CN106497712A - A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof - Google Patents

A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof Download PDF

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Publication number
CN106497712A
CN106497712A CN201610785221.3A CN201610785221A CN106497712A CN 106497712 A CN106497712 A CN 106497712A CN 201610785221 A CN201610785221 A CN 201610785221A CN 106497712 A CN106497712 A CN 106497712A
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amino acid
liquid detergent
acid
containing amino
detergent containing
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CN201610785221.3A
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CN106497712B (en
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谭小军
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Walch (guangzhou) Daily Articles Co Ltd
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Walch (guangzhou) Daily Articles Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to daily use chemicals technical field, do not wash clean to solve existing liquid detergent drift, dirt-removing power is poor, the shortcomings of hinder hand, the invention provides a kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof.Laundry liquid formulation of the present invention is ethoxylated alkyl sulfate, AEO, saturated fatty acid, unrighted acid, alkali, Citric Acid Mono, disodium ethylene diamine tetraacetate, lauroyl amido CAB, amino acid surfactant, sodium chloride, styrene acrylic copolymer, essence, preservative and deionized water, liquid detergent each component of the present invention cooperates, strong detergency, easily rinse, skin friendly, care both hands, without soapy feeling during hand washing.

Description

A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof
Technical field
The invention belongs to daily use chemicals technical field, and in particular to a kind of easy rinsing underwear liquid detergent containing amino acid and its system Preparation Method.
Background technology
Liquid detergent, main component are nonionic surface active agent, and its structure includes water-wet side and hydrophobic end, wherein oleophylic End is combined with spot, then spot is separated with fabric by physical motion (such as hand rubbing, machine movement);While surfactant Reduce the tension force of water, enable water to reach fabric face, make active ingredient play a role;The technology content of liquid detergent is higher, just In various active ingredients are added, clothing after washing, can be made fluffy, soft, smooth glossy, and the work(with degerming and lasting lasting Effect, low using integrated cost, just widely received by people.
Chinese patent application CN104212659A discloses a kind of ecology laundry liquid, and main component includes end group of amino acid Methoxypolyethylene glycol-polylactide block copolymer, coconut oleoyl diethanol amine, methyl p-hydroxybenzoate and para hydroxybenzene first Propyl propionate etc..Laundry with the methoxypolyethylene glycol-polylactide block copolymer of end group of amino acid as principal surfactant Liquid, its strong detergency, foam are low;Simultaneously there is a preferable Environmental compatibility, no biotoxicity and biodegradable, to environment friend Good, but in the invention, amino acid type surfactant consumption has reached 22-30%, and amino acid pattern activating agent consumption is not more Better, compatibility is unreasonable, and using methyl p-hydroxybenzoate and propylparaben be discharged in water, easily make Into water pollution.
Chinese patent CN103451037B discloses a kind of bactericidal liquid detergent containing epsilon-polylysine, the present invention relates to a kind of Bactericidal liquid detergent containing epsilon-polylysine.The bactericidal liquid detergent raw material includes surfactant, anti redeposition agent, chelating agent, increasing Thick dose, epsilon-polylysine, essence.Using epsilon-polylysine as bactericide, restraining and sterilizing bacteria effect is significant is safe for the invention, Meet demand of the consumer to natural prodcuts.But amino acid composition is unstable, apt to deteriorate, affect the soil release performance of liquid detergent Energy.
