CN105001671A - Compound brightening agent and washing agent composition containing compound brightening agent - Google Patents
Compound brightening agent and washing agent composition containing compound brightening agent Download PDFInfo
- Publication number
- CN105001671A CN105001671A CN201510371617.9A CN201510371617A CN105001671A CN 105001671 A CN105001671 A CN 105001671A CN 201510371617 A CN201510371617 A CN 201510371617A CN 105001671 A CN105001671 A CN 105001671A
- Authority
- CN
- China
- Prior art keywords
- white dyes
- whitening agent
- washing
- detergent composition
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 238000005406 washing Methods 0.000 title claims abstract description 29
- 150000001875 compounds Chemical class 0.000 title claims abstract description 22
- 238000005282 brightening Methods 0.000 title abstract 7
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 27
- 125000000129 anionic group Chemical group 0.000 claims abstract description 13
- 150000001768 cations Chemical class 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 239000003599 detergent Substances 0.000 claims description 26
- 230000002087 whitening effect Effects 0.000 claims description 22
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 21
- 150000002500 ions Chemical class 0.000 claims description 15
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 11
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 10
- 125000002091 cationic group Chemical group 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims description 9
- 235000021286 stilbenes Nutrition 0.000 claims description 9
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 8
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 7
- 239000004305 biphenyl Substances 0.000 claims description 6
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 241000282326 Felis catus Species 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 4
- PIGKXHAIBGNREV-UHFFFAOYSA-N C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1C=CC1=CC=CC=C1 Chemical group C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1C=CC1=CC=CC=C1 PIGKXHAIBGNREV-UHFFFAOYSA-N 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 4
- 229960000956 coumarin Drugs 0.000 claims description 4
- 235000001671 coumarin Nutrition 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- 239000000665 guar gum Substances 0.000 claims description 4
- 235000010417 guar gum Nutrition 0.000 claims description 4
- 229960002154 guar gum Drugs 0.000 claims description 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 150000003016 phosphoric acids Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000003019 stabilising effect Effects 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 26
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000004383 yellowing Methods 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 description 21
- 239000000047 product Substances 0.000 description 15
- 239000000126 substance Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910001414 potassium ion Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical class CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 208000023445 Congenital pulmonary airway malformation Diseases 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090000856 Lyases Proteins 0.000 description 1
- 102000004317 Lyases Human genes 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- UHXQPQCJDDSMCB-UHFFFAOYSA-L disodium;3-[[9,10-dioxo-4-(2,4,6-trimethyl-3-sulfonatoanilino)anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C(S([O-])(=O)=O)=C1C UHXQPQCJDDSMCB-UHFFFAOYSA-L 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical group [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 239000000230 xanthan gum Chemical class 0.000 description 1
- 229920001285 xanthan gum Chemical class 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a compound brightening agent and a washing agent composition containing the compound brightening agent. The compound brightening agent comprises an anionic fluorescent brightening agent and a cationic polymer. The weak cationic polymer satisfies the following conditions of a1, polymer cation density of 0.01meq/g-1meq/g and a2, polymer number-average molecular weight of 20000-1000000 daltons. The washing agent composition containing the compound brightening agent can improve an anionic fluorescent brighting agent utilization rate and delay or prevent fabric yellowing.
Description
Technical field
The present invention relates to a kind of whitening agent and the application in the preparation of washing composition thereof, be specifically related to the whitening agent be composited by specific cationic polymers and white dyes and the detergent composition containing described whitening agent, obviously can delay after repeatedly using said composition process fabric or prevent fabric xanthochromia.
