JPH03152281A - Dyeing of cellulose-based fiber structure - Google Patents
Dyeing of cellulose-based fiber structureInfo
- Publication number
- JPH03152281A JPH03152281A JP1287967A JP28796789A JPH03152281A JP H03152281 A JPH03152281 A JP H03152281A JP 1287967 A JP1287967 A JP 1287967A JP 28796789 A JP28796789 A JP 28796789A JP H03152281 A JPH03152281 A JP H03152281A
- Authority
- JP
- Japan
- Prior art keywords
- pattern
- colored
- printed
- reactive dye
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 11
- 238000004043 dyeing Methods 0.000 title claims description 7
- 229920002678 cellulose Polymers 0.000 title claims description 4
- 239000001913 cellulose Substances 0.000 title claims description 4
- 239000000985 reactive dye Substances 0.000 claims abstract description 21
- 239000003513 alkali Substances 0.000 claims abstract description 17
- 239000004744 fabric Substances 0.000 claims abstract description 12
- 230000001788 irregular Effects 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 19
- 238000007639 printing Methods 0.000 claims description 11
- 238000004513 sizing Methods 0.000 abstract description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000975 dye Substances 0.000 abstract description 4
- 239000000661 sodium alginate Substances 0.000 abstract description 4
- 235000010413 sodium alginate Nutrition 0.000 abstract description 4
- 229940005550 sodium alginate Drugs 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 8
- 230000003113 alkalizing effect Effects 0.000 abstract 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- 239000002585 base Substances 0.000 description 7
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- IFEUBXRSLPUMSI-UHFFFAOYSA-N [ClH]1NN=NC=C1 Chemical compound [ClH]1NN=NC=C1 IFEUBXRSLPUMSI-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000019571 color Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 238000010018 discharge printing Methods 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 238000010021 flat screen printing Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatment Of Fiber Materials (AREA)
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、セルロース系繊維構造物の染色方法に関し、
点描画風の柄模様や、かすれ感のある柄模様など、複雑
で変化に富んだ柄模様の染色物を得ることを目的とする
。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for dyeing cellulose fiber structures,
The aim is to obtain dyed products with complex and varied patterns, such as pointillist-like patterns and patterns with a faded appearance.
［従来の技術とその問題点］
従来、反応染料を使用するセルロース系ｔ／ａＭの二相
法捺染においては、アルカリを含む台棚を繊維構造物全
体に均一に施与する方法が一般的でおり、複雑な柄模様
を得る方法としてはオーバープリント法、抜染法、防染
法等が用いられて来た。[Prior art and its problems] Conventionally, in cellulose-based t/aM two-phase printing using reactive dyes, the common method was to uniformly apply an alkali-containing base to the entire fiber structure. Overprinting methods, discharge printing methods, resist dyeing methods, etc. have been used to obtain complex patterns.
しかし、それらの方法では本発明が目的とする点描画風
の柄模様や、かすれ感のある柄模様など、複雑で変化に
富んだ柄模様の染色物を得ることは困難である。However, with these methods, it is difficult to obtain a dyed product with a complex and varied pattern, such as a pointillist-like pattern or a pattern with a faded appearance, which is the object of the present invention.
［課題を解決するための手段］
本発明者は、反応染料を含む色糊を付与する工程とは別
途に、アルカリを布帛に部分的に（布帛全体にではなく
、模様を描くように）付与することによって、色糊とア
ルカリの重複部分のみに染料が固着され、色糊の施与の
際に描かれた模様とアルカリの施与の際に描かれた模様
との組合せによる、複雑で変化に富んだ柄模様を有する
染色物が１ｑられることを見出し、本発明を完成した。[Means for Solving the Problems] The present inventor applied alkali partially to the fabric (not to the entire fabric, but in a pattern) separately from the process of applying a color paste containing a reactive dye. By doing this, the dye is fixed only in the overlapping areas of the colored paste and the alkali, and the combination of the pattern drawn when the colored paste is applied and the pattern drawn when the alkali is applied creates a complex and varied pattern. It was discovered that a dyed product having a pattern rich in color can be produced by 1q, and the present invention was completed.
すなわち本発明は、セルロース系ｉｌｉ雑構造物の染色
において、
（ａ）反応染料を含む色糊を布帛に付与する工程、及び
（ｂ）反応染料を付与された、または付与されるべき布
帛面の一部分にのみ所定の模様または不規則な模様でア
ルカリを付与する工程
を含む捺染方法である。That is, the present invention provides a method for dyeing cellulose-based ili miscellaneous structures, including (a) a step of applying a color paste containing a reactive dye to a fabric, and (b) a step of applying a color paste containing a reactive dye to a fabric, and (b) a step of applying a color paste containing a reactive dye to a fabric surface. This is a printing method that includes a step of applying alkali only to a portion in a predetermined pattern or in an irregular pattern.
