CN102586039B - Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt - Google Patents
Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt Download PDFInfo
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- CN102586039B CN102586039B CN 201210009500 CN201210009500A CN102586039B CN 102586039 B CN102586039 B CN 102586039B CN 201210009500 CN201210009500 CN 201210009500 CN 201210009500 A CN201210009500 A CN 201210009500A CN 102586039 B CN102586039 B CN 102586039B
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Abstract
The invention provides a clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt. The clothes washing rinsing synergist containing the methyl sulfate-based quaternary ammonium salt consists of the following components in part by weight: 0.5-5 parts of polyethoxylated fatty alcohol, 0.5-4 parts of polyethoxylated heterogeneous fatty alcohol, 1-5 parts of citric acid, 5-15 parts of sodium citrate, 0.1-1 part of polydimethylsiloxane, 0.2-3 parts of distearate-ethoxyl-methyl-ammonium methyl sulfate, 0.1-3 parts of methyl-oleamide ethyl-oleic acid base-imidazoline ammonium methyl sulfate, 0.1-0.4 part of essence and 55-80 parts of neutral inorganic salt, wherein neutral inorganic salt is sodium sulfate, potassium sulfate, sodium chloride, potassium chloride, neutral sodium silicate and the like; and the clothes washing rinsing synergist containing the methyl sulfate-based quaternary ammonium salt is produced by the process for producing powdery washing powder.
Description
Technical field
The present invention relates to the daily chemical products field, specially refer to the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt.
Background technology
In the detergent washing clothings such as our every day use washing powder, washing liquid, often clean laundry because being eager, the amount ratio of washing composition is larger.Usually, we use washing powder or washing liquid at home with laundry washer clothes, sheet, quilt cover, can find that foam is quite a lot of.Press the old process washing of washing machine, often wash by rinse repeatedly, also have a lot of foams during dehydration, again rinse again.In the washing process of routine, eliminate foam, remove chemical residual, compliant fabric in the washing composition, all must adopt the washing post-processing technology of specialty.So, in the laundry of specialty, can take the method for specialty to solve these problems.
If the washing clothing do not clean up, also have a large amount of foams in the washings, prove that tensio-active agent and the washing assistant in the washing composition remains on the clothing in a large number, and have very strong basicity, clothing can become because alkalescence is residual jaundice, harden.Moreover, the chemical residual of these tensio-active agents and washing assistant is gone back Diazolidinyl Urea, can allow the people wear rear generation fash when serious.
Induction-arrangement, there are following defective in existing washing composition and washing synergy product:
1, residual chemicals on fabric.
Foam is too many when 2, cleaning, and is difficult to quick rinse.
3, wash rear clothing jaundice, hardening.
Summary of the invention
The object of the present invention is to provide a kind of laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt; to solve in daily life; behind the washing clothes such as washing powder, washing liquid, when cleaning, often can run into the problems such as foam hardens after being difficult to quick rinse, laundry too much.
For achieving the above object, technical scheme of the present invention is:
A kind of laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt is characterized in that: each ingredients weight parts component is in the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt:
Polyethoxylated Fatty Alcohol(C12-C14 and C12-C18) 0.5-5 part
Polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18) 0.5-4 part
Citric acid 1-5 part
Trisodium Citrate 5-15 part
Polydimethylsiloxane 0.1-1 part
Two stearyl-hydroxyethyls-methyl-sulfate methyl ammonium 0.2-3 part
Methyl-oleylamide ethyl-oleic acid base-tetrahydroglyoxaline sulfate methyl ammonium 0.1-3 part
Essence 0.1-0.4 part
Neutral inorganic 55-80 part.
Described neutral inorganic is sodium sulfate, vitriolate of tartar, sodium-chlor, Repone K, neutral sodium silicate etc.
Positively effect of the present invention is:
1, just can eliminate foam, quick rinse in the rinsing first time, eliminate chemical residual, prevent that the hair-weaving xanthochromia is hard, make fabric recover soft and fluffy.In laundry processes, for the first time during rinse, synergistic agent at first reduces the surface tension of washing lotion, and demineralized water, and can remove fast foam makes that laundry processes more saves time, water-saving, reaches the effect of quick washing.
2, this synergistic agent can also infiltrate into the fabric depths, removes the residual tensio-active agent of washing composition, and neutralization helps the residual alkali in the washing composition, residual chlorine, the minimizing chemical residual.
3, the special novel environment friendly positively charged ion softener that adds in this synergistic agent can avoid clothing to harden, and makes clothing more fluffy, soft.
4, the effect by synergistic agent, the order laundry is more convenient, really realizes eliminating that foam, neutralization are residual, compliant fabric, flavouring lasting once finish, and Bai Yigeng is white, color dress is more gorgeous, and delicate fragrance is pleasant, lasting is lasting.
Embodiment
Further specify the specific embodiment of the present invention below in conjunction with embodiment, each component is parts by weight of component among each embodiment.
