CN1222565A - Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent - Google Patents
Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent Download PDFInfo
- Publication number
- CN1222565A CN1222565A CN 97121955 CN97121955A CN1222565A CN 1222565 A CN1222565 A CN 1222565A CN 97121955 CN97121955 CN 97121955 CN 97121955 A CN97121955 A CN 97121955A CN 1222565 A CN1222565 A CN 1222565A
- Authority
- CN
- China
- Prior art keywords
- sodium
- alcohol
- enzyme
- phosphorus
- washing powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000344 soap Substances 0.000 title claims abstract description 31
- 239000000843 powder Substances 0.000 title claims abstract description 27
- 238000005406 washing Methods 0.000 title claims abstract description 27
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims description 54
- 108090000790 Enzymes Proteins 0.000 title claims description 19
- 102000004190 Enzymes Human genes 0.000 title claims description 19
- 239000003795 chemical substances by application Substances 0.000 title claims description 19
- 229910019142 PO4 Inorganic materials 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- -1 olefin sulfonate Chemical class 0.000 claims description 34
- 239000011734 sodium Substances 0.000 claims description 27
- 229910052708 sodium Inorganic materials 0.000 claims description 27
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 18
- 239000011574 phosphorus Substances 0.000 claims description 18
- 229910052698 phosphorus Inorganic materials 0.000 claims description 18
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 18
- 235000011152 sodium sulphate Nutrition 0.000 claims description 18
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 15
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 10
- 235000019353 potassium silicate Nutrition 0.000 claims description 9
- 235000017550 sodium carbonate Nutrition 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000003599 detergent Substances 0.000 claims description 7
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 230000032683 aging Effects 0.000 claims description 3
- 238000000889 atomisation Methods 0.000 claims description 3
- 235000011194 food seasoning agent Nutrition 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000011343 solid material Substances 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims 3
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- PYOCETQQOOHMKG-UHFFFAOYSA-L [Cl+].[Na+].S(=O)(=O)([O-])[O-].[Na+] Chemical compound [Cl+].[Na+].S(=O)(=O)([O-])[O-].[Na+] PYOCETQQOOHMKG-UHFFFAOYSA-L 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The soap base washing powder contains surfactant greater than 20 wt%, electrolyte, efficient builder and efficient additive. It has pH value of 8.5-9.5 and water content less than 10%. It has powerful detergency and stable performance and is especially suitable for washing very dirty clothing, underwear, infant's clothing and beddings.
Description
The present invention relates to a kind of no benzene, without phosphorus, no enzyme, no fluorescent agent soap base washing powder, belong to daily-use chemical industry articles for washing series.
Linear alkylbenzene sulphonic acid, tripoly phosphate sodium STPP, Sumizyme MP, fluorescent bleaches are as the main raw material of articles for washing, because of it is cheap, easy to use, strong detergency is used widely.But above-mentioned substance all is poisonous and hazardous material, is detrimental to health, and the while is contaminate environment also, therefore develops the novel environment-friendly articles for washing, in the age from now on, is becoming the main product of detergent industry.
The objective of the invention is to solve the toxicity of Betengent product; adopt natural plant grease soap base, pure series of surfactants, the poly-hydroxy acid salt production of high-efficiency builder for detergent not to have stupid, without phosphorus, no enzyme, no fluorescent agent soap base washing powder, thereby protect HUMAN HEALTH, protection environment.
