CN101885605B - Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof - Google Patents
Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof Download PDFInfo
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- CN101885605B CN101885605B CN 201010212847 CN201010212847A CN101885605B CN 101885605 B CN101885605 B CN 101885605B CN 201010212847 CN201010212847 CN 201010212847 CN 201010212847 A CN201010212847 A CN 201010212847A CN 101885605 B CN101885605 B CN 101885605B
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Abstract
The invention discloses a ceramic particle with adsorption, ion exchange and negative ion generating functions. The ceramic particle is prepared by the following raw materials by weight percentage content: 15-35% of natural adsorption material, 10-25% of ion exchange material, 20-45% of natural negative ion releasing material, 1-15% of rare earth material, 0.05-1.5% of radioactivity material, 5-25% of binding material and 2-12% of water. The invention also discloses a preparation method of the ceramic particle. The ceramic particle of the invention has strong adsorption property, good ion exchange property and high negative ion releasing quantity and has good washing, cleaning and purifying capabilities.
Description
Technical field
The invention belongs to features stupalith category, particularly a kind of ceramic particle with adsorptivity, ion-exchange and generation anion function and preparation method thereof.
Background technology
Synthetic detergent is the essential articles for use of current people's cleaning clothes and tableware, because it is easy to use, the washing clean effect is good and be extensive use of.But it belongs to synthetic chemical, and human body and environment are had certain harm, and its maximum shortcoming is polluted water, causes and contains a large amount of tensio-active agents and washing auxiliary detergent in the water.In order to protect environment and ourselves, scientists study has been developed the cleaning product of new alternative washing powder, and wherein ceramic-like laundry particle is exactly one of them.At present, pottery laundry granule type products is because it belongs to the preliminary study stage, and its washing dirt-removing functions is single, and work-ing life is short.Therefore, need have the ceramic particle of multiple function, increasing the washing soil removability of ceramic particle, and research and analyse from the washing detergency mechanism, increase the work-ing life of ceramic particle simultaneously.Patent of invention: a kind of Ceramic Balls (number of patent application: the Ceramic Balls that 200610047297.2) relates to that produces far infrared rays and negative ion, has certain washing function, but mainly be far infrared function, it is not high that negative ion discharges number, and the function of other washing decontaminations is not enough; Patent of invention: ceramic washing ball and preparation technology thereof (number of patent application: 99125580.1) introduced a kind of ceramic washing ball, formed by clay, phyllite, tourmalinite and OB20, raw materials used is natural crystal, hypofunctions such as its negative ion can not fine satisfied washing, the Cress requirement.
Summary of the invention
The objective of the invention is can not fine satisfied washing in order to solve existing ceramic washing ball, the technical problem of Cress requirement, and a kind of ceramic particle with adsorptivity, ion-exchange and generation anion function and preparation method thereof is provided.
For achieving the above object, the ceramic particle with adsorptivity, ion-exchange and generation anion function that the present invention proposes, its raw material configuration by following weight percentage forms: natural sorbing material: 15～35%, ion-exchange material: 10～25%, natural negative ion releasable material: 20～45%, rare earth material: 1～15%, radio active material: 0.05～1.5%, matrix material: 5～25%, water: 2～12%.
The preparation method of the described ceramic particle that the present invention proposes comprises the steps:
With described ceramic particle raw material according to set of dispense than strict weighing, put into airtight stirrer and stir;
Be rolled onto the shaped granule of 2.0～15mm with the dressing machine, dry;
Fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Ceramic particle provided by the invention is to have natural sorptive material, ion-exchange material, and natural negative ion releasable material is main raw material, add rare earth material, radio active material and matrix material again, dry screening through ceramic particle moulding, high-temperature firing, washing and form.Its negative ion discharges high, and between making pottery and the porcelain stagnation point, micropore is tiny and dense in the particle, and sintering strength is good, is applicable to any water temperature, uses not produce any sedimentable matter in washing machine.Therefore can clean the place at tumbling-box washing machine, agitator type washing machine, pulsator washing machine, drying and washing machine and dishwasher etc. uses.
Compare with existing ceramic washing ball, the present invention has following beneficial effect:
1, ceramic particle of the present invention adopts the micron order material to form through high-temperature firing, the minim channel of particle internal adsorption material and the contact channels on each raw material surface have been increased, the matrix material of Shi Yonging and water resolve into gas and overflow and get through and increase the ceramic particle inner duct when high temperature simultaneously, its absorption property is improved greatly, help calcium ions and magnesium ions, heavy metal ion, suspended substance and particulate state spot in the planar water, reduce the secondary deposition of particulate species spot on clothing, improve washing and cleaning effect.
