CN101186863A - Low concentration water-saving type clothes washing agent and preparation method thereof - Google Patents
Low concentration water-saving type clothes washing agent and preparation method thereof Download PDFInfo
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- CN101186863A CN101186863A CNA2007101790356A CN200710179035A CN101186863A CN 101186863 A CN101186863 A CN 101186863A CN A2007101790356 A CNA2007101790356 A CN A2007101790356A CN 200710179035 A CN200710179035 A CN 200710179035A CN 101186863 A CN101186863 A CN 101186863A
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Abstract
The invention relates to light concentration water-saving washing agent and process for preparation. According to parts by weight, the invention comprises the following components, including 0.1-10 aliphatic alcohol polyvinyl chloride ether of short-chain branch (7), 0.1-10 aliphatic alcohol polyethenoxy ether (3), 0.1-5 aliphatic alcohol polyethenoxy ether (5), 0.1-14 aliphatic alcohol polyethenoxy ether (7), 0.1-14 aliphatic alcohol polyethenoxy ether (9), 1.0-14 aliphatic alcohol polyethenoxy ether sodium sulfate with 70% concentration, 0.001-5 sodium citrate, 0.001-5 soda, 0.001-5 potassium carbonate, 0.001-5 borax, 0.001-5 optical brightener, 0.1-0.4 essence, and 70-85 ionized water. The invention takes dissoluble non-ionic surface active agent of low water pollution as main component, and compounds with non-ionic hydrophilicity and anion active agent, thereby the invention has good detergency and relatively high apparent viscosity, as well as the utilization quantity is reduced. The residual quantity after washing and rinsing twice is less than that of the rinsing liquid of ordinary laundry powder, thereby greatly saving water, power and the like resources.
Description
Technical field
The present invention relates to household chemicals, relate in particular to low concentration water-saving type clothes washing agent and preparation method thereof.
Background technology
Washing liquid has become the requisite in the daily life, and cleaning clothes needs washing liquid, but needs repeatedly rinsing during rinsing clothes, could the clothing rinsing is clean, thereby consumed a large amount of water, wasted water resources, increased the work or the working strength of people and washing machine etc.This is owing to used the exhibiting high surface promoting agent in the washing liquid in the market, can form a large amount of foams, and is difficult for disappearing, and it is clean to be difficult to rinsing.
Washing liquid is compared with washing powder, owing to can not add too much auxiliary agent, therefore must increase detersive power by the content that improves tensio-active agent, but anti-hard water of general anion surfactant and antiredeposition are poor, therefore detersive power is not high, and nonionogenic tenside commonly used, though anti-hard water, antiredeposition is good, but go solid dirt ability relatively poor, therefore, generally adopt the compound detersive power that improves of more anion surfactant and nonionogenic tenside, but the surfactant dissolves degree is limited, must add dispersion agent and solubility promoter, and dispersion agent, the increase of solubility promoter can reduce apparent viscosity, and appearance effect is bad, this must add thickening material again, and can reduce detersive power like this, therefore, must strengthen the consumption of tensio-active agent again once more, and then cause the wasting of resources and washing after stain quantity discharged to increase, and it is clean to be difficult for rinsing.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, two kinds of low concentration water-saving type clothes washing agents and preparation method thereof are provided, the present invention is based on the low water solubility nonionogenic tenside, with the wetting ability nonionic, anion surfactant is compound, and good detersive power is promptly arranged, reduced usage quantity again, also have higher viscosity, twice of post rinsing of washing is also lower than the residual quantity of common washing powder rinsing three times, can save resources such as water power greatly.
The objective of the invention is to be achieved through the following technical solutions:
A kind of low concentration water-saving type clothes washing agent comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Fatty alcohol-polyoxyethylene ether (5) 0.1～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
Its preparation method is: by ratio of weight and the number of copies, with 70～85 parts of deionized waters wherein 30～40% be heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10 then successively, fatty alcohol-polyoxyethylene ether (3) 0.1～10, fatty alcohol-polyoxyethylene ether (5) 0.1～5, fatty alcohol-polyoxyethylene ether (7) 0.1～14, fatty alcohol-polyoxyethylene ether (9) 0.1～14, polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14, after Trisodium Citrate 0.001～5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001～5, salt of wormwood 0.001～5, borax 0.001～5, white dyes 0.001～0.5 stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence 0.1～0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
A kind of low concentration water-saving type clothes washing agent comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
Its preparation method is: by ratio of weight and the number of copies, with 70～85 parts of deionized waters wherein 30～40% be heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10 then successively, fatty alcohol-polyoxyethylene ether (3) 0.1～10, fatty alcohol-polyoxyethylene ether (7) 0.1～14, fatty alcohol-polyoxyethylene ether (9) 0.1～14, polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14, after Trisodium Citrate 0.001～5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001～5, salt of wormwood 0.001～5, borax 0.001～5, white dyes 0.001～0.5 stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence 0.1～0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
The invention has the beneficial effects as follows: detersive power of the present invention reaches national sector standard QB1224-1991 requirement.Surfactant content of the present invention is less than 13%, and solid content is less than 20%.Processable of the present invention is good, and detersive power is good, and foaming is few, can reduce the rinsing number of times, and water-saving performance is good, can reduce the work or the working strength of people and washing machine.The present invention is satisfying under the condition of detersive power, than standard washing powder water saving 1/4～1/3, lacks rinsing once than common washing powder.
