JPH02311600A - Detergent composition in tablet form - Google Patents
Detergent composition in tablet formInfo
- Publication number
- JPH02311600A JPH02311600A JP13412789A JP13412789A JPH02311600A JP H02311600 A JPH02311600 A JP H02311600A JP 13412789 A JP13412789 A JP 13412789A JP 13412789 A JP13412789 A JP 13412789A JP H02311600 A JPH02311600 A JP H02311600A
- Authority
- JP
- Japan
- Prior art keywords
- water
- tablet
- weight
- particle size
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 239000003599 detergent Substances 0.000 title claims description 25
- 239000002245 particle Substances 0.000 claims abstract description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 15
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 14
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 102000004190 Enzymes Human genes 0.000 abstract description 2
- 108090000790 Enzymes Proteins 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004902 Softening Agent Substances 0.000 abstract description 2
- 239000007844 bleaching agent Substances 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract description 2
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 239000004034 viscosity adjusting agent Substances 0.000 abstract description 2
- QMGYPNKICQJHLN-UHFFFAOYSA-M Carboxymethylcellulose cellulose carboxymethyl ether Chemical compound [Na+].CC([O-])=O.OCC(O)C(O)C(O)C(O)C=O QMGYPNKICQJHLN-UHFFFAOYSA-M 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 238000004040 coloring Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- -1 alkylbenzene sulfonate Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
童且上立机皿分更
本発明は、水中で容易に崩壊し、がっ、製造時における
金型からの離型性に優れたタブレット洗剤組成物に関す
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a tablet detergent composition that easily disintegrates in water and has excellent releasability from molds during production.
従来五■夏
従来の衣料用洗剤は、組成物中に洗浄性能にはほとんど
寄与しない増量剤(通常は芒硝が用いられる)を添加し
、かつこれを噴霧乾燥等により嵩密度0.3 g /c
c程度のビーズ状中空粒子として製造していた。Conventional laundry detergents have a bulk density of 0.3 g / c.
It was produced as bead-shaped hollow particles of about
しかし、このような洗剤は比重が軽く活性剤濃度も低い
ため、輸送コストがかさむ上、保管・陳列にもかなりの
スペースが必要であった。さらに一般家庭においても、
置き場所に困ったり、計量しにくいという不便があった
。そこで最近では、少ない洗剤使用量で洗浄が可能な高
嵩密度粒状洗剤が上申されている。However, such detergents have a low specific gravity and a low concentration of active agent, which increases transportation costs and requires a considerable amount of space for storage and display. Furthermore, in ordinary households,
There were inconveniences such as having trouble finding a place to store it and making it difficult to weigh it. Therefore, recently, high bulk density granular detergents that can be used for cleaning with a small amount of detergent have been promoted.
さらに簡便性の向上を図るため、最近タブレット洗剤の
開発が試みられている。しかし、タブレット洗剤は、簡
便で利用しやすいという反面、水中で速やかに崩壊する
ことが容易でないという欠点がある。In order to further improve convenience, attempts have recently been made to develop tablet detergents. However, while tablet detergents are simple and easy to use, they have the disadvantage that they do not easily disintegrate in water.
このような易水中崩壊性は、医薬品や食品などの他の分
野で用いられるタブレットにおいても要求されている。Such easy disintegration in water is also required for tablets used in other fields such as pharmaceuticals and foods.
そこで、このようなタブレットにおいては一般的に、主
成分に加え、コハク酸と炭酸ナトリウムまたは炭酸水素
ナトリウムとを乾燥状態で混合して打錠成形し、水と接
触した際に酸と炭酸塩とを反応させて二酸化炭素を発生
せしめることにより、崩壊性を改善し主成分の溶解を促
進するという方法が取られている。Therefore, in general, such tablets are made by mixing the main ingredients with succinic acid and sodium carbonate or sodium bicarbonate in a dry state and forming a tablet, so that when it comes into contact with water, the acid and carbonate are mixed together. A method has been adopted in which the disintegrability is improved and the dissolution of the main component is promoted by reacting with carbon dioxide to generate carbon dioxide.
しかしながら、タブレット洗剤においては、上記のよう
な発泡成分に対して、優れた洗浄力が認められるアニオ
ン性界面活性剤を主活性成分として配合すると、112
造時に金型付着が生じて製造性が著しく劣化し、また、
タブレットの崩壊性が不十分であるという問題があった
。さらに、タブレット洗剤の保存中に、その中に含まれ
ている水分や空気中の水分を吸収し、徐々に酸−アルカ
リ反応が起こって二酸化炭素が発生するため、保存後に
タブレット洗剤を水中に投入すると、崩壊性が著しく劣
化するという問題があった。However, in tablet detergents, when an anionic surfactant, which is recognized to have excellent detergency, is added as the main active ingredient to the above-mentioned foaming ingredients, the amount of 112
Mold adhesion occurs during manufacturing, significantly deteriorating manufacturability, and
There was a problem that the disintegration properties of the tablets were insufficient. Furthermore, while the tablet detergent is being stored, it absorbs the moisture contained in it and the moisture in the air, and an acid-alkaline reaction gradually occurs, generating carbon dioxide, so the tablet detergent is poured into water after storage. Then, there was a problem that the disintegration property deteriorated significantly.
