CN111040889A - Cleaning composition, application thereof and cleaning agent - Google Patents
Cleaning composition, application thereof and cleaning agent Download PDFInfo
- Publication number
- CN111040889A CN111040889A CN201811198188.XA CN201811198188A CN111040889A CN 111040889 A CN111040889 A CN 111040889A CN 201811198188 A CN201811198188 A CN 201811198188A CN 111040889 A CN111040889 A CN 111040889A
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- 239000000203 mixture Substances 0.000 title claims abstract description 64
- 238000004140 cleaning Methods 0.000 title claims abstract description 48
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 28
- 239000002738 chelating agent Substances 0.000 claims abstract description 27
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 27
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 19
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims description 43
- 239000000843 powder Substances 0.000 claims description 24
- -1 polydimethylsiloxane Polymers 0.000 claims description 19
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 102000004190 Enzymes Human genes 0.000 claims description 13
- 108090000790 Enzymes Proteins 0.000 claims description 13
- 229940088598 enzyme Drugs 0.000 claims description 13
- 238000009472 formulation Methods 0.000 claims description 9
- 239000003755 preservative agent Substances 0.000 claims description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- 239000004382 Amylase Substances 0.000 claims description 5
- 102000013142 Amylases Human genes 0.000 claims description 5
- 108010065511 Amylases Proteins 0.000 claims description 5
- 108010059892 Cellulase Proteins 0.000 claims description 5
- 102000004882 Lipase Human genes 0.000 claims description 5
- 239000004367 Lipase Substances 0.000 claims description 5
- 108090001060 Lipase Proteins 0.000 claims description 5
- 108091005804 Peptidases Proteins 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 229920002873 Polyethylenimine Polymers 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 235000019418 amylase Nutrition 0.000 claims description 5
- 229940106157 cellulase Drugs 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 235000019421 lipase Nutrition 0.000 claims description 5
- 239000003002 pH adjusting agent Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 4
- 239000003899 bactericide agent Substances 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 235000019419 proteases Nutrition 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 claims description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 3
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 3
- VKTHZHSHTVVWPN-UHFFFAOYSA-N [Na].[Na].[Na].[Na].[Na].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCNCCN Chemical compound [Na].[Na].[Na].[Na].[Na].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCNCCN VKTHZHSHTVVWPN-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000002781 deodorant agent Substances 0.000 claims description 3
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 229920000141 poly(maleic anhydride) Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 239000002674 ointment Substances 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 239000004034 viscosity adjusting agent Substances 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 abstract description 4
- 238000004383 yellowing Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 20
- 239000007921 spray Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- NHKHUHXMKHSOJT-UHFFFAOYSA-N 2-methyl-1,2-thiazolidin-4-one Chemical compound CN1CC(=O)CS1 NHKHUHXMKHSOJT-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the field of cleaning agents, and relates to a cleaning composition, application thereof and a cleaning agent, wherein the composition contains a chelating agent, a polymer containing a polyoxyethylene ether chain segment, a defoaming agent, a nonionic surfactant and an anionic surfactant, and relative to 100 parts by weight of the chelating agent, the content of the polymer containing the polyoxyethylene ether chain segment is 1-25 parts by weight, the content of the defoaming agent is 0.5-20 parts by weight, the content of the nonionic surfactant is 30-80 parts by weight, and the content of the anionic surfactant is 1-30 parts by weight. The cleaning composition provided by the invention can effectively remove various stains on shoes when being used for cleaning the shoes, and the shoes cleaned by using the cleaning composition provided by the invention do not have yellowing phenomenon.
Description
Technical Field
The invention belongs to the field of cleaning agents, and particularly relates to a cleaning composition, application thereof and a cleaning agent containing the cleaning composition.
Background
The currently marketed shoe washing powder and liquid for washing shoes have two main disadvantages: firstly, dirt on the shoes cannot be removed completely; and secondly, the shoes cleaned by the washing powder and the washing liquid sold in the market are obviously yellow.
