JP2018184606A - Cleaning agent - Google Patents
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- JP2018184606A JP2018184606A JP2018122090A JP2018122090A JP2018184606A JP 2018184606 A JP2018184606 A JP 2018184606A JP 2018122090 A JP2018122090 A JP 2018122090A JP 2018122090 A JP2018122090 A JP 2018122090A JP 2018184606 A JP2018184606 A JP 2018184606A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/164—Organic compounds containing a carbon-carbon triple bond
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
Description
本発明は、請求項１の序文に記載の洗浄剤に関する。 The present invention relates to a cleaning agent according to the preamble of claim 1.
本発明の目的は、耐水性の、特に非繊維表面の洗浄に使用したとき、改善された洗浄作用を示し、最適な結果を実現する洗浄剤を提供することである。さらなる目的は、洗浄機での使用に最適である洗浄剤を提供することである。 It is an object of the present invention to provide a cleaning agent that exhibits improved cleaning action and achieves optimum results when used for cleaning water resistant, especially non-fiber surfaces. A further object is to provide a cleaning agent that is optimal for use in a cleaning machine.
本発明の目的は、請求項１に記載の特徴を有する洗浄剤で達成される。 The object of the invention is achieved with a cleaning agent having the features of claim 1.
繊維製品の伝統的な洗浄方法とは対照的に、本発明による洗浄剤の作用様式は、界面活性剤による汚れの乳化の原理に基づくよりも、むしろ２つの洗浄技術の組合せからなるものである。使用する湿潤剤により、水で希釈した洗浄剤の表面張力がごく短時間（１秒未満）で３０ｍＮ／ｍ未満（室温で測定）に低下し、その結果、洗浄の機械的強度と組み合わさった洗浄水溶液が洗浄液中に汚れ粒子を懸濁させることを可能にする。再沈着防止剤との組合せにより、汚れ粒子は懸濁液中に保持され、再沈着を妨げる。 In contrast to traditional cleaning methods for textile products, the mode of action of the cleaning agent according to the present invention consists of a combination of two cleaning techniques rather than based on the principle of emulsification of soils with surfactants. . The wetting agent used reduced the surface tension of the cleaning agent diluted with water to less than 30 mN / m (measured at room temperature) in a very short time (less than 1 second), resulting in a combination with the mechanical strength of the cleaning. The aqueous cleaning solution allows the dirt particles to be suspended in the cleaning solution. In combination with the anti-redeposition agent, the dirt particles are retained in the suspension and prevent re-deposition.
乳化剤は、低水溶性湿潤剤の洗浄液中での急速で均一な分布の実現を可能にし、驚くべきことに強力に改善された乳化効果を付与する。このように懸濁した弱く負に帯電した汚れ粒子は、中和されたポリアスパラギン酸の負電荷により懸濁液中に電気立体的に保持される。ポリアスパラギン酸の繊維洗浄液での公知の使用とは対照的に、ポリアスパラギン酸は、ここでは、存在するＣａ２＋イオンへの結合のために用いられるのではなく、むしろ負に帯電した汚れ粒子の同様に負に帯電した長鎖分子による電気立体的反発のために用いられる。 The emulsifier makes it possible to achieve a rapid and uniform distribution of the low water-soluble wetting agent in the wash liquor and surprisingly provides a strongly improved emulsifying effect. The weakly negatively charged soil particles suspended in this way are electrosterically retained in the suspension by the negative charge of the neutralized polyaspartic acid. In contrast to the known use of polyaspartic acid in textile washing solutions, polyaspartic acid is not used here for binding to existing Ca 2+ ions, but rather of negatively charged soil particles. Similarly, it is used for electrosteric repulsion by negatively charged long chain molecules.
本発明により得られる利点は、本質的に以下の通りである。 The advantages obtained by the present invention are essentially as follows.
