CN105441211A - Compound softening agent and preparation method thereof - Google Patents
Compound softening agent and preparation method thereof Download PDFInfo
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- CN105441211A CN105441211A CN201510782080.5A CN201510782080A CN105441211A CN 105441211 A CN105441211 A CN 105441211A CN 201510782080 A CN201510782080 A CN 201510782080A CN 105441211 A CN105441211 A CN 105441211A
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- softening agent
- deionized water
- polydimethylsiloxane
- polyvinyl alcohol
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Abstract
The invention provides a compound softening agent. The compound softening agent comprises the following components in parts by weight: 20-40 parts of polydimethylsiloxane, 10-15 parts of fatty acid polyoxyethylene ether, 20-40 parts of polyethylene glycol, 3-5 parts of diisocyanate, 3-5 parts of dihexadecyl dimethyl ammonium chloride, 1-3 parts of citric acid, 2-5 parts of nano titanium dioxide, 10-15 parts of polyvinyl alcohol and 40-60 parts of deionized water. The compound softening agent provided by the invention is environment-friendly, safe, easily soluble, good in flexibility and strong in texture protecting and sterilizing capabilities, and the washing cost can be reduced; and by adopting the compound softening agent provided by the invention, time can be saved, water usage during washing can be saved, softening and sterilizing processes are completed in one step, and thus the energy can be saved.
Description
Technical field
The present invention relates to household chemicals field, particularly relate to a kind of softening agent.
Background technology
Present people wash clothes and generally use washing powder or washing liquid washing, anion surfactant is generally added with as sodium alkyl benzene sulfonate, AES, K-12 etc. in these washing powder, nonionogenic tenside is as AEO-9, TX-10 etc., also have some functional aids as citric acid, carbonate, EDTA, zeolite, anti redeposition agent etc., the PH of these washing powder is generally about 9, its degreasing power is very strong, the natural fats and oils of cotton fabric, wool can be removed.When repeated washing, micro fiber on cotton fabric ruptures and breaks, mechanical friction in washing process produces electrostatic, electrostatic makes the primitive fiber of exsiccation vertical with fiber, these primitive fibers, as one " overhead kick ", suppress the slip between Fiber-Fiber, disturb the flexibility of fiber, when fiber is coarse through skin sense of touch, the reason of clothes roughen in washing process that Here it is.
Along with the raising of people's quality of life, more and more higher to the requirement of daily necessities, require that cotton fabric is more soft better, it is equally soft gorgeous that washed after image is newly bought.At this moment softening agent is just applied and gives birth to.Softening agent is generally cats product.After washing powder washing, softening agent is added during rinsing, these softening agents by chemistry and physical adsorption on fabric, reduce accumulation of static electricity, improve the interaction between Fiber-Fiber, primitive fiber is lied down parallel with fibrous bundle, eliminate " overhead kick ", and by covering and lubricant fiber bundle, decreasing interfibrous friction, obtaining more soft, flexible fiber.Picture calcium soap, oil, clay and cats product, by above-mentioned mechanism, improve the feel of fiber.Because fiber itself is with negative charge, cats product precipitates efficiently and is adsorbed on fiber, even if under the condition of low dosage, also effectively can reduce the electrostatic of primitive fiber and interfibrous friction, after cats product process, minimum on the detersive efficiency impact of next time.In a word, add softening agent and there is following benefit: 1. improve fabric feeling; 2. usually contain essence in softening agent, have after making fabric washing clearly; 3. reduce the accumulation of static electricity of fabric, thus avoid the absorption of fabric to dust; 4. reduce the damage of machinery to fiber, be easy to flatiron, extend fabric life.
Summary of the invention
For the problems referred to above, the object of this invention is to provide composite softening agent that a kind of technique is simple, result of use is good and preparation method thereof.
Technical scheme of the present invention is as follows:
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20 ~ 40
Aliphatic acid polyethenoxy ether 10 ~ 15
Polyoxyethylene glycol 20 ~ 40
Vulcabond 3 ~ 5
Varisoft 432PPG 3 ~ 5
Citric acid 1 ~ 3
Nano titanium oxide 2 ~ 5
Polyvinyl alcohol 10 ~ 15
Deionized water 40 ~ 60.
Preferably, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20 ~ 25
Aliphatic acid polyethenoxy ether 10 ~ 15
Polyoxyethylene glycol 30 ~ 40
Vulcabond 3 ~ 5
Varisoft 432PPG 3 ~ 5
Citric acid 1 ~ 3
Nano titanium oxide 2 ~ 5
Polyvinyl alcohol 10 ~ 15
Deionized water 40 ~ 60.