In particular, as the living standard of people increases, a spray type shoe washing machine capable of automatically washing shoes has been marketed. The washing powder and the laundry detergent applied to the spray type shoe washing machine for automatically cleaning the shoes also have the two defects.
However, no shoe washing powder or liquid suitable for a spray type shoe washing machine in the prior art has been searched. Therefore, a new formulation is needed for cleaning shoes, especially for spraying type shoe washing machines.
Disclosure of Invention
The invention aims to overcome the defects that shoe washing powder and shoe washing liquid for cleaning shoes in the prior art cannot clean stains on the shoes and the shoes cleaned by applying the currently-sold washing powder and washing liquid are obviously yellow, and provides a novel cleaning agent formula suitable for cleaning the shoes.
The inventor of the present invention found that shoes cannot be cleaned on a spray type shoe washing machine by using commercially available washing powder or laundry detergent, mainly because:
1) the abundant foam hinders the scouring force of water flow to the shoes.
2) The washing powder and the formula of the washing liquid mainly aim at the stains such as blood stains, milk stains, fruit stains, sebum stains and the like of clothes, and the stains on shoes mainly comprise soil, carbon black and grass stains.
In addition, the inventor also finds that the shoes washed by the commercial washing powder are yellow, mainly because the washing powder usually contains alkaline components such as sodium silicate, sodium carbonate and the like, so that the pH value of the washing powder aqueous solution is 9-11 and becomes alkaline. After washing, these alkaline components remain on the surface of the shoe, and cause it to yellow.
In order to achieve the object of the present invention, a first aspect of the present invention provides a cleaning composition comprising a chelating agent, a polymer containing a polyoxyethylene ether segment, an antifoaming agent, a nonionic surfactant, and an anionic surfactant, wherein the polymer containing a polyoxyethylene ether segment is contained in an amount of 1 to 25 parts by weight, the antifoaming agent is contained in an amount of 0.5 to 20 parts by weight, the nonionic surfactant is contained in an amount of 30 to 80 parts by weight, and the anionic surfactant is contained in an amount of 1 to 30 parts by weight, based on 100 parts by weight of the chelating agent; and the polymer containing the polyoxyethylene ether segment is a polyethyleneimine polymer with the weight-average molecular weight of 2000-100000 and/or a polyethylene glycol polymer with the weight-average molecular weight of 100-10000; the chelating agent is at least one of citric acid, sodium citrate, ethylene diamine tetraacetic acid disodium, diethylenetriamine pentaacetic acid pentasodium, sodium tripolyphosphate, polyacrylic acid, sodium polyacrylate, polymethacrylic acid, polymaleic anhydride and fumaric acid-propylene sulfonic acid copolymer.
The inventors of the present invention have found that stains on the upper such as mud, specifically montmorillonite, are a 2:1 type layered aluminosilicate mineral composed of two silicon-oxygen tetrahedral sheets and one aluminum (magnesium) oxygen (hydroxyl) octahedral sheet sandwiched therebetween, and since Al substitutes for Si, there are excessive negative charges in the structure thereof, and therefore exchangeable cations such as Na +, Ca2+, Mg2+ and the like exist between the montmorillonite layers; the chelating agent in the composition of the invention can be combined with the cations in a complexing mode, so that the structure of soil is damaged, and the soil on the vamp is cleaned.
In addition, the polymer containing polyoxyethylene ether chain segments in the composition can accelerate the hydration of soil spots and expand the lamellar structure of soil by being adsorbed on the surface of soil particles, so that the aim of damaging the structure of the soil spots is fulfilled.
Moreover, the defoaming agent can reduce the amount of foam in the shoe washing process to the minimum; thereby the spraying force of the water flow is exerted to the maximum, and the shoe cleaning is facilitated.
A second aspect of the invention provides the use of a composition as described in the preceding first aspect for cleaning footwear.