口が解 しようとする課題
本発明は、このような従来のタブレット洗剤がもつ欠点
を克服し、製造時における金型からの離型性に優れ、し
かも、水中で容易に崩壊するタブレット洗剤を提供する
ものである。The present invention overcomes the drawbacks of conventional tablet detergents, and provides a tablet detergent that has excellent releasability from molds during production and also easily disintegrates in water. It is something to do.
見肌夏盪撲
本発明のタブレット洗剤組成物は、以下の(A)および
(B)成分を含有することを特徴とする。The tablet detergent composition of the present invention is characterized by containing the following components (A) and (B).
(A)粉末状のアニオン性界面活性剤=5〜50重量%
。(A) Powdered anionic surfactant = 5-50% by weight
.
(B) 200メツシュ篩日通過フラクションが80%
以上の粒度を有する水難溶性のカルボキシメチルセルロ
ース粉末:1〜30重量%。(B) 80% fraction passed through 200 mesh sieve
Slightly water-soluble carboxymethyl cellulose powder having a particle size of 1 to 30% by weight.
以下1本発明についてさらに詳細に説明する。The present invention will be explained in more detail below.
(A)成分のアニオン性界面活性剤としては、例えば以
下のものが例示できる。Examples of the anionic surfactant as component (A) include the following.
1)平均炭素数8〜16のアルキル基を有する直鎖アル
キルベンゼンスルホン酸塩、
2)平均炭素数10〜20のα−オレフィンスルホン酸
塩。1) Straight-chain alkylbenzene sulfonate having an alkyl group having an average carbon number of 8 to 16; 2) α-olefin sulfonate having an average carbon number of 10 to 20.
3)脂肪酸残基の炭素数8〜22の脂肪酸低級アルキル
エステルのスルホン酸塩、
4)平均炭素数10〜20のアルキル硫酸塩、5)平均
炭素数10〜20の直鎖または分岐鎖のアルキル基もし
くはアルケニル基を有し、平均0.5〜8モルのエチレ
ンオキサイドを付加したアルキルエーテル硫酸塩または
アルケニルエーテル硫酸塩、
6)平均炭素数lθ〜22の飽和または不飽和脂肪酸塩
。3) Sulfonate of a fatty acid lower alkyl ester having 8 to 22 carbon atoms as a fatty acid residue; 4) Alkyl sulfate having an average of 10 to 20 carbon atoms; 5) Straight chain or branched alkyl having an average of 10 to 20 carbon atoms. or alkenyl group, and an alkyl ether sulfate or alkenyl ether sulfate to which an average of 0.5 to 8 moles of ethylene oxide is added; 6) a saturated or unsaturated fatty acid salt having an average carbon number of lθ to 22;
これらのアニオン性界面活性剤における対イオンとして
は1通常ナトリウムやカリウムなどのアルカリ金属塩が
適当である。As counter ions in these anionic surfactants, alkali metal salts such as sodium and potassium are usually suitable.
これらアニオン性界面活性剤は、1種を単独で用いても
よく、2種以上組合わせて使用してもよい。These anionic surfactants may be used alone or in combination of two or more.
(A)アニオン性界面活性剤は、タブレット洗剤組成物
中に5〜50重量%、好ましくは10〜40重量%配合
される。配合量が5重量%未満では、洗浄力を満足させ
るためにタブレットの形状を大きくするか、あるいは使
用個数を多くしなければならず、実用上問題がある。一
方、50重量%を超えると、ビルダーなどの他の成分の
配合量が少なくなり好ましくない。(A) The anionic surfactant is blended in the tablet detergent composition in an amount of 5 to 50% by weight, preferably 10 to 40% by weight. If the blending amount is less than 5% by weight, the shape of the tablet must be made larger or the number of tablets used must be increased in order to satisfy the cleaning power, which poses a practical problem. On the other hand, if it exceeds 50% by weight, the amount of other components such as builders will be reduced, which is not preferable.
また、(A)アニオン性界面活性剤または打錠する場合
の中間原料の含水率は10重量%以下が適当であり、1
〜10重量%が好適である。含水率を1重量%未満では
、製造のために多大のエネルギーを必要とし、経済面か
ら実用性がない。In addition, it is appropriate that the water content of (A) the anionic surfactant or the intermediate raw material for tableting is 10% by weight or less;
~10% by weight is preferred. If the water content is less than 1% by weight, a large amount of energy is required for production and it is not practical from an economical point of view.