ここで、アルカリを反応染料の付与されたまたは付与さ
れるべき布帛面の一部分にのみ、所定の模様または不規
ロリな模様で付与することが本発明の小要な要件である
。このことによって、布帛に付ちされた反応染料の全て
が染着されることなく、色糊とアルカリの重複部分のみ
が染色されて、複雑で変化に富んだ柄模様を得ることが
出来る。Here, it is a minor requirement of the present invention that the alkali be applied only to a portion of the fabric surface to which the reactive dye has been applied or to be applied, in a predetermined pattern or an irregular pattern. As a result, all of the reactive dye applied to the fabric is not dyed, and only the overlapping areas of the colored paste and alkali are dyed, making it possible to obtain a complex and varied pattern.
本発明で用いられる反応染料には特に制限はなく、置換
型反応染料例えばビニルスルホン系染料、７付加形反応
染料例えばクロルトリアジン系染料等のいずれをも使用
することが出来る。具体的な例としてチバガイギー社の
Ｃ１ｂａＣｒＯｎ （商標〉、１、Ｃ，１，社のＰｒ
ｏｃｉｏｎ （商標）、日本化薬株式会社のＫａｙａｃ
ｉｏｎ （商標）等が挙げられるが、これらに限定さ
れない。本発明において反応染料は、曲型的には中性ま
たは弱酸性色糊として施与される。The reactive dye used in the present invention is not particularly limited, and any of substituted reactive dyes such as vinyl sulfone dyes, heptaadduct reactive dyes such as chlortriazine dyes, etc. can be used. Specific examples include Ciba Geigy's C1baCrOn (trademark), 1, C, 1, Pr.
ocion (trademark), Kayac of Nippon Kayaku Co., Ltd.
ion (trademark) and the like, but are not limited to these. In the present invention, the reactive dye is applied as a neutral or weakly acidic color paste.
反応染料は、色糊に対し、慣用の通常の母にて、０、０
１〜１０重母％程度加えられる。The reactive dye is 0,0
It is added in an amount of about 1 to 10%.
本発明の染色法で用いられるアルカリは、反応染料を固
着させるために使用するものであり、型費、ソーダ灰、
苛性ソーダ、ケイ酸ソーダ、トリクロル酢酸ソーダ等、
慣用の種々のものを用いることが出来る。好ましい例と
しては、型費、ソーダ灰が挙げられる。アルカリの付与
は、好ましくはアルカリを含んだ台棚を印捺することに
よって行なわれるが、アルカリの水性溶液を噴霧するこ
とによって不規則な模様で付与することも出来る。The alkali used in the dyeing method of the present invention is used to fix the reactive dye, and is used for molding, soda ash,
Caustic soda, sodium silicate, sodium trichloroacetate, etc.
Various commonly used ones can be used. Preferred examples include mold ash and soda ash. Application of the alkali is preferably carried out by printing a plate containing an alkali, but it can also be applied in an irregular pattern by spraying an aqueous solution of the alkali.
台網中に含まれるアルカリのＩＵは、使用するアルカリ
や被染色繊維構造物の種類、色糊中の反応染料のｍ度等
によって異なるが、通常は１．５〜３重母％程度である
。The IU of alkali contained in the base net varies depending on the alkali used, the type of fiber structure to be dyed, the m degree of reactive dye in the color paste, etc., but is usually about 1.5 to 3%. .
色糊及び台棚に使用する糊剤としては、慣用の反応染料
印捺の際に使用される種々の糊剤を用いることが出来る
が、アルギン酸ソーダ、カルボキシメチルセルロース、
天然ガム等が好ましい。他に、色糊としてケロシンまた
はテルペンのエマルジョンを混合したエマルジョン糊、
ハーフエマルジョン糊を使用しても良い。As the color paste and the paste used for the shelf, various pastes used in conventional reactive dye printing can be used, including sodium alginate, carboxymethyl cellulose,
Natural gum etc. are preferred. In addition, emulsion paste mixed with kerosene or terpene emulsion as color paste,
Half emulsion glue may also be used.