A third aspect of the invention provides the use of a composition according to the first aspect as hereinbefore described in a spray-on shoe washing machine.
In a fourth aspect of the present invention, there is provided a cleaning agent comprising the composition for cleaning according to the first aspect of the present invention and an additive, wherein the additive is at least one of a solvent, a preservative, an aromatic agent, a deodorant, and a bactericide.
The cleaning composition provided by the invention can effectively remove various stains on shoes when being used for cleaning the shoes, and the shoes cleaned by using the cleaning composition provided by the invention do not have yellowing phenomenon.
Detailed Description
As described above, the first aspect of the present invention provides a cleaning composition comprising a chelating agent, a polymer containing a polyoxyethylene ether segment, an antifoaming agent, a nonionic surfactant, and an anionic surfactant, wherein the polymer containing a polyoxyethylene ether segment is contained in an amount of 1 to 25 parts by weight, the antifoaming agent is contained in an amount of 0.5 to 20 parts by weight, the nonionic surfactant is contained in an amount of 30 to 80 parts by weight, and the anionic surfactant is contained in an amount of 1 to 30 parts by weight, based on 100 parts by weight of the chelating agent; and the polymer containing the polyoxyethylene ether segment is a polyethyleneimine polymer with the weight-average molecular weight of 2000-100000 and/or a polyethylene glycol polymer with the weight-average molecular weight of 100-10000; the chelating agent is at least one of citric acid, sodium citrate, ethylene diamine tetraacetic acid disodium, diethylenetriamine pentaacetic acid pentasodium, sodium tripolyphosphate, polyacrylic acid, sodium polyacrylate, polymethacrylic acid, polymaleic anhydride and fumaric acid-propylene sulfonic acid copolymer.
The cleaning composition provided by the invention can effectively remove stains on the shoe upper when being used for cleaning shoes, particularly when being placed in a spray type shoe cleaning machine for cleaning the shoes, and the shoes cleaned by using the cleaning composition are tested to find that the reflectivity whiteness value of the shoes cleaned by using the cleaning composition is obviously higher than that of the shoes cleaned by using the cleaning composition in the prior art.
In order to make the reflectance whiteness value of the shoes washed using the washing composition of the present invention higher, that is, to make the soil-release effect of the washing composition of the present invention more excellent, according to a preferred embodiment, the polymer containing a polyoxyethylene ether segment is contained in the composition in an amount of 5 to 20 parts by weight, the antifoaming agent is contained in an amount of 5 to 20 parts by weight, the nonionic surfactant is contained in an amount of 35 to 60 parts by weight, and the anionic surfactant is contained in an amount of 10 to 18 parts by weight, relative to 100 parts by weight of the chelating agent.
In order to make the reflectance whiteness value of the shoes cleaned by the cleaning composition of the invention higher, that is, to make the decontamination effect of the cleaning composition of the invention better, preferably, the chelating agent is at least one of citric acid, sodium citrate, ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetate and pentasodium diethylenetriaminepentaacetate.
According to a preferred embodiment, the polyethyleneimine polymer has a repeating structural unit represented by the following formula (1),
in the formula (1), R is H or C1-20Alkoxy group of (2). More preferably, in formula (1), R is C2-12Alkoxy group of (2).
Preferably, the defoamer comprises at least one silicone-based defoamer.
Preferably, the silicone oil type defoaming agent is at least one selected from polydimethylsiloxane, fluorosilicone and polyethylene glycol siloxane. More preferably, the fluorosilicone is selected from at least one of poly (heptadecafluorodecyl) methylsiloxane, poly (nonafluorohexyl) siloxane, polymethyl (trifluoropropyl) siloxane, and polytetrafluoroethylene.
Preferably, the nonionic surfactant is selected from at least one of polyoxyethylene ether of EO/PO block of fatty alcohol, isooctanol polyoxyethylene ether, phosphate ester of isooctanol ether, ethoxylated derivative of fatty acid methyl ester.
