CN105779159A - Softening clothes washing condensate ball and preparation method thereof - Google Patents
Softening clothes washing condensate ball and preparation method thereof Download PDFInfo
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- CN105779159A CN105779159A CN201610216176.XA CN201610216176A CN105779159A CN 105779159 A CN105779159 A CN 105779159A CN 201610216176 A CN201610216176 A CN 201610216176A CN 105779159 A CN105779159 A CN 105779159A
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- Prior art keywords
- fatty alcohol
- polyoxyethylene ether
- washing
- alcohol
- pearl
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- 238000005406 washing Methods 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 39
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 39
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 16
- 239000003094 microcapsule Substances 0.000 claims abstract description 16
- 108091005658 Basic proteases Proteins 0.000 claims abstract description 14
- -1 polyoxyethylene Polymers 0.000 claims abstract description 14
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 13
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 42
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 30
- 239000004033 plastic Substances 0.000 claims description 15
- 229920003023 plastic Polymers 0.000 claims description 15
- 238000004806 packaging method and process Methods 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- 125000003368 amide group Chemical group 0.000 claims description 11
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- DAZXVJBJRMWXJP-UHFFFAOYSA-N n,n-dimethylethylamine Chemical compound CCN(C)C DAZXVJBJRMWXJP-UHFFFAOYSA-N 0.000 claims description 11
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 150000001768 cations Chemical class 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003205 fragrance Substances 0.000 abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 239000004902 Softening Agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000003599 detergent Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000002752 cationic softener Substances 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 206010011732 Cyst Diseases 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 101710093543 Probable non-specific lipid-transfer protein Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 210000001938 protoplast Anatomy 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C11D2111/12—
Abstract
The invention discloses a softening clothes washing condensate ball and a preparation method thereof.The clothes washing condensate ball is prepared from 25% to 35% of heterogeneous C13 fatty alcohol-polyoxyethylene ether, 10% to 20% of fatty alcohol-polyoxyethylene ether (9EO), 10% to 20% of polyoxyethylene fatty alcohol sodium sulfate, 5% to 10% of fatty alcohol-polyoxyethylene ether (7EO), 1.5% to 2.5% of washing synergist WR, 1.5% to 2.5% of alcohol alkoxylate, 0.8% to 1.5% of cationic softening agent, 0.02% to 0.05% of bactericide, 0.5% to 1.0% of microcapsule essence, 0.01% to 0.03% of alkaline protease and 20% to 38% of solvent (propylene glycol).The softening clothes washing condensate ball has the advantages of being high in fragrance giving performance, safe and convenient to use, good in washing capacity and softening effect and the like.
Description
Technical field
The present invention relates to a kind of concentrated type liquid detergent, coagulate pearl more particularly to a kind of softening laundry.
Background technology
The solidifying pearl of laundry is that one aims at machine washing design, simple to operate, the dirtiest convenient hands, and the slight solidifying pearl of a laundry can wash a clothes.Fragrant, the thick moderate character gentleness of the soft cunning of quality do not hinders medicated clothing, and distinctive low bubble concentrates lock color formula, is more easy to rinsing, and solidifying pearl meets the instant noresidue of water, moreover it is possible to the most quickly remove stain clean as new by medicated clothing.The adventitia of the solidifying pearl of laundry can bear the weight of 15 kilograms, meet the most again water instant, can rapidly will the cold water enzyme in " cool beauty concentration " elite and be used for removing the gorgeous color chelating agen of dark stupid stain and incorporate in water.2010, green wave releasing its brand-new concentrated type liquid detergent, this is that green wave entrance Chinese market releases the liquid detergent as high-end washing category first.Pearl is coagulated in the laundry that studies in China develops at present, and it composes fragrance, washability and submissive less effective.Therefore, exploitation is efficient, compose fragrance and the submissive solidifying pearl of effective laundry is necessary, additionally, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only has washing cleaning action, submissive less effective.
Summary of the invention
For the problems referred to above, the invention provides kind of a softening laundry and coagulate pearl, solve washability and the poor shortcoming of submissive effect.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is: a kind of softening laundry coagulates pearl, it includes 25～35% isomery C13 fatty alcohol-polyoxyethylene ether, 10～20% fatty alcohol-polyoxyethylene ether (9EO), 10～15% polyoxyethylenated alcohol sodium sulfate, 5～10% fatty alcohol-polyoxyethylene ether (7EO), 1.5～2.5 % wash synergist WR, 1.5～2.5 % isomeric alcohol polyethenoxy ether, 1.0～2.0% cation softener, 0.02～0.05% antibacterial, 0.5～1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20～38 % solvents (propylene glycol).
