CN102876483A - Low-foam and easily bleachable laundry detergent composition and preparation method thereof - Google Patents
Low-foam and easily bleachable laundry detergent composition and preparation method thereof Download PDFInfo
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- CN102876483A CN102876483A CN2012103841847A CN201210384184A CN102876483A CN 102876483 A CN102876483 A CN 102876483A CN 2012103841847 A CN2012103841847 A CN 2012103841847A CN 201210384184 A CN201210384184 A CN 201210384184A CN 102876483 A CN102876483 A CN 102876483A
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Abstract
The invention discloses a low-foam and easily bleachable laundry detergent composition and a preparation method thereof. The laundry detergent composition is prepared by 0.1-20% of an unsaturated fatty acid, 0.1-50% of a saturated fatty acid, 0.1-5% of an alkali neutralizer, 1.0-25.0% of a nonionic surfactant, 1.0-25% of an anionic surfactant and 0.5-20% of other auxiliary agents and water. Due to the complex of the saturated fatty acid and the unsaturated fatty acid in the formula of the laundry detergent composition, the prepared laundry detergent composition reduces the washing foam content of the laundry detergent and solves the difficult bleaching problems of the laundry detergent in hand washing. The employed unsaturated fatty acid solves the difficult problem of poor low-temperature stability of a laundry detergent with high fatty acid content. The laundry detergent composition has the advantages of good detergency power, easily bleachable property, good stability, etc.
Description
Technical field
The present invention relates to a kind of washing liquid composition, belong to daily use chemicals cleaning product technical field, particularly relate to a kind of low bubble that has good stability and easily float type washing liquid composition and method of making the same.
Background technology
In China, along with the raising of living standards of the people, the human consumer more and more favors in using the good washing liquid of solvability.With respect to washing powder, washing liquid has the characteristics of gentleness, soluble, less energy-consumption.Washing liquid market keeps growing at top speed recent years always.Along with popularizing of washing liquid, its shortcoming also slowly found by the human consumer, wherein the easy shortcoming that generally reflects of the poor human consumer of being of floating property of hand washing.
The way that generally solves liquid washing agent rinsing difficulty in the industry is to add soap or silicone antifoam agent control foam in washing composition.A kind of low foam laundry liquid is disclosed such as CN 101372648, by 1 ~ 9 part of sodium laurate as defoamer; CN 10199379 discloses low foam laundry liquid, realizes low bubble by adding 1% ~ 2% C12 ~ C18 lipid acid sylvite or ammonium salt.Silicone antifoam agent is froth breaking fast, but can not improve easily floating property of washing liquid, and the washing liquid that adds the organosilicon prescription still has foam through rinsing repeatedly, and organosilicon stability in washing liquid also is a difficult problem generally acknowledged in the industry.
Salt of saturated fatty acid can reduce the foam of washing liquid significantly, also can to a certain degree improve easily floating property, but can not obtain the gratifying effect of easily floating in the situation that add mass percent in the soap less than 3%.(Krafft Point) is all higher in the Krafft's point of saturated fatty acid, and the increase along with carbochain, the linear rising in Krafft's point, Krafft's point such as the C12 sodium soap is 38 ℃, and C14 sodium soap Krafft's point is 58 ℃, and C18 sodium soap Krafft's point is 79 ℃, generally, if the interpolation mass percent of saturated soap is greater than 3% in washing liquid, its low-temperature stability is relatively poor, the phenomenon that soap is separated out can occur 0 ℃ of placement.
The unsaturated fatty acid salt especially Krafft's point of sylvite is lower, and the low-temperature stability in washing liquid is good, but easily the floating property of independent unsaturated fatty acid salt is relatively poor, can not solve the easily difficult problem of floating property of washing liquid.
Summary of the invention
The problem that exists in order to solve above-mentioned prior art, the object of the present invention is to provide a kind of new low bubble easily to float type washing liquid composition, by adopting unsaturated fatty acid salt can obviously improve the easily difficult problem of floating property of washing liquid with Salt of saturated fatty acid is composite, have simultaneously good low-temperature stability, and detersive power is good.
Another object of the present invention is to provide a kind of low bubble easily to float the preparation method of type washing liquid composition.