According to a preferred embodiment, the anionic surfactant is at least one of alkyl benzene sulfonic acid, sodium alkyl benzene sulfonate, sodium alkyl sulfate and sodium fatty alcohol polyoxyethylene ether sulfate; particularly preferably, the anionic surfactant is at least one selected from the group consisting of dodecylbenzene sulfonic acid, sodium dodecylbenzene sulfonate and sodium lauryl sulfate.
According to a preferred embodiment, the composition further comprises a complex enzyme.
Preferably, the content of the complex enzyme is 0.01-1 part by weight relative to 100 parts by weight of the chelating agent.
Preferably, the complex enzyme contains at least two enzymes of protease, lipase, amylase and cellulase.
According to a preferred embodiment, the complex enzyme comprises protease, lipase, amylase and cellulase. More preferably, in the compound enzyme, the content weight ratio of the protease, the lipase, the amylase and the cellulase is 1: (0.1-10): (0.1-10): (0.1-10).
The present invention is not particularly limited in particular with respect to the types of protease, lipase, amylase and cellulase, and various enzymes having a cleaning function which are conventionally used in the art can be used.
According to a preferred embodiment, the composition of the invention further comprises a filler.
Preferably, the filler is contained in an amount of 100-300 parts by weight with respect to 100 parts by weight of the chelating agent.
Preferably, the filler is at least one of mirabilite, sodium chloride, 4A zeolite, and silica.
Preferably, the composition further comprises a viscosity regulator and/or a pH regulator. The invention has no special limitation on the type and specific dosage of the viscosity regulator, and a person skilled in the art can determine the appropriate type and dosage of the viscosity regulator according to actual needs. Also, the present invention is not particularly limited in kind and specific amount of the pH adjusting agent, and those skilled in the art can determine a suitable kind and a suitable amount of the pH adjusting agent according to actual needs, and the pH adjusting agent may be, for example, various acids or bases conventionally used in the art, such as hydrochloric acid, sulfuric acid, carbonic acid, citric acid, ethanolamine, sodium hydroxide, and the like.
As mentioned above, a second aspect of the invention provides the use of a composition according to the first aspect as hereinbefore described for cleaning footwear.
As mentioned above, a third aspect of the present invention provides the use of a composition according to the first aspect as described above in a spray-type shoe washing machine.
In particular, in the present invention, when the composition is applied to a spray type shoe washing machine, the composition of the present invention may be applied to pre-treat the surface of shoes, and then the pre-treated shoes are washed by the spray type shoe washing machine filled with the composition of the present invention.
As described above, the fourth aspect of the present invention provides a cleaning agent comprising the cleaning composition according to the first aspect of the present invention and an additive, wherein the additive is at least one of a solvent, a preservative, an aromatic, a deodorant, and a bactericide.
The present invention is not particularly limited with respect to the specific kinds of solvents, preservatives, fragrances, deodorizers, and bactericides, and substances conventionally used in the art can be used. For example, the solvent may be water, methanol, ethanol, propanol, propylene glycol, or the like; the preservative may be, for example, 2-methylisothiazolinone, 1, 2-benzisothiazolin-3-one, or the like.
According to a preferred embodiment, the cleaning composition is present in the cleaning agent in an amount of 5 to 50 wt.%.
Preferably, the formulation of the cleaning agent is at least one of solution, paste and powder.
Preferably, the cleaning agent of the present invention is a solution, and the pH of the solution is 4 to 8, more preferably 6 to 8.
The present invention is not particularly limited with respect to the specific preparation method of the solution, paste and powder of the cleanser, and those skilled in the art can prepare the cleanser of the present invention by the method of preparing the aforementioned formulation, which is conventionally used in the art.
For example, a solution can be prepared by dissolving a chelating agent in, for example, water, adding an appropriate amount of, for example, propylene glycol thereto, then adding thereto an antifoaming agent, a preservative, a polymer containing a polyoxyethylene ether segment, a nonionic surfactant and an anionic surfactant, and then adjusting the pH of the resulting solution to an appropriate value using a pH adjuster.