Embodiment
Provide embodiments of the invention and preparation method below
A kind of low concentration water-saving type clothes washing agent comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Fatty alcohol-polyoxyethylene ether (5) 0.1～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
Embodiment 1:
The 100kg low concentration water-saving type clothes washing agent comprises following component:
Fatty alcohol-polyoxyethylene ether (7) 6kg
Fatty alcohol-polyoxyethylene ether (9) 1kg
Fatty alcohol-polyoxyethylene ether (3) 0.3kg
Polyoxyethylenated alcohol sodium sulfate (70%) 4kg
Soda ash 0.3kg
Salt of wormwood 2kg
Borax 1kg
Fatty alcohol-polyoxyethylene ether (5) 1.5kg
Trisodium Citrate 1kg
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.3kg
White dyes 0.8kg
Essence 0.2kg
Deionized water 82.6kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 11.9%;
Viscosity: greater than 60 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4～1/3.
Embodiment 2:
The 100kg low concentration water-saving type clothes washing agent comprises following component:
Fatty alcohol-polyoxyethylene ether (7) 0.1kg
Fatty alcohol-polyoxyethylene ether (9) 11kg
Fatty alcohol-polyoxyethylene ether (3) 0.6kg
Polyoxyethylenated alcohol sodium sulfate (70%) 1kg
Soda ash 0.001kg
Salt of wormwood 3kg
Borax 0.001kg
Fatty alcohol-polyoxyethylene ether (5) 0.5kg
Trisodium Citrate 1kg
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1kg
White dyes 0.02kg
Essence 0.1kg
Deionized water 82.578kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 12.9%;
Viscosity: greater than 60 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4～1/3.
Embodiment 3:
The 100kg low concentration water-saving type clothes washing agent comprises following component:
Fatty alcohol-polyoxyethylene ether (7) 1kg
Fatty alcohol-polyoxyethylene ether (9) 0.1kg
Fatty alcohol-polyoxyethylene ether (3) 1kg
Polyoxyethylenated alcohol sodium sulfate (70%) 4kg
Soda ash 0.001kg
Salt of wormwood 0.001kg
Borax 0.001kg
Fatty alcohol-polyoxyethylene ether (5) 0.1kg
Trisodium Citrate 5kg
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 8kg
White dyes 0.5kg
Essence 0.4kg
Deionized water 79.897kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 12.9%;
Viscosity: less than 45 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4～1/3.
In the component of the present invention, fatty alcohol-polyoxyethylene ether (3) (English name abbreviation AEO-3), fatty alcohol-polyoxyethylene ether (5) (English name abbreviation AEO-5), fatty alcohol-polyoxyethylene ether (7) (English name abbreviation AEO-7), fatty alcohol-polyoxyethylene ether (9) (English name abbreviation AEO-9) etc. are nonionogenic tenside, and greasy dirt is had well emulsify, solublization.Wherein fatty alcohol-polyoxyethylene ether (3) is the water-insoluble tensio-active agent, but compound with other tensio-active agent, water soluble can increase surfactivity greatly, increases the perviousness and the power of deoiling, and can also increase viscosity.Fatty alcohol-polyoxyethylene ether (5), fatty alcohol-polyoxyethylene ether (7) are the low water solubility tensio-active agent, and emulsification greasy dirt power is strong, and fatty alcohol-polyoxyethylene ether (9) is the hydrophilic surfactant active, can decontamination.To be 70% polyoxyethylenated alcohol sodium sulfate (English name abbreviation AES) be anti-hard water anion surfactant preferably to concentration, and it is strong to remove the solid dirt.White dyes (English name abbreviation CF-351) can improve the appearance effect of solution, can increase the whiteness behind the clothes washing again.Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) (English name abbreviation XL-70) has very strong infiltration decontamination promoter action.