The objective of the invention is to realize by following technical proposals:
A kind of low bubble easily floats type washing liquid composition, is prepared by the component of following mass percent:
A kind of low bubble easily floats type washing liquid composition, also can be prepared by the component of following mass percent:
A kind of low bubble easily floats type washing liquid composition, can also be prepared by the component of following mass percent:
It mainly is to reduce the foam that produces in the washing liquid laundry processes that the present invention adopts unsaturated fatty acids and saturated fatty acid composite, solves the difficult problem that washing liquid is difficult to rinsing.
Described unsaturated fatty acids is that monounsaturated fatty acids is the series fatty acid of ω-9(Omega-9), multi-source is applicable to the non-limiting example of monounsaturated fatty acids of the present invention and comprises: C16:1 physetoleic acid, C18:1 oleic acid, C20:1 arachidonic acid, C22:1 sinapinic acid, C24:1 Selacholeic acid and arbitrary composition thereof in the natural animal-plant grease.Be fit to unsaturated fatty acids of the present invention and can be selected from commercially produced product, such as the Palmera A1813 of KLK company.
Described saturated fatty acid multi-source is applicable to the non-limiting example of saturated fatty acid of the present invention and comprises in the natural animal-plant grease: the positive certain herbaceous plants with big flowers acid of C10:0, C12:0 lauric acid, C14:0 tetradecanoic acid, C16:0 palmitinic acid, C17:0 pearly-lustre resin acid, C18:0 stearic acid, C20:0 eicosanoic acid, C22:0 behenic acid and arbitrary composition thereof.Be fit to saturated fatty acid of the present invention and can select commercially produced product, such as the hydrogenated coconut oleic acid of beneficial Hai Jiali.
Described alkali neutralizing agent is produced soap for neutralize above-mentioned saturated fatty acid and unsaturated fatty acids, is applicable to non-limiting example of the present invention and comprises: sodium hydroxide, potassium hydroxide, monoethanolamine, diethanolamine, trolamine and arbitrary composition thereof.
Described nonionogenic tenside is applicable to non-limiting example of the present invention and comprises:
1) fatty alcohol-polyoxyethylene ether of C12-C18, its oxyethyl group adduct number can be 9 or 7, preferred 7 can select BASF
The nonionogenic tenside of series or Shell Co. Ltd
Series non-ionic surfactants.
2) C12-C14 alkyl glycoside nonionogenic tenside.Can select Kening Co.,Ltd
The nonionogenic tenside of series.
3) condenses of C12-C18 alcohol and ethylene oxide/propylene oxide segmented copolymer, optional BASF AG
The nonionogenic tenside of PE series or the Tergitol of the Dow Chemical Company
TMSeries non-ionic surfactants.
4) C8-C20 branched-chain alcoho Soxylat A 25-7 nonionogenic tenside.Can select the ECOSURF of the Dow Chemical Company
TMThe nonionogenic tenside of EH series.
Described anion surfactant is applicable to non-limiting example of the present invention and comprises:
1) C11 ~ C18 alkylbenzene sulfonate (LAS);
2) C12 ~ C18 alkyl alkoxy sulfate (AES);
3) C14 ~ C18 fatty acid methyl ester sulfonate (MES);
Other auxiliary agents include but not limited to following several:
1) zymin
Described zymin can be any or the mixture more than the two in proteolytic enzyme, amylase, lipase, cellulase, peroxidase, the mannase; Preferred protease.
Enzyme used in the present invention can be selected the commerical prod on the market, such as Novozymes Company
The proteolytic enzyme of series, company of outstanding person's energy section
The proteolytic enzyme of series.
2) zymin stablizer
In order to make the zymin among the present invention stable in prescription, need in prescription, add the zymin stablizer.The zymin stablizer can be anyly can make that zymin is stable and with the good material of formula system compatibleness, it can be the above mixture of one or both of following material:
A) calcium ion or magnesium ion; Preferred calcium ion.Calcium ion plays an important role to the stability of zymin, its can with the active centre of proteolytic enzyme in conjunction with suppressing its activity.
B) derivative of borate or boric acid.
C) carboxylate salt of C1 ~ C4 is preferentially selected formate.
D) alcohol is such as propylene glycol, ethanol, sorbyl alcohol.Preferential propylene glycol and the ethanol selected.
