CN111874868B - Portable oxygen generator capable of synchronously releasing negative ions - Google Patents

Portable oxygen generator capable of synchronously releasing negative ions Download PDF

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Publication number
CN111874868B
CN111874868B CN202010806303.8A CN202010806303A CN111874868B CN 111874868 B CN111874868 B CN 111874868B CN 202010806303 A CN202010806303 A CN 202010806303A CN 111874868 B CN111874868 B CN 111874868B
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pellet
powder
negative ion
anion
oxygen
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CN111874868A (en
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刘建军
边义军
贾奇
沈文广
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Hunan Jiakang Medical Device Manufacturing Co ltd
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Jiangxi Baoan New Material Tech Co ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0259Physical processing only by adsorption on solids
    • C01B13/0262Physical processing only by adsorption on solids characterised by the adsorbent
    • C01B13/0274Other molecular sieve materials
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0046Nitrogen
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225Yttrium oxide or oxide-forming salts thereof
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3227Lanthanum oxide or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229Cerium oxides or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Abstract

The invention discloses a portable oxygen generator capable of synchronously releasing negative ions, which comprises a machine body and an oxygen separation column arranged in the machine body, wherein the oxygen separation column is prepared by uniformly mixing a molecular sieve pellet and a negative ion ceramic pellet according to a proportion, filling, pressing and sealing, the negative ion ceramic pellet is prepared by mixing 40-60 wt% of kaolin, 10-20 wt% of negative ion powder and 20-40 wt% of rare earth metal oxide powder, adding the kaolin, the negative ion powder and the rare earth metal oxide powder into a ball mill for ball milling and ball agglomerating, preparing into a ceramic pellet, putting into a kiln, heating, preserving heat, cooling and discharging to prepare the negative ion ceramic pellet, mixing the molecular sieve pellet and the negative ion ceramic pellet, filling into a column tube, and pressing into a columnar oxygen separation column. The invention not only increases the function of generating negative ions, but also occupies no space, simplifies the manufacture and reduces the use cost under the condition that the prior oxygen generator does not change the size and the structure of the oxygen separation column.