Its preparation method is: 30～40% of deionized water 7 is heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) then successively, fatty alcohol-polyoxyethylene ether (3), fatty alcohol-polyoxyethylene ether (5), fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), polyoxyethylenated alcohol sodium sulfate (concentration 70%), after Trisodium Citrate stirs, add remaining deionized water, all after the dissolving, add soda ash, salt of wormwood, borax, the white dyes stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
It is noted that: the entire operation process must guarantee the quality of deionized water, and Fe can not be arranged
2+, Mg
2+, Ca
2+Plasma is brought into and is precipitated.Soda ash, salt of wormwood, borax if any impurity should first dissolution filter after usefulness again, can not have mechanical impurity band to go into.Entire operation clean environment health, dustproof.
A kind of low concentration water-saving type clothes washing agent comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
Embodiment 4:
The 100kg low concentration water-saving type clothes washing agent comprises following component:
Fatty alcohol-polyoxyethylene ether (7) 2kg
Fatty alcohol-polyoxyethylene ether (9) 2.5kg
Fatty alcohol-polyoxyethylene ether (3) 0.3kg
Polyoxyethylenated alcohol sodium sulfate (70%) 10kg
Soda ash 0.3kg
Salt of wormwood 2kg
Borax 1kg
Trisodium Citrate 1kg
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.3kg
White dyes 0.02kg
Essence 0.2kg
Deionized water 80.38kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 11.9%;
Viscosity: less than 45 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4～1/3.
In the component of the present invention, fatty alcohol-polyoxyethylene ether (3), fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether anion surfactants such as (9) have well emulsify, increase the effect of living greasy dirt.Wherein fatty alcohol-polyoxyethylene ether (3) is the water-insoluble tensio-active agent, but compound with other tensio-active agent, water soluble can increase surfactivity greatly, increases the perviousness and the power of deoiling, and can also increase viscosity.Fatty alcohol-polyoxyethylene ether (7) is the low water solubility tensio-active agent, and emulsification greasy dirt power is strong, and fatty alcohol-polyoxyethylene ether (9) is the hydrophilic surfactant active, can decontamination.Polyoxyethylenated alcohol sodium sulfate (concentration is 70%) is an anti-hard water anion surfactant preferably, and it is strong to remove the solid dirt.White dyes can improve the appearance effect of solution, can increase the whiteness behind the clothes washing again.Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) has very strong infiltration decontamination promoter action.Do not contain fatty alcohol-polyoxyethylene ether (5) in the component of the present invention.
Its preparation method is: 30～40% of deionized water is heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) then successively, fatty alcohol-polyoxyethylene ether (3), fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), polyoxyethylenated alcohol sodium sulfate (concentration 70%), after Trisodium Citrate stirs, add remaining deionized water, all after the dissolving, add soda ash, salt of wormwood, borax, the white dyes stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.。
It is noted that: the entire operation process must guarantee the quality of deionized water, and Fe can not be arranged
2+, Mg
2+, Ca
2+Plasma is brought into and is precipitated.Soda ash, salt of wormwood, borax if any impurity should first dissolution filter after usefulness again, can not have mechanical impurity band to go into.Entire operation clean environment health, dustproof.
Claims (8)
1. a low concentration water-saving type clothes washing agent is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Fatty alcohol-polyoxyethylene ether (5) 0.1～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
2. low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 6
Fatty alcohol-polyoxyethylene ether (9) 1
Fatty alcohol-polyoxyethylene ether (3) 0.3
Polyoxyethylenated alcohol sodium sulfate (70%) 4
Soda ash 0.3
Salt of wormwood 2
Borax 1
Fatty alcohol-polyoxyethylene ether (5) 1.5
Trisodium Citrate 1
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.3
White dyes 0.8
Essence 0.2
Deionized water 82.6.
3. low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1
Fatty alcohol-polyoxyethylene ether (9) 11
Fatty alcohol-polyoxyethylene ether (3) 0.6
Polyoxyethylenated alcohol sodium sulfate (70%) 1
Soda ash 0.001
Salt of wormwood 3
Borax 0.001
Fatty alcohol-polyoxyethylene ether (5) 0.5
Trisodium Citrate 1
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1
White dyes 0.02
Essence 0.1
Deionized water 82.578.
4. low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 1
Fatty alcohol-polyoxyethylene ether (9) 0.1
Fatty alcohol-polyoxyethylene ether (3) 1
Polyoxyethylenated alcohol sodium sulfate (70%) 4
Soda ash 0.001
Salt of wormwood 0.001
Borax 0.001
Fatty alcohol-polyoxyethylene ether (5) 0.1
Trisodium Citrate 5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 8
White dyes 0.5
Essence 0.4
Deionized water 79.897.