元糊には、尿素、還元防止剤、金属イオン封鎖剤等、ア
ルカリ以外の反応染料発色用助剤を添ｈＤしておくのが
好ましい。これらの助剤は、色糊と台棚のいずれかに、
あるいは両方に添加することが可能であるが、好ましく
は色糊中にのみ添加される。It is preferable to add to the base paste a reactive dye coloring aid other than alkali, such as urea, a reduction inhibitor, a metal ion sequestering agent, etc. These auxiliary agents can be added to either colored glue or stand shelves.
Alternatively, it is possible to add it to both, but preferably it is added only to the color paste.
本発明で対象とするセルロース系繊維構造物とは、例え
ばセルロース系繊維を３０重量％程度以上含有する繊維
構造物であり、好ましくはセルロース系繊維を５０重に
％程度以上、特に好ましくは８０重母％程度以上含有す
る繊維構造物である。セルロース系繊維としては、綿、
麻等の天然繊維、ビスコースレーヨン、銅アンモニアレ
ーヨン等の再生セルロース１ｉｉｌｔ等が挙げられる。The cellulosic fiber structure targeted by the present invention is, for example, a fiber structure containing about 30% by weight or more of cellulose fibers, preferably about 50% by weight or more of cellulose fibers, particularly preferably about 80% by weight. It is a fiber structure containing at least about % of the base. Cellulose fibers include cotton,
Examples include natural fibers such as hemp, regenerated cellulose such as viscose rayon, copper ammonia rayon, etc.
ｔａＭ構造物は、公知の通常の方法にて、毛焼、糊汰き
、精練、漂白、及びシルケット加工を行っておくことが
好ましい。The taM structure is preferably subjected to sintering, sizing, scouring, bleaching, and mercerization using conventional methods.
本発明において、色糊及び台棚の印捺は、ハンドプリン
ト、フラットスクリーン捺染、ロータリー捺染、ローラ
ー捺染等、いずれの慣用の方法にても行うことが出来る
。また、台棚の付与においては、上記の方法以外に、コ
ーティング法等を用いることも可能である。色糊と台棚
の付与の順序はいずれでも良く、色糊、台棚それぞれの
付与の後に、中間乾燥を行うのが好ましい。また、本発
明に従う捺染工程を、慣用の一相法及び／または二相法
捺染、さらには浸染工程と組み合わせて、より複雑な柄
模様を１ｑることも出来る。In the present invention, the color paste and the stand can be printed by any conventional method such as hand printing, flat screen printing, rotary printing, roller printing, etc. Moreover, in addition to the above-mentioned method, it is also possible to use a coating method or the like in providing the shelf. The colored paste and the shelf may be applied in any order, and it is preferable to perform intermediate drying after applying the colored paste and the shelf. It is also possible to combine the printing process according to the present invention with conventional one-phase and/or two-phase printing, or even with a dip dyeing process to produce 1q more complex patterns.
反応染料を固着させる熱処理は、湿熱スチーミング法、
乾熱ベーキング法等、いずれの方法を用いることも出来
、湿熱スチーミング法にて９５〜１０５℃で７〜１２分
間の処理を行うのが好ましい。Heat treatments to fix reactive dyes include moist heat steaming method,
Any method such as a dry heat baking method can be used, and it is preferable to perform the treatment at 95 to 105° C. for 7 to 12 minutes using a wet heat steaming method.
熱処理後に、慣用の方法にて洗浄、乾燥を行う。After the heat treatment, washing and drying are performed using a conventional method.
以下、実施例により本発明をさらに説明する。The present invention will be further explained below with reference to Examples.
［実施例１
実施例１
中粘度アルギン酸ソーダ（３％） ８０重量％、ヘキ糧
ノメタリン酸ソーダ０．１重但％、ｍ−ニトロベンゼン
スルホン酸ソーダ１小母％、尿素８重囲％より成る元糊
に、カラーインデックスナンバー（Ｃｏ ｌ −ｏｕｒ
Ｉｎｄｅｘ Ｎｏ、以下Ｃ，１，と略′？ｔ）リアク
ティブレッド２４１小母％を溶解して調製した色糊を、
経４０番手１３０本、１７ｉ！４０番手７０本、日付１
２０ｇ／〆のブロードに、フラットスクリーンにより印
捺し、１００℃で３分８１１の乾燥処理を行った。[Example 1 Example 1 Element consisting of 80% by weight of medium viscosity sodium alginate (3%), 0.1% by weight of sodium hexanetaphosphate, 1% by weight of sodium m-nitrobenzenesulfonate, and 8% by weight of urea. Color index numbers (Col-our) are added to the glue.
