CN102418249B - Dyeing and finishing technology for cuprammonium-linen interwoven fabric and cuprammonium-linen interwoven fabric - Google Patents
Dyeing and finishing technology for cuprammonium-linen interwoven fabric and cuprammonium-linen interwoven fabric Download PDFInfo
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Abstract
The invention relates to a dyeing and finishing technology for a cuprammonium-linen interwoven fabric, which uses a gray cuprammonium-linen interwoven fabric as a raw material. The flow of dyeing and finishing technology is shown as the following: preshrinking-> scouring-> water washing-> enzyme water washing-> dyeing-> water washing-> drying through a setting machine-> adding softener-> setting through the setting machine-> sand washing-> steam setting. By interweaving linen fibers and cuprammonium fibers to obtain the cuprammonium-linen interwoven fabric and by dyeing and finishing the interwoven fabric, the cuprammonium-linen interwoven fabric has the advantages of the two kinds of fibers, the defects that a common linen fabric feels coarse, is apt to be wrinkled and the like are overcome and the fabric is highly comfortable. Beside, compared with a cuprammonium fabric, the cost of the cuprammonium-linen interwoven fabric provided by the invention is lower.
Description
Technical field
The invention belongs to the fabric field, particularly a kind of dyeing finishing technique of cuprammonium mixed-woven linen and cuprammonium flax interwoven fabric.
Background technology
At the society of uphold nature health, green living, environmental protection consumption have become people's life new concept, and people make great efforts to build the living environment of a health environment-friendly.Aspect garment material, natural string is subject to consumer's generally favor once again.As the natural environmental-protective fabric of generally acknowledging, flax is owing to it has moisture absorption, well-pressed, nice and cool, intensity advantages of higher enjoys favor, yet, spinnability and the wrinkle resistance of linen fibre are poor, and flax impurity is more, and the fabric background color is very dark behind the mercerising, and, common flax product feel is coarse, easily fold.
In addition, also the known copper ammonia fabric of being made by copper ammonia fibre is the more welcome fabric of another kind, copper ammonia fibre has meeting breathing, salubrious, antistatic, drapability good four large functions, its purposes is substantially the same with viscose, but the single fiber of copper ammonia fibre is thinner than viscose, the wearability of its product is splendid, and performance is similar to silk, has the sense of dangling.Add that it has preferably anlistatig function, even still have good sense of touch in the dress of the area of drying, can avoid producing sultry discomfort, this is to make it to become the always major reason of welcome underwear lining, and still is in so far irreplaceable status.Copper ammonia fibre is pushed fabric to from lining at present, becomes the best material of senior suit.It is soft as fabric, gloss is soft, meet environmental protection dress ornament trend, make senior textile so commonly use, be specially adapted to and wool, synthetic fiber blending or pure spinning, do high-grade knitted thing, as make knitting and woven underwear, lady's socks and silk weaving satin silk fabric women's dress shirt, wind coat, trousering, overcoat etc.
Summary of the invention
Technical problem to be solved by this invention provides a kind of dyeing finishing technique of cuprammonium mixed-woven linen, by this technique gained cuprammonium flax interwoven fabric, combine copper ammonia fabric and flax fabric advantage separately, overcome copper ammonia fabric and flax fabric deficiency separately, fabric is comfortable, gracefulness, and cost is lower.
