CN103865669A - Heavy-duty laundry detergent - Google Patents
Heavy-duty laundry detergent Download PDFInfo
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- CN103865669A CN103865669A CN201410055877.0A CN201410055877A CN103865669A CN 103865669 A CN103865669 A CN 103865669A CN 201410055877 A CN201410055877 A CN 201410055877A CN 103865669 A CN103865669 A CN 103865669A
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- sodium
- heavy
- washing powder
- duty
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- 239000003599 detergent Substances 0.000 title abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 paratoluenesulfonic acid sodium salt Chemical class 0.000 claims abstract description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 7
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 6
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 6
- 239000003240 coconut oil Substances 0.000 claims abstract description 6
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 6
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 6
- 238000007796 conventional method Methods 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 23
- 238000005406 washing Methods 0.000 claims description 23
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 claims description 10
- UXDAWVUDZLBBAM-UHFFFAOYSA-N n,n-diethylbenzeneacetamide Chemical compound CCN(CC)C(=O)CC1=CC=CC=C1 UXDAWVUDZLBBAM-UHFFFAOYSA-N 0.000 claims description 10
- YYXSCUSVVALMNW-FOWTUZBSSA-N pyriminostrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(NC=2C(=CC(Cl)=CC=2)Cl)=N1 YYXSCUSVVALMNW-FOWTUZBSSA-N 0.000 claims description 10
- 239000005897 Etoxazole Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 5
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003139 biocide Substances 0.000 claims 1
- 241000238876 Acari Species 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 3
- 239000008233 hard water Substances 0.000 abstract description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002401 inhibitory effect Effects 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 241001128004 Demodex Species 0.000 description 1
- 241000238713 Dermatophagoides farinae Species 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008029 eradication Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003129 miticidal effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a heavy-duty laundry detergent which is prepared from the following raw materials in parts by weight according to the conventional method: 20-30 parts of sodium dodecyl benzene sulfonate, 4-8 parts of coconut oil acid monoethanolamine, 8-12 parts of sodium silicate, 1-3 parts of paratoluenesulfonic acid sodium salt, 1-3 parts of sodium carboxymethylcellulose, 25-35 parts of sodium sulphate, 25-35 parts of sodium tripolyphosphate, 0.1-0.3 part of flourescent brightener and 4-8 parts of water. The heavy-duty laundry detergent disclosed by the invention is convenient to use, has strong detergency, resists hard water and does not damage cloth and is capable of effectively inhibiting and killing mites.
Description
Technical Field
The invention relates to washing powder, in particular to heavy-duty washing powder.
Background
The Washing powder, English Washing powder, synthetic detergent, uses surfactant as main component, and is matched with proper quantity of detergency builders with different functions. The washing powder is a powdery (granular) synthetic detergent.
After the 40 th century, with the development of chemical industry, people made detergents with better performance than soaps by using sodium dodecylbenzenesulfonate extracted from petroleum. Later, phosphate which can soften hard water and improve the decontamination effect of the detergent is added into the detergent, so that the performance of the detergent is more perfect. In order to facilitate use, carrying, storage, transportation and the like, people manufacture the detergent into the washing powder.
The washing powder can show good decontamination effect on well water, river water, tap water, spring water, even seawater and other water qualities, and is widely applied to various fabrics, so the production and the use of the washing powder are rapidly developed. At present, the washing powder is almost a necessary washing article for every family.
Disclosure of Invention
The heavy-duty washing powder is prepared from the following raw materials in parts by weight according to a conventional method: 20-30 parts of sodium dodecyl benzene sulfonate, 4-8 parts of coconut oil acyl monoethanolamine, 8-12 parts of sodium silicate, 1-3 parts of sodium p-toluenesulfonate, 1-3 parts of sodium carboxymethylcellulose, 25-35 parts of sodium sulfate, 25-35 parts of sodium tripolyphosphate, 0.1-0.3 part of fluorescent whitening agent and 4-8 parts of water.
Preferably, the first and second electrodes are formed of a metal,
the heavy-duty washing powder is prepared from the following raw materials in parts by weight according to a conventional method: 20-30 parts of sodium dodecyl benzene sulfonate, 4-8 parts of coconut oil acyl monoethanolamine, 8-12 parts of sodium silicate, 1-3 parts of sodium p-toluenesulfonate, 1-3 parts of sodium carboxymethylcellulose, 25-35 parts of sodium sulfate, 25-35 parts of sodium tripolyphosphate, 0.1-0.3 part of fluorescent whitening agent, 4-8 parts of water and 0.3-0.7 part of mite removing agent.
The mite removing agent is one or a mixture of N, N-diethyl-2-phenyl acetamide, pyriminostrobin and etoxazole.