Index No., hereinafter abbreviated as C,1,'? t) Color paste prepared by dissolving 241% of Reactive Red,
130 pieces of warp 40, 17i! 40th number 70 pieces, date 1
Printing was carried out on a 20 g/broad paper using a flat screen, and a drying process was performed at 100° C. for 3 minutes.
次に、中粘度アルギン酸ソーダ（３％） ８０重量％、
型費２重量％、水１８千ｍ％より成る台幅を、色糊印捺
面上にフラットスクリーンによりたたき柄として印捺し
、１００℃で３分間の乾燥処理を行った。Next, medium viscosity sodium alginate (3%) 80% by weight,
A base width consisting of 2% by weight of the mold and 18,000 m% of water was printed as a pattern on the color paste printing surface using a flat screen, and dried at 100° C. for 3 minutes.
このものに１００℃で８分間のスチーミング処理を施し
た後、洗浄、乾燥を行うと、美麗な赤色の点描画風柄模
様を有する染色物が１ｑられた。This product was steamed at 100° C. for 8 minutes, washed and dried to yield 1 q of dyed material with a beautiful red pointillist pattern.
実施例２
実施例１で用いた元糊に、Ｃ，１，リアクティブブラッ
ク８０．５単量％を溶解し、色糊を調製した。Example 2 80.5% monomer of C, 1, reactive black was dissolved in the base paste used in Example 1 to prepare a colored paste.
別途に、実施例１で用いた元糊に１費２重量％、Ｃ，１
，リアクティブイエロー２１重量％を溶解した色糊を調
製した。これら二つの色糊を別々のプリントパターンで
、実施例１で用いたのと同様の繊ｗＬ構造物にフラット
スクリーン法にて印捺し、以下、実施例１と同様にして
、乾燥、アルカリ台網のたたき柄印捺、乾燥、及びスチ
ーミング処理を行った。アルカリを含まない色糊を印捺
した部分が点描画風に染色されたのに対し、重管を添加
した色糊を印捺した部分は均一に染色され、黒色の点描
画風染色部分と黄色の均一染色部分との組合わせによる
美麗な染色物が１ｑられた。Separately, add 2% by weight of C,1 to the base glue used in Example 1.
, a colored paste was prepared by dissolving 21% by weight of Reactive Yellow. These two colored pastes were printed in separate print patterns on the same fiber wL structure as used in Example 1 using a flat screen method, and then dried in the same manner as in Example 1. The tataki pattern was printed, dried, and steamed. The area printed with color paste that does not contain alkali was dyed in a pointillist style, whereas the area printed with color paste containing heavy tubes was dyed uniformly, with a black pointillist style dyed area and a yellow color. 1q of beautiful dyed products were produced by combining the uniformly dyed parts of
Claims (1)
帛面の一部分にのみ所定の模様または不規則な模様でア
ルカリを付与する工程 を含む捺染方法。[Claims] 1. In the dyeing of cellulose-based fiber structures, (a) a step of applying a color paste containing a reactive dye to a fabric; and (b) a fabric to which the reactive dye has been or is to be applied. A printing method that includes a step of applying alkali to only a portion of the surface in a predetermined or irregular pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1287967A JPH03152281A (en) | 1989-11-07 | 1989-11-07 | Dyeing of cellulose-based fiber structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1287967A JPH03152281A (en) | 1989-11-07 | 1989-11-07 | Dyeing of cellulose-based fiber structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03152281A true JPH03152281A (en) | 1991-06-28 |
Family
ID=17724073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1287967A Pending JPH03152281A (en) | 1989-11-07 | 1989-11-07 | Dyeing of cellulose-based fiber structure |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03152281A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102418249A (en) * | 2011-09-19 | 2012-04-18 | 吴江德伊时装面料有限公司 | Dyeing and finishing technology for cuprammonium-linen interwoven fabric and cuprammonium-linen interwoven fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50121583A (en) * | 1974-03-13 | 1975-09-23 | ||
| JPS5455678A (en) * | 1977-09-29 | 1979-05-02 | Sandoz Ag | Dyeing and printing of cellulosic fiber |
-
1989
- 1989-11-07 JP JP1287967A patent/JPH03152281A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50121583A (en) * | 1974-03-13 | 1975-09-23 | ||
| JPS5455678A (en) * | 1977-09-29 | 1979-05-02 | Sandoz Ag | Dyeing and printing of cellulosic fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102418249A (en) * | 2011-09-19 | 2012-04-18 | 吴江德伊时装面料有限公司 | Dyeing and finishing technology for cuprammonium-linen interwoven fabric and cuprammonium-linen interwoven fabric |
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