For example, when preparing a powder, a chelating agent may be added to a double-screw conical mixer, and the defoaming agent, the nonionic surfactant, and the anionic surfactant may be slowly introduced, stirred, and then subjected to shearing granulation by a swing granulator. The granules are sieved and the resulting granules are mixed with fillers and the like in a tumbler mixer.
Also, the preparation of solutions and powders is provided as an example in the examples of the present invention, and those skilled in the art should not be construed as limiting the invention.
Several specific examples are provided below to illustrate the technical solution of the present invention, and those skilled in the art should not be construed as limiting the scope of the technical solution of the present invention.
In the following examples, the various starting materials used are all commercially available without specific mention.
Plurafac LF224 used below was purchased from BASF corporation; dodecyl benzene sulfonic acid was purchased from Shanghai spectra materials chemical science and technology, Inc.; polyimine fatty alcohol polyoxyethylene ethers (trade name Sokalan HP96) available from BASF corporation; polymethyl (trifluoropropyl) siloxane was purchased from maireil chemical technology, inc; complex enzymes (Totalase KP0490) were purchased from Novozyme.
Example 1
This example was used to prepare cleaning solutions.
The formula is as follows:
dissolving a chelating agent in 300g of water, adding 10g of 1, 2-propylene glycol, uniformly stirring, adding a defoaming agent, a preservative, a polymer containing polyoxyethylene ether segments, a nonionic surfactant and an anionic surfactant, and adjusting the pH value of the obtained solution to 7.5 by using a pH regulator for later use.
Example 2
This example was used to prepare cleaning solutions.
The formula is as follows:
dissolving a chelating agent in 300g of water, adding 15g of ethanol, stirring uniformly, adding a defoaming agent, a preservative, a polymer containing polyoxyethylene ether chain segments, a nonionic surfactant and an anionic surfactant, and adjusting the pH value of the obtained solution to 8 by using a pH regulator for later use.
Example 3
This example was used to prepare a cleaning powder.
The formula is as follows:
adding sodium citrate into a double-helix conical mixer, slowly introducing a defoaming agent, a nonionic surfactant and an anionic surfactant, stirring for 10 minutes, and then shearing and granulating by using a swing granulator. And sieving the particles by a sieve with 10 meshes to obtain particles passing through the sieve with 10 meshes, returning the sieved large particles to the mixer to be mixed with the next pot again, and re-granulating. Mixing the above obtained granules with Natrii sulfas and complex enzyme in a drum mixer to obtain cleaning powder for use.
Example 4
This example refers to the formulation of example 1 except that the amount of the polymer having a polyoxyethylene ether segment used in this example was 2g, and the rest was the same as in example 1.
And a cleaning solution was prepared for use in the same manner as in example 1.
Example 5
This example refers to the formulation of example 1 except that the amount of the polymer having polyoxyethylene ether segments used in this example was 25g, and the rest was the same as in example 1.
And a cleaning solution was prepared for use in the same manner as in example 1.
Example 6
This example refers to the formulation of example 2 except that the amount of defoamer used in this example was 0.5g, which was the same as in example 2.
And a cleaning solution was prepared for use in the same manner as in example 2.
Example 7
This example refers to the formulation of example 1, except that the polymer containing polyoxyethylene ether segments in this example is polyethylene glycol 6000, and the rest is the same as in example 1.
And a cleaning solution was prepared for use in the same manner as in example 1.
Example 8
This example was conducted in accordance with the formulation of example 1 except that the chelating agent used in this example was sodium polyacrylate (Sokalan PA 25) obtained from BASF corporation, and the same as in example 1.
And a cleaning solution was prepared for use in the same manner as in example 1.
Comparative example 1
The laundry detergent is prepared by adopting a national standard laundry detergent (without a defoaming agent) purchased from Taiyuan daily chemical institute of China daily chemical research.