Description

Portable oxygen generator capable of synchronously releasing negative ions
Technical Field
The invention relates to an oxygen generator, in particular to a portable oxygen generator which can generate oxygen and synchronously release negative ions.
Background
Most of the existing oxygen generators adopt the adsorption performance of a molecular sieve, and separate nitrogen and oxygen in air by taking a large-displacement oil-free compressor as power through a physical principle to finally obtain high-concentration oxygen. Generally, a household sample making machine adopts a 220V alternating current power supply, and a portable oxygen generator adopts a 12V lithium battery direct current power supply for carrying convenience. The negative ions are known in the medical community as "air vitamins". Medical research shows that the negatively charged particles in the air can increase the oxygen content in blood, is favorable for blood oxygen transportation, absorption and utilization, and has the functions of promoting human body metabolism, improving human body immunity, enhancing human body muscle energy and regulating body function balance. The anion can purify and clean air, improve the living environment and enhance the physique of human bodies, and the standard published by the world health organization is that more than 1000 anions are contained in each cubic centimeter to be beneficial to the human bodies. Therefore, the anion function is mostly added to the existing oxygen generator, the oxygen absorption capacity of a user can be effectively improved, and the machine efficiency and the experience feeling are improved.
Most of the existing oxygenerators are added with negative ions and are realized by arranging a negative ion generator in the oxygenerator. The principle of the anion generator mainly comprises that a circuit composed of an impulse type circuit, an overvoltage current-limiting circuit, a high-voltage and low-voltage isolation circuit and the like is increased to alternating-current high voltage, then pure direct-current negative high voltage is obtained after rectification and filtering of special grade electronic materials, the direct-current negative high voltage is connected to a release tip made of metal or carbon elements, high corona is generated by the tip direct-current high voltage, a large amount of electrons (e-) are emitted at high speed, and the electrons can be immediately captured by oxygen molecules (O2) in the air, so that air anions are generated.
The built-in oxygen generator which can realize the production of negative ions while producing oxygen by the existing oxygen generator by additionally arranging the negative ion generator needs a complete set of negative ion generator, electrical elements and a power supply, so that the manufacturing difficulty and the manufacturing cost of the negative ion oxygen generator are high, the volume of the oxygen generator is increased, the household space is occupied, the carrying is not convenient, the maintenance workload is increased, and the use cost is increased.
In the prior art, an anion generating module and an internal circuit are connected through a lead and controlled by a switch to release anions, and some anion lamps are similar to an anion generator in form, and need to use alternating direct current and an electronic element circuit board, so that the problems pointed out in the background art exist.
Disclosure of Invention
Aiming at the problems of the anion oxygen generator in the prior art, the invention provides the portable oxygen generator which can synchronously release a large amount of anions while preparing oxygen by the existing oxygen generator only by changing the raw material composition of the oxygen separation column in the existing oxygen generator without additionally assembling an anion generator and related electronic elements and without power supply coordination.
The technical scheme adopted by the invention to solve the technical problem is as follows: a portable oxygen generator capable of synchronously releasing negative ions comprises a machine body and an oxygen separation column arranged in the machine body, wherein the oxygen separation column is prepared by uniformly mixing molecular sieve pellets and negative ion ceramic pellets in proportion and filling the mixture into a column tube for pressing and sealing, and the negative ion ceramic pellets consist of 40-60 wt% of kaolin, 10-20 wt% of negative ion powder and 20-40 wt% of rare earth metal oxide powder and are prepared by the following steps:
1. adding kaolin, anion powder and rare earth metal oxide powder into a ball mill according to the proportion for ball milling, adding a proper amount of water to prepare wet powder,
2. adding the powder into a ball machine for ball forming to prepare wet blank ceramic balls with the thickness of 0.2-0.4cm,
3. drying and shaping the surface of the wet green ceramic pellet, placing the wet green ceramic pellet into a kiln, heating the wet green ceramic pellet to 600-800 ℃, keeping the temperature for 10-20 hours, cooling and discharging the wet green ceramic pellet out of the kiln to prepare negative ion ceramic pellets,
4. mixing a molecular sieve pellet with the particle size of 0.2-0.4cm and a negative ion ceramic pellet with the particle size of 0.2-0.4cm according to the weight ratio of 2-4: 0.5 to 1.5, after being mixed evenly, the mixture is filled into a column tube and pressed into a column shape, and the column tube is taken out and hermetically packaged to prepare the oxygen separation column.
The negative ion powder is natural tourmaline powder or a mixture of natural tourmaline powder and rare earth oxide.
The weight ratio of the molecular sieve beads to the negative ion ceramic beads is preferably 3:1.
the rare earth metal oxide is lanthanum oxide (La) 2 0 3 ) Cerium oxide (Ce 0) 2 ) Neodymium oxide (Nb) 2 0 3 ) Yttrium oxide (Y) 2 0 3 ) And so on.
The zeolite molecular sieves, which are primarily sodium-modified (sodium type) or lithium-modified (lithium type), are commercially available from both factories and markets. The molecular sieve is a hydrate of a crystalline aluminosilicate metal salt, the main components being alumina and silica.
The invention firstly mixes kaolin, anion powder and rare earth metal oxide powder to prepare anion ceramic pellets, and then mixes the anion ceramic pellets with molecular sieve pellets to prepare the oxygen separation column. Wherein the molecular sieve plays a role in enriching and separating oxygen mainly through pressure swing adsorption. The anion ceramic pellet has certain radioactivity, so that gas molecules can generate electron transfer, and lost electrons are combined with oxygen in the air to form oxygen anions.
