CN101457185B - Environment friendly washing granule and preparation method thereof - Google Patents
Environment friendly washing granule and preparation method thereof Download PDFInfo
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- CN101457185B CN101457185B CN2008102418204A CN200810241820A CN101457185B CN 101457185 B CN101457185 B CN 101457185B CN 2008102418204 A CN2008102418204 A CN 2008102418204A CN 200810241820 A CN200810241820 A CN 200810241820A CN 101457185 B CN101457185 B CN 101457185B
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Abstract
The invention discloses an environment friendly washing particle mixed by a powder material A component and a liquid material B component, wherein the A component is formed by the following materials by weight percentage: 2. 3-42. 925210240f calcium carbonate, 1. 2-12. 21f sodium metasilicate pentahydrate, 2. 9-21. 90f sodium carbonate, 2. 5-26. 80f 4A zeolite, 0. 2-5. 50f sodium carboxymethylcellulose, 2. 1-21. 31f sodium sulfate, 1. 2-17. 30f powdered soap, 1. 2-14. 80f sodium citrate, 0. 8-170f sodium stearate, 2. 1-310f alpha-alkenyl sodium sulfonate; the B component is formed by the following materials by weight percentage: 1. 2-14. 816764762567f fatty alcohol polyoxyethylene ether, 0. 8-12. 20f fatty monoethanol amide, 1. 6-210f fatty alcohol ether sulfate, and 2. 6-35. 50f epoxy adhesive. The invention also discloses a method for preparing the environment friendly bowl washing particle. The environment friendly bowl washing particle of the invention can be safely used for multi-times without toxic and have advantages of good biodegradability for the activity constituent and good cleaning effect for the dishware.
Description
Technical field
The present invention relates to sanitary washing article, relate in particular to a kind of environment friendly washing granule that is used for washing clothes and similar articles and preparation method thereof.
Background technology
Washing powder and washing composition are the essential articles for use of current people's cleaning clothes.Since easy to use, strong detergency, and they are subjected to consumers in general's welcome very much.But what people will be clear that recognizes, washing powder has brought a burst of pain for equally our physical environment, HUMAN HEALTH.Medical research shows, the high phosphorous washing powder of life-time service, and the phosphorus in the middle of the washing powder can directly influence the absorption of human body to calcium, causes the human body calcium deficiency or brings out infantile osteomalacia; While is phosphorous too much, causes the eutrophication state of water, contaminate environment.In addition, the strong phosphorous washing powder of alkalescence also damages fabric easily, and is especially textile.
At the harm of washing powder product, scientists study goes out the cleaning product of a lot of environmental protection, the patent of invention Phosphateless environmentally friendly washing powder (patent No.: 02124187.2) introduced and be particularly related to Phosphateless environmentally friendly washing powder.Described washing powder is formed: yellow soda ash, water glass, anhydrous sodium sulphate, fatty alcohol-polyoxyethylene ether, cocounut oil powder, Xylo-Mucine.(patent No.: 200410018721.1b) relate to a kind of is raw material with the natural phant to patent of invention plant type environmental protection washing powder, environmental protection washing powder of alternative synthetic detergent powder and preparation method thereof.Adopt the Chinese honey locust shell, rice, bamboo carbon powder, ginger, blue or green bamboo leaf and other natural plant is starting material.Pulverize via cell wall breaking, physical method such as mix and process.(patent No.: 98206728.3) introduced the high-molecular active solid slow-releasing granules is to make with tensio-active agent, auxiliary composition and polymer binder to utility model patent environment friendly laundry ball, its tensio-active agent is selected aliphatic alcohol sulfate, alkyl polyoxyethylene glycol etc. for use, polymer binder uses resin, auxiliary composition is foaming booster, washing assistant, anti-heavy agent, whitening agent, corrosion inhibitor, enzyme, thinner, spices, water etc., but do not see its concrete embodiment.It is convenient inadequately that the product that above patented technology is made, detersive power are difficult to surpass washing powder, making is used, and is unfavorable for environmental requirement equally.