・負に帯電した汚れ粒子が電気立体的に反発されること、
・過剰量の水和した負に帯電した錯形成剤画分により、主として負に帯電することが経験上知られている汚れ粒子に対して、相互反発力が働くこと、
・溶液が、極めて良好な再沈着防止作用を有すること、
・驚くべきことに、本発明による洗浄剤には強力に改善された乳化能力があり、これは乳化剤の相乗効果に起因すること、および
・高発泡性界面活性剤を使用しないため、消泡剤を不要にできること。
-Negatively charged dirt particles are repelled electrosterically,
A mutual repulsive force acts on dirt particles, which are known to be negatively charged primarily by experience, due to an excessive amount of hydrated negatively charged complexing agent fraction,
The solution has a very good anti-redeposition effect;
Surprisingly, the cleaning agent according to the present invention has a strongly improved emulsifying capacity, which is due to the synergistic effect of the emulsifier, and because no high foaming surfactant is used, an antifoaming agent Can be made unnecessary.
本発明のさらに有利な実施形態は以下のように示すことができる。 Further advantageous embodiments of the invention can be shown as follows.
負に帯電した有機高分子は、有利にはポリマー再沈着防止剤であり、以下の物質部類：アミノポリカルボキシレート、有機ホスホネート、ポリカルボキシレートまたはこれらのコポリマーから選択できる。特に、少なくとも１つの負に帯電した有機高分子は、ポリアスパラギン酸またはこの水溶性塩であってよい。 The negatively charged organic polymer is advantageously a polymer re-deposition inhibitor and can be selected from the following substance classes: aminopolycarboxylates, organic phosphonates, polycarboxylates or copolymers thereof. In particular, the at least one negatively charged organic polymer may be polyaspartic acid or a water-soluble salt thereof.
負に帯電した有機高分子は、好ましくは分子量４，０００から６，０００のポリアクリレート、例えば、アクリルホモポリマーであってもよい。 The negatively charged organic polymer may be a polyacrylate, preferably an acrylic homopolymer, preferably having a molecular weight of 4,000 to 6,000.
非イオン性湿潤剤は、アセチルジオール、好ましくはアルコキシル化アセチルジオールであってよく、アニオン性湿潤剤は、アニオン性パーフルオロアルキルポリマーまたはアルキルスルホスクシネートであってよく、カチオン性湿潤剤は、カチオン性パーフルオロアルキルコポリマーであってよく、両性湿潤剤は、アルキルアミドプロピルベタインであってよい。湿潤剤は、１つ以上のエトキシル化アセチルジオールを含むこともできる。 The non-ionic wetting agent may be an acetyl diol, preferably an alkoxylated acetyl diol, the anionic wetting agent may be an anionic perfluoroalkyl polymer or an alkyl sulfosuccinate, and the cationic wetting agent is It can be a cationic perfluoroalkyl copolymer and the amphoteric wetting agent can be an alkylamidopropyl betaine. The wetting agent can also include one or more ethoxylated acetyldiols.
非イオン性乳化剤は、脂肪アルコールアルコキシレートの群から選択でき、アニオン性乳化剤は、アルキルスルフェートまたはアルキルエーテルスルフェートの群から選択でき、カチオン性乳化剤は、第４級アンモニウム化合物の群から選択でき、両性乳化剤は、ベタインおよびスルタインの群から選択できる。乳化剤は、１つ以上の好ましくは分岐のエトキシル化脂肪アルコールも含むことができる。 The nonionic emulsifier can be selected from the group of fatty alcohol alkoxylates, the anionic emulsifier can be selected from the group of alkyl sulfates or alkyl ether sulfates, and the cationic emulsifier can be selected from the group of quaternary ammonium compounds. The amphoteric emulsifier can be selected from the group of betaines and sultaines. The emulsifier may also contain one or more preferably branched ethoxylated fatty alcohols.
ポリアスパラギン酸（またはこの塩）は、好ましくは平均分子量１０００から１０，０００ｇ／ｍｏｌを有し、好ましくは２０００から３０００ｇ／ｍｏｌを有する。 The polyaspartic acid (or salt thereof) preferably has an average molecular weight of 1000 to 10,000 g / mol, preferably 2000 to 3000 g / mol.