The present invention does not have benzene, without phosphorus, no enzyme, no fluorescent agent soap base washing powder material component and comprises tensio-active agent, ionogen, high-efficiency builder for detergent and effective additive, wherein belongs to the feed composition of tensio-active agent and the weight percent of shared raw material thereof and is:
Fatty acid sodium soap 10-15
α-sodium olefin sulfonate 3-6
Fatty alcohol-polyoxyethylene ether 2-4
Polyoxyethylenated alcohol sodium sulfate 5-9
Lauric alcohol acid amides 1-3
The per-cent that constitutes the weight of electrolytical feed composition and shared raw material thereof is:
Sodium-chlor 2-5
Sodium sulfate 30-40
The per-cent of the material component of formation high-efficiency builder for detergent and the weight of shared raw material thereof is:
Yellow soda ash 8-12
Sodium bicarbonate 10-15
Starso 3-6
Water glass 2-5
Poly-hydroxy acid salt 2-4
The per-cent that constitutes the weight of the feed composition of effective additive and shared raw material thereof is:
Sodium cellulose glycolate 1-3
Essence 0.08-0.1
No benzene, without phosphorus, no enzyme, no fluorescent agent soap base washing powder, the alkyl chain length in its fatty acid sodium soap is C preferably
18Two key acid; Fatty Alcohol(C12-C14 and C12-C18) in the polyoxyethylenated alcohol sodium sulfate generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and oxyethyl group condensation number is 3-5; Fatty Alcohol(C12-C14 and C12-C18) in the fatty alcohol-polyoxyethylene ether generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and oxyethyl group condensation number is 7-9; Lipid acid is C in the lauric alcohol acid amides
12Straight-chain acid, amine are monoethanolamine or diethanolamine; The α thiazolinyl of α-sodium olefin sulfonate is C
12-C
18Alkene; Poly-hydroxy acid salt adopts toxilic acid, acroleic acid polymerization to form.
Prepare burden after by the above-mentioned raw materials prescription each feed composition being converted into the weight real number, its compound method is as follows:
Fatty acid sodium soap, fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, lauric alcohol acid amides, sodium-chlor, water glass are mixed in a mixing bowl; and 70-80 ℃ of temperature of maintenance; squeeze in the software tablets press by pump of constant delivery type; atomisation; and and α-sodium olefin sulfonate, yellow soda ash, sodium bicarbonate, sodium sulfate, sodium cellulose glycolate, Starso solid materials mix; elder generation is through 90-110 ℃ of temperature hot-air seasoning in vibrated fluidized bed; aging through cold wind again; in the batching of back, add poly-hydroxy acid salt and essence, can pack.
Finished surface active agent content of the present invention＞20%, pH value is at 8.5-9.5, moisture content＜10%, and detersive power is greater than standard specimen powder (Xuzhou standard specimen powder).
The present invention compared with prior art has following advantage:
1, because the present invention does not have benzene, without phosphorus, no enzyme, no fluorescent agent, environment is not polluted, harmless, be the articles for washing of a kind of environment-friendly type, safety type.
2, detergency ability is good, and detersive power is compared with domestic synthetic detergent powder greater than standard specimen washing powder (Xuzhou standard specimen powder), and detersive power is better than synthetic detergent powder.
3, alkalescence is moderate, and is non-stimulated to reaching skin.
4, be particularly suitable for washing underwear, infant clothes and sheet, coverlet etc.
Below in conjunction with embodiment in detail the present invention is described in detail:
| Feed composition | Weight percent (%) | |||
| Prescription one | Prescription two | Prescription three | ||
| Tensio-active agent | Fatty acid sodium soap α-sodium olefin sulfonate fatty alcohol-polyoxyethylene ether polyoxyethylenated alcohol sodium sulfate lauric alcohol acid amides | ????15 ????5 ????4 ????6 ????2 | ????15 ????5 ????2 ????5 ????2 | ????13 ????5 ????4 ????9 ????2 |
| Ionogen | Sodium-chlor sodium sulfate | ????3 ????38 | ????3 ????40 | ????3 ????38 |
| High-efficiency builder for detergent | Yellow soda ash sodium bicarbonate Starso water glass (mould in 40Be °) gathers hydroxy acid salt | ????10 ????15 ????5 ????2 ????2.5 | ????10 ????15 ????5 ????2 ????2.5 | ????10 ????15 ????5 ????3 ????2.5 |
| Additive | Sodium cellulose glycolate essence | ????1 ????0.1 | ????1 ????0.08 | ????1 ????0.08 |
Prepare burden after the weight percent content of each component in the above-mentioned table is converted into the weight real number, with fatty acid sodium soap, fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, the lauric alcohol acid amides, sodium oxide, water glass mixes in a mixing bowl, and 70-80 ℃ of temperature of maintenance, squeeze in the software grain-making machine by pump of constant delivery type, atomisation, and and α-sodium olefin sulfonate, yellow soda ash, sodium bicarbonate, sodium sulfate, methylol fiber base sodium, the Starso solid materials mixes, in vibration sulfuration bed, earlier through 90-110 ℃ of hot-air seasoning, aging through cold wind again, in the batching of back, add poly-hydroxy acid salt and essence, get final product through packing.