3) sequestrant
Sequestrant used in the present invention mainly is to reduce calcium ion in the washing process, magnesium ion to washing the impact of detersive power.Available sequestrant has: alkali metal citrates, succsinic acid an alkali metal salt, organophosphate type sequestrant.
4) anti redeposition agent
The anti redeposition agent that the present invention was suitable for has: polyoxyethylene glycol, acrylate copolymer, vinylformic acid/maleic acid.Can select the commerical prod on the market, such as the CARBOWAX of the Dow Chemical Company
TMPEGS series product, the ACUSOL of the Dow Chemical Company
TMSeries product, BASF AG
Series product.
5) sanitas
Sanitas used in the present invention can adopt commerical prod commonly used in the industry, such as isothiazolinone sanitas, alcohols sanitas, formaldehyde release-type sanitas.
6) whitening agent
Whitening agent used in the present invention can use commercially produced product commonly used in the industry, such as the CBS-X of BASF AG, and the 31# whitening agent.
7) antioxidant
The present composition can comprise antioxidant, is used for improving the difficult problem of fatty acids washing composition high temperature xanthochromia.Being fit to antioxidant of the present invention can be selected from: 2,6 di tert butyl 4 methyl phenol (BHT), butylated hydroxy anisole (BHA), trimethoxybenzoic acid (TMBA), vitamin-E, Sorbic Acid and salt thereof, sulphite.
8) essence and pigment
The present invention can select suitable commercialization essence according to consumer survey research, selects suitable commercialization pigment to obtain different appearance colors according to investigation.
9) pH adjusting agent
For the pH value that makes composition of the present invention reaches predetermined scope, can adopt pH adjusting agent to regulate, the alkaline pH conditioning agent can use potassium hydroxide, sodium hydroxide, monoethanolamine, and acidic ph modifier can use citric acid, hydrochloric acid.
Above-mentioned low bubble easily floats the preparation method of type washing liquid composition, may further comprise the steps:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add the alkali neutralizing agent;
(3) add saturated fatty acid and unsaturated fatty acids in agitator kettle, the lipid acid that is stirred in the pot dissolves fully;
(4) in agitator kettle, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in agitator kettle, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) the pH value of reaction system is 7 ~ 9 in the adjusting agitator kettle;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again zymin, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
Advantage and beneficial effect that the present invention has are:
Adopt saturated fatty acid and the composite use of unsaturated fatty acids in the washing liquid composite formula of the present invention, effect is the foam that has reduced the washing liquid washing, has solved the difficult problem that the washing liquid hand washing is difficult to rinsing; Owing to adopting the unsaturated fatty acids acid constituents, having solved the poor difficult problem of high fatty acid content washing liquid low-temperature stability; In addition, washing liquid composition of the present invention also has the advantages such as good, the easy rinsing of detersive power, good stability.
Embodiment
Below in conjunction with specific embodiment and comparative example the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Comparative example 1
The present embodiment is comparative example, and what adopt is the prior art washing liquid, and component and the content of this washing liquid are as shown in table 1, and the preparation process of this washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) in agitator kettle, add hydrogenated coconut oleic acid;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) with citric acid/potassium hydroxide the pH value of system being transferred to is 7.0 ~ 9.0;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again zymin, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of the washing liquid of table 1 comparative example 1
| Material name | Addition (%) |
| C 11~C 13Alkylbenzene sulfonate | 4.0 |
| C 12~C 18Alkyl alkoxy (3EO) vitriol (AES) | 17.0 |
| C 12~C 14Fatty alcohol-polyoxyethylene ether (EO=7) | 6.5 |
| Trisodium Citrate | 4.0 |
| Hydrogenated coconut oleic acid (saturated fatty acid) | 1.0 |
| Potassium hydroxide | 0.26 |
| Citric acid/potassium hydroxide | The pH value transfers to 7.0 ~ 9.0 |
| Acusol 445N | 2.0 |
| Proteolytic enzyme | 0.5 |
| Amylase | 0.07 |
| Cellulase | 0.2 |
| Lipase | 0.05 |
| Mannase | 0.01 |
| BHT | 0.1 |
| Propylene glycol | 5.0 |
| Sodium Tetraborate | 2.0 |
| Calcium chloride | 0.02 |