The invention mixes kaolin, anion powder and rare earth metal oxide to prepare anion ceramic balls with the diameter of 0.2-0.4 cm. Mixing the negative ion ceramic balls and the molecular sieve balls according to a certain proportion, filling a column tube, and pressing to prepare the oxygen separation column. Under the condition of not changing the principle and the structure of the oxygen generator, forest negative ions of about 2000 to 3000/cm & lt 3 & gt can be released while oxygen is generated without any external condition, and the product experience of the oxygen generator is effectively improved.
Compared with the prior art, the invention has the following characteristics:
1. the invention can spontaneously generate and release negative ions without additional conditions such as high pressure and the like, is particularly suitable for a portable oxygen generator,
2. the invention utilizes natural mineral to spontaneously generate negative ions without generating ozone, solves the problem that the traditional negative ion generating device in a high-pressure mode can generate ozone while generating negative ions, the ozone is toxic to human bodies,
3. the invention does not change the principle and structure of the oxygen generator, and under the condition of not changing the precursor of the size and structure of the oxygen separation column, the invention not only increases the function of generating negative ions, but also does not occupy space, simplifies the manufacture and reduces the use cost.
Detailed Description
The first embodiment is a portable oxygen generator capable of synchronously releasing negative ions, which comprises a machine body and an oxygen separation column arranged in the machine body. The oxygen separation column is prepared by physically mixing a molecular sieve pellet and an anion ceramic pellet according to a certain proportion, filling, pressing and sealing, wherein the anion ceramic pellet consists of 50wt% of kaolin, 15wt% of anion powder and 35wt% of lanthanum oxide powder (the mesh number is 200-300), and is prepared by the following steps:
1. adding kaolin, anion powder and lanthanum oxide powder into a ball mill according to the proportion for ball milling, adding proper amount of water (the powder is preferably bonded into a cluster) to prepare wet powder,
2. adding the powder into a ball machine for ball forming to prepare wet blank ceramic balls with the thickness of 0.2-0.4cm,
3. drying and shaping the surface of the wet blank ceramic pellet, placing the wet blank ceramic pellet into a kiln, heating the wet blank ceramic pellet to 750 ℃, keeping the temperature for 14 hours, cooling and discharging the wet blank ceramic pellet out of the kiln to prepare negative ion ceramic pellets,
4. mixing a molecular sieve pellet with the particle size of 0.2-0.4cm and a negative ion ceramic pellet with the particle size of 0.2-0.4cm according to the weight ratio of 3: and 1, filling the mixture into a column tube, pressing the mixture into a column shape, taking out the column tube, and sealing and packaging the column tube to prepare the oxygen separation column.
In the second embodiment, the portable oxygen generator capable of synchronously releasing negative ions comprises a machine body and an oxygen separation column arranged in the machine body, the oxygen removal separation column of the oxygen generator has the same structure as the existing oxygen generator except that the raw material composition of the oxygen separation column in the oxygen generator is different from that of the oxygen separation column in the oxygen generator in the prior art. The oxygen separation column is formed by physically mixing molecular sieve pellets and anion ceramic pellets according to a proportion, filling the mixture into a column tube, pressing and sealing the mixture, wherein the anion ceramic pellets consist of 40wt% of kaolin, 20wt% of anion powder and 40wt% of cerium oxide powder (the mesh number is 200-300), and the oxygen separation column is prepared according to the following method steps:
1. adding kaolin, anion powder and cerium oxide powder into a ball mill according to the proportion for ball milling, adding a proper amount of water (the powder is preferably bonded into a cluster shape) to prepare wet powder,
2. adding the powder into a ball machine for ball forming to prepare wet blank ceramic balls with the thickness of 0.2-0.4cm,
3. drying and shaping the surface of the wet blank ceramic pellet, placing the wet blank ceramic pellet into a kiln, heating the wet blank ceramic pellet to 680 ℃, keeping the temperature for 18 hours, cooling the wet blank ceramic pellet out of the kiln to prepare negative ion ceramic pellets,
4. mixing a molecular sieve pellet with the particle size of 0.2-0.4cm and a negative ion ceramic pellet with the particle size of 0.2-0.4cm according to the weight ratio of 2.5:1.5, after physical mixing, filling the mixture into a column tube, pressing the mixture into a column shape, taking the column tube out, and sealing and packaging the column tube to prepare the oxygen separation column.
The oxygen separation column of the oxygen generator has different raw material compositions with the oxygen separation column in the existing oxygen generator, and other structures are the same as the structure of the oxygen generator in the prior art. The oxygen separation column is prepared by physically mixing a molecular sieve pellet and an anion ceramic pellet according to a certain proportion, refilling, pressing and sealing, wherein the anion ceramic pellet consists of 58wt% of kaolin, 12wt% of anion powder and 30wt% of praseodymium oxide powder (the mesh number is 200-300), and is prepared by the following steps:
1. adding kaolin, anion powder and praseodymium oxide powder into a ball mill according to the proportion for ball milling, adding proper amount of water (the powder is preferably bonded into a cluster shape) to prepare wet powder,
2. adding the powder into a ball machine for ball forming to prepare wet blank ceramic balls with the thickness of 0.2-0.4cm,
3. drying and shaping the surface of the wet blank ceramic pellet, placing the wet blank ceramic pellet into a kiln, heating the wet blank ceramic pellet to 700 ℃, keeping the temperature for 14.5 hours, cooling and discharging the wet blank ceramic pellet out of the kiln to prepare negative ion ceramic pellets,
4. mixing a molecular sieve pellet with the particle size of 0.2-0.4cm and a negative ion ceramic pellet with the particle size of 0.2-0.4cm according to the weight ratio of 2:0.8, filling the mixture into a column tube, pressing the mixture into a column shape, taking out the column tube, and sealing and packaging the column tube to prepare the oxygen separation column.