Preferably, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 25
Aliphatic acid polyethenoxy ether 15
Polyoxyethylene glycol 40
Vulcabond 4
Varisoft 432PPG 5
Citric acid 3
Nano titanium oxide 2
Polyvinyl alcohol 10
Deionized water 40.
Preferably, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20
Aliphatic acid polyethenoxy ether 10
Polyoxyethylene glycol 35
Vulcabond 5
Varisoft 432PPG 5
Citric acid 2
Nano titanium oxide 4
Polyvinyl alcohol 15
Deionized water 60.
The preparation method of above-mentioned composite softening agent, comprise the steps: by ratio of weight and the number of copies, remove ionized water 40 ~ 60 parts, 60 DEG C ~ 80 DEG C are heated to by 60% ~ 70% of described deionized water, then the polydimethylsiloxane of 20 ~ 40 parts is added while stirring, the aliphatic acid polyethenoxy ether of 10 ~ 15 parts, the polyvinyl alcohol of the Varisoft 432PPG of 3 ~ 5 parts and 10 ~ 15 parts carries out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 20 ~ 40 parts is added, the vulcabond of 3 ~ 5 parts, the nano titanium oxide of 2 ~ 5 parts and residue deionized water, the citric acid of 1 ~ 3 part is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Polydimethylsiloxane in composite softening agent of the present invention is easy to concentrated on the interface of air, makes material have hydrophobic self-shield coating, can improve the antifouling antiscale of whole softening agent; Aliphatic acid polyethenoxy ether is a kind of nontoxic, non-stimulated, has good emulsifying, dispersiveness, water-soluble, soil release performance; Varisoft 432PPG is a kind of cats product, belongs to non oxidizing bactericide, has wide spectrum, efficiently sterilization algae removal ability, and has certain dispersion, osmosis, have certain deoiling and deodorizing capability simultaneously; Vulcabond can prevent clothing from turning yellow; Polyoxyethylene glycol has excellent oilness, moisture retention and dispersiveness; Between raw material in above-mentioned composite softening agent, mutual compatibility makes composite softening agent of the present invention have softness and sterilizing function concurrently simultaneously, Varisoft 432PPG wherein and polydimethylsiloxane and lipid acid polyoxy ether act synergistically mutually, make composite softening agent environmental protection of the present invention, safety, processable is good, flexibility is good, protection fabric, sterilizing power are strong, can reduce washing cost; Use composite softening agent of the present invention both can save time, can save again water consumption during washing, softness is degerming once to be completed, and can save the energy.
Embodiment
In order to make object, technical scheme and the advantage of composite softening agent of the present invention and preparation method thereof clearly understand, below in conjunction with specific embodiment, the present invention is further elaborated.
It should be noted that, when not conflicting, the embodiment in the application and the feature in embodiment can combine mutually.
The raw material used in following examples and equipment are commercially available medical grade raw material if not otherwise indicated.
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20 ~ 40
Aliphatic acid polyethenoxy ether 10 ~ 15
Polyoxyethylene glycol 20 ~ 40
Vulcabond 3 ~ 5
Varisoft 432PPG 3 ~ 5
Citric acid 1 ~ 3
Nano titanium oxide 2 ~ 5
Polyvinyl alcohol 10 ~ 15
Deionized water 40 ~ 60.
Be described below by way of specific embodiment.
Embodiment one
A kind of composite softening agent, comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20
Aliphatic acid polyethenoxy ether 10
Polyoxyethylene glycol 20
Vulcabond 3
Varisoft 432PPG 3
Citric acid 1
Nano titanium oxide 2
Polyvinyl alcohol 10
Deionized water 40.
Its preparation method is: remove ionized water 40g, 60 DEG C ~ 80 DEG C are heated to by 60% of described deionized water, then the polydimethylsiloxane of 20g is added while stirring, the aliphatic acid polyethenoxy ether of 10g, the Varisoft 432PPG of 3g and the polyvinyl alcohol of 10g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 20g is added, the vulcabond of 3g, the nano titanium oxide of 2g and residue deionized water, the citric acid of 1g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Embodiment two
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 40
Aliphatic acid polyethenoxy ether 15
Polyoxyethylene glycol 40
Vulcabond 5
Varisoft 432PPG 5
Citric acid 3
Nano titanium oxide 5
Polyvinyl alcohol 15
Deionized water 60.