| Whitening agent CBS-X | 0.1 |
| Sodium formiate | 3.0 |
| Essence | 0.4 |
| Sanitas (CMIT/MIT) | 0.2 |
| Deionized water | Surplus |
Comparative example 2
The composition of the washing liquid of this comparative example is as shown in table 2, and the preparation process of this washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) in agitator kettle, add hydrogenated coconut oleic acid;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) with citric acid/potassium hydroxide the pH value of system being transferred to is 7.0 ~ 9.0;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again enzyme, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of table 2 comparative example 2 washing liquids
| Material name | Addition (%) |
| C 11~C 13Alkylbenzene sulfonate | 4.0 |
| C 12~C 18Alkyl alkoxy (3EO) vitriol (AES) | 16.0 |
| C 12~C 14Fatty alcohol-polyoxyethylene ether (EO=7) | 6.0 |
| Trisodium Citrate | 4.0 |
| Hydrogenated coconut oleic acid (saturated fatty acid) | 4.0 |
| Potassium hydroxide | 1.1 |
| Citric acid/potassium hydroxide | The pH value transfers to 7.0 ~ 9.0 |
| Acusol 445N | 2.0 |
| Proteolytic enzyme | 0.5 |
| Amylase | 0.07 |
| Cellulase | 0.2 |
| Lipase | 0.05 |
| Mannase | 0.01 |
| BHT | 0.1 |
| Propylene glycol | 5.0 |
| Sodium Tetraborate | 2.0 |
| Calcium chloride | 0.02 |
| Whitening agent CBS-X | 0.1 |
| Sodium formiate | 3.0 |
| Essence | 0.4 |
| Sanitas (CMIT/MIT) | 0.2 |
| Deionized water | Surplus |
Comparative example 3
The composition of comparative example 3 washing liquids is as shown in table 3, and the preparation process of washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) add oleic acid in agitator kettle, the lipid acid that is stirred in the pot dissolves fully;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) regulate within the pH value to 7.0 of washing liquid in the agitator kettle ~ 9.0 scopes;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again enzyme, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of table 3 comparative example 3 washing liquids
Below be specific embodiments of the invention.
Embodiment 1
The composition of the embodiment of the invention 1 washing liquid is as shown in table 4, and the preparation process of washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) add hydrogenated coconut oleic acid and oleic acid in agitator kettle, the lipid acid that is stirred in the pot dissolves fully;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) regulate within the pH value to 7.0 of washing liquid in the agitator kettle ~ 9.0 scopes;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again enzyme, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of table 4 embodiment 1 washing liquid
Embodiment 2
The composition of the embodiment of the invention 2 washing liquids is as shown in table 5, and the preparation process of washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) add hydrogenated coconut oleic acid and oleic acid in agitator kettle, the lipid acid that is stirred in the pot dissolves fully;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) regulate within the pH value to 7.0 of washing liquid in the agitator kettle ~ 9.0 scopes;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again enzyme, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of table 5 embodiment 2 washing liquids
Embodiment 3
The composition of the embodiment of the invention 3 washing liquids is as shown in table 6, and the preparation process of washing liquid is as follows:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add potassium hydroxide;
(3) add hydrogenated coconut oleic acid and oleic acid in agitator kettle, the lipid acid that is stirred in the pot dissolves fully;
(4) in pot, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in pot, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) regulate within the pH value to 7.0 of washing liquid in the agitator kettle ~ 9.0 scopes;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again enzyme, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
The composition of table 6 embodiment 3 washing liquids
The performance evaluation of above-mentioned comparative example 1-3 and the obtained washing liquid composition of embodiment 1-3
Detergency evaluation
In order to verify the detersive power of washing liquid of the present invention, carry out detergency test.Adopt GB carbon black JB-01, GB albumen JB-02, GB sebum JB-03.Carry out specimen and be comparative example 1, comparative example 2, comparative example 3, embodiment 1,
Embodiment 2, embodiment 3 preparation-obtained washing liquids.
Experiment condition is: adopting 250ppm hard water, wash concentration is that 3g/L, washing time 20 minutes, temperature are 30 ℃, to adopt RQHL type Terg-O-Tometer, the rotating speed of GB regulation be 60 to turn.