Comparative example 2
The washing powder is prepared by using national standard washing powder (without chelating agent) purchased from Taiyuan daily chemical institute of China daily chemical research.
Test example 1
The standard carbon black polluted cloth specified in appendix C of GB/T4288-2018 household and similar-purpose electric washing machines is cut into 60x60mm sample blocks, the sample blocks are sewn on the vamps of experimental shoes, the shoe washing liquid and the shoe washing powder in the embodiment and the comparative example of the invention are used for washing on a spray type shoe washing machine (XP10A) for 99 minutes, and then the national standard carbon black polluted cloth is taken down and dried. The reversed color was measured with a Hunter LAB Scan XE reflectance spectrophotometer and the stain removal performance of the formulated cleaning solutions and powders of the examples and comparative examples was evaluated using the resulting reflectance whiteness values. The resulting whiteness values were recorded and the results are shown in table 1.
Test example 2
Clean white shoes were used as experimental shoes, and the shoe washing liquids and the shoe washing powders of the examples and comparative examples of the present invention were used to wash the experimental shoes for 99 minutes in a spray type shoe washer (XP10A), and then the experimental shoes were removed, dried, left at room temperature for 3 days, and then observed with naked eyes to see whether the upper was yellow. The results are shown in table 1.
TABLE 1
| Sample source | Reflectance whiteness value | Whether it is yellow or not |
| Example 1 | 42.84 | Whether or not |
| Example 2 | 42.36 | Whether or not |
| Example 3 | 44.38 | Whether or not |
| Example 4 | 40.23 | Whether or not |
| Example 5 | 40.89 | Whether or not |
| Example 6 | 40.05 | Whether or not |
| Example 7 | 40.16 | Whether or not |
| Example 8 | 39.12 | Whether or not |
| Comparative example 1 | 30.03 | Whether or not |
| Comparative example 2 | 31.59 | Is that |
From the results of the invention, the cleaning agent provided by the invention can effectively remove stains, the reflectivity whiteness value of the cleaned shoe is obviously higher than that of the cleaned shoe by the cleaning agent in the prior art, and the cleaned shoe by the cleaning agent provided by the invention is not yellow.
Further, as can be seen from the results of comparing examples 4 and 5 of the present invention with example 1, the content of the polymer containing a polyoxyethylene ether segment is controlled within the preferable range of the present invention, and the reflectance whiteness value of the washed shoes of the cleaning agent obtained by matching the remaining technical features in the technical means of the present invention is higher.
Comparing the results of example 6 and example 2 of the present invention, it can be seen that the content of the antifoaming agent is controlled within the preferred range of the present invention, and the whiteness value of the reflectance of the washed shoes with the cleaning agent obtained by matching the remaining technical features of the technical solution of the present invention is higher.
In addition, as can be seen from the comparison of the results of example 8 and example 1 of the present invention, the reflectance whiteness value of the washed shoes with the detergent obtained by selecting the chelating agent type within the preferable range of the present invention and matching the remaining technical features in the technical means of the present invention is higher.
Therefore, the cleaning composition and the cleaning agent effectively solve the problem of excessive foam when washing powder and laundry detergent are used for washing shoes by a spray type shoe washing machine by selecting low-foam surfactant and defoaming agent, and the compounded formula can effectively remove various stains on the shoes.
Claims (14)
1. A cleaning composition comprising a chelating agent, a polymer containing a polyoxyethylene ether segment, an antifoaming agent, a nonionic surfactant and an anionic surfactant, wherein the content of the polymer containing a polyoxyethylene ether segment is 1 to 25 parts by weight, the content of the antifoaming agent is 0.5 to 20 parts by weight, the content of the nonionic surfactant is 30 to 80 parts by weight and the content of the anionic surfactant is 1 to 30 parts by weight, based on 100 parts by weight of the chelating agent; and the polymer containing the polyoxyethylene ether segment is a polyethyleneimine polymer with the weight-average molecular weight of 2000-100000 and/or a polyethylene glycol polymer with the weight-average molecular weight of 100-10000; the chelating agent is at least one of citric acid, sodium citrate, ethylene diamine tetraacetic acid disodium, diethylenetriamine pentaacetic acid pentasodium, sodium tripolyphosphate, polyacrylic acid, sodium polyacrylate, polymethacrylic acid, polymaleic anhydride and fumaric acid-propylene sulfonic acid copolymer.