The present invention also will provide a kind of novel cuprammonium flax interwoven fabric simultaneously, and it has had cuprammonium and flax advantage separately concurrently, and comfortable, gracefulness, and cost is lower,
For solving above technical problem, a kind of technical scheme that the present invention takes is:
A kind of dyeing finishing technique of cuprammonium mixed-woven linen, take the grey cloth of described cuprammonium mixed-woven linen as raw material, the flow process of this dyeing finishing technique is: softener → setting machine typing → sand washing → decatize typing is dried → gone up to preshrunk → concise → washing → ferment enzyme washing → dyeing → washing → setting machine, wherein:
Described preshrunk is soaked two in open width two and is rolled in the preshrinking machine and carry out, and the temperature of the first tank is controlled to be 68 ℃～72 ℃, and the temperature of the second tank is controlled to be 88 ℃～92 ℃;
Described refining is carried out in overflow dyeing machine, and the refining bath raio is controlled to be 1: 20～1: 22, the consisting of of refining solution: liquid caustic soda 34～36g/l, refining agent 0.8～1.2g/l, precious 1.3～1.7g/l and all the other be water in the bath, control 78 ℃～82 ℃ of refining temperatures, 100～125 minutes time;
Overflow jet dyeing machine is adopted in described dyeing; bath raio is controlled to be 1: 20～1: 23; consisting of of dyeing liquor: REACTIVE DYES 0.1～6%; glauber salt 45～80g/l, liquid caustic soda 0.6～1.0g/l, soda ash 4～8g/l; precious 1.2～1.8g/l and all the other be water in the bath; dyeing course is as follows: cloth and water are entered in the overflow jet dyeing machine, add in the bath of formula ratio preciously, keep 28 ℃～32 ℃ of temperature; turn 4～6 minutes; then be warming up to 38 ℃～42 ℃, add the REACTIVE DYES of formula ratio, turn 13～17 minutes after; add again the glauber salt of formula ratio; after turning 13～17 minutes, add the soda ash of formula ratio, turn 13～17 minutes after; add the liquid caustic soda of formula ratio; turn 32～37 minutes, finish dyeing, the discharge dyeing liquor;
Water-washing process after the described dyeing is: add entry in the overflow jet dyeing machine after finishing to dyeing, be warming up to 60 ℃～70 ℃, turn 5～15 minutes, draining adds the liquid of soaping again, be warming up to 80 ℃～90 ℃, turn 10～30 minutes, discharge the liquid of soaping, add again at last entry, under 60 ℃～70 ℃, clean, go out cloth;
The oven dry of described setting machine is carried out under 115 ℃～125 ℃ of temperature; The setting temperature of described setting machine typing is 125 ℃～135 ℃;
Described sand washing is carried out in the air-flow sand washer, and temperature is 70 ℃～80 ℃, and the time is 60～90 minutes;
The temperature of described decatize typing is 140 ℃～150 ℃.
Preferably, above-mentioned REACTIVE DYES is the L-type REACTIVE DYES of its chemical inc of Town in Shanghai promise.According to a concrete aspect, the consisting of of described dyeing liquor: REACTIVE DYES is L-HLF indigo plant 0.1%～0.14%; L-3R Huang 0.25%～0.3%; L-4B is red 0.07%～0.085%, glauber salt 45～55g/l; Liquid caustic soda 0.6～1.0g/l; Soda ash 4～6g/l, precious 1.2～1.8g/l and all the other are water in the bath, the color after the cuprammonium mixed-woven linen dyes is cream-coloured, preferably, dyeing liquor consist of L-HLF indigo plant 0.12%; L-3R Huang 0.26%; L-4B is red 0.079%, glauber salt 50g/l; Liquid caustic soda 0.8g/l; Soda ash 5g/l, precious 1.5g/l and all the other are water in the bath.
According to another concrete aspect, the consisting of of described dyeing liquor: L-3G dark blue 1.5%～2.0%; L-3R Huang 2.2%～2.5%; L-4B is red 0.8%～1.0%, glauber salt 60～80g/l; Liquid caustic soda 0.6～1.0g/l; Soda ash 6～8g/l, precious 1.2～1.8g/l and all the other be water in the bath, the color after the cuprammonium mixed-woven linen dyes is coffee color.Preferably, consisting of of dyeing liquor: L-3G dark blue 1.85%; L-3R Huang 2.47%; L-4B is red 0.96%, glauber salt 70g/l; Liquid caustic soda 0.8g/l; Soda ash 7g/l, precious 1.5g/l and all the other are water in the bath.
According to a preferred aspect of the present invention, the water-washing process after the described refining is: after refining finishes, discharge refining solution, add entry, be heated to 65 ℃～75 ℃, washed 15～25 minutes, draining adds water, be heated to 50 ℃～60 ℃, washed draining 10～15 minutes.The process of the ferment enzyme washing before the described dyeing is: in the overflow dyeing machine after the washing, add the ferment enzyme washing lotion, be heated to 45 ℃～55 ℃ lower washings 25～35 minutes, draining, add again clear water, be heated to 50 ℃～60 ℃, wash to draining pH be 7～8.The pH of preferred ferment enzyme washing lotion is 4～5, and by acetic acid 1.8～2.2g/l, ferment enzyme 1.3～1.7g/l and surplus are that water forms.
The another technical scheme that the present invention takes is: a kind of cuprammonium flax interwoven fabric, it obtains after being processed through above-mentioned dyeing finishing technique by the cuprammonium mixed-woven linen, and described cuprammonium flax grey cloth that interweaves is that copper ammonia fibre and parallel are that linen fibre is interwoven by warp.