Experimental result following (following result is the decontamination value with respect to standard washing powder):
The washing liquid detergency evaluation of table 7 comparative example 1-3 and embodiment 1-3
Can find out from the data of table 7, relatively example 3 uses the comprehensive detersive power of single oleic acid relatively poor, and embodiments of the invention 1, embodiment 2 and embodiment 3 adopt saturated fatty acid and the composite use of unsaturated fatty acids, and its comprehensive detersive power is better.
Estimation of stability
In order to verify the present invention's stability under various conditions, carried out 0 ℃ of low temperature and placed 1 month stability test, 45 ℃ and place 1 month stability test, freeze-thaw cycle test, cold cycling test.Carrying out specimen is comparative example 1, comparative example 2, comparative example 3, embodiment 1, embodiment 2, embodiment 3 preparation-obtained washing liquid compositions.
0 ℃ of stability test condition: 0 ℃ of cryostat was placed 1 month, recovered room temperature and observed;
45 ℃ of stability test conditions: 45 ℃ of thermostat containers were placed 1 month, recovered room temperature and observed;
Freeze-thaw cycle :-20 ℃ ~-15 ℃ cryostats were placed 24 hours, recovered room temperature and placed 24 hours, continued 3 circulations;
The cold cycling test :-20 ℃ ~-15 ℃ cryostats were placed 24 hours, were placed on 45 ℃ of baking ovens and placed 24 hours, continued 3 circulations.
The stability study test of table 8 comparative example 1-3 and embodiment 1-3
Can find out from table 8 test data, comparative example 2 all occurs unusual in 0 ℃ of stability test, freeze-thaw cycle test, cold cycling test, Precipitation is arranged, and adds the less stable of single saturated fatty acid.Without unusual, stability better by every test for comparative example 1, comparative example 3, embodiment 1, embodiment 2, embodiment 3.
STATIC FOAM is estimated
Adopt the Luo Shi Latherometer to test condition determination: temperature is 40 ℃, 150ppm hard water, and it is 2.5g/L that washing liquid is measured concentration, observes initial, 5 minutes, 10 minutes, 15 minutes foam heights.Carrying out specimen is comparative example 1, comparative example 2, comparative example 3, embodiment 1, embodiment 2, embodiment 3 preparation-obtained washing liquids.
The STATIC FOAM evaluation of table 9 comparative example 1-3, embodiment 1-3
| Initially (mm) | 5 minutes (mm) | 10 minutes (mm) | 15 minutes (mm) | |
| Comparative example 1 | 180 | 170 | 160 | 155 |
| Comparative example 2 | 140 | 120 | 100 | 50 |
| Comparative example 3 | 180 | 178 | 176 | 170 |
| Embodiment 1 | 135 | 90 | 50 | 20 |
| Embodiment 2 | 130 | 91 | 55 | 22 |
| Embodiment 3 | 129 | 89 | 54 | 20 |
Can see from the data of table 9, comparative example 3 contains the oleic acid of 5% weight, and initial foam is higher, and froth breaking speed is also slow, fails to reach low foaming effect.Comparative example 1 contains 1% hydrogenated coconut oleic acid, and initial foam is also higher, and embodiment 3 is fast for the froth breaking speed ratio, but 155mm height foam was still arranged after 15 minutes, and froth breaking belongs to slower level.Comparative example 2 contains 4% hydrogenated coconut oleic acid, and initial foam only has 140mm, and froth breaking speed is also very fast, only has 50mm after 15 minutes.
Embodiments of the invention 1 and embodiment 2, embodiment 3 employing saturated fatty acids and unsaturated fatty acids are composite, and initial foam is in minimum level, and froth breaking speed is the highest.
Hand washing relatively
Wash concentration is sample concentration 3g/L, and 150ppm hard water adopts white towel as the washing object, the mode of hand washing is washed, and towel twisting, adds 2L water and carries out rinsing after washing is finished, judge whether that by the bubbly water foam in the laundry basin rinsing is clean, record rinsing number of times.Carrying out specimen is Comparative Examples 1-3, the preparation-obtained washing liquid of embodiment 1-3.
The test of table 10 hand washing rinsing number of times
| The rinsing number of times | |
| Comparative example 1 | 3 |
| Comparative example 2 | 2 |
| Comparative example 3 | 3 |
| Embodiment 1 | 1 |
| Embodiment 2 | 1 |
| Embodiment 3 | 1 |
Can find out from the data of table 10, easily floating property is best in the hand washing of the embodiment 1-3 that employing saturated fatty acid and unsaturated fatty acids are composite, as long as it is clean to get final product rinsing 1 time.
