeing technology: in initial dye liquor, add REACTIVE DYES under the room temperature, in dye liquor, add glauber salt behind the dyeing 5min, make that the concentration of glauber salt is 30g/L, speed with 1 ℃/min behind the 10min is warming up to 60 ℃ with dye liquor, in dye liquor, add glauber salt and soda ash once more, make that the concentration of soda ash is 8g/L in the dye liquor, add soda ash behind the 30min once more, the 30min that then dyes gets final product; (4) cloth of fabric post-treatment after with the dyeing and finishing concentration that places the amino silicone softener HS-01 of nonionic to form is that the dressing liquid of 15g/L floods 2min, and the pH value of dressing liquid is 6.5-9.5; Cross roll afterwards, make the cloth liquid carrying rate maintain 70%, 80 ℃ of oven dry down, bake 2min at 100 ℃ at last and get final product then.In addition, in the described step (3), when carrying out reactive dyeing technology, glauber salt and soda ash twice is added to equivalent to be added.
Embodiment 1
The door width of cloth: 108 inches cotton 60S * Acetate 120D 32f/173 * 130; Formation is knitted effect through the light blue filling satin look of shallow coffee latitude;
The cotton yarn that cotton fiber is spun into as warp thread with as the diacetate fibre cellulose fiber long filament of weft yarn according to the jacquard weave interleaving mode knit cottonly-diacetate fibre cellulose fiber jacquard fabric grey cloth after, carry out pre-treatment: singe → destarch → refining → bleaching → washing.Described singeing: gas singeing, 2 positive 2 is anti-; Described desizing: Suhong Desizyme 2000L 1.0g/L, nonionic penetrant 0.5g/L, dipping 3 roads under the calcium ion concentration 30ppm, 80 ℃, the condition of pH value 6.5-7.0, per pass is cultivated 20min, after washing; Described boiling and bleaching process: refining agent 25g/L, 30% hydrogen peroxide 5g/L, ammoniacal liquor 10g/L, sodium metasilicate 2g/L, detergent-7960 3g/L, under the condition about 85 ℃, impregnation process 60min, after washing.
The dyeing processing formula
DISPERSE DYES disperse dyes Y:2.5 o.w.f; DISPERSE DYES R:1 o.w.f.; DISPERSE DYES B:0.7 o.w.f;
The grand yellow FN-2R REACTIVE DYES of REACTIVE DYES prescription vapour Bark: 13 o.w.f; The vapour Bark swells bright red LS-2G REACTIVE DYES: 4 o.w.f; The vapour Bark swells blue LS-3R REACTIVE DYES: 0 o.w.f; The vapour Bark swells orange FN-R REACTIVE DYES: 9 o.w.f.
The dyeing work flow: 30 ℃ are advanced cloth → disperse dyeing → discharge opeing → reduction cleaning → reactive dyeing → soap → hot water wash → cold wash → drying.
Described disperse dyeing process: in 30 ℃ initial dye liquor, add acetic acid or ammoniacal liquor and regulate the pH value to neutral alkalescence partially, be generally about pH8, and adding dispersant, make that dispersant concentration is 1g/L in the dye liquor, then the heating rate with 1.5 ℃/min is warming up to 70 ℃ with dye liquor, add DISPERSE DYES, then the heating rate with 1 ℃/min is warming up to 85 ℃ with dye liquor, discharge opeing behind the insulation dyeing 60min; Described reduction cleaning technology: will be dipped in concentration through the cloth after the disperse dyeing is in the HY01 reduction cleaning liquid of 1.5g/L, handles 20min 80 ℃ of insulations, and the pH value of this HY01 reduction cleaning liquid adopts acetic acid or ammoniacal liquor to be adjusted to 6.5-7.5; Described reactive dyeing technology: in 30 ℃ initial dye liquor, add REACTIVE DYES, glauber salt and soda ash are divided into 2 parts respectively, in dye liquor, add a copy of it glauber salt behind the dyeing 5min, make that the concentration of glauber salt is 30g/L in the dye liquor, speed with 1 ℃/min behind the 10min is warming up to 60 ℃ with dye liquor, in dye liquor, add remaining a glauber salt and a copy of it soda ash once more, make that the concentration of soda ash is 8g/L in the dye liquor, add remaining another part soda ash behind the 30min once more, the 30min that then dyes gets final product.