Summary of the invention
Purpose of the present invention to solve existing washing composition to HUMAN HEALTH produce unfavorable, cause environmental pollution, detersive power strong inadequately and use the technical problem of trouble easily, propose a kind of strong detergency, manufacture conveniently, environmental protection and the environment friendly washing granule that can repeatedly recycle.
Another object of the present invention is the preparation method who proposes a kind of environment friendly washing granule.
For achieving the above object, the environment friendly washing granule that the present invention proposes is mixed by powder material A component and liquid material B component.Described A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-2.3～42.9%, metasilicate pentahydrate sodium-1.2～12.2%, yellow soda ash-2.9～21.9%, 4A zeolite-2.5～26.8%, Xylo-Mucine-0.2～5.5%, sodium sulfate-2.1～21.3%, soap powder-1.2～17.3%, Trisodium Citrate-1.2～14.8%, sodium stearate-0.8～17%, α-sodium olefin sulfonate-2.1～31%;
Described B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-1.2～14.8%, fatty acid distribution of coconut oil single ethanol amide-0.8～12.2%, polyoxyethylene alkyl ether sulfate salt-1.6～21%, epoxy resin binder-2.6～35.5%, epoxy curing agent-2.6～35.5%.
Preferred version of the present invention, described A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-13%, metasilicate pentahydrate sodium-3%, yellow soda ash-8%, 4A zeolite-8%, Xylo-Mucine-2%, sodium sulfate-7%, soap powder-4%, Trisodium Citrate-4%, sodium stearate-3%, α-sodium olefin sulfonate-12;
The B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-5%, fatty acid distribution of coconut oil single ethanol amide-3%, polyoxyethylene alkyl ether sulfate salt-4%, epoxy resin binder-12%, epoxy curing agent-12%.
The preparation method of environment friendly washing granule of the present invention comprises the steps:
(1) with the material of described A component according to weight accurately weighing successively, put in the stirred vessel of sealing, mix;
(2) with the material of described B component according to weight accurately weighing successively, put into the stainless steel stirred vessel, mix;
Above-mentioned two steps also can carry out in no particular order simultaneously;
(3) then the B component material that mixes is poured in the airtight stirred vessel of the A component that stirs, restir mixes;
(4) mixture of taking-up A, B two components drops into the particle pellet processing machine, makes the circular granular of 4～15 millimeters of diameters;
(5) with the circular granular for preparing, put into the baking oven baking, tackiness agent solidifies the back and takes out.
Wherein, the agitating vane rotating speed of the material of described A component is 60r/min, stirs 6～20 minutes; The mixing speed of described B component is 150r/min, stirs 4～8 minutes; The mixture mixing speed of described A, B two components is 40r/min, stirs 6～15 minutes; The temperature of described baking oven baking is 40～70 ℃, toasts 4～10 hours.
Beneficial effect of the present invention:
1, the prepared novel environment friendly washing granule washing effect of the present invention is good, can replace washing powder, and can repeatedly recycle.
2, the used effective raw material soap powder of main body, α-sodium olefin sulfonate, fatty alcohol-polyoxyethylene ether, coconut oil fatty acid monoethanolamide, polyoxyethylene alkyl ether sulfate salt, the epoxy resin binder of the present invention is environment-friendly materials, have up to the biological degradability more than 95%, and safety non-toxic, satisfy environmental requirement fully, few to the pollution of environment.
3, the novel environment friendly washing granule of the present invention's preparation is after washing effect completely loses, and the component of its no washing effect remains with particle form, is convenient to treatment of wastes produced, and is free from environmental pollution.
4, the present invention is simple to operate, and the mark mixed is even by weight only to need raw material with A, B component, and with particle pill mechanism particle, baking is accelerated to solidify and get final product, and required equipment is few, and it is little to take up room, and it is easy to produce.