2, ceramic particle of the present invention can discharge negative ion owing to interpolation and rare earth material and radio active material under any temperature condition, and its negative ion discharges number height.Negative ion H
3O
2 -Water clusters is diminished, seepage force and the washing force of the son that moisturizes; Organic substances such as oxygenolysis oil stain, protein increase the washing clean effect.
3, the ion-exchange material of ceramic particle of the present invention discharges Na in water
+, K
+Ion is with in the water and the Ca of spot
2+, Mg
2+Plasma carries out ion-exchange, makes the water-soluble increase of the spot that is deposited on the clothing and is dissolved in water.
4, ceramic particle of the present invention adopts the micron order material to form through high-temperature firing, and interior each raw material combination of particle is tight, smooth in appearance, and function is lasting, long service life.
5, the alternative synthetic detergent of ceramic particle of the present invention, laundry effect is good, and non-foam need not rinsing, water and electric saving, not polluted water and environment, safety and environmental protection.
Embodiment:
Ceramic particle with adsorptivity, ion-exchange and generation anion function of the present invention, raw material configuration by following weight percentage forms: natural sorbing material: 15～35%, ion-exchange material: 10～25%, natural negative ion releasable material: 20～45%, rare earth material: 1～15%, radio active material: 0.05～1.5%, matrix material: 5～25%, water: 2～12%.
Wherein: natural sorbing material can adopt one or more in natural zeolite, diatomite and the medical stone, and its fineness is 0.5～50um.
Ion-exchange material can adopt natural zeolite, one or more in stone needle and the aluminite, and its fineness is 5～100um.
Natural negative ion releasable material can adopt tourmalinite, serpentine, and one or more in opal and the deep-sea volcanic ash, its fineness is 0.5～50um.
Rare earth material can adopt rare earth oxide, one or more in rare-earth mineral and the rare-earth element salt, and its fineness is 5～100um.
Radio active material can adopt one or more in thorium dioxide and the titanium dioxide radium, and its fineness is 5～100um.
Matrix material can adopt one or more and the kaolin in polyacrylic resin, polyoxyethylene glycol, Magnesium Stearate, the dextrin to mix, and its fineness is 5～100um.
Function ceramics particle of the present invention washs, the Cress ultimate principle is as follows:
1, function ceramics particle of the present invention is owing to exist a large amount of micropores, and is very strong with adsorptive power.After water contacts, can adsorb, the free chlorine in the water of decomposition and impurity, organism, assorted bacterium etc., stoped the secondary deposition of dirty spot on clothing, and chlorine class material is to the pollution of clothing, the effect of bleaching when playing clothes washing; Micropore can adsorb toxic and harmful and suspended particles simultaneously, plays the effect of Cress.
2, the ion-exchange material that contains of function ceramics particle of the present invention discharges Na in water
+, K
+Ion is with in the water and the Ca of spot
2+, Mg
2+Plasma carries out ion-exchange, reduces water hardness, simultaneously Na
+, K
+Ion-exchange has replaced Ca
2+, Mg
2+Plasma has just increased Ca
2+, Mg
2+Plasma spot and sedimentary solvability are impelled the water-soluble increase of the spot that is deposited on the clothing and to be dissolved in water separated.
3, function ceramics particle of the present invention is in the radiation of radio active material self and generate energy, with rare earth material as the medium transmission capacity, excite piezoelectricity and the pyroelectricity of natural negative ion releasable material, make positive and negative charge center relative displacement in the natural negative ion releasable material crystalline structure, cause the variation of electric distance in the crystal, cause asymmetric, the anharmonicity vibration of the coordination electronics in its lattice vacancy, produce little electric current, cause in the water and the slight electrolysis of airborne water molecules, produce negative ion H
3O
2 -, water clusters is diminished, reduce the surface tension of the aqueous solution, seepage force and the washing force of the son that moisturizes; While negative ion H
3O
2 -Have certain oxidation susceptibility, organic substances such as oxygenolysis oil stain, protein increase the washing clean effect.Negative ion H in addition
3O
2 -Can combine with bacterium, dust, smoke particles and water droplet, reach the purpose of Cress.