Claims (3)

1. The utility model provides a portable oxygenerator that can release anion in step, it includes organism and the oxygen separation post of setting in the organism, its characterized in that: the oxygen separation column is prepared by uniformly mixing molecular sieve pellets and anion ceramic pellets in proportion, filling the mixture into a column tube, pressing and sealing the mixture, wherein the anion ceramic pellets are prepared by mixing 40-60 wt% of kaolin, 10-20 wt% of anion powder and 20-40 wt% of rare earth metal oxide powder and are prepared by the following steps:
a. adding kaolin, anion powder and rare earth metal oxide powder into a ball mill according to the proportion for ball milling, adding a proper amount of water to prepare wet powder,
b. adding the powder into a ball machine for ball forming to prepare wet blank ceramic balls with the thickness of 0.2-0.4cm,
c. drying and shaping the surface of the wet green ceramic pellet, placing the wet green ceramic pellet into a kiln, heating the wet green ceramic pellet to 600-800 ℃, keeping the temperature for 10-20 hours, cooling and discharging the wet green ceramic pellet out of the kiln to prepare negative ion ceramic pellets,
d. mixing a molecular sieve pellet with the particle size of 0.2-0.4cm and a negative ion ceramic pellet with the particle size of 0.2-0.4cm according to the weight ratio of 2-4: 0.5 to 1.5, filling the mixture into a column tube, pressing the mixture into a column shape, taking out the column tube, and sealing and packaging the column tube to prepare the oxygen separation column.
2. The portable oxygen generator capable of synchronously releasing negative ions according to claim 1, wherein: the rare earth metal oxide is lanthanum oxide, cerium oxide, neodymium oxide or yttrium oxide.
3. The portable oxygen generator capable of synchronously releasing negative ions according to claim 1, wherein: the weight ratio of the molecular sieve pellets to the negative ion ceramic pellets is 3:1.
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004016549A1 (en) * 2002-08-13 2004-02-26 科学技術振興事業団 Method for generating negative ion of oxygen and system for generating negative ion of oxygen
CN201470293U (en) * 2009-08-14 2010-05-19 上海沃姆珂尔环境技术有限公司 Portable oxygen generator with negative oxygen ion generating device
CN101885605A (en) * 2010-06-28 2010-11-17 深圳市成为生物科技有限公司 Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof
CN104086165A (en) * 2014-07-15 2014-10-08 任新年 Anion ceramic ball and preparation method thereof
CN105200726A (en) * 2015-10-14 2015-12-30 海宁市中科新材料有限公司 Washing ball with cleaning function and manufacturing method thereof
CN106185823A (en) * 2015-04-30 2016-12-07 曹荣华 Tool supply oxygen and the ventilative material of negative oxygen ion function
CN106830893A (en) * 2017-03-23 2017-06-13 马伟忠 Multifunction negative ion ceramics that can be breathed and preparation method thereof and application
CN206853310U (en) * 2017-06-26 2018-01-09 山东乐康电器科技有限公司 A kind of oxygenation increases the screen pack of anion
CN210885302U (en) * 2019-08-16 2020-06-30 黄伟辉 Separation type oxygen generation system of oxygen generator

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004016549A1 (en) * 2002-08-13 2004-02-26 科学技術振興事業団 Method for generating negative ion of oxygen and system for generating negative ion of oxygen
CN201470293U (en) * 2009-08-14 2010-05-19 上海沃姆珂尔环境技术有限公司 Portable oxygen generator with negative oxygen ion generating device
CN101885605A (en) * 2010-06-28 2010-11-17 深圳市成为生物科技有限公司 Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof
CN104086165A (en) * 2014-07-15 2014-10-08 任新年 Anion ceramic ball and preparation method thereof
CN106185823A (en) * 2015-04-30 2016-12-07 曹荣华 Tool supply oxygen and the ventilative material of negative oxygen ion function
CN105200726A (en) * 2015-10-14 2015-12-30 海宁市中科新材料有限公司 Washing ball with cleaning function and manufacturing method thereof
CN106830893A (en) * 2017-03-23 2017-06-13 马伟忠 Multifunction negative ion ceramics that can be breathed and preparation method thereof and application
CN206853310U (en) * 2017-06-26 2018-01-09 山东乐康电器科技有限公司 A kind of oxygenation increases the screen pack of anion
CN210885302U (en) * 2019-08-16 2020-06-30 黄伟辉 Separation type oxygen generation system of oxygen generator

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