適切には、粒子形態で存在する、少なくとも１つの負に帯電した有機高分子および好ましくは少なくとも１つのポリアスパラギン酸またはこの水溶性塩の粒径分布Ｄ５０は、０．１ｍｍである。０．０７ｍｍまたはさらに０．０１ｍｍの粒径分布Ｄ５０は、特に良好な結果をもたらす。 Suitably, the particle size distribution D50 of the at least one negatively charged organic polymer and preferably at least one polyaspartic acid or its water-soluble salt present in particulate form is 0.1 mm. A particle size distribution D50 of 0.07 mm or even 0.01 mm gives particularly good results.
洗浄剤は、好ましくは貯蔵を簡便にする顆粒またはタブレットの形態で用いられる。タブレットは、少なくとも１ｃｍ３、好ましくは少なくとも５ｃｍ３の体積を適切には有する。体積は、適切には１００ｃｍ３以下、好ましくは１２ｃｍ３以下である。 The detergent is preferably used in the form of granules or tablets that facilitate storage. The tablet suitably has a volume of at least 1 cm 3 , preferably at least 5 cm 3 . The volume is suitably 100 cm 3 or less, preferably 12 cm 3 or less.
タブレットの最大直径は、適切には１０ｃｍ、好ましくは７ｃｍである。タブレットの最小直径は、適切には１ｃｍ、好ましくは３ｃｍである。これらの大きさは、水への最適な投与および溶解を可能にする。 The maximum diameter of the tablet is suitably 10 cm, preferably 7 cm. The minimum diameter of the tablet is suitably 1 cm, preferably 3 cm. These sizes allow for optimal administration and dissolution in water.
本発明による洗浄剤は、使用の少し前に水に適切に溶解させる。３つの成分ａ）＋ｂ）＋ｃ）の合計１重量部に対して、水５００から１００，０００重量部がこの溶解に用いられる。適切には水６００から１９００重量部、好ましくは水９００から１３００重量部が、溶解に使用できる。 The cleaning agent according to the invention is suitably dissolved in water shortly before use. For a total of 1 part by weight of the three components a) + b) + c), 500 to 100,000 parts by weight of water are used for this dissolution. Suitably 600 to 1900 parts by weight of water, preferably 900 to 1300 parts by weight of water can be used for dissolution.
有利には、洗浄剤は、水で膨張する物質、例えばポリビニルピロリドンをさらに含有する。したがって、顆粒またはタブレットの形態で存在する洗浄剤は、水に早く溶解する。タブレットとして形成された洗浄剤は、１０分未満、好ましくは２分未満で水に残渣なしで適切に溶解すべきである。室温での洗浄剤水溶液の表面張力は、最大１秒以内、好ましくは最大０．６秒以内に４０ｍＮ／ｍ未満、好ましくは３０ｍＮ／ｍ未満の値まで低下する。 Advantageously, the cleaning agent further contains a water swellable material, such as polyvinylpyrrolidone. Thus, detergents present in the form of granules or tablets dissolve quickly in water. The detergent formed as a tablet should dissolve properly in water in less than 10 minutes, preferably in less than 2 minutes, without residue. The surface tension of the aqueous cleaning solution at room temperature falls to a value of less than 40 mN / m, preferably less than 30 mN / m within a maximum of 1 second, preferably within a maximum of 0.6 seconds.
特定の実施形態において、洗浄剤は、以下の追加の成分：
ｄ）好ましくは等モル量の炭酸塩および有機酸の発泡性混合物
を含有する。
In certain embodiments, the cleaning agent has the following additional ingredients:
d) Preferably contains an equimolar amount of a foamable mixture of carbonate and organic acid.
発泡性混合物は、クエン酸、炭酸水素ナトリウムおよび／または炭酸ナトリウムの混合物であることが好ましい。顆粒またはタブレットの使用形態において、洗浄剤は、炭酸塩ならびに有機酸、例えばクエン酸および／またはクエン酸塩と混合することにより発泡性混合物を形成し得る。過剰量のクエン酸塩は、カルシウムイオンの錯形成に役立つ。 The effervescent mixture is preferably a mixture of citric acid, sodium bicarbonate and / or sodium carbonate. In the use form of granules or tablets, the detergent may form an effervescent mixture by mixing with carbonates and organic acids such as citric acid and / or citrate. Excess citrate helps to complex calcium ions.