Background technology
Daily washing composition is usually containing multiple water-insoluble washing auxiliary detergent, and anion surfactant in hard water environment also easily and calcium, magnesium ion etc. interact, form the mixture of poorly water-soluble, above-mentioned water-insoluble material easily deposits to fabric face, reduce fabric to light reflectance, cause fabric to turn to be yellow dimmed.For delaying or preventing fabric xanthochromia, traditional method is in Betengent product, add the colour protecting agent such as white dyes, cationic polymers.White dyes is by absorbing the invisible ultraviolet portion in sunlight, be excited into visible bluish voilet fluorescence, become white light with the yellow light mix on fabric, reach and eliminate original gold-tinted on fabric, improve fabric whiteness, preferred water-soluble anionic Stilbene-based derivative.Zhu Haiyang, Geng Jingkun etc. discuss cationic polymers can form thin film at cellulose surface, thus the dyestuff that minimizing comprises whitening agent comes off, and reaches fixation, protects the effect of look.
But, the most price of white dyes is more expensive, in washing composition, addition is lower again, and because fabric face is usually with negative charge, white dyes can come off to a certain extent, cause being difficult in washing process obtain satisfied whitening effect, therefore effective use water soluble fluorescers is the optimal path embodying its whitening effect.Procter & Gamble discloses the detergent composition simultaneously containing toning agent and whitening agent in patent CN103339245B, is greater than the independent either method used to lifting effect of fabric whiteness.The water-soluble height of disulfonic acid fluorescent whitening agent composition disclosed in patent CN102924972B, cost performance are high, the whitening effect that more single disulfonic acid fluorescent whitening agent product is more excellent.
Summary of the invention
For making up the above-mentioned defect of traditional method, an object of the present invention is to provide a kind of compound whitening agent, it is characterized in that comprising component (a) anionic white dyes and component (b) cationic polymers, and the weight ratio of described component (a) and described component (b) is 1:100-1:0.01, be preferably 1:50-1:0.02.
Described anionic white dyes is selected from stilbene biphenyl type white dyes, triazine radical amido stilbene type white dyes, two (1,2,3-triazole-2-base) in stilbene type white dyes, two (cumarone-2-base) biphenyl fluorescent whitening agent, 1,3-phenylbenzene-2-pyrazoline white dyes or coumarin type white dyes one or more.
The positive ion density of described cationic polymers is 0.01meq/g-1meq/g, and molecular weight is 20,000 Da-100 ten thousand Da.
For promoting effect, further preferred cationic density is 0.01meq/g-0.5 meq/g, the cationic polymers of molecular weight 100,000 Da-100 ten thousand Da;
Described cationic polymers be preferably cationic cellulose, cation guar gum, cationic polyacrylamide one or more.
Another object of the present invention relates to a kind of detergent composition containing described compound whitening agent, and described detergent composition comprises the following component of the weight fraction of the gross weight based on washing composition:
Described detergent composition may also be the following component of the weight fraction of the gross weight comprised based on washing composition:
Wherein, in described compound whitening agent, the weight ratio of component (a) white dyes and component (b) cationic polymers is 1:100-1:0.01.
Described anion surfactant be alkylbenzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, soap, a-alkene sulfonate, aliphatic alcohol polyethenoxy phosphoric acid salt, aliphatic alcohol polyethenoxy carboxylate salt one or more.
Described nonionogenic tenside be fatty alcohol-polyoxyethylene ether, alkyl glycoside, fatty acid alkyl amide, fatty acid alkyl ester Soxylat A 25-7, aliphatic acid polyethenoxy ether one or more.
Described detergent composition also comprises the amphoterics of weight fraction less than 30% and/or the cats product of weight fraction less than 30%.
The formulation of described detergent composition comprises washing lotion, emulsion, Colloidal fluid, pulvis or blocks of solid.