2. The composition according to claim 1, wherein the polymer containing a polyoxyethylene ether segment is contained in an amount of 5 to 20 parts by weight, the antifoaming agent is contained in an amount of 5 to 20 parts by weight, the nonionic surfactant is contained in an amount of 35 to 60 parts by weight, and the anionic surfactant is contained in an amount of 10 to 18 parts by weight, relative to 100 parts by weight of the chelating agent.
3. The composition of claim 1 or 2, wherein the chelating agent is at least one of citric acid, sodium citrate, ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetate, and pentasodium diethylenetriaminepentaacetate.
4. The composition according to any one of claims 1 to 3, wherein the polyethyleneimine polymer has a repeating structural unit represented by the following formula (1),
in the formula (1), R is H or C1-20Alkoxy group of (a);
preferably, in formula (1), R is C2-12Alkoxy group of (2).
5. The composition of any of claims 1-4, wherein the defoamer comprises at least one silicone-based defoamer;
preferably, the silicone oil type defoaming agent is selected from at least one of polydimethylsiloxane, fluorosilicone, polyethylene glycol siloxane and polyether modified silicone;
preferably, the fluorosilicone is selected from at least one of poly (heptadecafluorodecyl) methylsiloxane, poly (nonafluorohexyl) siloxane, polymethyl (trifluoropropyl) siloxane, and polytetrafluoroethylene.
6. The composition according to any one of claims 1 to 5, wherein the nonionic surfactant is selected from at least one of polyoxyethylene ether of EO/PO block of fatty alcohol, isooctanol polyoxyethylene ether, phosphate ester of isooctanol ether, ethoxylated derivative of fatty acid methyl ester.
7. The composition of any one of claims 1-5, wherein the anionic surfactant is at least one of alkyl benzene sulfonic acid, sodium alkyl benzene sulfonate, sodium alkyl sulfate, and sodium fatty alcohol polyoxyethylene ether sulfate;
preferably, the anionic surfactant is selected from at least one of dodecylbenzene sulfonic acid, sodium dodecylbenzene sulfonate and sodium lauryl sulfate.
8. The composition according to any one of claims 1 to 5, wherein the composition further comprises a complex enzyme;
preferably, the content of the complex enzyme is 0.01-1 part by weight relative to 100 parts by weight of the chelating agent;
preferably, the complex enzyme contains at least two enzymes of protease, lipase, amylase and cellulase.
9. The composition of any of claims 1-5, further comprising a filler;
preferably, the filler is contained in an amount of 100-300 parts by weight relative to 100 parts by weight of the chelating agent;
preferably, the filler is at least one of salt cake, sodium chloride, 4A zeolite, and silica.
10. The composition according to any one of claims 1 to 5, wherein the composition further comprises a viscosity modifier and/or a pH modifier;
preferably, the pH of the composition is 4-8;
further preferably, the pH of the composition is 6-8.
11. Use of a composition according to any one of claims 1 to 10 for cleaning footwear.
12. Use of a composition according to any one of claims 1 to 10 in a spray-type shoe washing machine.
13. A cleaning agent comprising a cleaning composition according to any one of claims 1 to 10 and an additive selected from at least one of a solvent, a preservative, an aromatic, a deodorant and a bactericide;
preferably, the content of the cleaning composition in the cleaning agent is 5 to 50% by weight.
14. The cleanser of claim 12 or 13 wherein the formulation of said cleanser is at least one of a solution, an ointment and a powder.
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