Finished surface active agent content of the present invention＞20%, pH value 8.5-9.5, detersive power are greater than standard specimen powder (Xuzhou standard specimen powder), and moisture content＜10%, and stable performance weigh dirty clothes and underwear to washing, and infant clothes and sheet, coverlet are especially suitable.
Claims (12)
1, no benzene, without phosphorus, no enzyme, no fluorescent agent soap base washing powder, feed composition comprise tensio-active agent, ionogen, high-efficiency builder for detergent, effective additive, it is characterized in that:
The feed composition (weight %) of a, formation tensio-active agent is:
Fatty acid sodium soap 10-15
α-sodium olefin sulfonate 3-6
Fat Soxylat A 25-7 2-4
Polyoxyethylenated alcohol sodium sulfate 5-9
Lauric alcohol acid amides 1-3
B, constitute electrolytical feed composition (weight %) and be:
Sodium-chlor 2-5
Sulfuric acid 30-40
The material component (weight %) of c, formation high-efficiency builder for detergent is:
Yellow soda ash 8-12
Hydrogen-carbonate 10-15
Starso 3-6
Water glass 2-5
Poly-hydroxy acid salt 2-4
The feed composition (weight %) of d, the effective additive of formation is:
Sodium cellulose glycolate 1-3
Essence 0.08-0.1
2, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that the alkyl chain length C preferably in the fatty acid sodium soap
18Two key acid.
3, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that the Fatty Alcohol(C12-C14 and C12-C18) in the polyoxyethylenated alcohol sodium sulfate generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and oxyethyl group condensation number is 3-5.
4, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that the Fatty Alcohol(C12-C14 and C12-C18) in the fatty alcohol-polyoxyethylene ether generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and oxyethyl group condensation number is 7-9.
5, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that lipid acid is C in the lauric alcohol acid amides
12Straight-chain acid, amine are monoethanolamine or diethanolamine.
6, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder, the α thiazolinyl that it is characterized in that α-sodium olefin sulfonate is C
12-C
18Alkene.
7, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that poly-hydroxy acid salt adopts toxilic acid, acroleic acid polymerization to form.
8, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that optimum feed stock prescription (weight %) is:
Fatty acid sodium soap 15
α-sodium olefin sulfonate 5
Polyoxyethylenated alcohol sodium sulfate 6
Fatty alcohol-polyoxyethylene ether 4
Lauric alcohol acid amides 2
Sodium-chlor 3
Sodium sulfate 38
Yellow soda ash 10
Sodium bicarbonate 15
Starso 5
Water glass (mould in 40Be °) 2
Hydroxymethyl cellulose sodium 1
Poly-hydroxy acid salt 2.5
Essence 0.1
9, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that optimum feed stock prescription (weight %) is:
Fatty acid sodium soap 15
α-sodium olefin sulfonate 5
Polyoxyethylenated alcohol sodium sulfate 5
Fatty alcohol-polyoxyethylene ether 2
Lauric alcohol acid amides 2
Sodium oxide 3
Sodium sulfate 40
Yellow soda ash 10
Sodium bicarbonate 15
Starso 5
Water glass (mould in 40Be °) 2
Hydroxymethyl cellulose sodium 1
Poly-hydroxy acid salt 2.5
Essence 0.08
10, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that optimum feed stock prescription (weight %) is:
Fatty acid sodium soap 13
α-sodium olefin sulfonate 5
Polyoxyethylenated alcohol sodium sulfate 9
Fatty alcohol-polyoxyethylene ether 4
Lauric alcohol acid amides 2
Sodium-chlor 3
Sodium sulfate 38
Yellow soda ash 10
Sodium bicarbonate 15
Starso 5
Water glass (mould in 40Be °) 3
Hydroxymethyl cellulose sodium 1
Poly-hydroxy acid salt 2.5
Essence 0.08
11; no benzene according to claim 1; without phosphorus; no enzyme; the compound method of no fluorescent agent soap base washing powder; it is characterized in that fatty acid sodium soap; fatty alcohol-polyoxyethylene ether; polyoxyethylenated alcohol sodium sulfate; the lauric alcohol acid amides; sodium-chlor; water glass mixes in a mixing bowl; and 70-80 ℃ of temperature of maintenance; squeeze in the software tablets press by pump of constant delivery type; atomisation; and and α-sodium olefin sulfonate; yellow soda ash; sodium bicarbonate; sodium sulfate; sodium cellulose glycolate; the Starso solid materials mixes; elder generation is through 90-110 ℃ of hot-air seasoning in vibrated fluidized bed; aging through cold wind again, in the batching of back, add poly-hydroxy acid salt and essence.