Present inventor finds, in the solution cationic polymers can with anionic optical brighteners generation electrostatic interaction, form the mixture of poorly water-soluble, separate out from solution and easily deposit to fabric face, but too high positive ion density can cause formed mixture to be reunited in a large number forms bulk precipitation, can affect the whitening effect of fabric on the contrary.Present inventor also finds, along with the molecular weight of cationic polymers increases, the molecular dimension of polymkeric substance increases, and white dyes combines the large micelle of rear easily formation.The effect of cationic polymers and white dyes and the structural relation of polymkeric substance less, therefore, the weak cation polymkeric substance with suitable electric density and molecular weight all can play the effect promoting white dyes utilization ratio preferably.Based on above-mentioned discovery, the cationic polymers that cationic polymers selected by the present invention preferably meets the following conditions simultaneously: the positive ion density of (a1) polymkeric substance is 0.01 meq/g ~ 1 meq/g; (a2) number-average molecular weight of polymkeric substance is 20,000 dalton ~ 1,000,000 dalton.Term " positive ion density " describes the content of cationic polymers cationic groups in one, be commonly defined as the exchange capacity (as meq) of 1g polymkeric substance cationic, adopt titration measuring positive ion density, if the positive ion density measuring cation guar gum C14-S with the PCD04 type charge analysis instrument of German BTG company is 0.63 meq/g.
The white dyes that the present invention relates to is selected from stilbene biphenyl type, triazine radical amido stilbene type, two (1,2,3-triazole-2-base) stilbene type, two (cumarone-2-base) biphenyl, one or more of 1,3-phenylbenzene-2-pyrazoline and coumarin type.Described white dyes is sulfonated products, exist with its alkali metal salt, preferably including but not limited to toluylene fundamental mode compound, as 4,4 '-bis-(2-sodium sulfonate styryl) biphenyl, two triazinyl diphenyl ethylene derivatives, content in detergent composition of the present invention is 0.01%-2%, is preferably 0.01%-1%.
The present invention relates to surfactant system and include but not limited to anion surfactant, nonionogenic tenside, one or more of cats product and amphoterics.Preferred surfactant system comprises anion surfactant and nonionogenic tenside.
The content of anion surfactant is the 0.1%-30% of detergent composition, preferred alkyl benzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, soap, a-alkene sulfonate, aliphatic alcohol polyethenoxy phosphoric acid salt, one or more of aliphatic alcohol polyethenoxy carboxylate salt.
In certain embodiments, the mixture of anion surfactant is preferably containing alkylbenzene sulfonate and derivative thereof.Described alkylbenzene sulfonate meets following general formula:
Wherein R to be carbon number be 8 to 18 alkyl, can be the alkyl of straight chain, also can be the alkyl of side chain; Can be saturated alkyl, also can be undersaturated alkyl.M is positively charged ion, as sodium ion, and potassium ion, ammonium ion etc.Suitable example is Sodium dodecylbenzene sulfonate.
In certain embodiments, the mixture of anion surfactant contains fatty alcohol polyoxyethylene ether sulfate.Fatty alcohol polyoxyethylene ether sulfate has following general formula:
Wherein R to be carbon number be 8 to 18 alkyl, can be the alkyl of straight chain, also can be the alkyl of side chain; Can be saturated alkyl, also can be undersaturated alkyl.M is positively charged ion, as sodium ion, and potassium ion, ammonium ion etc.N is the number of repeat unit of ethylene glycol segment, is 0.5 to 10, is preferably 0.5 to 3.Suitable example is the Texapon N70 of BASF AG.
In certain embodiments, containing a-alkene sulfonate, there is following general formula:
Wherein R to be carbon number be 8 to 18 alkyl, can be the alkyl of straight chain, also can be the alkyl of side chain; Can be saturated alkyl, also can be undersaturated alkyl.M is positively charged ion, as sodium ion, and potassium ion, ammonium ion etc.N is 0 to 2.
In certain embodiments, the mixture of anion surfactant contains soap, and its alkyl chain can be the alkyl of straight chain, also can be the alkyl of side chain; Can be saturated alkyl, also can be undersaturated alkyl.Suitable example is sodium laurate, sodium stearate.Described soap also comprises aliphatic alcohol polyethenoxy ether carboxylate, and the carbon number of alkyl chain is 8 to 18, and oxyethylation degree is 2 to 10.
