CN102704289B - Fixation method of natural plant indigo dye for wax printing - Google Patents
Fixation method of natural plant indigo dye for wax printing Download PDFInfo
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- CN102704289B CN102704289B CN201210057703.9A CN201210057703A CN102704289B CN 102704289 B CN102704289 B CN 102704289B CN 201210057703 A CN201210057703 A CN 201210057703A CN 102704289 B CN102704289 B CN 102704289B
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Abstract
The invention discloses a fixation method of natural plant indigo dye for wax printing. The fixation method is realized by combining a method for removing surface dyeing through oxidation with a method for fixation through a composite dye-fixing agent. The fixation method comprises the following steps of: putting a fiber product which is dyed by the natural plant indigo dye and dried into an alkaline solution of hydrogen peroxide and a detergent (sodium dodecyl benzene sulfonate or lauryl sodium sulfate and the like), and digesting at the temperature of between 95 and 100 DEG C for 10 to 30 minutes, washing and drying, wherein the concentration (mass percent) of hydrogen peroxide is 0.05 to 0.1 percent, the concentration (mass percent) of sodium dodecyl benzene sulfonate is 0.1 to 0.3 percent, the pH value is 10 to 12, and the bath ratio is 1:20; and digesting the fiber product which is treated by oxidation surface dyeing removal in the solution of the composite dye-fixing agent which consists of animal glue and polyquaternium at the temperature of between 60 and 70 DEG C for 10 to 30 minutes, washing and drying, wherein the concentration (mass percent) of the animal glue in the solution is 1 to 2 percent, and the concentration (mass percent) of polyquaternium is 1 to 3 percent. The plant fiber product obtained by the dye-fixing process keeps the plant indigo fragrance, is bright in color, difficult to fade during friction, formaldehyde-free, green and environment-friendly.
Description
Technical field:
The present invention relates to a kind of color-fixing method of natural plants bipseudoindoxyl dye for batik, belong to technical field of textile printing.
Background technology:
Vegetable indigo is the traditional handicraft of Chinese Minority Nationalities---a kind of natural plant dye the most widely that batik adopts, a kind of nontoxic, harmless, pollution-free, the dyestuff with peat-reek and health care, its dyeing articles is bright in colour, tone is graceful and good hand feeling is abundant, have advantages of chemical synthetic dye incomparable.In ancient times, vegetable indigo is most widely used general and most important dyestuff, can dye throwing, hair, cotton, the fibre such as numb.In minority areas such as Yunnan Province of China, Guizhou, Guangxi and Hainan Deng Di Yao nationality, Miao ethnic group, Zhuangs, continue to use the traditional handicraft of vegetable indigo dyeing always, the batik and waxprinting article of these ethnic groups has characteristic, except the einnehmen function as them, be to be also deeply subject to visitor's tourist souvenir that especially foreign tourist welcomes now.
Traditional indigo wax-dyeing process, generally comprises following steps: dye liquor prepare-is waxed on floral designs, and--dyeing-dewaxing--crosses the five steps such as glue-decatize (or drying).Detailed process is: 1, first in indigo dye liquor, add the batchings such as lime or plant ash, vinasse or swill, make the effect of dye liquor generation fermentation reducing.2, on the floral designs of fibre (cloth), wax, 3, when dyeing, cloth is put into dye liquor, soak half an hour and take out, dry, then put into dye liquor and dye again, so repeatedly dye every day three times, dye continuously a couple of days and can become blue cloth.4, the cloth that dyes required color was carried out to glue and process, to increase fabric strength and to improve dyefastness, the glue adopting is generally the animal glue such as gelatin, gelatine.5, the stained clot-h of crossing after glue was put into pot decatize after approximately 20 minutes, take out solarization (drying in the air) and do.
By above traditional resulting batik and waxprinting article of vegetable indigo dyeing, there is the problem of crock fastness poor (easily decolouring), had a strong impact on the quality of vegetable indigo batiks.