12, no benzene according to claim 1, without phosphorus, no enzyme, no fluorescent agent soap base washing powder is characterized in that finished surface active agent content＞20%, pH value 8.5-9.5, moisture content＜10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97121955 CN1222565A (en) | 1997-11-28 | 1997-11-28 | Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97121955 CN1222565A (en) | 1997-11-28 | 1997-11-28 | Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1222565A true CN1222565A (en) | 1999-07-14 |
Family
ID=5176571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97121955 Pending CN1222565A (en) | 1997-11-28 | 1997-11-28 | Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1222565A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100439484C (en) * | 2006-02-21 | 2008-12-03 | 杨解定 | Non-phosphate benzene-free washing powder and its preparation method |
| CN100506964C (en) * | 2007-01-10 | 2009-07-01 | 谢仁华 | Phosphate-free and benzene-free laundry soap powder |
| CN101457185B (en) * | 2008-12-23 | 2010-10-13 | 深圳市成为生物科技有限公司 | Environment friendly washing granule and preparation method thereof |
| CN101457184B (en) * | 2008-12-23 | 2011-01-26 | 深圳市成为生物科技有限公司 | Environment friendly dishwashing granule and preparation method thereof |
| CN103232909A (en) * | 2013-04-17 | 2013-08-07 | 武汉创新资源环保循环有限公司 | Laundry liquid and preparation method thereof |
| CN103666789A (en) * | 2013-11-28 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Cleaning agent for textiles for infants and preparation method of cleaning agent |
| CN104845780A (en) * | 2015-06-15 | 2015-08-19 | 马建剑 | Novel laundry soap for underwear and preparation method of laundry soap |
-
1997
- 1997-11-28 CN CN 97121955 patent/CN1222565A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100439484C (en) * | 2006-02-21 | 2008-12-03 | 杨解定 | Non-phosphate benzene-free washing powder and its preparation method |
| CN100506964C (en) * | 2007-01-10 | 2009-07-01 | 谢仁华 | Phosphate-free and benzene-free laundry soap powder |
| CN101457185B (en) * | 2008-12-23 | 2010-10-13 | 深圳市成为生物科技有限公司 | Environment friendly washing granule and preparation method thereof |
| CN101457184B (en) * | 2008-12-23 | 2011-01-26 | 深圳市成为生物科技有限公司 | Environment friendly dishwashing granule and preparation method thereof |
| CN103232909A (en) * | 2013-04-17 | 2013-08-07 | 武汉创新资源环保循环有限公司 | Laundry liquid and preparation method thereof |
| CN103666789A (en) * | 2013-11-28 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Cleaning agent for textiles for infants and preparation method of cleaning agent |
| CN103666789B (en) * | 2013-11-28 | 2015-07-22 | 万潇熠 | Cleaning agent for textiles for infants and preparation method of cleaning agent |
| CN104845780A (en) * | 2015-06-15 | 2015-08-19 | 马建剑 | Novel laundry soap for underwear and preparation method of laundry soap |
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