The content of described nonionogenic tenside is 0.1% ~ 30% of detergent composition, is preferably fatty alcohol-polyoxyethylene ether, alkyl glycoside, fatty acid alkyl amide, fatty acid alkyl ester Soxylat A 25-7, one or more of fatty acid methyl ester Soxylat A 25-7.
In certain embodiments, nonionogenic tenside preferably containing fatty alcohol-polyoxyethylene ether, has following general formula:
Wherein n is 8 to 18, x is 0.5 to 30.
The fatty alcohol of described fatty alcohol-polyoxyethylene ether preferably but be not limited to octanol, certain herbaceous plants with big flowers alcohol, lauryl alcohol, different tridecanol, cetyl alcohol, stearyl alcohol, one or more of oleyl alcohol.Oxyethylation degree x preferably 2 to 12.Suitable ion is the NEODOL series straight chain fatty polyoxyethylenated alcohol product of SHELL company, the Lutensol XL series of BASF AG and XP series product.
In certain embodiments, non-ionic surfactant mixture contains APG, has following general formula:
Wherein n is 8 to 18, y is 1 to 3.Suitable example has the alkyl glycoside series product of Shanghai Fakai Chemical Co., Ltd..
In certain embodiments, nonionogenic tenside can contain fatty acid methyl ester Soxylat A 25-7, and general formula is as follows:
Wherein n is 8 to 18, a is 2 to 12.Suitable example is the FMEE product of Pemex company.
The invention still further relates to other tensio-active agents, comprise the zwitterionics of 0 ~ 30%, the cats product of 0 ~ 30%.Zwitterionics comprises betaine type amphoteric surfactant, amino acid type surfactant, Imidazoline Surfactants, amine oxide type tensio-active agent.Cationic surfactant comprises quaternary ammonium salt cationic surfactant, heterocyclic tensio-active agent.
The washing assistant that detergent composition of the present invention relates to is selected from zymin, enzyme stabilising system, anti redeposition agent, inorganic salt and other component etc.
Described zymin is selected from proteolytic enzyme, amylase, cellulase, at, esterase, lipase, peroxidase, lyase, maltin, zytase etc.The content of zymin is the 0%-5% of detergent composition, is preferably 0%-3%; Described enzyme stabilising system contains boric acid, borax, propylene glycol, glycerine, one or more of polyvalent alcohol, and content is 0%-5%.
Described anti redeposition agent includes, but are not limited to following compound: derivatived cellulose, as carboxymethyl cellulose, and Natvosol; Polyvinyl alcohol; Acrylate homopolymer, vinylformic acid/copolymer-maleic anhydride, the homopolymer of vinyl pyrrolidone and multipolymer, as Polyvinylpyrolidone (PVP), the multipolymer of NVP and N-vinyl imidazole.
Described inorganic salt can including but not limited to following compound: sodium carbonate, sodium-chlor, water glass, phosphoric acid salt, 4A zeolite and sodium sulfate.
Other components that the present invention relates to comprise viscosity modifier, organic salt, sanitas, tinting material, essence.Described viscosity modifier can including but not limited to following compound: inorganic salt, fatty alcohol, sizing material, polyacrylamide, fatty acid alcohol amides.Suitable example has sodium-chlor, xanthan gum, polyacrylamide derivative, cocoanut fatty acid diethanolamide.Described organic salt can include but not limited to following compound: Trisodium Citrate, disodium ethylene diamine tetraacetate.Described tinting material comprises dyestuff and pigment, can select the product in be applied in Betengent product, can including but not limited to acid blue 80, acid red G, directly indigo plant 86.
By technique scheme, compared with prior art, the application has following beneficial effect:
(1) cationic polymers selected by is excellent at fabric face film forming, colour fixation, increases gorgeous colored fabric with can work in coordination with after described white dyes compound, delays or prevent the xanthochromia of white fabrics;
(2) cationic polymers added and anionic white dyes electrostatic adhesion form the mixture of low water solubility, then are deposited on fabric face, effectively improve the utilization ratio of white dyes.When equivalent fluorescent brightener levels, the washing composition adding cationic polymers effectively can promote the whiteness conservation degree of fabric more than 7%.