5, the novel environment friendly washing granule of the present invention's preparation is used for washing clothes and similar articles, can use separately, also can mix other special washing composition and mix use, and is easy to use, wide application.
Embodiment
The environment friendly washing granule that the present invention proposes is mixed by powder material A component and liquid material B component.Wherein the A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-2.3～42.9%, metasilicate pentahydrate sodium-1.2～12.2%, yellow soda ash-2.9～21.9%, 4A zeolite-2.5～26.8%, Xylo-Mucine-0.2～5.5%, sodium sulfate-2.1～21.3%, soap powder-1.2～17.3%, Trisodium Citrate-1.2～14.8%, sodium stearate-0.8～17%, α-sodium olefin sulfonate-2.1～31%;
Described B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-1.2～14.8%, fatty acid distribution of coconut oil single ethanol amide-0.8～12.2%, polyoxyethylene alkyl ether sulfate salt-1.6～21%, epoxy resin binder-2.6～35.5%, epoxy curing agent-2.6～35.5%.
In the preferred version of the present invention, described A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-13%, metasilicate pentahydrate sodium-3%, yellow soda ash-8%, 4A zeolite-8%, Xylo-Mucine-2%, sodium sulfate-7%, soap powder-4%, Trisodium Citrate-4%, sodium stearate-3%, α-sodium olefin sulfonate-12
The B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-5%, fatty acid distribution of coconut oil single ethanol amide-3%, polyoxyethylene alkyl ether sulfate salt-4%, epoxy resin binder-12%, epoxy curing agent-12%.
The present invention will be further described below in conjunction with specific embodiment.According to prescription of the present invention, dispose the material of the preparation environment friendly washing granule of following different ratios.
Embodiment 1 (most preferred embodiment): raw material weight mark prescription:
The A component:
Lime carbonate: 13, metasilicate pentahydrate sodium: 3, yellow soda ash: 8, the 4A zeolite: 8, Xylo-Mucine: 2, sodium sulfate: 7, soap powder: 4, Trisodium Citrate: 4, sodium stearate: 3, α-sodium olefin sulfonate: 12.
The B component:
Fatty alcohol-polyoxyethylene ether: 5, the fatty acid distribution of coconut oil single ethanol amide: 3, polyoxyethylene alkyl ether sulfate salt: 4, epoxy resin binder: 12, epoxy curing agent: 12.
Embodiment 2: raw material weight mark prescription:
The A component:
Lime carbonate: 15, metasilicate pentahydrate sodium: 5, yellow soda ash: 6, the 4A zeolite: 6, Xylo-Mucine: 1.5, sodium sulfate: 5.5, soap powder: 4, Trisodium Citrate: 3, sodium stearate: 3, α-sodium olefin sulfonate: 9.
The B component:
Fatty alcohol-polyoxyethylene ether: 8, the fatty acid distribution of coconut oil single ethanol amide: 6, polyoxyethylene alkyl ether sulfate salt: 4, epoxy resin binder: 20, epoxy curing agent: 4.
Embodiment 3: raw material weight mark prescription:
The A component:
Lime carbonate: 10, metasilicate pentahydrate sodium: 4, yellow soda ash: 6, the 4A zeolite: 10, Xylo-Mucine: 2.5, sodium sulfate: 6.5, soap powder: 3, Trisodium Citrate: 3, sodium stearate: 3, α-sodium olefin sulfonate: 7.
The B component:
Fatty alcohol-polyoxyethylene ether: 8, the fatty acid distribution of coconut oil single ethanol amide: 6, polyoxyethylene alkyl ether sulfate salt: 6, epoxy resin binder: 20, epoxy curing agent: 5.
Embodiment 4: raw material weight mark prescription:
The A component:
Lime carbonate: 20, metasilicate pentahydrate sodium: 5, yellow soda ash: 6, the 4A zeolite: 6, Xylo-Mucine: 2, sodium sulfate: 4, soap powder: 4, Trisodium Citrate: 3, sodium stearate: 3, α-sodium olefin sulfonate: 5.