Further, described washing synergist elects washing synergist WR as and isomeric alcohol polyethenoxy ether mixes.
Further, described antibacterial is preferably trichloro hydroxyl diphenyl ether or CDMP.
Further, described cation softener is selected from behenyl amido propyl ethyldimethyl amine sulfovinate, quaternary, fatty acid ester type, right wax pattern, polyethylene, organic siliconresin type etc..
A kind of softening laundry coagulates pearl preferably 30% isomery C13 fatty alcohol-polyoxyethylene ether, 15% fatty alcohol-polyoxyethylene ether (9EO), 12% polyoxyethylenated alcohol sodium sulfate, 8% fatty alcohol-polyoxyethylene ether (7EO), 2% washing synergist WR, 2 % isomeric alcohol polyethenoxy ether, 1.5% cation softener, 0.03% antibacterial, 0.8% microcapsule essence, 0.02% alkaline protease and 28.65 % solvents (propylene glycol).
A kind of described softening laundry coagulates the preparation method of pearl, it is characterised in that comprise the steps；Respectively fixed measured fatty alcohol-polyoxyethylene ether (9EO), fatty alcohol-polyoxyethylene ether (7EO), behenyl amido propyl ethyldimethyl amine sulfovinate are placed in beaker, are placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；Respectively the most measured isomery C13 fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, propylene glycol, washing synergist WR, isomeric alcohol polyethenoxy ether are sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into the most measured antibacterial, alkaline protease, microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
From the above-mentioned description to present configuration, compared to the prior art, present invention have the advantage that
Among these, microcapsule essence is a kind of technology essence being completely enclosed within a tunic and forming microcapsule, diameter is generally 1～1000 nanometers, microcapsule essence is an important branch in microcapsule technology, also it is that of microcapsule technology the most typically applies, the wall material of Micro-encapsulation in Essence can be depending on core, general requirement is strong mechanical property, nontoxic, have no side effect, nonirritant, there is compatibility, do not affect the effect of essence and flavoring agent, and there is satisfactory viscosity, permeability, there are some strength and plasticity etc., essence is after micro encapsulation, sealing function due to cyst wall can effectively suppress the volatilization loss of essence, improve storage and the stability of use of essence；Sensitive composition can be protected, be greatly improved oxytolerant, fast light and heat-resisting ability, increase its stability in clothing surface, it is possible to make essence have slow release function.
When washing synergist is ratio 30:1:1 being proved active surface activating agent, washing synergist WR and isomeric alcohol polyethenoxy ether by series of experiments, its clean result can improve 35～50%.
Cation softener is selected from behenyl amido propyl ethyldimethyl amine sulfovinate, quaternary, fatty acid ester type, right wax pattern, polyethylene, organic siliconresin type etc., behenyl amido propyl ethyldimethyl amine sulfovinate in this formula submissive effect is found through experiments best；
To sum up the present invention has stronger tax fragrance, safe and convenient to use, washability and the submissive effect feature such as preferably.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The present invention further will be understood by following explanation, but protection scope of the present invention will be not limited to this.
Isomery C13 fatty alcohol-polyoxyethylene ether belongs to green surfactant, and product, through world-leading quality and the Intertek internal authority detection examination certification of security service company, meets the environmental requirement of European Union, the U.S. and Japan;The nonionic surfactant of function admirable, can be widely applied to wash daily use chemicals, weaving, leather and other chemical industries;It is efficient emulsifying agent, penetrating agent and wetting agent, is the excellent succedaneum of NPE, sodium tripolyphosphate etc., and its performance is the most excellent compared with natural alcohol ether.
Fatty alcohol-polyoxyethylene ether (9EO) and fatty alcohol-polyoxyethylene ether (7EO) are a kind of good with the compatibility of other surfactants.Insensitive to hard water, that cold washing performance is good surfactant.Washing industry, as nonionic surfactant, plays emulsifying, foaming, decontamination.It it is the main active of handwashing liquid, liquid detergent, bath gel, detergent, liquid detergent, metal cleaner.