Embodiment
Unless otherwise indicated, in detergent composition of the present invention, the accounting of each component is weight percentage, and the weight of listed each component is the content of active substance, does not comprise the solvent or by product that may contain in commercially available prod.
Table 1 embodiment 1-7 is the liquid washing agent embodiment of adding composite whitening agent, and not add cationic polymers for comparative example, after the washing of embodiment liquid washing agent, fabric whiteness all has obvious lifting, in table 2.Table 3 embodiment 8 is the powdered detergent embodiment of adding composite whitening agent, and not add cationic polymers for comparative example, after the washing of embodiment powdered detergent, fabric whiteness has obvious lifting, in table 4.
Retention of whiteness energy test experiments flow process is as follows: adopt rotary drum washing machine (two-power washing machine is enjoyed only by Haier) to carry out continuous several times washing to white fabrics, wash conditions is as follows: water temperature 30C, hardness 250 ppm, washing time 20 min, rinsing 2 times.Cloth specimen is dried with clothes drying machine after drying.After continuous washing 10 times, Datacolor 600 is adopted to measure the whiteness conservation degree of fabric.
The calculation formula of whiteness conservation degree is:
The calculation formula of whiteness conservation degree enhancing rate is:
Except as otherwise noted, all content is weight percentage, and the content of each composition is the content being converted into active substance, and trade(brand)name or the abbreviation of constituent part are as follows:
C14-S: cation guar gum, positive ion density is about 0.63 meq/g, Rhodia Products.
LK-400: cationic cellulose, positive ion density is about 0.2 meq/g, Dow Chemical Products.
CPAM: cationic polyacrylamide, positive ion density is about 0.1 meq/g.
LAS: Sodium dodecylbenzene sulfonate, anion surfactant.
AES: polyoxyethylenated alcohol sodium sulfate, fatty alcohol carbon number is 12-14, and oxyethylation degree is 2 ~ 3, anion surfactant.
AOS:a-sodium olefin sulfonate, anion surfactant.
AEO9: fatty alcohol-polyoxyethylene ether, average ethylene oxide degree is 9, nonionogenic tenside.
APG: sucrose polyester, nonionogenic tenside.
CAB: cocoamidopropyl betaine, zwitterionics.
BS-12: Varion CDG-K, zwitterionics.
1227: dodecyl benzyl dimethyl ammonium chloride, cats product.
CBS-X: white dyes, 4,4 '-bis-(2-sodium sulfonate styryl) biphenyl.
31#: white dyes, two triazinyl diphenyl ethylene derivatives.
Table 1 liquid washing agent embodiment proportioning
Table 2 embodiment 1-7 and comparative example wash rear fabric whiteness conservation degree
The wherein composition consisting of corresponding embodiment not cation-containing copolymer of comparative example.
Embodiment 8
Powdered detergent is configured according to table 3:
Table 3 embodiment 8 proportioning
Table 4 embodiment 8 and comparative example wash rear fabric whiteness conservation degree
The wherein composition consisting of corresponding embodiment not cation-containing copolymer of comparative example.
The above embodiment not does any pro forma restriction to the present invention, therefore everyly do not depart from technical solution of the present invention content, the any simple modification done above embodiment according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a compound whitening agent, it is characterized in that: comprise component (a) anionic white dyes and component (b) cationic polymers, and the weight ratio of described component (a) and described component (b) is 1:100-1:0.01, be preferably 1:50-1:0.02;
Described anionic white dyes is selected from stilbene biphenyl type white dyes, triazine radical amido stilbene type white dyes, two (1,2,3-triazole-2-base) in stilbene type white dyes, two (cumarone-2-base) biphenyl fluorescent whitening agent, 1,3-phenylbenzene-2-pyrazoline white dyes or coumarin type white dyes one or more;
The positive ion density of described cationic polymers is 0.01meq/g-1 meq/g, molecular weight is 20,000 Da-100 ten thousand Da.