The present invention will be further described below in conjunction with specific embodiment.According to prescription of the present invention, dispose the material of the described ceramic particle of preparation of following different ratios.Wherein each component concentration is: components in weight percent content umber.As, A component: 10 parts, represent that namely the A component concentration is 10% of gross weight.
Embodiment one
Natural zeolite: 45 parts, tourmalinite: 27 parts, rare earth oxide: 3 parts, thorium dioxide: 0.08 part, polyacrylic resin: 3.92 parts, kaolin: 16 parts, water: 5 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment two
Diatomite: 21.5 parts, natural zeolite: 18.5 parts, tourmalinite: 19 parts, serpentine: 6 parts, rare-earth mineral: 7 parts, titanium dioxide radium: 0.06 part, polyacrylic resin: 2.5 parts, polyoxyethylene glycol: 1.44 parts, high mountain range scholar: 15 parts, water: 9 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment three
Natural zeolite: 8.5 parts, diatomite: 5 parts, medical stone: 8.5 parts, stone needle: 3.5 parts; aluminite: 2.5 parts, tourmalinite: 9 parts, serpentine: 7.5 parts, opal: 11.5 parts; the deep-sea volcanic ash: 8 parts, rare earth oxide: 3 parts, rare-earth mineral: 2.5 parts; rare-earth element salt: 1.5 parts, thorium dioxide: 0.05 part, titanium dioxide radium: 0.05 part; polyacrylic resin: 2 parts, polyoxyethylene glycol: 1.2 parts, Magnesium Stearate: 1.5 parts; dextrin: 2.2 parts, kaolin: 14 parts, water: 8 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment four
Diatomite: 14.5 parts, medical stone: 10.5 parts, stone needle: 3.5 parts; aluminite: 4.5 parts, serpentine: 15 parts, opal: 10 parts; deep-sea volcanic ash: 7 parts; rare-earth mineral: 3 parts, rare-earth element salt: 4 parts, titanium dioxide radium: 0.5 part; polyoxyethylene glycol: 3 parts; Magnesium Stearate: 2.5 parts, kaolin: 12 parts, water: 10 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment five
Natural zeolite: 15 parts, medical stone: 7 parts, stone needle: 5 parts, serpentine: 9 parts; the deep-sea volcanic ash: 21 parts, rare earth oxide: 5.5 parts, rare-earth element salt: 6.5 parts, thorium dioxide: 0.05 part; polyacrylic resin: 1.95 parts, dextrin: 4 parts, kaolin: 16 parts, water: 9 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment six
Natural zeolite: 16 parts, medical stone: 7 parts, aluminite: 6 parts; tourmalinite: 19 parts, opal: 9 parts, deep-sea volcanic ash: 5 parts; rare-earth mineral: 7.5 parts; rare-earth element salt: 4.5 parts, titanium dioxide radium: 0.08 part, polyacrylic resin: 3 parts; Magnesium Stearate: 1.4 parts; dextrin: 1.52 parts, kaolin: 12 parts, water: 8 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment seven
Natural zeolite: 13 parts, diatomite: 7 parts, stone needle: 6.5 parts; aluminite: 1.5 parts, opal: 23 parts, deep-sea volcanic ash: 17 parts; rare-earth mineral: 2 parts; rare-earth element salt: 3 parts, thorium dioxide: 0.5 part, titanium dioxide radium: 0.5 part; polyoxyethylene glycol: 4.5 parts; dextrin: 5.5 parts, kaolin: 12 parts, water: 4 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment eight
Diatomite: 3 parts, medical stone: 9 parts, stone needle: 7 parts, aluminite: 4 parts, tourmalinite: 24 parts, serpentine: 10 parts, rare earth oxide: 7 parts, rare-earth element salt: 6 parts, thorium dioxide: 1.0 parts, polyacrylic resin: 4 parts, polyoxyethylene glycol: 2 parts, dextrin: 5 parts, kaolin: 11 parts, water: 8 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment nine
Medical stone: 25 parts, aluminite: 18 parts, tourmalinite: 21 parts, the deep-sea volcanic ash: 3 parts, rare-earth mineral: 5 parts, rare-earth element salt: 6 parts, titanium dioxide radium: 1.0 parts, Magnesium Stearate: 2 parts, dextrin: 3 parts, kaolin: 9 parts, water: 7 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Embodiment ten
Medical stone: 20 parts, stone needle: 10 parts, opal: 8 parts, the deep-sea volcanic ash: 17 parts, rare earth oxide: 13 parts, thorium dioxide: 0.5 part, titanium dioxide radium: 0.5 part, dextrin: 10 parts, kaolin: 12 parts, water: 9 parts.With above component, put into airtight stirrer and stir, be rolled onto the shaped granule of 2.0～15mm then with the dressing machine, after tentatively drying, fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Ceramic particle provided by the invention is smooth in appearance, and inside has spherosome or the column ceramic particle of a large amount of micro channels.