Polyoxyethylenated alcohol sodium sulfate, soluble in water, there is excellent decontamination, emulsifying, foam performance and hard water resistance performance, gentle washing character will not injured skin.It is noted that in the case of without viscosity modifier, if it is diluted to the aqueous solution containing 30% or 60% active substance, the gel that a kind of viscosity is high often can be caused during use.For avoiding this phenomenon, correct method is to be added in the water of specified quantity by high activity product, is stirred simultaneously.And do not add water to high activity raw material, the most just may cause the formation of gel.
Washing synergist WR has the cleaning capacity of uniqueness, acidproof, alkaline-resisting, can show splendid detergency performance in various environment, and degreasing power is strong, has good oil rub resistance redeposition ability and biological degradability.
Isomeric alcohol polyethenoxy ether is colourless or weak yellow liquid, soluble in water, has excellent emulsifying, washing performance.Belong to nonionic surfactant.Can be used as dispersant, wetting agent, penetrating agent, detergent, be widely used in household washing field.
Behenyl amido propyl ethyldimethyl amine sulfovinate belongs to cationic surfactant, it is soluble in isopropanol, ethanol, water soluble, clear solution can be formed with other surfactant after heating, and can be with anion, cation, nonionic and amphoteric surfactant compatibility, there is softness, antistatic, decontamination, foam performance, wash liquid, the oils and fats in hair products system, silicone oil have notable potentiation adsorption, it all has good stability in the range of PH widely, is a kind of novel softener.
4-chloro-3,5-xylenol is preservative, antibacterial.It is applied in medicine, Emulsion, cosmetics, ink, plywood, plastics, thermostability and good weatherability, this product low toxicity.Mouse oral LD50 is 3450mg/kg.
Alkaline protease is the most popular detergent additive, can increase substantially washing dirt-removing power, especially to protide dirts such as bloodstain, sweat stain, milk stain, oil stains, has the clean result of uniqueness.Alkaline protease uses bacterial protoplast mutagenic treatment method technically, produce research bacterium 2709 bacillus subtilis from domestic basic protein bacterium to select and some stablize high-performance bacterial strain, in post processing, employing is removed slag salt precipitation method, decrease impurity content and the distinctive abnormal smells from the patient of product of protease, improve dissolution velocity, have more preferable compatibility with detergent, extend the shelf-life.
Propylene glycol and water, ethanol and multiple immiscible organic solvent.Cosmetics, toothpaste and fancy soap can coordinate with glycerol or sorbitol and be used as wetting agent.In hair dye, it is used as damping, even agent, also serves as antifreezing agent.It is to prevent from table from living to meet hydrogel at this formula Main Function.
The invention discloses a kind of softening laundry and coagulate pearl, it includes 25～35% isomery C13 fatty alcohol-polyoxyethylene ether, 10～20% fatty alcohol-polyoxyethylene ether (9EO), 10～15% polyoxyethylenated alcohol sodium sulfate, 5～10% fatty alcohol-polyoxyethylene ether (7EO), 1.5～2.5 % washing synergist WR, 1.5～2.5 % isomeric alcohol polyethenoxy ether, 1.0～2.0% cation softener, 0.02～0.05% antibacterial, 0.5～1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20～38 % solvents (propylene glycol)；Described washing synergist elects washing synergist WR as and isomeric alcohol polyethenoxy ether mixes；Described antibacterial is preferably trichloro hydroxyl diphenyl ether or 4-chloro-3,5-xylenol；Described cation softener is selected from behenyl amido propyl ethyldimethyl amine sulfovinate, quaternary, fatty acid ester type, right wax pattern, polyethylene, organic siliconresin type etc..