5. a low concentration water-saving type clothes washing agent is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 0.1～14
Fatty alcohol-polyoxyethylene ether (9) 0.1～14
Fatty alcohol-polyoxyethylene ether (3) 0.1～10
Polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14
Soda ash 0.001～5
Salt of wormwood 0.001～5
Borax 0.001～5
Trisodium Citrate 0.001～5
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10
White dyes 0.001～0.5
Essence 0.1～0.4
Deionized water 70～85.
6. low concentration water-saving type clothes washing agent according to claim 5 is characterized in that, comprises following component by ratio of weight and the number of copies:
Fatty alcohol-polyoxyethylene ether (7) 2
Fatty alcohol-polyoxyethylene ether (9) 2.5
Fatty alcohol-polyoxyethylene ether (3) 0.3
Polyoxyethylenated alcohol sodium sulfate (70%) 10
Soda ash 0.3
Salt of wormwood 2
Borax 1
Trisodium Citrate 1
Short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.3
White dyes 0.02
Essence 0.2
Deionized water 80.38.
7. low concentration water-saving type clothes washing agent preparation method as claimed in claim 1, it is characterized in that: by ratio of weight and the number of copies, with 70～85 parts of deionized waters wherein 30～40% be heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10 then successively, fatty alcohol-polyoxyethylene ether (3) 0.1～10, fatty alcohol-polyoxyethylene ether (5) 0.1～5, fatty alcohol-polyoxyethylene ether (7) 0.1～14, fatty alcohol-polyoxyethylene ether (9) 0.1～14, polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14, after Trisodium Citrate 0.001～5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001～5, salt of wormwood 0.001～5, borax 0.001～5, white dyes 0.001～0.5 stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence 0.1～0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
8. low concentration water-saving type clothes washing agent preparation method as claimed in claim 5, it is characterized in that: by ratio of weight and the number of copies, with 70～85 parts of deionized waters wherein 30～40% be heated to 65 ℃～75 ℃, in the addingization material still, under agitation add short-chain branch type poly alkyl alcohol vinylchlorid ether (7) 0.1～10 then successively, fatty alcohol-polyoxyethylene ether (3) 0.1～10, fatty alcohol-polyoxyethylene ether (7) 0.1～14, fatty alcohol-polyoxyethylene ether (9) 0.1～14, polyoxyethylenated alcohol sodium sulfate (70%) 1.0～14, after Trisodium Citrate 0.001～5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001～5, salt of wormwood 0.001～5, borax 0.001～5, white dyes 0.001～0.5 stirring and dissolving, when being cooled to 35 ℃～45 ℃, adding essence 0.1～0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
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| CNB2007101790356A CN100554395C (en) | 2007-12-10 | 2007-12-10 | Low concentration water-saving type clothes washing agent and preparation method thereof |
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| CNB2007101790356A CN100554395C (en) | 2007-12-10 | 2007-12-10 | Low concentration water-saving type clothes washing agent and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796626A (en) * | 2012-08-29 | 2012-11-28 | 朱上翔 | Activating agent for low-temperature energy-saving main washing and bleach washing of ion washing machine |
| CN102876517A (en) * | 2012-10-30 | 2013-01-16 | 葛新 | Mineral-element quick clothing cleaning agent |
| CN103666805A (en) * | 2012-08-29 | 2014-03-26 | 狮王株式会社 | Liquid detergent |
| CN109810802A (en) * | 2019-01-31 | 2019-05-28 | 余可嘉 | A kind of anti-net detergent of staining silk hair and preparation method thereof |
| CN117510972A (en) * | 2023-12-21 | 2024-02-06 | 河北雄沃防火科技有限公司 | Low-carbon environment-friendly foaming agent and preparation method thereof |
-
2007
- 2007-12-10 CN CNB2007101790356A patent/CN100554395C/en active Active
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796626A (en) * | 2012-08-29 | 2012-11-28 | 朱上翔 | Activating agent for low-temperature energy-saving main washing and bleach washing of ion washing machine |
| CN103666805A (en) * | 2012-08-29 | 2014-03-26 | 狮王株式会社 | Liquid detergent |
| CN103666805B (en) * | 2012-08-29 | 2018-06-05 | 狮王株式会社 | Liquid detergent |
| CN102796626B (en) * | 2012-08-29 | 2019-04-26 | 朱上翔 | A kind of activator washed and rinsed for ionic washer low-temperature energy-saving master |
| CN102876517A (en) * | 2012-10-30 | 2013-01-16 | 葛新 | Mineral-element quick clothing cleaning agent |
| CN109810802A (en) * | 2019-01-31 | 2019-05-28 | 余可嘉 | A kind of anti-net detergent of staining silk hair and preparation method thereof |
| CN117510972A (en) * | 2023-12-21 | 2024-02-06 | 河北雄沃防火科技有限公司 | Low-carbon environment-friendly foaming agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100554395C (en) | 2009-10-28 |
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