Content of the invention
In order to solve poor detergency present in prior art, high cost, be difficult the deficiencies such as rinsing, the invention provides one The easy rinsing underwear liquid detergent of kind containing amino acid and preparation method thereof, is matched somebody with somebody with other components using amino acid type surfactant 5, the detergency of liquid detergent is improve, easily rinsing and nonirritant performance.
For achieving the above object, the present invention is employed the following technical solutions.
A kind of easy rinsing underwear liquid detergent containing amino acid, key component and its percentage by weight are:Ethoxylated alkyl Sodium sulphate 2-10%, AEO 1-5%, saturated fatty acid 1-5%, unrighted acid 1-5%, alkali 1.0- 1.5%th, Citric Acid Mono 0.1-3%, disodium ethylene diamine tetraacetate 0.1-1.0%, lauroyl amido CAB 0.2- 5%th, amino acid surfactant 0.2-5%, sodium chloride 0.2-3%, styrene acrylic copolymer 0.08-0.12%, essence 0.1-0.2%, preservative 0.08-0.12% and water 70-90%.
Styrene acrylic copolymer:Ou Nuo forensic chemistries (Shanghai) Co., Ltd., article No. TILAMARTMOP40
Preferably, key component and its percentage by weight are:Ethoxylated alkyl sulfate 3-7%, fatty alcohol polyoxy second Alkene ether 1-3%, saturated fatty acid 3-5%, unrighted acid 1-3%, alkali 1.1-1.3%, Citric Acid Mono 0.1-0.5%, Disodium ethylene diamine tetraacetate 0.1-0.2%, lauroyl amido CAB 1-3%, amino acid surfactant 1.5- 2.5%th, sodium chloride 1-2%, styrene acrylic copolymer 0.08-0.12%, essence 0.1-0.15%, preservative 0.1- 0.12% and water 78-82%.
Preferably, described saturated fatty acid is a kind of in laurate, myristic acid, palmitic acid and stearic acid or two kinds Combination of the above.
Preferably, described unrighted acid is that one or two combine oleic acid with linoleic acid.
Preferably, described alkali is that one or two combine NaOH with potassium hydroxide.
Preferably, described AEO is AEO7With AEO9In one or two combination.
Preferably, described amino acid surfactant is cocoyl Sodium Glycinate, cocoyl glycine potassium, bay Acyl glutamic acid sodium is with lauroyl glutamate potassium, one or more combine.
Preferably, described preservative is Kathon CG.
Further, present invention also offers the preparation method of easy rinsing underwear liquid detergent containing amino acid, step is,
S1:Temperature rise period, sodium chloride and alkali is added in deionized water, heated while stirring, after being warming up to 55-65 DEG C, Saturated fatty acid and unrighted acid is added, is continued stirring and is warmed up to 75-85 DEG C, and insulated and stirred reaction 25-40min, obtain Uniform mixed liquor;
S2:Temperature-fall period, when the uniform mixed liquor that step S1 is obtained is cooled to 55-65 DEG C, adds ethoxylated alkyl Sodium sulphate, AEO, amino acid type surfactant, lauroyl amido CAB, Citric Acid Mono and Disodium ethylene diamine tetraacetate, stirs, and when continuing to be cooled to 35-45 DEG C, adds essence and preservative while stirring, and stirring is Even mixed liquor;
S3:Deionized water dilutes styrene acrylic copolymer, deionized water and styrene acrylic copolymer volume Than for 12-18:1, stir, be subsequently adding in the mixed liquor of step S2 gained, stir, obtain final product.
The present invention has prior art to compare, with advantages below:
1st, strengthen dirt-removing power:The present invention generates soap base using alkali with the reaction of the compositions such as aliphatic acid, oleic acid when making, its The alkali metal salt of middle oleic acid is a kind of preferable emulsifying agent, is conducive to mutually merging between component in liquid detergent, and can be with which His component compatibility reaches chelated metal ions, strengthens dirt-removing power;