Its preparation method is: remove ionized water 60g, 60 DEG C ~ 80 DEG C are heated to by 70% of described deionized water, then the polydimethylsiloxane of 40g is added while stirring, the aliphatic acid polyethenoxy ether of 15g, the Varisoft 432PPG of 5g and the polyvinyl alcohol of 15g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 40g is added, the vulcabond of 5g, the nano titanium oxide of 5g and residue deionized water, the citric acid of 3g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Embodiment three
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20
Aliphatic acid polyethenoxy ether 10
Polyoxyethylene glycol 30
Vulcabond 3
Varisoft 432PPG 3
Citric acid 1
Nano titanium oxide 2
Polyvinyl alcohol 10
Deionized water 40.
Its preparation method is: remove ionized water 40g, 60 DEG C ~ 80 DEG C are heated to by 70% of described deionized water, then the polydimethylsiloxane of 20g is added while stirring, the aliphatic acid polyethenoxy ether of 10g, the Varisoft 432PPG of 3g and the polyvinyl alcohol of 10g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 30g is added, the vulcabond of 3g, the nano titanium oxide of 2g and residue deionized water, the citric acid of 1g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Embodiment four
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 25
Aliphatic acid polyethenoxy ether 15
Polyoxyethylene glycol 40
Vulcabond 5
Varisoft 432PPG 5
Citric acid 3
Nano titanium oxide 5
Polyvinyl alcohol 15
Deionized water 60.
Its preparation method is: remove ionized water 60g, 60 DEG C ~ 80 DEG C are heated to by 70% of described deionized water, then the polydimethylsiloxane of 25g is added while stirring, the aliphatic acid polyethenoxy ether of 15g, the Varisoft 432PPG of 5g and the polyvinyl alcohol of 15g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 40g is added, the vulcabond of 5g, the nano titanium oxide of 5g and residue deionized water, the citric acid of 3g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Embodiment five
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 25
Aliphatic acid polyethenoxy ether 15
Polyoxyethylene glycol 40
Vulcabond 4
Varisoft 432PPG 5
Citric acid 3
Nano titanium oxide 2
Polyvinyl alcohol 10
Deionized water 40.
Its preparation method is: remove ionized water 40g, 60 DEG C ~ 80 DEG C are heated to by 60% of described deionized water, then the polydimethylsiloxane of 25g is added while stirring, the aliphatic acid polyethenoxy ether of 15g, the Varisoft 432PPG of 5g and the polyvinyl alcohol of 10g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 40g is added, the vulcabond of 4g, the nano titanium oxide of 2g and residue deionized water, the citric acid of 3g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Embodiment six
A kind of composite softening agent, it comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20
Aliphatic acid polyethenoxy ether 10
Polyoxyethylene glycol 35
Vulcabond 5
Varisoft 432PPG 5
Citric acid 2
Nano titanium oxide 4
Polyvinyl alcohol 15
Deionized water 60.
Its preparation method is: remove ionized water 60g, 60 DEG C ~ 80 DEG C are heated to by 60% of described deionized water, then the polydimethylsiloxane of 20g is added while stirring, the aliphatic acid polyethenoxy ether of 10g, the Varisoft 432PPG of 5g and the polyvinyl alcohol of 15g carry out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 35g is added, the vulcabond of 5g, the nano titanium oxide of 4g and residue deionized water, the citric acid of 2g is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claim.
Claims (5)
1. a composite softening agent, is characterized in that, comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20 ~ 40
Aliphatic acid polyethenoxy ether 10 ~ 15
Polyoxyethylene glycol 20 ~ 40
Vulcabond 3 ~ 5
Varisoft 432PPG 3 ~ 5
Citric acid 1 ~ 3
Nano titanium oxide 2 ~ 5
Polyvinyl alcohol 10 ~ 15
Deionized water 40 ~ 60.
2. composite softening agent according to claim 1, is characterized in that, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20 ~ 25
Aliphatic acid polyethenoxy ether 10 ~ 15
Polyoxyethylene glycol 30 ~ 40
Vulcabond 3 ~ 5
Varisoft 432PPG 3 ~ 5
Citric acid 1 ~ 3
Nano titanium oxide 2 ~ 5
Polyvinyl alcohol 10 ~ 15
Deionized water 40 ~ 60.
3. composite softening agent according to claim 2, is characterized in that, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 25
Aliphatic acid polyethenoxy ether 15
Polyoxyethylene glycol 40
Vulcabond 4
Varisoft 432PPG 5
Citric acid 3
Nano titanium oxide 2
Polyvinyl alcohol 10
Deionized water 40.