A kind of described softening laundry coagulates the preparation method of pearl, it is characterised in that comprise the steps；Respectively fixed measured fatty alcohol-polyoxyethylene ether (9EO), fatty alcohol-polyoxyethylene ether (7EO), behenyl amido propyl ethyldimethyl amine sulfovinate are placed in beaker, are placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；Respectively the most measured isomery C13 fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, propylene glycol, washing synergist WR, isomeric alcohol polyethenoxy ether are sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into the most measured antibacterial, alkaline protease, microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
Embodiment
1
Weigh 1.5kg fatty alcohol-polyoxyethylene ether (9EO), 800g fatty alcohol-polyoxyethylene ether (7EO), 150g behenyl amido propyl ethyldimethyl amine sulfovinate respectively in 3L beaker, be placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；
Weigh respectively 3kg isomery C13 fatty alcohol-polyoxyethylene ether, 1.2kg polyoxyethylenated alcohol sodium sulfate, 2.87kg propylene glycol, 200g washing synergist WR, 200g isomeric alcohol polyethenoxy ether be sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into 3g antibacterial, 2g alkaline protease, 80g microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；
Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
Embodiment
2
Weigh 1.5kg fatty alcohol-polyoxyethylene ether (9EO), 800g fatty alcohol-polyoxyethylene ether (7EO), 150g behenyl amido propyl ethyldimethyl amine sulfovinate respectively in 3L beaker, be placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；
Weigh respectively 3kg isomery C13 fatty alcohol-polyoxyethylene ether, 1.2kg polyoxyethylenated alcohol sodium sulfate, 2.87kg propylene glycol, 200g washing synergist WR, 200g isomeric alcohol polyethenoxy ether be sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into 3g antibacterial, 2g alkaline protease, the common essence of 100g after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；
Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
Embodiment
3
Weigh 1.5kg fatty alcohol-polyoxyethylene ether (9EO), 800g fatty alcohol-polyoxyethylene ether (7EO), 150g quaternary ammonium salt cationic softener respectively in 3L beaker, be placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；
Weigh respectively 3kg isomery C13 fatty alcohol-polyoxyethylene ether, 1.2kg polyoxyethylenated alcohol sodium sulfate, 2.87kg propylene glycol, 200g washing synergist WR, 200g isomeric alcohol polyethenoxy ether be sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into 3g antibacterial, 2g alkaline protease, 80g microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；
Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
Embodiment
4
Weigh 1.5kg fatty alcohol-polyoxyethylene ether (9EO), 800g fatty alcohol-polyoxyethylene ether (7EO), 150g quaternary ammonium salt cationic softener respectively in 3L beaker, be placed in 45 DEG C of water-baths heating, stir with Glass rod, standby；
Weigh respectively 3kg isomery C13 fatty alcohol-polyoxyethylene ether, 1.2kg polyoxyethylenated alcohol sodium sulfate, 2.87kg propylene glycol, 400g washing synergist WR be sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into 3g antibacterial, 2g alkaline protease, 80g microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；
Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
Embodiment
5
The softening laundry prepared in embodiment 1,2,3,4 coagulates pearl and commercially available green wave board laundry solidifying pearl contrast, and the result obtained is as shown in table 1:
The solidifying pearl technical performance index relative analysis table of table 1 laundry
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not limited by above-described embodiment
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all any amendment, equivalent and improvement etc. made within the spirit and principles in the present invention, should be included within the scope of the present invention.
Claims (5)
1. a softening laundry coagulates pearl, it is characterised in that: it includes 25～35% isomery C13 fatty alcohol-polyoxyethylene ether, 10～20% fatty alcohol-polyoxyethylene ether, 10～15% polyoxyethylenated alcohol sodium sulfate, 5～10% fatty alcohol-polyoxyethylene ether, 1.5～2.5 % washing synergist WR, 1.5～2.5 % isomeric alcohol polyethenoxy ether, 1.0～2.0% cation softener, 0.02～0.05% antibacterial, 0.5～1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20～38 % solvents.
The most according to claim 1, a kind of softening laundry coagulates pearl, it is characterised in that: described washing synergist mixes for washing synergist WR and isomeric alcohol polyethenoxy ether.
The most according to claim 1, a kind of softening laundry coagulates pearl, it is characterised in that: described antibacterial is trichloro hydroxyl diphenyl ether or CDMP.
The most according to claim 1, a kind of softening laundry coagulates pearl, it is characterised in that: described cation softener is selected from behenyl amido propyl ethyldimethyl amine sulfovinate, quaternary, fatty acid ester type, right wax pattern, polyethylene, the one of which of organic siliconresin type or two or more.
5. a softening laundry as claimed in claim 1 coagulates the preparation method of pearl, it is characterised in that comprise the steps；Respectively the most measured fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, behenyl amido propyl ethyldimethyl amine sulfovinate are placed in beaker, are placed in 45 DEG C of water-bath heating, stir with Glass rod, standby；Respectively the most measured isomery C13 fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, propylene glycol, washing synergist WR, isomeric alcohol polyethenoxy ether are sequentially added in agitator, stir 30 minutes, it is added slowly with stirring mix homogeneously feed liquid in above-mentioned beaker, it is sequentially added into the most measured antibacterial, alkaline protease, microcapsule essence after adding stirring 10 minutes, stirring is stopped after stirring 30 minutes, feed liquid is poured in Plastic Drum, seal standby；Open Plastic Drum and seal lid, be added to feed liquid do washing in solidifying pearl automatic packaging machine charge door, carry out producing packaging.