Embodiment one
Get 0.5 part of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 1.5 parts of citric acids, 5 parts of Trisodium Citrates, 0.1 part of polydimethylsiloxane, two stearyl-hydroxyethyl-0.2 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.1 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.1 part in essence, 70 parts in sodium sulfate, 10 parts in sodium-chlor is by the laundry rinse synergistic agent of producing powdery washing powder explained hereafter and go out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment two
Get 2.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 1 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 2.5 parts of citric acids, 7 parts of Trisodium Citrates, 0.3 part of polydimethylsiloxane, two stearyl-hydroxyethyl-0.4 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.2 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.2 part in essence, 65 parts in sodium sulfate, 15 parts in Repone K is by the laundry rinse synergistic agent of producing powdery washing powder explained hereafter and go out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment three
Get 3 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 0.5 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of citric acids, 8 parts of Trisodium Citrates, 0.15 part of polydimethylsiloxane, two stearyl-hydroxyethyl-1 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.6 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.3 part in essence, 60 parts of vitriolate of tartar, 15 parts of vitriolate of tartar are by the laundry rinse synergistic agent of producing powdery washing powder explained hereafter and go out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment four
Get 2.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of citric acids, 9 parts of Trisodium Citrates, 0.5 part of polydimethylsiloxane, two stearyl-hydroxyethyl-0.8 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-2 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.3 part in essence, 65 parts of vitriolate of tartar, 10 parts of neutral sodium silicates are by the laundry rinse synergistic agent of producing powdery washing powder explained hereafter and go out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment five
Get 3 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 3 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 1 part of citric acid, 6 parts of Trisodium Citrates, 0.2 part of polydimethylsiloxane, two stearyl-hydroxyethyl-2 parts of methyl-sulfate methyl ammoniums, methyl-oleylamide ethyl-oleic acid base-1 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.3 part in essence, 20 parts in sodium sulfate, 40 parts in sodium-chlor, go out the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt by production powdery washing powder explained hereafter.
Embodiment six
Get 3.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 1 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of citric acids, 5 parts of Trisodium Citrates, 0.4 part of polydimethylsiloxane, two stearyl-hydroxyethyl-2.5 parts of methyl-sulfate methyl ammoniums, methyl-oleylamide ethyl-oleic acid base-2.5 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.3 part in essence, 50 parts in sodium sulfate, 5 parts of neutral sodium silicates, go out the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt by production powdery washing powder explained hereafter.
Embodiment seven
Get 20 parts of 1 part of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 4 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3 parts of citric acids, 10 parts of Trisodium Citrates, 0.5 part of polydimethylsiloxane, two stearyl-hydroxyethyl-0.8 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-2 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.4 part in essence, sodium sulfate 60, Repone K, by the laundry rinse synergistic agent of producing powdery washing powder explained hereafter and go out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment eight
Get 5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 5 parts of citric acids, 15 parts of Trisodium Citrates, 1 part of polydimethylsiloxane, two stearyl-hydroxyethyl-0.9 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-3 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.1 part in essence, 50 parts in sodium sulfate, 5 parts in Repone K, go out the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt by production powdery washing powder explained hereafter.
Example detection result
The above only is non-limiting embodiment of the present invention; for the person of ordinary skill of the art; not breaking away from the invention design and not making under the prerequisite of creative work, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (2)
1. the laundry rinse synergistic agent of a sulfur acid methoxycarbonyl quaternary ammonium salt, it is characterized in that: the weight part of each component is in the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt:
Polyethoxylated Fatty Alcohol(C12-C14 and C12-C18) 0.5-5 part
Polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18) 0.5-4 part
Citric acid 1-5 part
Trisodium Citrate 5-15 part
Polydimethylsiloxane 0.1-1 part
Two stearyl-hydroxyethyls-methyl-sulfate methyl ammonium 0.2-3 part
Methyl-oleylamide ethyl-oleic acid base-tetrahydroglyoxaline sulfate methyl ammonium 0.1-3 part
Essence 0.1-0.4 part
Neutral inorganic 55-80 part.
2. the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt according to claim 1, it is characterized in that: described neutral inorganic is sodium sulfate, vitriolate of tartar, sodium-chlor, Repone K, neutral sodium silicate.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201210009500 CN102586039B (en) | 2012-01-13 | 2012-01-13 | Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210009500 CN102586039B (en) | 2012-01-13 | 2012-01-13 | Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt |
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| CN102586039A CN102586039A (en) | 2012-07-18 |
| CN102586039B true CN102586039B (en) | 2013-02-13 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6249424B2 (en) * | 2015-06-30 | 2017-12-20 | 花王株式会社 | Powder cleaning composition for clothing |
| CN111040889B (en) * | 2018-10-15 | 2022-04-12 | 重庆海尔洗衣机有限公司 | Cleaning composition, application thereof and cleaning agent |
| CN110467971A (en) * | 2019-08-30 | 2019-11-19 | 广州市拓瑞科技有限公司 | A kind of environmentally protective sterilizing waterless nano liquid detergent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225670A (en) * | 1996-05-17 | 1999-08-11 | 普罗格特-甘布尔公司 | Detergent composition |
| CN101812381A (en) * | 2009-06-08 | 2010-08-25 | 广州立白企业集团有限公司 | Washing and softening laundry detergent composition |
| CN101935949A (en) * | 2010-08-27 | 2011-01-05 | 上海制皂有限公司 | Clothes softener |
| CN102002445A (en) * | 2010-11-30 | 2011-04-06 | 广州星业科技股份有限公司 | Washing powder and soap powder viscosity reduction synergist |
| CN102230278A (en) * | 2011-06-07 | 2011-11-02 | 廊坊乐万家联合家化有限公司 | Concentrated fabric softener and preparation method thereof |
-
2012
- 2012-01-13 CN CN 201210009500 patent/CN102586039B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225670A (en) * | 1996-05-17 | 1999-08-11 | 普罗格特-甘布尔公司 | Detergent composition |
| CN101812381A (en) * | 2009-06-08 | 2010-08-25 | 广州立白企业集团有限公司 | Washing and softening laundry detergent composition |
| CN101935949A (en) * | 2010-08-27 | 2011-01-05 | 上海制皂有限公司 | Clothes softener |
| CN102002445A (en) * | 2010-11-30 | 2011-04-06 | 广州星业科技股份有限公司 | Washing powder and soap powder viscosity reduction synergist |
| CN102230278A (en) * | 2011-06-07 | 2011-11-02 | 廊坊乐万家联合家化有限公司 | Concentrated fabric softener and preparation method thereof |
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