For improving the crock fastness (improve colour fixation) of vegetable indigo on goods, the present invention has provided a kind of vegetable indigo fixation new method, the method is on traditional handicraft basis, when crossing glue, first by the method being oxidized, the loose colour on stained clot-h is sloughed, then with animal glue and cation quaternary ammonium salt compound as color-fixing agent to the indigo fixation treatment of carrying out.The dyeing articles obtaining with traditional handicraft is compared, better with the resulting dyeing articles colour fixation of color-fixing method provided by the invention, can keep that dyeing articles is bright in colour, tone is graceful simultaneously, and good hand feeling is abundant, fragrance is pleasant and the feature such as health care.
Summary of the invention:
The invention relates to the method for the crock fastness that improves natural plants bipseudoindoxyl dye batik and waxprinting article, is that the method for being sloughed loose colour and being adopted composite solid toner fixation to combine by oxidation realizes.
The feature of the de-loose colour step of oxidation be by with natural plants indigo dyeing the fibre that dries in the alkaline solution of hydrogen peroxide and washing agent (neopelex or lauryl sodium sulfate etc.), at 95～100 ℃, digestion is after 10～30 minutes, and washing is dried.Hydrogen peroxide concentration (mass fraction) is 0.05～0.1%, and neopelex concentration (mass fraction) is 0.1～0.3%, pH10～12, bath raio 1: 20.
The feature of vegetable indigo fixation step is to use the fibre being oxidized after de-loose colour is processed in the solution of the composite color-fixing agent being comprised of animal glue and polyquaternium, and at 60-70 ℃ of temperature, digestion, after 10～30 minutes, is cleaned and dried.In body lotion, animal glue concentration (mass fraction) is 1～2%, and polyquaternium concentration (mass fraction) is 1～3%.
By following examples, the present invention is described:
Embodiment 1 is by after 3 milliliter of 30% hydrogen peroxide, 1g neopelex, 1g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, by putting into solution digestion with the plant fiber products that vegetable indigo dyeing has also dewaxed, after 30 minutes, take out, with clear water washing, make loose colour depart from fiber surface, dry.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 60 ℃ of digestions after 30 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 2 is by after 2 milliliter of 30% hydrogen peroxide, 2g lauryl sodium sulfate, 2g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, by putting into solution digestion with the plant fiber products that vegetable indigo dyeing has also dewaxed, after 20 minutes, take out, with clear water washing, make loose colour depart from fiber surface, dry.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 60 ℃ of digestions after 30 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 3 is by after 2 milliliter of 30% hydrogen peroxide, 3g neopelex, 3g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, will put into solution with the plant fiber products that vegetable indigo dyeing has also dewaxed, digestion took out after 10 minutes, with clear water washing, make loose colour depart from fiber surface, dry.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 60 ℃ of digestions after 20 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.。
Embodiment 4 is by after 2 milliliter of 30% hydrogen peroxide, 3g lauryl sodium sulfate, 4g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, by putting into solution digestion with the plant fiber products that vegetable indigo dyeing has also dewaxed, after 10 minutes, take out, with clear water washing, make loose colour depart from fiber surface, dry.20g gelatin and 10g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 60 ℃ of digestions after 10 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 5 is by after 3 milliliter of 30% hydrogen peroxide, 2g neopelex, 0.4g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, by putting into solution digestion with the plant fiber products that vegetable indigo dyeing has also dewaxed, after 30 minutes, take out, with clear water washing, make loose colour depart from fiber surface, dry.10g ox glue and 20g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 70 ℃ of digestions after 30 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 6 is by after 3 milliliter of 30% hydrogen peroxide, 3g neopelex, 0.04g dissolution of sodium hydroxide are in 1L water, solution is heated to approach after boiling (95～100 ℃), in the bath raio ratio of 1: 20, by putting into solution digestion with the plant fiber products that vegetable indigo dyeing has also dewaxed, after 30 minutes, take out, with clear water washing, make loose colour depart from fiber surface, dry.10g ox glue and 30g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in 1L water, put into the plant fiber products after the de-loose colour of oxidation, be heated to 70 ℃ of digestions after 30 minutes, take out and wash and dry.Gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Claims (3)
1. the color-fixing method of natural plants bipseudoindoxyl dye for a batik, it is characterized in that: the fibre after processing with the de-loose colour of oxidation is placed in to the composite solid toner solution being comprised of animal glue and polyquaternium, in composite solid toner solution, animal glue mass concentration is 1～2%, polyquaternium mass concentration 1～3%; bath raio 1: 20; digestion, after 10～30 minutes, is cleaned and dried at 60-70 ℃ of temperature.