2nd, gently do not stimulate:As fatty acid soaps have excitant to skin, amino acid type surfactant can be therewith Compatibility, reduces excitant, and in the present invention, oleic acid is little with the soap base excitant that Citric Acid Mono is generated, and mutually compatibility reduces thorn Sharp property;
3rd, easily rinse:The present invention uses soap base surfactant decontamination, with drop bubble, subtracts sliding effect.
Using the clothing of the underwear liquid detergent washing of the present invention, all kinds of soap bases of introducing can be quick in the water of high rigidity All kinds of heavy metal ion are chelated, surfactant high-effective cleansing in formula system is made;Can play very well in the water of soft Surface-active, in formula, other surfaces activating agent cooperates and removes all kinds of spots.The present invention provide component and proportion be through Cross substantial amounts of experimental verification to obtain, component interphase interaction is complemented each other, and with good decontamination, does not stimulate, easily rinsing is good Good performance.
Specific embodiment
The present invention is described in further detail below by embodiment, but embodiments of the present invention not limited to this.(1) Embodiment 1-4 is as shown in table 1 below with laundry liquid formulation obtained in comparative example 1-5:
1. embodiment 1-4 of table and the formula of liquid detergent obtained in comparative example 1-5
Comparative example 1 with the difference of embodiment 1 is:Without saturated fatty acid;
Comparative example 2 with the difference of embodiment 1 is:Without amino acid type surfactant;
Comparative example 3 with the difference of embodiment 1 is:Using more amino acid type surfactant;
Comparative example 4 with the difference of embodiment 1 is:Without ethoxylated alkyl sulfate and lauroyl aminocarbonyl propyl beet Alkali;
Comparative example 5 with the difference of embodiment 1 is:Without oily bronsted lowry acids and bases bronsted lowry;
Embodiment 1-4 is as follows with comparative example 1-5 preparation method:
S1:Temperature rise period, sodium chloride, alkali is added in deionized water, heated while stirring, after being warming up to 60 DEG C, add Saturated fatty acid and unrighted acid, continue stirring and are warmed up to 80 DEG C, and insulated and stirred reaction 30min, obtain uniform mixed liquor;
S2:Temperature-fall period, when the uniform mixed liquor that step S1 is obtained is cooled to 60 DEG C, adds ethoxylated alkyl sulfates Sodium, AEO, amino acid type surfactant, lauroyl amido CAB, Citric Acid Mono and second two Amine tetraacethyl disodium, stirs, and when continuing to be cooled to 40 DEG C, adds essence and preservative while stirring, stirs and must mix Close liquid;
S3:Deionized water dilutes styrene acrylic copolymer, deionized water and styrene acrylic copolymer volume Than for 15:1, stir, be subsequently adding in the mixed liquor of step S2 gained, stir, obtain final product.
(2) detergency test experiment
Test object:Liquid detergent obtained in embodiment 1-4, comparative example 1-5 and two kinds of commercial laundry liquid.
Method of testing:According to GB/T13174-2008《Dress material detergent detergency and the measure of circulation scourability》In The method of regulation is tested, and test detergency ratio result is as shown in table 2 below.
2. embodiment 1-4 of table and liquid detergent obtained in comparative example 1-5 and commercial laundry liquid detergency ratio
Product Carbon black soiled cotton Sebum soiled cotton
Embodiment 1 1.35 1.39
Embodiment 2 1.32 1.36
Embodiment 3 1.30 1.35
Embodiment 4 1.29 1.32
Comparative example 1 0.98 1.12
Comparative example 2 1.10 0.95
Comparative example 3 1.05 1.01
Comparative example 4 0.91 0.96
Comparative example 5 1.06 1.10
Commercial laundry liquid 1 1.12 1.10
Commercial laundry liquid 2 1.09 1.05