The B component:
Fatty alcohol-polyoxyethylene ether: 8, the fatty acid distribution of coconut oil single ethanol amide: 5, polyoxyethylene alkyl ether sulfate salt: 5, epoxy resin binder: 18, epoxy curing agent: 6.
Embodiment 5: raw material weight mark prescription:
The A component:
Lime carbonate: 12, metasilicate pentahydrate sodium: 6, yellow soda ash: 6, the 4A zeolite: 6, Xylo-Mucine: 1, sodium sulfate: 6, soap powder: 4, Trisodium Citrate: 3, sodium stearate: 6, α-sodium olefin sulfonate: 4.
The B component:
Fatty alcohol-polyoxyethylene ether: 6, the fatty acid distribution of coconut oil single ethanol amide: 4, polyoxyethylene alkyl ether sulfate salt: 6, epoxy resin binder: 15, epoxy curing agent: 15.
Embodiment 6: raw material weight mark prescription:
The A component:
Lime carbonate: 23, metasilicate pentahydrate sodium: 5, yellow soda ash: 6, the 4A zeolite: 10, Xylo-Mucine: 2, sodium sulfate: 7, soap powder: 2, Trisodium Citrate: 3, sodium stearate: 8, α-sodium olefin sulfonate: 1.
The B component:
Fatty alcohol-polyoxyethylene ether: 8, the fatty acid distribution of coconut oil single ethanol amide: 6, polyoxyethylene alkyl ether sulfate salt: 4, epoxy resin binder: 16, epoxy curing agent: 8.
Embodiment 7: raw material weight mark prescription:
The A component:
Lime carbonate: 5, metasilicate pentahydrate sodium: 8, yellow soda ash: 5, the 4A zeolite: 12, Xylo-Mucine: 1.5 sodium sulfate: 10.5, soap powder: 8, Trisodium Citrate: 3, sodium stearate: 8, α-sodium olefin sulfonate: 2.
The B component:
Fatty alcohol-polyoxyethylene ether: 2, the fatty acid distribution of coconut oil single ethanol amide: 6, polyoxyethylene alkyl ether sulfate salt: 7, epoxy resin binder: 15, epoxy curing agent 15.
Embodiment 8: raw material weight mark prescription:
The A component:
Lime carbonate: 18, metasilicate pentahydrate sodium: 5, yellow soda ash: 3, the 4A zeolite: 5, Xylo-Mucine: 1.5, sodium sulfate: 9.5, soap powder: 4, Trisodium Citrate: 2, sodium stearate: 2, α-sodium olefin sulfonate: 6.
The B component:
Fatty alcohol-polyoxyethylene ether: 8, the fatty acid distribution of coconut oil single ethanol amide: 6, polyoxyethylene alkyl ether sulfate salt: 2, epoxy resin binder: 14, epoxy curing agent: 14.
The powder raw material selection soap powder granularity that the present invention prepares A component in the environment friendly washing granule is 325 orders～1250 orders; The lime carbonate granularity is 325 orders～1250 orders; Yellow soda ash granularity 325 orders～1250 orders; 4A zeolite particle size 325 orders～1250 orders; The Xylo-Mucine granularity is 325 orders～600 orders; The sodium sulfate granularity is 325 orders～1250 orders; The Trisodium Citrate granularity is 325 orders～600 orders; The metasilicate pentahydrate sodium granularity is 325 orders～600 orders; The sodium stearate granularity is 100 orders～325 orders; α-sodium olefin sulfonate granularity is 100 orders～325 orders.Fatty alcohol-polyoxyethylene ether adopts biodegradable fatty alcohol-polyoxyethylene ether, its active component content 〉=65%; The active component content of fatty acid distribution of coconut oil single ethanol amide 〉=65%; The active component content of polyoxyethylene alkyl ether sulfate salt 〉=65%.Epoxy curing agent is a kind of in polyamide curing agent, polymeric amide affixture solidifying agent, amido amine solidifying agent, the modification amido amine solidifying agent.Epoxy resin binder is the amino acid derived Resins, epoxy of poisonless biological degradable, and the bonding ratio range of epoxy resin binder and epoxy curing agent is 1: 1～5: 1; At normal temperatures, Resins, epoxy surface drying set time was 2～16 hours after epoxy resin binder and epoxy curing agent were bonding.