特定の実施形態において、分岐エトキシル化脂肪アルコールは、ｉｓｏ−Ｃ８−Ｃ１８非イオン性界面活性剤であり、これは２から２０のエチレンオキシド単位で好ましくはエーテル化される。とりわけ、分岐エトキシル化脂肪アルコールは、ｉｓｏ−Ｃ１０−Ｃ１４非イオン性界面活性剤であり、これは好ましくは５から１０のエチレンオキシド単位でエーテル化される。ｉｓｏ−Ｃ８−Ｃ１８非イオン性界面活性剤は、ｉｓｏ−Ｃ１３（１０ＥＯ）またはｉｓｏ−Ｃ１１（７ＥＯ）であってよい。 In certain embodiments, the branched ethoxylated fatty alcohol is an iso-C8-C18 nonionic surfactant, which is preferably etherified with 2 to 20 ethylene oxide units. In particular, the branched ethoxylated fatty alcohol is an iso-C10-C14 nonionic surfactant, which is preferably etherified with 5 to 10 ethylene oxide units. The iso-C8-C18 nonionic surfactant may be iso-C13 (10EO) or iso-C11 (7EO).
本発明による洗浄剤の成分ａ）、ｂ）およびｃ）の比率は、互いに対して以下の比率：
成分ａ） ０．１から１００重量部、
成分ｂ） ０．０５から５０重量部および
成分ｃ） ０．０１から５０重量部
を有し得る。
The proportions of the components a), b) and c) of the detergent according to the invention are as follows with respect to each other:
Component a) 0.1 to 100 parts by weight,
Component b) 0.05 to 50 parts by weight and component c) 0.01 to 50 parts by weight.
適切には、成分ａ）、ｂ）およびｃ）は、互いに対して以下の比率：
成分ａ） １から１０重量部、
成分ｂ） ０．５から５重量部および
成分ｃ） ０．１から５．０重量部
を有し得る。
Suitably components a), b) and c) are in the following ratios relative to each other:
Component a) 1 to 10 parts by weight,
Component b) may have 0.5 to 5 parts by weight and component c) 0.1 to 5.0 parts by weight.
有利には、成分ａ）、ｂ）およびｃ）は、互いに対して以下の比率：
成分ａ） ３から５重量部、
成分ｂ） １から２重量部および
成分ｃ） １から２重量部
を有し得る。
Advantageously, components a), b) and c) are in the following ratios relative to each other:
Component a) 3 to 5 parts by weight,
Component b) may have 1 to 2 parts by weight and component c) 1 to 2 parts by weight.
成分ａ）、ｂ）およびｃ）の比率に加えて、成分ｄ）の以下の比率：
成分ｄ）：０．３から１５０重量部、好ましくは３．０から１５．０重量部
も与えることができる。
In addition to the proportions of components a), b) and c), the following proportions of component d):
Component d): 0.3 to 150 parts by weight, preferably 3.0 to 15.0 parts by weight, can also be provided.
本発明による洗浄剤は、洗浄機での使用にとりわけ適している。これは、モップによる水拭きおよび手作業用または工業用フォームに特に適している。 The cleaning agents according to the invention are particularly suitable for use in cleaning machines. This is particularly suitable for mop wiping and manual or industrial foam.
特定の実施形態において、洗浄剤は、錯形成剤をさらに含有できる。 In certain embodiments, the cleaning agent can further contain a complexing agent.
本発明および本発明のさらなる改良を、いくつかの配合物に関して以下でより詳細に説明する。配合物は、投与単位（例えば、１タブレット、または１サシェまたは１粉末部など）の組成物を表し、これを８から１０リッターの水に溶解させ、適切な洗浄溶液を得る。 The invention and further improvements of the invention are described in more detail below with respect to some formulations. The formulation represents a composition of dosage units (eg, 1 tablet, or 1 sachet or 1 powder part), which is dissolved in 8 to 10 liters of water to obtain a suitable wash solution.