Optimally, the mite removing agent consists of the following raw materials in percentage by weight: 50-70% of N, N-diethyl-2-phenyl acetamide, 10-30% of pyriminostrobin and 10-30% of etoxazole.
The heavy-duty washing powder can be prepared by adopting a spray drying method commonly used in the field.
Wherein,
cocoyl monoethanolamine, CAS No.: 68140-00-1, english name: amides, coco, N- (2-hydroxyethyl) -.
N, N-diethyl-2-phenylacetamide, CAS No.: 2431-96-1, English name: n, N-Diethyl-2-phenylacetamide; pyriminostrobin, english name, pyriminostrobin, CAS number: 1257598-43-8; etoxazole, english name: etoxazole, CAS number 153233-91-1.
The heavy-duty washing powder disclosed by the invention is convenient to use, strong in detergency, hard water-resistant, free from damaging cloth, and capable of effectively inhibiting and killing mites.
Detailed Description
Unless otherwise specified, the starting materials of the present invention are based on 100% by weight of the active ingredient content.
Examples 1 to 4
The raw materials were weighed out according to the components and contents specified in table 1 for the corresponding examples 1 to 4. And then the heavy-duty washing powder is prepared by adopting a spray drying method which is commonly used in the field.
Table 1: the formulation of the heavy-duty washing powder is as follows: kilogram (kilogram)
| Components | Example 1 | Example 2 | Example 3 | Example 4 |
| Sodium dodecyl benzene sulfonate | 25 | 25 | 25 | 25 |
| Coconut oil acyl monoethanolamine | 6 | 6 | 6 | 6 |
| Sodium silicate | 10 | 10 | 10 | 10 |
| Sodium p-toluenesulfonate | 2 | 2 | 2 | 2 |
| Sodium carboxymethylcellulose | 2 | 2 | 2 | 2 |
| Sodium sulfate | 30 | 30 | 30 | 30 |
| Sodium tripolyphosphate | 30 | 30 | 30 | 30 |
| Fluorescent whitening agent | 0.2 | 0.2 | 0.2 | 0.2 |
| Water (W) | 6 | 6 | 6 | 6 |
| N, N-diethyl-2-phenylacetamide | 0.3 | / | 0.3 | 0.3 |
| Pyriminostrobin | 0.1 | 0.25 | / | 0.2 |
| Etoxazole | 0.1 | 0.25 | 0.2 | / |
Test example 1 heavy-duty detergent powder mite-killing effect test
Detection conditions are as follows: the temperature is 20 plus or minus 1 ℃, and the relative humidity is 75 plus or minus 2 percent;
test insects: dust mites (Dermatophagoides farinae), male and female adults;
detecting an object: washing the heavy-duty detergent to be detected with water according to the weight ratio of 1: diluting at 50 concentration to 10mg/cm2The dosage of (A) is uniformly smeared on filter paper to be detected.
The detection method comprises the following steps:
placing filter paper coated with heavy-duty washing powder in a culture dish with diameter of about 9cm, smearing mixture of white oil and vaseline (1: 1) on the inner periphery of the culture dish to prevent mites from crawling out, placing a certain number of mites in the center of the culture dish, and counting the number N of tested mites1Allowing it to crawl freely. Immediately timing, placing the filter paper in a mite-feeding chamber, observing and recording the death number N of mites on the filter paper in 72 hours2。
Mite eradication rate = mite death number N2Test mite number N1×100%
The data are tested as shown in table 2 below.
Table 2: mite killing rate data table for heavy-duty washing powder
| A mite-killing rate of 72 hours% | |
| Example 1 | 54.8 |
| Example 2 | 42.6 |
| Example 3 | 52.3 |
| Example 4 | 51.4 |
As can be seen from the test data in the table 2, the acaricidal property is synergistic by compounding N, N-diethyl-2-phenylacetamide, pyriminostrobin and etoxazole.
Test example 2: skin irritation test of miticidal agent
Demodex (60 wt% N, N-diethyl-2-phenylacetamide, 20wt% pyriminostrobin and 20wt% etoxazole) for skin irritation test: two side hairs of the spinal column of 10 Japanese big ear standard laboratory rabbits were cut off, and gauze impregnated with a 1wt% mite-removing agent aqueous solution was applied to the exposed skin on the right side. No irritation symptoms such as erythema and edema appear after 24 hours of observation on the skin of the application part.
Claims (4)
1. The heavy-duty washing powder is prepared from the following raw materials in parts by weight according to a conventional method: 20-30 parts of sodium dodecyl benzene sulfonate, 4-8 parts of coconut oil acyl monoethanolamine, 8-12 parts of sodium silicate, 1-3 parts of sodium p-toluenesulfonate, 1-3 parts of sodium carboxymethylcellulose, 25-35 parts of sodium sulfate, 25-35 parts of sodium tripolyphosphate, 0.1-0.3 part of fluorescent whitening agent and 4-8 parts of water.