Because the enforcement of above technical scheme, the present invention compared with prior art has following advantage:
The present invention interweaves linen fibre and copper ammonia fibre and obtains the cuprammonium mixed-woven linen, and to the arrangement of dyeing of this interwoven, gained cuprammonium flax fabric is except having two kinds of fibers advantage separately concurrently, overcome common flax fabric feel coarse, the deficiencies such as easy fold, fabric has high-comfort.In addition, compare with copper ammonia fabric, cuprammonium flax interwoven fabric cost of the present invention is lower.Consider the properties of gained cuprammonium flax interwoven fabric of the present invention, it is specially adapted to make the senior leisure overcoat of men and women scholar, casual pants etc.
The specific embodiment
The present invention will be further described in detail for following specific embodiment, but the invention is not restricted to following examples.
Embodiment 1
The present embodiment provides a kind of dyeing finishing technique of cuprammonium mixed-woven linen, and it comprises the steps:
(1), preshrunk
Preshrunk is soaked two in open width two and is rolled in the preshrinking machine and carry out, and the temperature of the first tank is controlled to be 70 ℃, and the temperature of the second tank is controlled to be 90 ℃, purpose be allow grey cloth in broadwise without evenly shrinking under the tension force, in order to avoid form vertical bar crape seal in the overflow dyeing machine the inside.
(2), refining
Refining is carried out in overflow dyeing machine, and the refining bath raio is controlled to be 1: 21, the consisting of of refining solution: liquid caustic soda 35g/l, and refining agent 1g/l, precious 1.5g/l and all the other are water in the bath, 80 ℃ of control refining temperatures are incubated 120 minutes.
(3), washing
After refining finishes, discharge refining solution, add entry, be heated to 70 ℃, washed 20 minutes, draining adds water, is heated to 60 ℃, washes draining 15 minutes.
(4), ferment enzyme washing
In the overflow dyeing machine after the washing, add the ferment enzyme washing lotion, be heated to 50 ℃, washed 30 minutes, draining adds clear water again, washed 15 minutes for 0 ℃, 50 degree washings 10 minutes keep pH value about 7, can dye, wherein, the pH of ferment enzyme washing lotion is 4.5, and by acetic acid 2g/l, ferment enzyme 1.5g/l and surplus are that water forms.
(5) dyeing
Overflow jet dyeing machine is adopted in dyeing; bath raio is controlled to be 1: 22; consisting of of dyeing liquor: L-HLF indigo plant 0.12%, L-3R Huang 0.26%, L-4B are red 0.079%, glauber salt 50g/l; liquid caustic soda 0.8g/l; soda ash 5g/l; precious 1.5g/l and all the other be water in the bath, the L-type REACTIVE DYES that wherein, L-HLF is blue, L-3R is yellow, the red three kinds of dyestuffs of L-4B are its chemical inc production of Town in Shanghai promise.This group dyestuff good level-dyeing property, cuprammonium and flax are painted to such an extent that plucked instrument evenly is difficult for the look flower with bathing, and dye-uptake is higher by 15%～20% than common REACTIVE DYES, and easy cleaning can reduce 5～6 tons of every cylinders of dyeing waste-water, is beneficial to energy-saving and emission-reduction.
Dyeing course is as follows: cloth and water entered in the overflow jet dyeing machine, and precious in the bath of adding formula ratio, keep 30 ℃ of temperature, turn 5 minutes, then be warming up to 40 ℃, add the REACTIVE DYES of formula ratio, after turning 15 minutes, add again the glauber salt of formula ratio, turn 15 minutes after, the soda ash that adds formula ratio, after turning 15 minutes, add the liquid caustic soda of formula ratio, turn 35 minutes, finish dyeing, discharge dyeing liquor.Cloth after the dyeing is cream-coloured.
(6) washing
Add entry in the overflow jet dyeing machine after finishing to dyeing, be warming up to 60 ℃, turn 10 minutes, draining adds the liquid of soaping again, is warming up to 85 ℃, turns 15 minutes, discharges the liquid of soaping, and adds at last entry again, cleans under 70 ℃, goes out cloth.
(7) arrangement after
Through the cloth of washing, after the centrifugal dehydrator dehydration, manual open-width (not using the scutcher open-width, to prevent the cloth cover rub).Through the setting machine oven dry, 120 ℃ of temperature, 40 m/mins of the speed of a motor vehicle are carried out super-soft processing at flat cylinder after the oven dry, softener 10g/l, 40 ℃ of * 5 roads, purpose is that the pliability of cloth cover is consistent, again through setting machine typing, 130 ℃ of temperature, 35 m/mins of the speed of a motor vehicle.Afterwards, cloth is sent into the air-flow sand washer, under the transmission guide wheel drove, cloth circulated in machine, and injected air-flow is patted.Whole process is controlled by computer, 60～90 minutes time, temperature 70 C～80 ℃, 400～600 m/mins of circulation cloth speed.The air-flow sand washing is to implement to reach one of important procedure of fabric style feature in published this method.Use device name: air-flow sand washing softening finishing machine or feel improvement machine.With the equipment best results that Italy produces, the sand washing temperature should not be too high, prevents the fabric flavescence.The final step arranging process is the decatize typing, and open-width is manual, prevents from damaging body, 50 m/mins of setting cloth speed, temperature 145, overfeeding 8～12%.Make that cloth cover is soft, unique style.