Above-described embodiment is the better embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. a low bubble easily floats type washing liquid composition, it is characterized in that: be that component by following mass percent prepares:
Described other auxiliary agents comprise zymin, zymin stablizer, sequestrant, anti redeposition agent, sanitas, whitening agent, antioxidant, essence and pigment, reach pH adjusting agent.
2. low bubble according to claim 1 easily floats type washing liquid composition, it is characterized in that: be that component by following mass percent prepares:
Described other auxiliary agents comprise zymin, zymin stablizer, sequestrant, anti redeposition agent, sanitas, whitening agent, antioxidant, essence and pigment, reach pH adjusting agent.
3. low bubble according to claim 2 easily floats type washing liquid composition, it is characterized in that: be that component by following mass percent prepares:
Described other auxiliary agents comprise zymin, zymin stablizer, sequestrant, anti redeposition agent, sanitas, whitening agent, antioxidant, essence and pigment, reach pH adjusting agent.
4. each described low bubble easily floats type washing liquid composition according to claim 1-3, and it is characterized in that: described unsaturated fatty acids is selected from: any in C16:1 physetoleic acid, C18:1 oleic acid, C20:1 arachidonic acid, C22:1 sinapinic acid, the C24:1 Selacholeic acid or the mixture that the two is above.
5. each described low bubble easily floats type washing liquid composition according to claim 1-3, and it is characterized in that: described saturated fatty acid is selected from: any in the positive certain herbaceous plants with big flowers acid of C10:0, C12:0 lauric acid, C14:0 tetradecanoic acid, C16:0 palmitinic acid, C17:0 pearly-lustre resin acid, C18:0 stearic acid, C20:0 eicosanoic acid, the C22:0 behenic acid or the mixture that the two is above.
6. each described low bubble easily floats type washing liquid composition according to claim 1-3, it is characterized in that: described alkali neutralizing agent is selected from: any in sodium hydroxide, potassium hydroxide, monoethanolamine, diethanolamine, the trolamine or the mixture that the two is above.
7. each described low bubble easily floats type washing liquid composition according to claim 1-3, and it is characterized in that: described nonionogenic tenside is selected from: the fatty alcohol-polyoxyethylene ether of C12-C18, C12-C14 alkyl glycoside, C12-C18 alcohol and the condenses of ethylene oxide/propylene oxide segmented copolymer, any or the two above mixture in the C8-C20 branched-chain alcoho Soxylat A 25-7.
8. each described low bubble easily floats type washing liquid composition according to claim 1-3, and it is characterized in that: described anion surfactant is selected from: any in C11 ~ C18 alkylbenzene sulfonate (LAS), C12 ~ C18 alkyl alkoxy sulfate (AES), the C14 ~ C18 fatty acid methyl ester sulfonate (MES) or the mixture that the two is above.
9. each described low bubble easily floats type washing liquid composition according to claim 1-3, it is characterized in that: described zymin is the above mixture of any or the two in proteolytic enzyme, amylase, lipase, cellulase, peroxidase, the mannase;
Described zymin stablizer is the above mixture of any or the two in calcium ion, borate, formate, propylene glycol, ethanol, the sorbyl alcohol;
Described sequestrant is the above mixture of any or the two in alkali metal citrates, succsinic acid an alkali metal salt, the organophosphate type sequestrant;
Described anti redeposition agent is the above mixture of any or the two in polyoxyethylene glycol, acrylate copolymer, the vinylformic acid/maleic acid;
Described sanitas is the above mixture of any or the two in thiazoline ketone sanitas, alcohols sanitas, the formaldehyde release-type sanitas;
Described antioxidant is the above mixture of any or the two in 2,6 di tert butyl 4 methyl phenol (BHT), butylated hydroxy anisole (BHA), trimethoxybenzoic acid (TMBA), vitamin-E, Sorbic Acid and salt thereof, the sulphite.