4. composite softening agent according to claim 2, is characterized in that, described composite softening agent comprises following component by ratio of weight and the number of copies:
Polydimethylsiloxane 20
Aliphatic acid polyethenoxy ether 10
Polyoxyethylene glycol 35
Vulcabond 5
Varisoft 432PPG 5
Citric acid 2
Nano titanium oxide 4
Polyvinyl alcohol 15
Deionized water 60.
5. the preparation method of a composite softening agent as claimed in claim 1, it is characterized in that, by ratio of weight and the number of copies, remove ionized water 40 ~ 60 parts, 60 DEG C ~ 80 DEG C are heated to by 60% ~ 70% of described deionized water, then the polydimethylsiloxane of 20 ~ 40 parts is added while stirring, the aliphatic acid polyethenoxy ether of 10 ~ 15 parts, the polyvinyl alcohol of the Varisoft 432PPG of 3 ~ 5 parts and 10 ~ 15 parts carries out ultrasonic disperse process after dissolving completely, be cooled to 35 DEG C ~ 45 DEG C, then the polyoxyethylene glycol of 20 ~ 40 parts is added, the vulcabond of 3 ~ 5 parts, the nano titanium oxide of 2 ~ 5 parts and residue deionized water, the citric acid of 1 ~ 3 part is added again after stirring, stir, leave standstill and can obtain described composite softening agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510782080.5A CN105441211A (en) | 2015-11-16 | 2015-11-16 | Compound softening agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510782080.5A CN105441211A (en) | 2015-11-16 | 2015-11-16 | Compound softening agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105441211A true CN105441211A (en) | 2016-03-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510782080.5A Pending CN105441211A (en) | 2015-11-16 | 2015-11-16 | Compound softening agent and preparation method thereof |
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| CN (1) | CN105441211A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385903A (en) * | 2018-10-26 | 2019-02-26 | 纳派化学(上海)有限公司 | A kind of Q sense softening agent |
| CN109705994A (en) * | 2018-12-25 | 2019-05-03 | 广东爱车小屋实业发展股份有限公司 | Decontamination fumet and preparation method thereof |
| CN111040889A (en) * | 2018-10-15 | 2020-04-21 | 青岛海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN112252040A (en) * | 2020-11-03 | 2021-01-22 | 上海锐鲨高新材料有限公司 | Antibacterial fluffy softening agent for fabric and preparation method thereof |
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| WO2011011247A1 (en) * | 2009-07-20 | 2011-01-27 | The Procter & Gamble Company | Liquid fabric enhancer composition comprising a di-hydrocarbyl complex |
| US8367601B2 (en) * | 2010-03-09 | 2013-02-05 | Ecolab Usa Inc. | Liquid concentrated fabric softener composition |
| CN103981697A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Static electricity-removed softening agent and preparation method thereof |
| CN104213402A (en) * | 2014-08-27 | 2014-12-17 | 无锡市奇盛针织手套厂 | Wool fabric softener and preparation method thereof |
| CN104562703A (en) * | 2015-02-09 | 2015-04-29 | 苏州陈恒织造有限公司 | Wool fabric softening agent as well as preparation method thereof |
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2015
- 2015-11-16 CN CN201510782080.5A patent/CN105441211A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011011247A1 (en) * | 2009-07-20 | 2011-01-27 | The Procter & Gamble Company | Liquid fabric enhancer composition comprising a di-hydrocarbyl complex |
| US8367601B2 (en) * | 2010-03-09 | 2013-02-05 | Ecolab Usa Inc. | Liquid concentrated fabric softener composition |
| CN103981697A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Static electricity-removed softening agent and preparation method thereof |
| CN104213402A (en) * | 2014-08-27 | 2014-12-17 | 无锡市奇盛针织手套厂 | Wool fabric softener and preparation method thereof |
| CN104562703A (en) * | 2015-02-09 | 2015-04-29 | 苏州陈恒织造有限公司 | Wool fabric softening agent as well as preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040889A (en) * | 2018-10-15 | 2020-04-21 | 青岛海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN111040889B (en) * | 2018-10-15 | 2022-04-12 | 重庆海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN109385903A (en) * | 2018-10-26 | 2019-02-26 | 纳派化学(上海)有限公司 | A kind of Q sense softening agent |
| CN109705994A (en) * | 2018-12-25 | 2019-05-03 | 广东爱车小屋实业发展股份有限公司 | Decontamination fumet and preparation method thereof |
| CN112252040A (en) * | 2020-11-03 | 2021-01-22 | 上海锐鲨高新材料有限公司 | Antibacterial fluffy softening agent for fabric and preparation method thereof |
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Application publication date: 20160330 |