Soap: soap flakes 2g/L, handle 15min under 90 ℃ of conditions; Fully washing afterwards.
Its technological process of fabric post-treatment technology is: flood → roll surplus → dry → bake
Particular content is: the concentration that places the amino silicone softener HS-01 of nonionic to form the cloth after the dyeing and finishing is that the dressing liquid of 15g/L floods 2min, and the pH value of dressing liquid is adjusted to neutral inclined to one side alkalescence by acetic acid or ammoniacal liquor; Cross roll afterwards, make the cloth liquid carrying rate maintain 70%, 80 ℃ of oven dry down, bake 2min at 100 ℃ at last and get final product then.
In the finished product lining, weft yarn forms the satin weave gloss of pale blue, and it is better to compare the interweave imitative staple fabric sheen that forms of cotton and viscose filament yarn, and the sense of dangling is also fine, therefore apparent class; It is more soft to compare the interweave imitative staple fabric feeling of formation of cotton and polyester filament, and diacetate fibre cellulose fiber long filament moisture absorption gas hydrofuge performance is better, thereby comfort is better.
Embodiment 2
The door width of cloth: 118 inches cotton 80S * Acetate 75D 32f/173 * 186; Formation is knitted effect through the pale yellow filling satin look of pink latitude;
The yarn that cotton spinning is become as warp thread with as the diacetate fibre cellulose fiber of weft yarn according to the jacquard weave interleaving mode knit cottonly-diacetate fibre cellulose fiber jacquard fabric grey cloth after, carry out pre-treatment: singe → destarch → refining → bleaching → washing.Described singeing: gas singeing, 2 positive 2 is anti-; Described desizing: Suhong Desizyme 2000L 1.0g/L, nonionic penetrant 0.5g/L, dipping 3 roads under the calcium ion concentration 30ppm, 80 ℃, the condition of pH value 7.0-9.5, per pass is cultivated 23min, after washing; Described boiling and bleaching process: refining agent 25g/L, 30% hydrogen peroxide 5g/L, ammoniacal liquor 10g/L, sodium metasilicate 2g/L, detergent-7960 3g/L, under 90 ℃ of left and right sides conditions, impregnation process 60min after washing.
The dyeing processing formula
DISPERSE DYES disperse dyes Y:0 o.w.f DISPERSE DYES R:0.5 o.w.f. DISPERSE DYES B:0.1 o.w.f;
The grand yellow FN-2R REACTIVE DYES of REACTIVE DYES prescription vapour Bark: 1.35 o.w.f; The vapour Bark swells bright red LS-2G REACTIVE DYES: 0.09 o.w.f; The vapour Bark swells blue LS-3R REACTIVE DYES: 0 .135o.w.f; The vapour Bark swells orange FN-R REACTIVE DYES: 0 o.w.f.
The dyeing work flow: 30 ℃ are advanced cloth → disperse dyeing → discharge opeing → reduction cleaning → reactive dyeing → soap → hot water wash → cold wash → drying.Carrying out soft finish through fabric post-treatment technology at last gets final product.
Described disperse dyeing process: in 30 ℃ initial dye liquor, add acetic acid or ammoniacal liquor and regulate the pH value to neutral subacidity partially, be generally about pH6.5, and adding dispersant, make that dispersant concentration is 1.2g/L in the dye liquor, then the heating rate with 1.5 ℃/min is warming up to 70 ℃ with dye liquor, add DISPERSE DYES, then the heating rate with 1 ℃/min is warming up to 85 ℃ with dye liquor, discharge opeing behind the insulation dyeing 60min; Described reduction cleaning technology: will be dipped in concentration through the cloth after the disperse dyeing is in the HY01 reduction cleaning liquid of 1.5g/L, handles 20min 80 ℃ of insulations, and the pH value of this HY01 reduction cleaning liquid adopts acetic acid or ammoniacal liquor to be adjusted to 6.5-7.5; Described reactive dyeing technology: in 30 ℃ initial dye liquor, add REACTIVE DYES, glauber salt and soda ash are divided into 2 parts respectively, in dye liquor, add a copy of it glauber salt behind the dyeing 5min, make that the concentration of glauber salt is 30g/L in the dye liquor, speed with 1 ℃/min behind the 10min is warming up to 60 ℃ with dye liquor, in dye liquor, add remaining a glauber salt and a copy of it soda ash once more, make that the concentration of soda ash is 8g/L in the dye liquor, add remaining another part soda ash behind the 30min once more, the 30min that then dyes gets final product.