10. the preparation method of each described washing liquid of claim 1-3 is characterized in that may further comprise the steps:
(1) in agitator kettle, adds deionized water, be heated to 50 ℃ ~ 60 ℃, start and stir;
(2) in agitator kettle, add the alkali neutralizing agent;
(3) add saturated fatty acid and unsaturated fatty acids in agitator kettle, the saturated fatty acid and the unsaturated fatty acids that are stirred in the pot dissolve fully;
(4) in agitator kettle, add anion surfactant, be stirred to anion surfactant and dissolve fully;
(5) in agitator kettle, add nonionogenic tenside, be stirred to nonionogenic tenside and dissolve fully;
(6) the pH value of reaction system is 7 ~ 9 in the adjusting agitator kettle;
(7) treat that temperature is down to below 45 ℃ in the agitator kettle, add again zymin, sequestrant, antioxidant, whitening agent, anti redeposition agent, sanitas, zymin stablizer, essence, stirred discharging 5 ~ 15 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103841847A CN102876483A (en) | 2012-10-11 | 2012-10-11 | Low-foam and easily bleachable laundry detergent composition and preparation method thereof |
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| CN103215143A (en) * | 2013-03-15 | 2013-07-24 | 金红叶纸业集团有限公司 | Cleaning composition and facial tissue using the same |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
| CN103305353A (en) * | 2013-05-08 | 2013-09-18 | 广州立白企业集团有限公司 | Heavy-duty greasy dirt detergent comprising wormlike micelle microstructures for kitchen and preparation method thereof |
| CN103320239A (en) * | 2013-07-11 | 2013-09-25 | 广州立白企业集团有限公司 | Methylisothiazolinone stabilizing system for liquid detergent |
| CN105154253A (en) * | 2015-10-09 | 2015-12-16 | 湖北穆兰同大科技有限公司 | Biological multienzyme cleaning agent and preparation method thereof |
| CN105296192A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Nano silver added powerful sterilizing and lasting bacteria-resisting laundry detergent and manufacturing method therefor |
| CN105886170A (en) * | 2014-12-12 | 2016-08-24 | 上海和黄白猫有限公司 | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof |
| CN105969536A (en) * | 2016-04-27 | 2016-09-28 | 苏智勇 | Fatty alcohol surfactant for preparing washing liquid and preparation method of fatty alcohol surfactant |
| CN106520410A (en) * | 2016-10-14 | 2017-03-22 | 无锡市华诚印染剂厂 | Water-soluble detergent capable of facilitating rinsing |
| CN106566686A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient and environment-friendly laundry detergent and preparation method thereof |
| CN106566680A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient laundry liquid and preparation method thereof |
| CN108130215A (en) * | 2017-12-28 | 2018-06-08 | 广州立白企业集团有限公司 | A kind of low-viscosity (mobile) liquid detergent composition with yield stress and preparation method thereof |
| CN109135954A (en) * | 2018-09-30 | 2019-01-04 | 北京洛娃日化有限公司 | A kind of environment-friendly high-efficiency liquid detergent |
| CN109706002A (en) * | 2018-12-28 | 2019-05-03 | 诺而曼环保科技（江苏）有限公司 | A kind of degradable aqueous cleaning agent and preparation method thereof |
| CN109897740A (en) * | 2019-03-21 | 2019-06-18 | 福建省纯杰绿色科技有限公司 | A kind of liquid detergent and preparation method thereof for hidrosis clothing |
| CN110452790A (en) * | 2019-08-27 | 2019-11-15 | 如皋市涤诺皂业有限公司 | A kind of Thief zone high activity object liquid detergent and preparation method thereof |
| CN110791391A (en) * | 2019-10-09 | 2020-02-14 | 上海柯灵展新化工有限公司 | Equipment pipeline deodorant and preparation method and application thereof |
| CN111040889A (en) * | 2018-10-15 | 2020-04-21 | 青岛海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN111269764A (en) * | 2020-02-28 | 2020-06-12 | 山东丽波日化股份有限公司 | Hand washing liquid detergent and preparation method thereof |
| CN111534388A (en) * | 2020-04-27 | 2020-08-14 | 北京金鱼科技有限责任公司 | Low-foam easy-to-bleach sterilization laundry detergent and preparation method thereof |