［実施例１］
８ｇ ポリアスパラギン酸ナトリウム塩
４ｇ 有機変性ポリジメチルシロキサン（湿潤剤として）
４ｇ ｉｓｏ−Ｃ１２−１４脂肪アルコール（８ＥＯ）（湿潤剤のための乳化剤として）
[Example 1]
8g Polyaspartic acid sodium salt 4g Organically modified polydimethylsiloxane (as wetting agent)
4 g iso-C12-14 fatty alcohol (8EO) (as emulsifier for wetting agent)
［実施例２］
６ｇ ポリアスパラギン酸ナトリウム塩
４ｇ ２，４，７，９−テトラメチル−５−デシン−４，７−ジオール（湿潤剤として）
２ｇ Ｃ１０−１２脂肪アルコールＥＯ／ＰＯ
[Example 2]
6 g polyaspartic acid sodium salt 4 g 2,4,7,9-tetramethyl-5-decyne-4,7-diol (as wetting agent)
2g C10-12 fatty alcohol EO / PO
［実施例３］
４ｇ ポリアスパラギン酸ナトリウム塩
２ｇ アニオン性フルオロ湿潤剤（Ｃ４−Ｃ６直鎖フッ素化炭化水素）
３ｇ ラウリルエーテル硫酸ナトリウム（２ＥＯ）（湿潤剤のための乳化剤として）
[Example 3]
4g Polyaspartic acid sodium salt 2g Anionic fluorowetting agent (C4-C6 linear fluorinated hydrocarbon)
3 g sodium lauryl ether sulfate (2EO) (as emulsifier for wetting agent)
［実施例４］
４ｇ ポリアスパラギン酸ナトリウム塩
４ｇ ジイソオクチルスルホコハク酸ナトリウム（湿潤剤として）
３ｇ Ｃ１０ゲルベアルコール（９ＥＯ）（湿潤剤のための乳化剤として）
[Example 4]
4 g Sodium polyaspartate 4 g Sodium diisooctyl sulfosuccinate (as wetting agent)
3 g C10 Gerve alcohol (9EO) (as emulsifier for wetting agent)
［実施例５］
７．８ｇ アクリルホモポリマー（ＭＷ４０００から６０００）
４．１ｇ アニオン性フルオロ湿潤剤（Ｃ４−Ｃ６直鎖フッ素化炭化水素）
４ｇ ｉｓｏ−Ｃ１２−１４脂肪アルコール（８ＥＯ）（湿潤剤のための乳化剤として）
０．１５ｇ ジエチレントリアミン（錯形成剤として）
[Example 5]
7.8 g acrylic homopolymer (MW 4000 to 6000)
4.1 g anionic fluorowetting agent (C4-C6 linear fluorinated hydrocarbon)
4 g iso-C12-14 fatty alcohol (8EO) (as emulsifier for wetting agent)
0.15 g Diethylenetriamine (as a complexing agent)
［実施例６］
５．９ｇ アクリルホモポリマー（ＭＷ４０００から６０００）
３．９ｇ ２，４，７，９−テトラメチル−５−デシン−４，７−ジオール（湿潤剤として）
２ｇ Ｃ１０−１２脂肪アルコールＥＯ／ＰＯ
[Example 6]
5.9 g acrylic homopolymer (MW 4000 to 6000)
3.9 g 2,4,7,9-tetramethyl-5-decyne-4,7-diol (as wetting agent)
2g C10-12 fatty alcohol EO / PO
［実施例７］
４ｇ アクリルホモポリマー（ＭＷ４０００から６０００）
２ｇ アニオン性フルオロ湿潤剤（Ｃ４−Ｃ６直鎖フッ素化炭化水素）
３ｇ ラウリルエーテル硫酸ナトリウム（２ＥＯ）（湿潤剤のための乳化剤として）
[Example 7]
4g acrylic homopolymer (MW 4000 to 6000)
2g anionic fluorowetting agent (C4-C6 linear fluorinated hydrocarbon)
3 g sodium lauryl ether sulfate (2EO) (as emulsifier for wetting agent)
［実施例８］
４ｇ アクリルホモポリマー（ＭＷ４０００から６０００）
４ｇ ジイソオクチルスルホコハク酸ナトリウム（湿潤剤として）
３ｇ Ｃ１０ゲルベアルコール（９ＥＯ）（湿潤剤のための乳化剤として）
[Example 8]
4g acrylic homopolymer (MW 4000 to 6000)
4g sodium diisooctyl sulfosuccinate (as wetting agent)
3 g C10 Gerve alcohol (9EO) (as emulsifier for wetting agent)
本発明の様々な実施形態が、上に記載したように存在するが、様々な特徴が単独および任意の所望の組合せの両方で使用できるものとして、これらは理解されるべきである。 While various embodiments of the present invention exist as described above, it should be understood that the various features can be used both alone and in any desired combination.