Standard liquid detergent 1 1
Obtained in embodiment 1-4, liquid detergent detergency is relatively good as can be seen from Table 2, wherein the decontamination effect of embodiment 1 Really best.Additionally, being compared with embodiment 1-4 from comparative example 1-5, the content of each component in laundry liquid formulation is to liquid detergent Dirt-removing power have important impact, and the more detergencies of non-surface-active agent are stronger.
(3) the easy evaluating rinsing performance of liquid detergent
Subjects:Embodiment 1-4, liquid detergent obtained in comparative example 1-5, commercial laundry liquid 1-2.
Experiment material:Using GB/T13174-2008《Dress material detergent detergency and the measure of circulation scourability》In Hard water, the full cotton cloth of 10 × 10cm.
Experimental technique:3ml liquid detergents are put in the beaker equipped with 500ml hard water, 1min is stirred, one piece of spinning cloth is put into, After continuing stirring 30min, stop stirring, wring out (holding wet cloth is three times of dry cloth weight), repeat aforesaid operations, until stopping After stirring, in 5 seconds, bubble is wholly absent, and stops operation, and counts number of repetition, as shown in table 3 below.
3 embodiment 1-4 of table and liquid detergent obtained in comparative example 1-5 and commercial laundry liquid rinsing times
Product Number of repetition
Embodiment 1 2
Embodiment 2 2
Embodiment 3 3
Embodiment 4 3
Comparative example 1 5
Comparative example 2 5
Comparative example 3 5
Comparative example 4 5
Comparative example 5 6
Commercial laundry liquid 1 5
Commercial laundry liquid 2 6
Standard liquid detergent 6
From table 3 it is observed that embodiment 1-4 liquid detergent is more easy to rinse.Additionally, by comparative example 1-5 and embodiment 1-4 ratio Compared with understanding, the content of each component in laundry liquid formulation has important impact to the easy rinsing performance of liquid detergent.
(4) liquid detergent irritation test
Test object:Liquid detergent prepared by embodiment 1-4 and comparative example 1-5 and two kinds of commercial laundry liquid
Method of testing:Tester with the aqueous solution hand wash laundry 15 minutes for being mixed with 0.3% liquid detergent, collects test respectively Person is to irritating assessment data.
Test result:Per group of 10 bit test persons, respectively using being mixed with embodiment 1-4 and washing prepared by comparative example 1-5 After the aqueous solution hand wash laundry of clothing liquid and two kinds of commercial laundry liquid, 10 bit test persons are calculated to liquid detergent excitant average ratings point (10 without any excitant, 1 most strong and stimulating), as shown in table 4.
The nonirritant evaluation of 4 liquid detergent of table
Product Averagely nonirritant evaluation score value
Embodiment 1 10
Embodiment 2 10
Embodiment 3 9
Embodiment 4 9
Comparative example 1 4
Comparative example 2 7
Comparative example 3 6
Comparative example 4 8
Comparative example 5 7
Commercial laundry liquid 1 7
Commercial laundry liquid 2 7
Standard liquid detergent 6
From table 4, it can be seen that liquid detergent is little to skin irritation obtained in embodiment 1-4, also, by comparative example 1-5 with Embodiment 1-4 compares and understands, the content of each component in laundry liquid formulation to liquid detergent gentle, not stimulate performance to have important Impact.
In sum, liquid detergent each component disclosed in this invention cooperates, strong detergency, easily rinses, skin friendly, Care both hands, without soapy feeling during hand washing.
The above only further illustrates the technology contents of the present invention with embodiment, is easier to understand in order to reader, But do not represent embodiments of the present invention and be only limitted to this, any technology extension that is done according to the present invention is recreated, and receives this Bright protection.