| CN115279877A (en) * | 2020-03-11 | 2022-11-01 | 联合利华知识产权控股有限公司 | Low foaming solid cleaning compositions |
| CN115368978A (en) * | 2022-06-30 | 2022-11-22 | 纳爱斯浙江科技有限公司 | Concentrated detergent with high-power dilution and thickening performance and preparation method thereof |
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| CN103215143A (en) * | 2013-03-15 | 2013-07-24 | 金红叶纸业集团有限公司 | Cleaning composition and facial tissue using the same |
| CN103305353A (en) * | 2013-05-08 | 2013-09-18 | 广州立白企业集团有限公司 | Heavy-duty greasy dirt detergent comprising wormlike micelle microstructures for kitchen and preparation method thereof |
| CN103305353B (en) * | 2013-05-08 | 2015-08-19 | 广州立白企业集团有限公司 | Heavy dirty grease dirt cleaning agent in a kind of kitchen containing vermiculate glues microtexture and preparation method thereof |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
| CN103275829B (en) * | 2013-06-17 | 2015-09-23 | 纳爱斯集团有限公司 | Not solvent-laden Superconcentrated washing liquid of one and preparation method thereof |
| CN103320239A (en) * | 2013-07-11 | 2013-09-25 | 广州立白企业集团有限公司 | Methylisothiazolinone stabilizing system for liquid detergent |
| CN103320239B (en) * | 2013-07-11 | 2014-12-24 | 广州立白企业集团有限公司 | Methylisothiazolinone stabilizing system for liquid detergent |
| CN105886170A (en) * | 2014-12-12 | 2016-08-24 | 上海和黄白猫有限公司 | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof |
| CN105154253A (en) * | 2015-10-09 | 2015-12-16 | 湖北穆兰同大科技有限公司 | Biological multienzyme cleaning agent and preparation method thereof |
| CN105296192A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Nano silver added powerful sterilizing and lasting bacteria-resisting laundry detergent and manufacturing method therefor |
| CN105969536A (en) * | 2016-04-27 | 2016-09-28 | 苏智勇 | Fatty alcohol surfactant for preparing washing liquid and preparation method of fatty alcohol surfactant |
| CN106566686A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient and environment-friendly laundry detergent and preparation method thereof |
| CN106566680A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient laundry liquid and preparation method thereof |
| CN106520410A (en) * | 2016-10-14 | 2017-03-22 | 无锡市华诚印染剂厂 | Water-soluble detergent capable of facilitating rinsing |
| CN108130215B (en) * | 2017-12-28 | 2020-03-24 | 广州立白企业集团有限公司 | Low-viscosity liquid detergent composition with yield stress and preparation method thereof |
| CN108130215A (en) * | 2017-12-28 | 2018-06-08 | 广州立白企业集团有限公司 | A kind of low-viscosity (mobile) liquid detergent composition with yield stress and preparation method thereof |
| CN109135954A (en) * | 2018-09-30 | 2019-01-04 | 北京洛娃日化有限公司 | A kind of environment-friendly high-efficiency liquid detergent |
| CN111040889A (en) * | 2018-10-15 | 2020-04-21 | 青岛海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN109706002A (en) * | 2018-12-28 | 2019-05-03 | 诺而曼环保科技（江苏）有限公司 | A kind of degradable aqueous cleaning agent and preparation method thereof |
| CN109897740A (en) * | 2019-03-21 | 2019-06-18 | 福建省纯杰绿色科技有限公司 | A kind of liquid detergent and preparation method thereof for hidrosis clothing |
| CN110452790A (en) * | 2019-08-27 | 2019-11-15 | 如皋市涤诺皂业有限公司 | A kind of Thief zone high activity object liquid detergent and preparation method thereof |
| CN110791391A (en) * | 2019-10-09 | 2020-02-14 | 上海柯灵展新化工有限公司 | Equipment pipeline deodorant and preparation method and application thereof |
| CN111269764A (en) * | 2020-02-28 | 2020-06-12 | 山东丽波日化股份有限公司 | Hand washing liquid detergent and preparation method thereof |
| CN115279877A (en) * | 2020-03-11 | 2022-11-01 | 联合利华知识产权控股有限公司 | Low foaming solid cleaning compositions |
| CN111534388A (en) * | 2020-04-27 | 2020-08-14 | 北京金鱼科技有限责任公司 | Low-foam easy-to-bleach sterilization laundry detergent and preparation method thereof |
| CN115368978A (en) * | 2022-06-30 | 2022-11-22 | 纳爱斯浙江科技有限公司 | Concentrated detergent with high-power dilution and thickening performance and preparation method thereof |
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