Body material of the present invention all adopts the environment-protecting asepsis material, and it is that raw material is made that soap powder is selected natural animal and plant grease for use, and biological degradability is good, health environment-friendly; α-sodium olefin sulfonate structural formula: RCH=CH (CH2) n-SO3Na RCH (OH) is n-SO3Na biological degradability good (degradation rate＞97%), nontoxic (LD50 2.5g/kg) (CH2); Fatty alcohol-polyoxyethylene ether is soluble in water, has good decontamination, wetting, emulsification, dispersion and foam performance, biodegradability good (degree of degradation is 99%); Thickening property that coconut oil fatty acid monoethanolamide is good and froth stability, few and thickening property of consumption and security are better than 6501, and biological degradability is good, and degradation rate can reach more than 97%; Polyoxyethylene alkyl ether sulfate salt C12H250 (Eo) 3S03Na has effects such as solubilising, decontamination, biological degradability good (degradation rate 95%), nontoxic (LD50 1.7g/kg), little to skin irritation; Epoxy resin binder adopts the amino acid derived Resins, epoxy of novel poisonless biological degradable.Material of the present invention all can be bought on market.
According to said ratio, the preparation method of environment friendly washing granule of the present invention, can carry out according to following steps:
Step 1: with lime carbonate %, metasilicate pentahydrate sodium, yellow soda ash, 4A zeolite, Xylo-Mucine, sodium sulfate, soap powder, Trisodium Citrate, sodium stearate, the α-sodium olefin sulfonate of described A component, according to weight accurately weighing successively, put in the stirred vessel of sealing, start and stir.The rotating speed of agitating vane is 60r/min, stirs 6～20 minutes, so that each powder raw material component mixes;
Step 2: with fatty alcohol-polyoxyethylene ether, fatty acid distribution of coconut oil single ethanol amide, polyoxyethylene alkyl ether sulfate salt, epoxy resin binder, the epoxy curing agent-2.6～35.5% of described B component, according to weight weighing accurately successively, put into the stainless steel stirred vessel, start and stir, the rotating speed of agitating vane is 150r/min, stirred 4～8 minutes, so that each liquid starting material component mixes;
Above-mentioned two steps also can carry out in no particular order simultaneously;
Step 3: then the B component that mixes is poured in the airtight stirred vessel that stirs the A component, started and stir, the rotating speed of agitating vane is 40r/min, stirs 6～15 minutes, closes stirrer;
Step 4: take out the A that stirs, the mixture of B two components, drop into the circular granular that the particle pellet processing machine is made 4～15 millimeters of diameters;
Step 5: with the circular granular for preparing, put into baking oven, between 40～70 ℃ of temperature, toasted 4～10 hours, tackiness agent is thoroughly solidified, bonding firm, thus make circular environment friendly washing granule of the present invention.
The target level of product quality that the present invention produces:
Outward appearance: white or talk yellow spheroidal particle; Diameter: 8 ± 1 millimeters;
Washing times 〉=40 time; Decontamination ratio (carbon black soiled cotton) 〉=1.6.
Annotate: decontamination ratio contrast standard washing powder, its prescription is: 15 parts of sodium alkyl benzene sulfonates, 17 parts of STPP (sodium tripolyphosphate), 10 parts of water glass, 3 parts in yellow soda ash, 1 part of Xylo-Mucine (CMC), 58 parts in sodium sulfate.