Claims (9)

1. a kind of easy rinsing underwear liquid detergent containing amino acid, it is characterised in that key component and its percentage by weight are:Ethoxy Base sodium alkyl sulfate 2-10%, AEO 1-5%, saturated fatty acid 1-5%, unrighted acid 1-5%, Alkali 1.0-1.5%, Citric Acid Mono 0.1-3%, disodium ethylene diamine tetraacetate 0.1-1.0%, lauroyl amido CAB 0.2-5%, amino acid surfactant 0.2-5%, sodium chloride 0.2-3%, styrene acrylic copolymer 0.08-0.12%, Essence 0.1-0.2%, preservative 0.08-0.12% and deionized water 70-90%.
2. the easy rinsing underwear liquid detergent containing amino acid according to claim 1, it is characterised in that key component and its weight Measuring percentage is:Ethoxylated alkyl sulfate 3-7%, AEO 1-3%, saturated fatty acid 3-5%, insatiable hunger With aliphatic acid 1-3%, alkali 1.1-1.3%, Citric Acid Mono 0.1-0.5%, disodium ethylene diamine tetraacetate 0.1-0.2%, bay Amido propyl betaine 1-3%, amino acid surfactant 1.5-2.5%, sodium chloride 1-2%, styrene acrylic copolymerization Thing 0.08-0.12%, essence 0.1-0.15%, preservative 0.1-0.12% and deionized water 78-82%.
3. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described saturation Aliphatic acid is a kind of in laurate, myristic acid, palmitic acid and stearic acid or two or more combinations.
4. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described insatiable hunger It is that one or two combine oleic acid with linoleic acid with aliphatic acid.
5. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described alkali is One or two combine NaOH with potassium hydroxide.
6. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described fat Alcohol APEO is AEO7With AEO9In one or two combination.
7. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described amino Acid surfaces activating agent is cocoyl Sodium Glycinate, cocoyl glycine potassium, sodium lauroyl glutamate and lauroyl paddy One or more combinations in propylhomoserin potassium.
8. the easy rinsing underwear liquid detergent containing amino acid according to claim 1 and 2, it is characterised in that described anti-corrosion Agent is Kathon CG.
9. the preparation method of the easy rinsing underwear liquid detergent containing amino acid according to any one of claim 1-8, its feature It is, step is,
S1:Temperature rise period, sodium chloride and alkali is added in deionized water, heated while stirring, after being warming up to 55-65 DEG C, add Saturated fatty acid and unrighted acid, continue stirring and are warmed up to 75-85 DEG C, and insulated and stirred reaction 25-40min, obtain uniformly Mixed liquor;
S2:Temperature-fall period, when the uniform mixed liquor that step S1 is obtained is cooled to 55-65 DEG C, adds ethoxylated alkyl sulfates Sodium, AEO, amino acid type surfactant, lauroyl amido CAB, Citric Acid Mono and second two Amine tetraacethyl disodium, stirs, and when continuing to be cooled to 35-45 DEG C, adds essence and preservative while stirring, stirs Mixed liquor;
S3:Deionized water dilutes styrene acrylic copolymer, and deionized water with styrene acrylic copolymer volume ratio is 12-18:1, stir, be subsequently adding in the mixed liquor of step S2 gained, stir, obtain final product.
CN201610785221.3A 2016-08-31 2016-08-31 A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof Active CN106497712B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057888A (en) * 2017-06-17 2017-08-18 安徽方翔羽绒制品有限公司 A kind of preparation method of feather products cleaning agent
CN107418772A (en) * 2017-06-17 2017-12-01 安徽方翔羽绒制品有限公司 A kind of preparation method of the cleaning agent of down products
CN109294763A (en) * 2018-11-22 2019-02-01 中山榄菊日化实业有限公司 A kind of full effect muting sensitive surface activator composition and the liquid detergent containing it

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492574A (en) * 2011-12-13 2012-06-13 江南大学 Tableware detergent containing N-acylglutamate
CN104540551A (en) * 2012-05-30 2015-04-22 科莱恩金融(Bvi)有限公司 Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamines and having improved foam quality and higher viscosity

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492574A (en) * 2011-12-13 2012-06-13 江南大学 Tableware detergent containing N-acylglutamate
CN104540551A (en) * 2012-05-30 2015-04-22 科莱恩金融(Bvi)有限公司 Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamines and having improved foam quality and higher viscosity

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057888A (en) * 2017-06-17 2017-08-18 安徽方翔羽绒制品有限公司 A kind of preparation method of feather products cleaning agent
CN107418772A (en) * 2017-06-17 2017-12-01 安徽方翔羽绒制品有限公司 A kind of preparation method of the cleaning agent of down products
CN109294763A (en) * 2018-11-22 2019-02-01 中山榄菊日化实业有限公司 A kind of full effect muting sensitive surface activator composition and the liquid detergent containing it

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