2. The heavy-duty washing powder is characterized by being prepared from the following raw materials in parts by weight according to a conventional method: 20-30 parts of sodium dodecyl benzene sulfonate, 4-8 parts of coconut oil acyl monoethanolamine, 8-12 parts of sodium silicate, 1-3 parts of sodium p-toluenesulfonate, 1-3 parts of sodium carboxymethylcellulose, 25-35 parts of sodium sulfate, 25-35 parts of sodium tripolyphosphate, 0.1-0.3 part of fluorescent whitening agent, 4-8 parts of water and 0.3-0.7 part of mite removing agent.
3. The heavy duty laundry powder of claim 2, wherein: the mite removing agent is one or a mixture of N, N-diethyl-2-phenyl acetamide, pyriminostrobin and etoxazole.
4. The heavy-duty washing powder according to claim 3, wherein the mite-killing agent comprises the following raw materials in percentage by weight: 50-70% of N, N-diethyl-2-phenyl acetamide, 10-30% of pyriminostrobin and 10-30% of etoxazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410055877.0A CN103865669A (en) | 2014-02-15 | 2014-02-15 | Heavy-duty laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410055877.0A CN103865669A (en) | 2014-02-15 | 2014-02-15 | Heavy-duty laundry detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103865669A true CN103865669A (en) | 2014-06-18 |
Family
ID=50904684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410055877.0A Withdrawn CN103865669A (en) | 2014-02-15 | 2014-02-15 | Heavy-duty laundry detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103865669A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893844A (en) * | 2015-05-18 | 2015-09-09 | 湖州江南恒盛炼染有限公司 | Novel peroxide-based bleaching washing powder used for colored fabrics and preparing method thereof |
| CN105670842A (en) * | 2014-11-21 | 2016-06-15 | 刘建华 | Composite washing soap and preparation method thereof |
| CN107236601A (en) * | 2017-07-06 | 2017-10-10 | 广西顺帆投资有限公司 | One kind removes acarid washing powder |
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|---|---|---|---|---|
| CN1477184A (en) * | 2002-08-20 | 2004-02-25 | 上海白猫有限公司 | Disinfectant sterilization washing powder and its production process |
| CN1836509A (en) * | 2005-03-25 | 2006-09-27 | 上海杜梆技术有限公司 | Use of N,N-diethylphenylacetamide compound in mite-resistance and bacteria-suppression |
| CN101368147A (en) * | 2008-09-03 | 2009-02-18 | 南风化工集团股份有限公司 | Neat soap washing powder and preparing technique thereof |
| CN102703266A (en) * | 2012-06-21 | 2012-10-03 | 南通顺阳化工有限公司 | Powder detergent for clothes |
| CN103045416A (en) * | 2012-12-17 | 2013-04-17 | 青岛天人环境股份有限公司 | Powder detergent |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
-
2014
- 2014-02-15 CN CN201410055877.0A patent/CN103865669A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477184A (en) * | 2002-08-20 | 2004-02-25 | 上海白猫有限公司 | Disinfectant sterilization washing powder and its production process |
| CN1836509A (en) * | 2005-03-25 | 2006-09-27 | 上海杜梆技术有限公司 | Use of N,N-diethylphenylacetamide compound in mite-resistance and bacteria-suppression |
| CN101368147A (en) * | 2008-09-03 | 2009-02-18 | 南风化工集团股份有限公司 | Neat soap washing powder and preparing technique thereof |
| CN102703266A (en) * | 2012-06-21 | 2012-10-03 | 南通顺阳化工有限公司 | Powder detergent for clothes |
| CN103045416A (en) * | 2012-12-17 | 2013-04-17 | 青岛天人环境股份有限公司 | Powder detergent |
| CN103355314A (en) * | 2013-08-02 | 2013-10-23 | 陕西上格之路生物科学有限公司 | Acaricidal composition containing pyriminostrobin and etoxazole |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670842A (en) * | 2014-11-21 | 2016-06-15 | 刘建华 | Composite washing soap and preparation method thereof |
| CN104893844A (en) * | 2015-05-18 | 2015-09-09 | 湖州江南恒盛炼染有限公司 | Novel peroxide-based bleaching washing powder used for colored fabrics and preparing method thereof |
| CN107236601A (en) * | 2017-07-06 | 2017-10-10 | 广西顺帆投资有限公司 | One kind removes acarid washing powder |
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Application publication date: 20140618 |