Novel environment friendly washing granule with above specific embodiment preparation, with the washing powder of buying on standard washing powder, the market, with reference to national standard CB/T13174-2003, the mensuration that dress material steeps deposition capability with washing composition detersive power and anti-soil is again carried out the test of decontamination value.
Concrete embodiment detersive power data such as following table:
| Material | Carbon black soiled cotton decontamination value | Sebum soiled cotton decontamination value | Albumen soiled cotton decontamination value |
| Standard washing powder | 16.4 | 17.6 | 4.7 |
| Material | Carbon black soiled cotton decontamination value | Sebum soiled cotton decontamination value | Albumen soiled cotton decontamination value |
| Commercially available washing powder | 24.6 | 26.4 | 7.1 |
| Embodiment 1 | 31.4 | 23.6 | 9.6 |
| Embodiment 2 | 29.7 | 22.5 | 9.2 |
| Embodiment 3 | 30.9 | 21.1 | 8.7 |
| Embodiment 4 | 29.3 | 21.8 | 9.1 |
| Embodiment 5 | 28.6 | 20.2 | 8.6 |
| Embodiment 6 | 30.5 | 22.7 | 9.2 |
| Embodiment 7 | 27.8 | 19.9 | 7.9 |
| Embodiment 8 | 30.8 | 22.6 | 8.8 |
Concrete embodiment washing granule changes in weight data such as following table:
| Material | Wash preceding weight/gram | Wash back weight/gram | Weight difference/gram |
| Embodiment 1 | 100 | 98.5 | 1.5 |
| Embodiment 2 | 100 | 98.2 | 1.8 |
| Embodiment 3 | 100 | 97.9 | 2.1 |
| Embodiment 4 | 100 | 98.0 | 2.0 |
| Embodiment 5 | 100 | 97.6 | 2.4 |
| Embodiment 6 | 100 | 97.4 | 2.6 |
| Embodiment 7 | 100 | 97.8 | 2.2 |
| Embodiment 8 | 100 | 98.3 | 1.7 |
By above data contrast, the novel environment friendly washing granule decontamination ratio (carbon black soiled cotton)=1.9 that the present invention is prepared, and commercially available washing powder decontamination ratio (carbon black soiled cotton)=1.5, the prepared novel environment friendly washing granule washing effect of the present invention is higher than commercially available washing powder, can substitute washing powder washing dress material fully.Simultaneously the prepared novel environment friendly washing granule of the present invention can satisfy washing times 〉=40 time, and repeatedly recirculation is used.
Claims (7)
1. an environment friendly washing granule is mixed by powder material A component and liquid material B component, it is characterized in that, described A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-2.3～42.9%, metasilicate pentahydrate sodium-1.2～12.2%, yellow soda ash-2.9～21.9%,
4A zeolite-2.5～26.8%, Xylo-Mucine-0.2～5.5%, sodium sulfate-2.1～21.3%,
Soap powder-1.2～17.3%, Trisodium Citrate-1.2～14.8%, sodium stearate-0.8～17%,
α-sodium olefin sulfonate-2.1～31%;
Described B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-1.2～14.8%, fatty acid distribution of coconut oil single ethanol amide-0.8～12.2%,
Polyoxyethylene alkyl ether sulfate salt-1.6～21%, epoxy resin binder-2.6～35.5%,
Epoxy curing agent-2.6～35.5%.
2. environment friendly washing granule according to claim 1 is characterized in that, described A component is formed by the raw material configuration of following weight percentage:
Lime carbonate-13%, metasilicate pentahydrate sodium-3%, yellow soda ash-8%, 4A zeolite-8%, Xylo-Mucine-2%,
Sodium sulfate-7%, soap powder-4%, Trisodium Citrate-4%, sodium stearate-3%, α-sodium olefin sulfonate-12%;
The B component is formed by the raw material configuration of following weight percentage:
Fatty alcohol-polyoxyethylene ether-5%, fatty acid distribution of coconut oil single ethanol amide-3%, polyoxyethylene alkyl ether sulfate salt-4%, epoxy resin binder-12%, epoxy curing agent-12%.