したがって、本発明は上記の特に好ましい実施形態のみに限定されるものではない。 Therefore, the present invention is not limited only to the particularly preferred embodiments described above.
Claims (42)
ａ）少なくとも１つの負に帯電した有機高分子、
ｂ）少なくとも１つの非イオン性、アニオン性、カチオン性または両性湿潤剤、
ｃ）少なくとも１つの湿潤剤のための少なくとも１つの非イオン性、アニオン性、カチオン性または両性乳化剤
を含有する洗浄剤であって、
ｂ１）非イオン性湿潤剤が、アセチレンジオールまたはポリジメチルシロキサンであり、
ｂ２）アニオン性湿潤剤が、アニオン性パーフルオロアルキルポリマーまたはアルキルスルホスクシネートであり、
ｂ３）カチオン性湿潤剤が、カチオン性パーフルオロアルキルコポリマーであり、
洗浄剤が、顆粒またはタブレットの形態で利用できる
ことを特徴とする洗浄剤。 The following ingredients:
a) at least one negatively charged organic polymer,
b) at least one nonionic, anionic, cationic or amphoteric wetting agent;
c) a detergent containing at least one nonionic, anionic, cationic or amphoteric emulsifier for at least one wetting agent,
b1) the nonionic wetting agent is acetylenic diol or polydimethylsiloxane;
b2) the anionic wetting agent is an anionic perfluoroalkyl polymer or alkyl sulfosuccinate;
b3) the cationic wetting agent is a cationic perfluoroalkyl copolymer;
A cleaning agent, characterized in that the cleaning agent can be used in the form of granules or tablets.
ｄ）好ましくは等モル量の炭酸塩および有機酸の発泡性混合物
を含有することを特徴とする、請求項１８から２３のいずれか一項に記載の洗浄剤。 The cleaning agent has the following additional ingredients:
d) A cleaning agent according to any one of claims 18 to 23, characterized in that it preferably contains an equimolar amount of a foamable mixture of carbonate and organic acid.
成分ａ） ０．１から１００重量部、
成分ｂ） ０．０５から５０重量部、
成分ｃ） ０．０１から５０重量部
を有することを特徴とする、請求項１から２９のいずれか一項に記載の洗浄剤。 The ratio of components a), b) and c) is relative to each other in the following relationship:
Component a) 0.1 to 100 parts by weight,
Component b) 0.05 to 50 parts by weight,
30. A cleaning agent according to any one of claims 1 to 29, characterized in that it has 0.01 to 50 parts by weight of component c).
成分ａ） １から１０重量部、
成分ｂ） ０．５から５重量部、
成分ｃ） ０．１から５．０重量部
を有することを特徴とする、請求項３０に記載の洗浄剤。 The ratio of components a), b) and c) is relative to each other in the following relationship:
Component a) 1 to 10 parts by weight,
Component b) 0.5 to 5 parts by weight,
31. Cleaning agent according to claim 30, characterized in that it has component c) 0.1 to 5.0 parts by weight.
成分ａ） ３から５重量部、
成分ｂ） １から２重量部、
成分ｃ） １から２重量部
を有することを特徴とする、請求項３１に記載の洗浄剤。 The ratio of components a), b) and c) is relative to each other in the following relationship:
Component a) 3 to 5 parts by weight,
Component b) 1 to 2 parts by weight,
32. A cleaning agent according to claim 31, characterized in that it has 1 to 2 parts by weight of component c).
成分ｄ） ０．３から１５０重量部、好ましくは３．０から１５．０重量部
として与えられることを特徴とする、請求項２４から３２のいずれか一項に記載の洗浄剤。 In addition to the ratio of components a), b) and c), the ratio of component d) is given as component d) 0.3 to 150 parts by weight, preferably 3.0 to 15.0 parts by weight The cleaning agent according to any one of claims 24 to 32.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE202013001148.3 | 2013-02-06 | ||
| DE202013001148.3U DE202013001148U1 (en) | 2013-02-06 | 2013-02-06 | cleaning supplies |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015556355A Division JP2016507620A (en) | 2013-02-06 | 2014-01-29 | Washing soap |
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|---|---|
| JP2018184606A true JP2018184606A (en) | 2018-11-22 |
Family
ID=50033295
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015556355A Pending JP2016507620A (en) | 2013-02-06 | 2014-01-29 | Washing soap |
| JP2018122090A Withdrawn JP2018184606A (en) | 2013-02-06 | 2018-06-27 | Cleaning agent |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015556355A Pending JP2016507620A (en) | 2013-02-06 | 2014-01-29 | Washing soap |
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| Country | Link |
|---|---|
| EP (1) | EP2954036B1 (en) |
| JP (2) | JP2016507620A (en) |
| DE (1) | DE202013001148U1 (en) |
| MY (1) | MY182079A (en) |
| PL (1) | PL2954036T3 (en) |
| SG (1) | SG11201506177RA (en) |
| WO (1) | WO2014121406A1 (en) |
| ZA (1) | ZA201505008B (en) |
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|---|---|---|---|---|
| US10676621B2 (en) | 2016-03-04 | 2020-06-09 | S. C. Johnson & Son, Inc. | Multi-purpose floor finish composition |
| BR112021017145A2 (en) | 2019-03-06 | 2021-11-09 | Ecolab Usa Inc | Solid cleaning composition and method for cleaning a hard surface |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4659496A (en) * | 1986-01-31 | 1987-04-21 | Amway Corporation | Dispensing pouch containing premeasured laundering compositions |
| US5085695A (en) * | 1990-07-13 | 1992-02-04 | Minnesota Mining And Manufacturing Company | Protective furniture polish composition |
| WO1992006161A1 (en) * | 1990-09-28 | 1992-04-16 | The Procter & Gamble Company | Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent |
| DE4239076A1 (en) * | 1992-11-20 | 1994-05-26 | Basf Ag | Mixtures of polymers of monoethylenically unsaturated dicarboxylic acids and polymers of ethylenically unsaturated monocarboxylic acids and / or polyaminocarboxylic acids and their use |
| FR2700775B1 (en) * | 1993-01-27 | 1995-03-10 | Rhone Poulenc Chimie | Solid detergent composition containing at least one biodegradable and non-hygroscopic polycarboxylic polymer. |
| DE4310995A1 (en) * | 1993-04-03 | 1994-10-06 | Basf Ag | Use of polyaspartic acid in cleaning formulations |
| US5500153A (en) * | 1994-07-05 | 1996-03-19 | The Procter & Gamble Company | Handwash laundry detergent composition having improved mildness and cleaning performance |
| US5902782A (en) * | 1995-01-20 | 1999-05-11 | Procter & Gamble Company | Detergent compositions comprising stabilised polyamino acid compounds |
| US5962389A (en) * | 1995-11-17 | 1999-10-05 | The Dial Corporation | Detergent having improved color retention properties |
| US5762647A (en) * | 1995-11-21 | 1998-06-09 | The Procter & Gamble Company | Method of laundering with a low sudsing granular detergent composition containing optimally selected levels of a foam control agent bleach activator/peroxygen bleaching agent system and enzyme |