Embodiment 2
According to the dyeing finishing technique of the cuprammonium mixed-woven linen of the present embodiment, substantially with embodiment 1.No is, the consisting of of the dyeing liquor that adopts in the present embodiment: L-3G dark blue 1.85%; L-3R Huang 2.47%; L-4B is red 0.96%, glauber salt 70g/l; Liquid caustic soda 0.8g/l; Soda ash 7g/l, precious 1.5g/l and all the other are water in the bath.The color of last gained interwoven fabric is coffee-like.
Cuprammonium mixed-woven linen to embodiment 1 and embodiment 2 is checked, and test basis is GB/T16605-2008 " regenerated rayon filament fabric " and GB18401-2003 " National Fundamental Safety Technical Standard For Textiles " category-B, and the result is referring to table 1.The result shows, all items all meets the high-class product requirement of GB/T16605-2008 standard code, meets the category-B requirement of GB18401-2003 standard code.
The performance indications of table 1 cuprammonium mixed-woven linen
Above the present invention has been done detailed description; its purpose is to allow the personage that is familiar with this art can understand content of the present invention and is implemented; can not limit protection scope of the present invention with this; the equivalence that all Spirit Essences according to the present invention are done changes or modifies, and all should be encompassed in protection scope of the present invention.
Claims (10)
1. the dyeing finishing technique of a cuprammonium mixed-woven linen, it is characterized in that: take the grey cloth of described cuprammonium mixed-woven linen as raw material, the flow process of described dyeing finishing technique is: softener → setting machine typing → sand washing → decatize typing is dried → gone up to preshrunk → refining → washing → ferment enzyme washing → dyeing → washing → setting machine, wherein:
Described preshrunk is soaked two in open width two and is rolled in the preshrinking machine and carry out, and the temperature of the first tank is controlled to be 68 ℃～72 ℃, and the temperature of the second tank is controlled to be 88 ℃～92 ℃;
Described refining is carried out in overflow dyeing machine, and the refining bath raio is controlled to be 1:20～1:22, the consisting of of refining solution: liquid caustic soda 34～36g/l, refining agent 0.8～1.2g/l, precious 1.3～1.7g/l and all the other be water in the bath, control 78 ℃～82 ℃ of refining temperatures, 100～125 minutes time;
Overflow jet dyeing machine is adopted in described dyeing; bath raio is controlled to be 1:20～1:23; consisting of of dyeing liquor: REACTIVE DYES 0.1～6%; glauber salt 45～80g/l, liquid caustic soda 0.6～1.0 g/l, soda ash 4～8g/l; precious 1.2～1.8 g/l and all the other be water in the bath; dyeing course is as follows: cloth and water are entered in the overflow jet dyeing machine, add in the bath of formula ratio preciously, keep 28 ℃～32 ℃ of temperature; turn 4～6 minutes; then be warming up to 38 ℃～42 ℃, add the REACTIVE DYES of formula ratio, turn 13～17 minutes after; add again the glauber salt of formula ratio; after turning 13～17 minutes, add the soda ash of formula ratio, turn 13～17 minutes after; add the liquid caustic soda of formula ratio; turn 32～37 minutes, finish dyeing, the discharge dyeing liquor;
Water-washing process after the described dyeing is: add entry in the overflow jet dyeing machine after finishing to dyeing, be warming up to 60 ℃～70 ℃, turn 5～15 minutes, draining adds the liquid of soaping again, be warming up to 80 ℃～90 ℃, turn 10～30 minutes, discharge the liquid of soaping, add again at last entry, under 60 ℃～70 ℃, clean, go out cloth;
The oven dry of described setting machine is carried out under 115 ℃～125 ℃ of temperature; The setting temperature of described setting machine typing is 125 ℃～135 ℃;
Described sand washing is carried out in the air-flow sand washer, and temperature is 70 ℃～80 ℃, and the time is 60～90 minutes;
The temperature of described decatize typing is 140 ℃～150 ℃.
2. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 1 is characterized in that: described REACTIVE DYES is the L-type REACTIVE DYES that its chemical inc of Town in Shanghai promise is produced.
3. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 2 is characterized in that: the consisting of of described dyeing liquor: L-HLF indigo plant 0.1%～0.14%; L-3R Huang 0.25%～0.3%; L-4B is red 0.07%～0.085%, glauber salt 45～55g/l; Liquid caustic soda 0.6～1.0 g/l; Soda ash 4～6g/l, precious 1.2～1.8 g/l and all the other are water in the bath, the color after the cuprammonium mixed-woven linen dyes is cream-coloured.
4. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 3 is characterized in that: the consisting of of described dyeing liquor: L-HLF indigo plant 0.12%; L-3R Huang 0.26%; L-4B is red 0.079%, glauber salt 50g/l; Liquid caustic soda 0.8 g/l; Soda ash 5g/l, precious 1.5g/l and all the other are water in the bath.
5. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 2 is characterized in that: the consisting of of described dyeing liquor: L-3G dark blue 1.5%～2.0%; L-3R Huang 2.2%～2.5%; L-4B is red 0.8%～1.0%, glauber salt 60～80g/l; Liquid caustic soda 0.6～1.0 g/l; Soda ash 6～8g/l, precious 1.2～1.8 g/l and all the other be water in the bath, the color after the cuprammonium mixed-woven linen dyes is coffee color.
6. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 5 is characterized in that: the consisting of of described dyeing liquor: L-3G dark blue 1.85%; L-3R Huang 2.47%; L-4B is red 0.96%, glauber salt 70g/l; Liquid caustic soda 0.8 g/l; Soda ash 7g/l, precious 1.5 g/l and all the other are water in the bath.
7. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 1, it is characterized in that: the water-washing process after the described refining is: after refining finishes, discharge refining solution, add entry, be heated to 65 ℃～75 ℃, washed 15～25 minutes, draining adds water, is heated to 50 ℃～60 ℃, washed draining 10～15 minutes.
8. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 7, it is characterized in that: the process of the ferment enzyme washing before the described dyeing is: in the overflow dyeing machine after the washing, add the ferment enzyme washing lotion, be heated to 45 ℃～55 ℃ lower washings 25～35 minutes, draining, add again clear water, be heated to 50 ℃～60 ℃, wash to draining pH be 7～8.
9. the dyeing finishing technique of cuprammonium mixed-woven linen according to claim 8, it is characterized in that: the pH of described ferment enzyme washing lotion is 4～5, and it is by acetic acid 1.8～2.2g/l, and ferment enzyme 1.3～1.7g/l and surplus are that water forms.
10. cuprammonium flax interwoven fabric, it is characterized in that: described interwoven fabric obtains after being processed through the described dyeing finishing technique of each claim in the claim 1 to 9 by the cuprammonium mixed-woven linen, and described cuprammonium flax grey cloth that interweaves is that copper ammonia fibre and parallel are that linen fibre is interwoven by warp.
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| CN103437032A (en) * | 2013-08-29 | 2013-12-11 | 苏州宏优纺织有限公司 | Ultraviolet-proof copper ammonia fiber fabric |
| CN105297218A (en) * | 2015-09-22 | 2016-02-03 | 太仓市特灵化纤有限公司 | Wear-resistant ultraviolet-resistant blending fiber |
| CN108660577A (en) * | 2018-04-02 | 2018-10-16 | 江苏工程职业技术学院 | A kind of production technology of fiber crops/cuprammonium elastic fabric |
| CN110129960A (en) * | 2019-06-14 | 2019-08-16 | 吴江德伊时装面料有限公司 | A kind of fabric preparation process containing copper ammonia fiber |
| CN110685105B (en) * | 2019-09-25 | 2022-11-11 | 鲁泰纺织股份有限公司 | Finishing method of copper ammonia hemp interwoven fabric |
| CN115262059B (en) * | 2022-07-21 | 2024-01-19 | 深圳市亿卓服饰科技有限公司 | Cotton fabric and preparation method thereof |
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| JPH03124887A (en) * | 1989-10-06 | 1991-05-28 | Kanebo Ltd | Dyeing of high density fabric woven with hard-twist yarn |
| JPH03152281A (en) * | 1989-11-07 | 1991-06-28 | Kanebo Ltd | Dyeing of cellulose-based fiber structure |
| CN100485113C (en) * | 2006-11-28 | 2009-05-06 | 吴江德伊时装面料有限公司 | Dyeing method of copper ammonia fiber and tencel interwoven fabric |
| CN100554572C (en) * | 2007-05-31 | 2009-10-28 | 吴江德伊时装面料有限公司 | Dyeing method of interwoven fabric of copper ammonia fiber, cotton and cotton-nylon core spun yarn |
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