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| CN106350279A (en) * | 2016-08-28 | 2017-01-25 | 广州舒雪健康科技有限公司 | Laundry detergent formulation |
| CN106497690A (en) * | 2016-10-12 | 2017-03-15 | 易洁(北京)科技有限公司 | A kind of liquid detergent processing technology |
| CN106544173A (en) * | 2016-10-28 | 2017-03-29 | 广州市南大实业有限公司 | Solidifying pearl of a kind of softening laundry and preparation method and application |
| CN106811335A (en) * | 2016-11-21 | 2017-06-09 | 浙江雅思丽化妆品有限公司 | A kind of environmentally friendly low foam laundry jelly |
| CN106833918A (en) * | 2017-01-05 | 2017-06-13 | 广州品圣洗涤用品有限公司 | A kind of quantitative softness detergent |
| CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
| CN107057876A (en) * | 2017-04-14 | 2017-08-18 | 广州市加茜亚化妆品有限公司 | A kind of solidifying pearl of antibacterial laundry and preparation method thereof |
| CN107711870A (en) * | 2017-09-30 | 2018-02-23 | 珠海国佳凝胶研究院有限公司 | The solidifying pearl of one kind sterilization and its application method |
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| CN109337764A (en) * | 2018-10-09 | 2019-02-15 | 王思淇 | A kind of solidifying pearl and preparation method thereof of doing washing |
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| CN101514306A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof |
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| CN106350279A (en) * | 2016-08-28 | 2017-01-25 | 广州舒雪健康科技有限公司 | Laundry detergent formulation |
| CN106497690A (en) * | 2016-10-12 | 2017-03-15 | 易洁(北京)科技有限公司 | A kind of liquid detergent processing technology |
| CN106544173A (en) * | 2016-10-28 | 2017-03-29 | 广州市南大实业有限公司 | Solidifying pearl of a kind of softening laundry and preparation method and application |
| CN106811335A (en) * | 2016-11-21 | 2017-06-09 | 浙江雅思丽化妆品有限公司 | A kind of environmentally friendly low foam laundry jelly |
| CN106833918A (en) * | 2017-01-05 | 2017-06-13 | 广州品圣洗涤用品有限公司 | A kind of quantitative softness detergent |
| CN106833918B (en) * | 2017-01-05 | 2020-08-04 | 广东优凯科技有限公司 | Quantitative fabric softening detergent |
| CN106906059B (en) * | 2017-02-20 | 2019-12-06 | 广州市南大实业有限公司 | Low-foam easy-rinsing washing gel bead and preparation method and application thereof |
| CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
| CN107057876A (en) * | 2017-04-14 | 2017-08-18 | 广州市加茜亚化妆品有限公司 | A kind of solidifying pearl of antibacterial laundry and preparation method thereof |
| CN107711870A (en) * | 2017-09-30 | 2018-02-23 | 珠海国佳凝胶研究院有限公司 | The solidifying pearl of one kind sterilization and its application method |
| CN108219993A (en) * | 2018-01-09 | 2018-06-29 | 广州市加茜亚化妆品有限公司 | A kind of micro-perfume capsule liquid detergent and preparation method thereof |
| CN108559678A (en) * | 2018-06-19 | 2018-09-21 | 福建省金鹿日化股份有限公司 | Four times of concentration liquid detergents of a kind of microcapsules perfume sweet smell and preparation method thereof |
| CN108865485A (en) * | 2018-06-22 | 2018-11-23 | 西安开米股份有限公司 | A kind of solvent type efficient concentration liquid detergent and preparation method thereof |
| CN109337764A (en) * | 2018-10-09 | 2019-02-15 | 王思淇 | A kind of solidifying pearl and preparation method thereof of doing washing |
| CN111073770A (en) * | 2020-01-09 | 2020-04-28 | 广州市加茜亚化妆品有限公司 | Washing gel bead containing cationic surfactant and preparation method thereof |
| CN111808688A (en) * | 2020-07-14 | 2020-10-23 | 福建恒安集团有限公司 | Antibacterial laundry gel bead and preparation method thereof |
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