3. as environment friendly washing granule as described in the claim 2, it is characterized in that the powder raw material selection soap powder granularity of described A component is 325 orders～1250 orders; The lime carbonate granularity is 325 orders～1250 orders; Yellow soda ash granularity 325 orders～1250 orders; 4A zeolite particle size 325 orders～1250 orders; The Xylo-Mucine granularity is 325 orders～600 orders; The sodium sulfate granularity is 325 orders～1250 orders; The Trisodium Citrate granularity is 325 orders～600 orders; The metasilicate pentahydrate sodium granularity is 325 orders～600 orders; The sodium stearate granularity is 100 orders～325 orders; α-sodium olefin sulfonate granularity is 100 orders～325 orders.
4. as environment friendly washing granule as described in the claim 3, it is characterized in that described epoxy curing agent is a kind of in polyamide curing agent, polymeric amide affixture solidifying agent, amido amine solidifying agent, the modification amido amine solidifying agent.
5. as environment friendly washing granule as described in the claim 4, it is characterized in that described epoxy resin binder is the amino acid derived Resins, epoxy of poisonless biological degradable, the bonding ratio range of epoxy resin binder and epoxy curing agent is 1: 1～5: 1; At normal temperatures, Resins, epoxy surface drying set time was 2～16 hours after epoxy resin binder and epoxy curing agent were bonding.
6. the preparation method of environment friendly washing granule according to claim 1 is characterized in that comprising the steps:
(1) elder generation according to weight accurately weighing successively, puts the material of described A component in the stirred vessel of sealing into, mixes;
(2) with the material of described B component according to weight accurately weighing successively, put into the stainless steel stirred vessel, mix;
Above-mentioned two steps perhaps carry out in no particular order simultaneously;
(3) then the B component material that mixes is poured in the airtight stirred vessel of the A component that stirs, restir mixes;
(4) mixture of taking-up A, B two components drops into the particle pellet processing machine, makes the circular granular of 4～15 millimeters of diameters;
(5) with the circular granular for preparing, put into the baking oven baking, take out after the adhering and solidifying.
7. as the preparation method of environment friendly washing granule as described in the claim 6, it is characterized in that the agitating vane rotating speed of the material of described A component is 60r/min, stirred 6～20 minutes; The mixing speed of described B component is 150r/min, stirs 4～8 minutes; The mixture mixing speed of described A, B two components is 40r/min, stirs 6～15 minutes; The temperature of described baking oven baking is 40～70 ℃, toasts 4～10 hours.
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| WO2014172902A1 (en) * | 2013-04-26 | 2014-10-30 | The Procter & Gamble Company | Detergent granules with a water-swellable component |
| CN103289830B (en) * | 2013-06-26 | 2015-02-11 | 长沙高新开发区厨净环保科技有限公司 | Board-spectrum low-temperature oil remover |
| CN103409246A (en) * | 2013-07-17 | 2013-11-27 | 涂秦华 | Ultra-concentrated detergent powder |
| CN107033047B (en) * | 2017-05-09 | 2019-03-26 | 濮阳宏业环保新材料股份有限公司 | A kind of stabilizer improving thiourea dioxide hydrothermal stability |
| CN110338722B (en) * | 2017-07-30 | 2021-09-17 | 长沙协赢知识产权服务有限公司 | Kitchen wall shaping and repairing method |
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| CN1239734A (en) * | 1999-01-16 | 1999-12-29 | 冯广华 | Children's washing powder |
| JP2006124590A (en) * | 2004-10-29 | 2006-05-18 | Soft99 Corporation | Detergent for polishing coating face |
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| CN101457185A (en) | 2009-06-17 |
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