| GB2315783B (en) * | 1996-07-27 | 2000-08-23 | Reckitt & Colman Inc | Cleaning composition imparting water and oil repellency |
| DK1149143T3 (en) * | 1999-02-02 | 2003-01-06 | Ecolab Gmbh & Co Ohg | Means for cleaning hard surfaces |
| US6034046A (en) * | 1999-03-26 | 2000-03-07 | Colgate Palmolive Company | All purpose liquid bathroom cleaning compositions |
| DE19918267A1 (en) * | 1999-04-22 | 2000-10-26 | Henkel Kgaa | Surfactant-containing material, e.g., a washing-up liquid, which includes microcapsules in which incompatible or sensitive components are enclosed |
| AU1765202A (en) * | 2000-12-22 | 2002-07-08 | Mir-Khaidarov, Renar Raulievich | Detergent |
| EP1397475A2 (en) * | 2001-05-31 | 2004-03-17 | Huntsman International Llc | Compactable powders |
| JP4324341B2 (en) * | 2002-03-22 | 2009-09-02 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | Liquid detergent composition for automatic dishwashers |
| JP4303155B2 (en) * | 2003-10-31 | 2009-07-29 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | Detergent composition for automatic dishwasher |
| US6974790B2 (en) * | 2003-11-06 | 2005-12-13 | Colgate-Palmolive Company | Cleaning compositions in the form of a tablet |
| US7378382B2 (en) * | 2004-05-05 | 2008-05-27 | The Clorox Company | Rheologically stabilized silicone dispersions comprising a polydimethylsiloxane mixture |
| CA2564763C (en) * | 2004-05-14 | 2012-08-07 | Virox Technologies Inc. | Hydrogen peroxide-based skin disinfectant |
| US20050276831A1 (en) * | 2004-06-10 | 2005-12-15 | Dihora Jiten O | Benefit agent containing delivery particle |
| KR20050122661A (en) * | 2004-06-25 | 2005-12-29 | 에스케이 주식회사 | Complex detergent composition for drycleaning soap |
| US7494963B2 (en) * | 2004-08-11 | 2009-02-24 | Delaval Holding Ab | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
| DE102004053015A1 (en) * | 2004-11-03 | 2006-05-04 | Lanxess Deutschland Gmbh | Use of water-soluble polymer polycarboxylate as dispersing agent for the cleaning of sooted surfaces e.g. tunnel linings, street signs, signaling devices, heating systems, engines, soot particle filters and window panes |
| JP5072219B2 (en) * | 2005-03-31 | 2012-11-14 | 小林製薬株式会社 | Hydrophilic treatment agent |
| US7288514B2 (en) * | 2005-04-14 | 2007-10-30 | The Clorox Company | Polymer-fluorosurfactant associative complexes |
| GB201021170D0 (en) * | 2010-12-10 | 2011-01-26 | Dow Corning | Granulated organopolysiloxane products |
-
2013
- 2013-02-06 DE DE202013001148.3U patent/DE202013001148U1/en not_active Expired - Lifetime
-
2014
- 2014-01-29 EP EP14702440.0A patent/EP2954036B1/en active Active
- 2014-01-29 MY MYPI2015702550A patent/MY182079A/en unknown
- 2014-01-29 PL PL14702440T patent/PL2954036T3/en unknown
- 2014-01-29 JP JP2015556355A patent/JP2016507620A/en active Pending
- 2014-01-29 SG SG11201506177RA patent/SG11201506177RA/en unknown
- 2014-01-29 WO PCT/CH2014/000011 patent/WO2014121406A1/en active Application Filing
-
2015
- 2015-07-13 ZA ZA2015/05008A patent/ZA201505008B/en unknown
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2018
- 2018-06-27 JP JP2018122090A patent/JP2018184606A/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014121406A1 (en) | 2014-08-14 |
| EP2954036B1 (en) | 2019-03-06 |
| EP2954036A1 (en) | 2015-12-16 |
| JP2016507620A (en) | 2016-03-10 |
| DE202013001148U1 (en) | 2014-05-07 |
| PL2954036T3 (en) | 2019-08-30 |
| MY182079A (en) | 2021-01-18 |
| ZA201505008B (en) | 2017-07-26 |
| SG11201506177RA (en) | 2015-09-29 |
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