Soap: soap flakes 2g/L, handle 15min under 90 ℃ of conditions; Fully washing afterwards.
Its technological process of fabric post-treatment technology is: flood → roll surplus → dry → bake
Particular content is: the concentration that places the amino silicone softener HS-01 of nonionic to form the cloth after the dyeing and finishing is that the dressing liquid of 15g/L floods 2min, and the pH value of dressing liquid is adjusted to neutral inclined to one side subacidity by acetic acid or ammoniacal liquor; Cross roll afterwards, make the cloth liquid carrying rate maintain 70%, 80 ℃ of oven dry down, bake 2min at 100 ℃ at last and get final product then.
In the finished product lining, warp thread adopts 80S long-staple cotton, weft yarn 75D diacetate fibre cellulose fiber long filament, all thinner through weft yarn, form fine and smooth Fabric Style, compare with the lining that silk broadcloth interweaves, gloss, dangle and feel and comfort level all can match in excellence or beauty with cotton, and price is material benefit more, is accepted by the consumer easily.

Claims (3)

1. cotton-diacetate fibre cellulose fiber jacquard fabric is characterized in that, the warp thread of described jacquard fabric adopts cotton yarn, weft yarn to adopt diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology and forms.
2. the processing method of the described cotton of claim 1-diacetate fibre cellulose fiber jacquard fabric is characterized in that, may further comprise the steps:
(1) grey cloth is weaved warp thread employing cotton yarn, weft yarn adopts diacetate fibre cellulose fiber long filament to weave according to figured texture weave technology;
(2) the grey cloth pre-treatment with the woven grey cloth of step (1) institute successively through singing, destarch, refining, bleaching and washing process to be to carry out pre-treatment processing;
(3) dyeing and finishing adopts dispersion/REACTIVE DYES two-bath dyeing method that the grey cloth through the described pre-treatment processing of step (2) is carried out dyeing and finishing, described dispersion/REACTIVE DYES two-bath dyeing method may further comprise the steps: advance cloth → disperse dyeing → discharge opeing → reduction cleaning → reactive dyeing → soap → hot water wash → cold wash → drying, described disperse dyeing process: at room temperature advance cloth, then regulate the pH value to 6.5-9.5, and adding dispersant, make that dispersant concentration is 1-1.3g/L in the dye liquor, then the heating rate with 1.5 ℃/min is warming up to 70 ℃ with dye liquor, add DISPERSE DYES, then the heating rate with 1 ℃/min is warming up to 85 ℃ with dye liquor, discharge opeing behind the insulation dyeing 60min; Described reduction cleaning technology: will be dipped in concentration through the cloth after the disperse dyeing and be in the HY01 reduction cleaning liquid of 1.5g/L, handle 20min under 80 ℃ condition, the pH value of this HY01 reduction cleaning liquid is 6.5-7.5; Described reactive dyeing technology: in initial dye liquor, add REACTIVE DYES under the room temperature, in dye liquor, add glauber salt behind the dyeing 5min, make that the concentration of glauber salt is 30g/L, speed with 1 ℃/min behind the 10min is warming up to 60 ℃ with dye liquor, in dye liquor, add glauber salt and soda ash once more, make that the concentration of soda ash is 8g/L in the dye liquor, add soda ash behind the 30min once more, the 30min that then dyes gets final product;
(4) cloth of fabric post-treatment after with the dyeing and finishing concentration that places the amino silicone softener HS-01 of nonionic to form is that the dressing liquid of 15g/L floods 2min, and the pH value of dressing liquid is 6.5-9.5; Cross roll afterwards, make the cloth liquid carrying rate maintain 70%, 80 ℃ of oven dry down, bake 2min at 100 ℃ at last and get final product then.
3. according to the processing method of the described cotton of claim 2-diacetate fibre cellulose fiber jacquard fabric, it is characterized in that in the described step (3), when carrying out reactive dyeing technology, glauber salt and soda ash twice is added to equivalent to be added.
CN201110026113.5A 2011-01-25 2011-01-25 Cotton-diacetate cellulose fiber jacquard fabric and processing method thereof Active CN102080295B (en)

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