2. compound whitening agent according to claim 1, is characterized in that: described cationic polymers be cationic cellulose, cation guar gum, cationic polyacrylamide one or more.
3. compound whitening agent according to claim 1 is in the application of washing composition, and described compound whitening agent is 0.02%-7% based on the weight fraction of the gross weight of described washing composition.
4. a detergent composition, is characterized in that: the following component comprising the weight fraction of the gross weight based on washing composition:
Compound whitening agent 0.02%-7%, anion surfactant 0.1%-30%, nonionogenic tenside 0.1%-30%, washing assistant 5%-80%, sanitas 0.02%-0.5%, essence 0.01%-0.5%, water surplus;
Described compound whitening agent comprises component (a) anionic white dyes and component (b) cationic polymers, and the weight ratio of described component (a) and described component (b) is 1:100-1:0.01, be preferably 1:50-1:0.02;
Described anionic white dyes is selected from stilbene biphenyl type white dyes, triazine radical amido stilbene type white dyes, two (1,2,3-triazole-2-base) in stilbene type white dyes, two (cumarone-2-base) biphenyl fluorescent whitening agent, 1,3-phenylbenzene-2-pyrazoline white dyes or coumarin type white dyes one or more;
The positive ion density of described cationic polymers is 0.01meq/g-1 meq/g, molecular weight is 20,000 Da-100 ten thousand Da.
5. detergent composition according to claim 4, is characterized in that: described anion surfactant be alkylbenzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, soap, a-alkene sulfonate, aliphatic alcohol polyethenoxy phosphoric acid salt, aliphatic alcohol polyethenoxy carboxylate salt one or more.
6. detergent composition according to claim 4, is characterized in that: described nonionogenic tenside be fatty alcohol-polyoxyethylene ether, alkyl glycoside, fatty acid alkyl amide, fatty acid alkyl ester Soxylat A 25-7, fatty acid methyl ester Soxylat A 25-7 one or more.
7. detergent composition according to claim 4, is characterized in that: also comprise the amphoterics of weight fraction less than 30% and/or the cats product of weight fraction less than 30%.
8. detergent composition according to claim 4, is characterized in that: described washing assistant comprises one or more of zymin, enzyme stabilising system, anti redeposition agent, bleaching assistant, inorganic salt and tinting material.
9. the detergent composition according to claim 4-8 any one, is characterized in that: its formulation is washing lotion, emulsion, Colloidal fluid, pulvis or blocks of solid.
10. the method for the preparation of the detergent composition in claim 4-8 described in any one, it is characterized in that: anionic white dyes, cationic polymers adopted pre-mixing or predissolve or the mode of directly adding to be fed in the preparation technology of detergent composition, wherein pre-composition, pre-molten thing or the input technique of directly adding are with independent to add anionic white dyes identical to the common process of composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510371617.9A CN105001671A (en) | 2015-06-29 | 2015-06-29 | Compound brightening agent and washing agent composition containing compound brightening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510371617.9A CN105001671A (en) | 2015-06-29 | 2015-06-29 | Compound brightening agent and washing agent composition containing compound brightening agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105001671A true CN105001671A (en) | 2015-10-28 |
Family
ID=54374549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510371617.9A Pending CN105001671A (en) | 2015-06-29 | 2015-06-29 | Compound brightening agent and washing agent composition containing compound brightening agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105001671A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105648760A (en) * | 2016-02-26 | 2016-06-08 | 苏州三和开泰花线织造有限公司 | Acid-resistant and alkali-resistant fluorescent whitening agent and preparation method thereof |