2. the color-fixing method of natural plants bipseudoindoxyl dye for batik according to claim 1, is characterized in that: described animal glue is ox glue or gelatin.
3. the color-fixing method of natural plants bipseudoindoxyl dye for batik according to claim 1, is characterized in that: described polyquaternium is dimethyl diallyl ammonium chloride-acrylamide copolymer or diallyldimethylammonium chloride monomer homopolymers.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210057703.9A CN102704289B (en) | 2012-03-07 | 2012-03-07 | Fixation method of natural plant indigo dye for wax printing |
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| CN201210057703.9A CN102704289B (en) | 2012-03-07 | 2012-03-07 | Fixation method of natural plant indigo dye for wax printing |
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| CN102704289B true CN102704289B (en) | 2014-10-29 |
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Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104074017A (en) * | 2014-07-15 | 2014-10-01 | 太仓市虹鹰印花有限公司 | Multi-batik method |
| CN105113301B (en) * | 2015-09-08 | 2017-09-29 | 广东名斯度服饰有限公司 | A kind of natural animal-plant source color fixing agent and preparation method thereof and color fixing process |
| CN105951482A (en) * | 2016-07-19 | 2016-09-21 | 广东德润纺织有限公司 | Fabric washing and color fixing consecutive processing technology |
| CN106283721A (en) * | 2016-07-31 | 2017-01-04 | 贵州省从江县盈茂农业科技开发有限公司 | A kind of manufacture method of the bright cloth of the Dong nationality |
| CN106366692A (en) * | 2016-08-30 | 2017-02-01 | 杭州吴越人家工艺服饰有限公司 | Manufacturing process for indigo dye and blue-dyed printed fabric |
| CN107268297B (en) * | 2017-08-07 | 2020-01-10 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Wax printing method for cotton cloth and wax printed cotton cloth |
| CN107245890B (en) * | 2017-08-07 | 2021-01-15 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Method for wax printing of linen and wax printed linen |
| CN108486913A (en) * | 2018-04-24 | 2018-09-04 | 无锡职业技术学院 | A kind of gorgeous degree and color fixing process improving indigo batik |
| CN108505370A (en) * | 2018-04-24 | 2018-09-07 | 无锡职业技术学院 | A kind of color fixing process of indigo batik |
| CN108716137A (en) * | 2018-05-07 | 2018-10-30 | 贵州西江阿幼民族文化博物馆有限公司 | A kind of color forming method of batik bipseudoindoxyl dye |
| CN108841010B (en) * | 2018-06-06 | 2020-10-27 | 常州纺织服装职业技术学院 | Preparation method and application of gelatin iron chelate |
| CN109457517A (en) * | 2018-10-29 | 2019-03-12 | 嘉兴珠韵服装有限公司 | The preparation of modified gelatin/cation-modified anorthite compound color fixing agent and the application in acid dyeing |
| CN110306358B (en) * | 2019-08-08 | 2021-11-23 | 苏州虹锦生态纺织科技有限公司 | Processing method for dyeing real silk fabric by natural dye |
| CN112252056A (en) * | 2020-10-22 | 2021-01-22 | 安顺市西秀区星月苗族蜡染工艺品有限公司 | Wax printing color fixing method for vegetable natural dye |
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