Claims (4)
1. ceramic particle with adsorptivity, ion-exchange and generation anion function, it is characterized in that: the raw material configuration by following weight percentage forms: natural sorbing material: 15～35%, ion-exchange material: 10～25%, natural negative ion releasable material: 20～45%, rare earth material: 1～15%, radio active material: 0.05～1.5%, matrix material: 5～25%, water: 2～12%;
Wherein:
Described natural sorbing material is natural zeolite, at least a in diatomite and the medical stone, and its fineness is 0.5～50
μ m
Described ion-exchange material is natural zeolite, at least a in stone needle and the aluminite, and its fineness is 5～100
μ m
Described natural negative ion releasable material is tourmalinite, serpentine, and at least a in opal and the deep-sea volcanic ash, its fineness is 0.5～50
μ m
Described radio active material is thorium dioxide, and its fineness is 5～100
μ m
2. ceramic particle as claimed in claim 1, it is characterized in that: described rare earth material is rare earth oxide, at least a in rare-earth mineral and the rare-earth element salt, its fineness is 5～100
μ m
3. ceramic particle as claimed in claim 1, it is characterized in that: described matrix material is that at least a and kaolin in polyacrylic resin, polyoxyethylene glycol, Magnesium Stearate, the dextrin mixes, and its fineness is 5～100
μ m
4. the preparation method of ceramic particle according to claim 1 comprises the steps:
With described ceramic particle raw material according to set of dispense than strict weighing, put into airtight stirrer and stir;
Be rolled onto the shaped granule of 2.0～15mm with the dressing machine, dry;
Fire with 800～1500 ℃ of High Temperature Furnaces Heating Apparatuss and to form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010212847 CN101885605B (en) | 2010-06-28 | 2010-06-28 | Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010212847 CN101885605B (en) | 2010-06-28 | 2010-06-28 | Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof |
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| CN101885605B true CN101885605B (en) | 2013-09-04 |
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| GB201018318D0 (en) | 2010-10-29 | 2010-12-15 | Xeros Ltd | Improved cleaning method |
| GB201100627D0 (en) * | 2011-01-14 | 2011-03-02 | Xeros Ltd | Improved cleaning method |
| CN102249630A (en) * | 2011-04-28 | 2011-11-23 | 北京工业大学 | Cement-based material able to adsorb heavy metal ions |
| CN103127904B (en) * | 2011-11-29 | 2015-11-04 | 新星有限公司 | For removing the LNS pottery of radioactive material contamination and anti-oxidant water |
| CN102584191B (en) * | 2012-03-22 | 2014-05-14 | 上海大学 | Method for preparing cordierite ceramics by using serpentine tailings |
| GB201212098D0 (en) | 2012-07-06 | 2012-08-22 | Xeros Ltd | New cleaning material |
| CN103030213B (en) * | 2012-12-11 | 2014-04-23 | 刘建明 | Aquarium filtering material with high porosity and preparation method thereof |
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| GB201319782D0 (en) | 2013-11-08 | 2013-12-25 | Xeros Ltd | Cleaning method and apparatus |
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| CN105175599A (en) * | 2015-09-21 | 2015-12-23 | 安徽皖东化工有限公司 | Preparing method for heat-resistant strong-base type anion exchange resin |
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| CN109250900B (en) * | 2018-12-07 | 2021-08-31 | 佛山市东鹏陶瓷有限公司 | Anion powder, glaze and preparation method thereof |
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| CN111874868B (en) * | 2020-08-12 | 2022-11-29 | 江西宝安新材料科技有限公司 | Portable oxygen generator capable of synchronously releasing negative ions |
| CN114874540B (en) * | 2022-04-06 | 2024-02-23 | 佛山市顺德区美的洗涤电器制造有限公司 | Negative ion material, preparation method thereof, dish washer and application of tourmaline material in preparation of negative ion material for dish washer |
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