| WO2018107410A1 (en) * | 2016-12-15 | 2018-06-21 | Rhodia Operations | Composition for fabric treatment |
| CN111117801A (en) * | 2019-12-30 | 2020-05-08 | 广州大白生物科技有限公司 | Anti-cross-color laundry detergent and preparation method thereof |
| CN111589370A (en) * | 2020-05-27 | 2020-08-28 | 嵊州市天美助剂厂 | Dispersing agent for polyester fluorescent whitening agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1596299A (en) * | 2002-02-25 | 2005-03-16 | 西巴特殊化学品控股有限公司 | Process for the treatment of textile fibre materials |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
| WO2015042087A1 (en) * | 2013-09-18 | 2015-03-26 | The Procter & Gamble Company | Laundry care composition comprising carboxylate dye |
-
2015
- 2015-06-29 CN CN201510371617.9A patent/CN105001671A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1596299A (en) * | 2002-02-25 | 2005-03-16 | 西巴特殊化学品控股有限公司 | Process for the treatment of textile fibre materials |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
| WO2015042087A1 (en) * | 2013-09-18 | 2015-03-26 | The Procter & Gamble Company | Laundry care composition comprising carboxylate dye |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105648760A (en) * | 2016-02-26 | 2016-06-08 | 苏州三和开泰花线织造有限公司 | Acid-resistant and alkali-resistant fluorescent whitening agent and preparation method thereof |
| CN105648760B (en) * | 2016-02-26 | 2018-05-11 | 苏州三和开泰花线织造有限公司 | A kind of acid-fast alkali-proof fluorescent whitening agent and preparation method thereof |
| WO2018107410A1 (en) * | 2016-12-15 | 2018-06-21 | Rhodia Operations | Composition for fabric treatment |
| CN110088387A (en) * | 2016-12-15 | 2019-08-02 | 罗地亚经营管理公司 | Composition for fabric treating |
| CN111117801A (en) * | 2019-12-30 | 2020-05-08 | 广州大白生物科技有限公司 | Anti-cross-color laundry detergent and preparation method thereof |
| CN111589370A (en) * | 2020-05-27 | 2020-08-28 | 嵊州市天美助剂厂 | Dispersing agent for polyester fluorescent whitening agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2424793T3 (en) | Compositions for washing clothes | |
| CN102311891B (en) | Laundry detergent compositions with efficient hueing dye | |
| MXPA05002497A (en) | Structuring systems for fabric treatment compositions. | |
| CA2503144A1 (en) | Laundry detergent composition | |
| CN103917221A (en) | Surface treatment compositions including shielding salts | |
| US5500151A (en) | Heavy duty fabric softening laundry detergent composition | |
| CN102257109A (en) | Laundry detergent composition | |
| CN105001671A (en) | Compound brightening agent and washing agent composition containing compound brightening agent | |
| CN102453620A (en) | Multifunctional liquid laundry detergent | |
| CN103695187B (en) | Method for improving detergency of detergent composition under high-hardness water quality environment and detergent composition | |
| GB2200377A (en) | Protected additives for cleaning compositions | |
| CN105647678B (en) | Lift method and detergent composition of the cleaning compositions to albumen soil removal capabilities | |
| KR20010032541A (en) | Low-concentration highly viscous liquid detergents | |
| ES2393529T3 (en) | Laundry compositions | |
| CA2667135C (en) | Fabric treatment composition with a fabric substantive dye | |
| KR20010032542A (en) | Stable high viscosity liquid detergents | |
| CA2431979A1 (en) | Laundry detergent comprising highly ethoxylated nonionic surfactant | |
| EP1987123A1 (en) | Liquid whitening maintenance composition | |
| AU2005313875A1 (en) | Laundry detergent composition with mixed builder system | |
| EP2366009B1 (en) | Laundry compositions | |
| US20070203052A1 (en) | Laundry Composition | |
| KR20030011010A (en) | Liquid softeners | |
| EP0426906A1 (en) | Heavy duty fabric softening laundry detergent composition | |
| CN115717094A (en) | Washing powder composition capable of preventing cross-color and protecting color and preparation method thereof | |
| CA2001762A1 (en) | Heavy duty fabric softening laundry detergent compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151028 |