一方、含水率が10重量%を超えると、製造時に金型に
タブレットが付着し、離型が困難となる。On the other hand, if the water content exceeds 10% by weight, the tablets will adhere to the mold during production, making release from the mold difficult.
(B)成分の水難溶性カルボキシメチルセルロースとし
ては、遊離(酸型)のカルボキシメチルセルロース、カ
ルボキシメチルセルロースカルシウム、カルボキシメチ
ルセルロースマグネシウム、カルボキシメチルセルロー
スアルミニウムなどが挙げられ、これらは単独であるい
は2種以上組み合わせて用いられる。カルボキシメチル
セルロースナトリウムのような水溶性塩を用いても、金
型からの離型性および水中崩壊性のいずれもが改善され
ない。Examples of the poorly water-soluble carboxymethylcellulose of component (B) include free (acid type) carboxymethylcellulose, carboxymethylcellulose calcium, carboxymethylcellulose magnesium, carboxymethylcellulose aluminum, and the like, and these may be used alone or in combination of two or more. Even when a water-soluble salt such as sodium carboxymethylcellulose is used, neither the mold release property nor the water disintegration property is improved.
カルボキシメチルセルロースにおいて、カルボキシメチ
ル基はセルロース中のブドー糖の第1級または第2級ア
ルコール性水酸基に分布しており、理論的には置換度(
エーテル化度)3.0のものまで得られる。本発明にお
いては、置換度0.2〜0.8のカルボキシメチルセル
ロースが好適である。また、カルボキシメチルセルロー
スの含水率は10重重量以下が好ましい。In carboxymethylcellulose, carboxymethyl groups are distributed in the primary or secondary alcoholic hydroxyl groups of glucose in cellulose, and theoretically the degree of substitution (
Etherification degree) up to 3.0 can be obtained. In the present invention, carboxymethyl cellulose having a degree of substitution of 0.2 to 0.8 is preferred. Moreover, the water content of carboxymethyl cellulose is preferably 10 weight or less.
(B)カルボキシメチルセルロースは、200メツシュ
篩目通過フラクションが80%以上、好ましくは10〜
50μmの粒度を有するものが用いられる。粒度がこの
範囲以外のものを用いると、カルボキシメチルセルロー
ス粒子の膨潤が遅くなって洗濯物に付着し、使用感が損
なわれ好ましくない。(B) The carboxymethyl cellulose has a fraction passing through a 200 mesh sieve of 80% or more, preferably 10 to 10%.
A particle size of 50 μm is used. If particles having a particle size outside this range are used, the swelling of the carboxymethyl cellulose particles will be delayed and the particles will adhere to laundry, impairing the feeling of use, which is undesirable.
(B)カルボキシメチルセルロースは、タブレット洗剤
組成物中に1〜30重量%、好ましくは10〜25重量
%配合される。配合量が1重量%未満では本発明の効果
が十分に発揮されず、一方。(B) Carboxymethylcellulose is blended in the tablet detergent composition in an amount of 1 to 30% by weight, preferably 10 to 25% by weight. On the other hand, if the blending amount is less than 1% by weight, the effects of the present invention will not be fully exhibited.
30重重量を超えて配合しても、量の増加の割に効果の
向上がなく無意味である。Even if it is blended in an amount exceeding 30 weight, it is meaningless as the effect does not improve in spite of the increase in the amount.
本発明の洗剤組成物には、上記(A)、 (B)両成分
に加え、さらに、トリポリリン酸ナトリウムやビロリン
酸ナトリウムのような無機ビルダー;アルミノケイ酸塩
(ゼオライト)、クエン酸ナトリウム、エチレンジアミ
ン四酢酸ナトリウム、ニトリロ三酢酸塩、ポリアクリル
酸ナトリウム、アクリル酸ナトリウム−無水マレイン酸
ナトリウム共重合物、ポリアセタールカルボキシレート
等のカルシウムイオン捕捉ビルダー;炭酸塩。In addition to the above components (A) and (B), the detergent composition of the present invention further contains inorganic builders such as sodium tripolyphosphate and sodium birophosphate; aluminosilicate (zeolite), sodium citrate, and ethylenediaminetetra Calcium ion scavenging builders such as sodium acetate, nitrilotriacetate, sodium polyacrylate, sodium acrylate-sodium maleate anhydride copolymer, polyacetal carboxylate; carbonate;
珪酸塩等のアルカリビルダー;亜硫酸塩、硫酸塩;ポリ
エチレングリコール等の再汚染防止剤ニックラドルエン
スルホン酸塩、トルエンスルホン酸塩、キシレンスルホ
ン酸塩、尿素などの粘度調整剤;プロテアーゼ、リパー
ゼ、セルラーゼ、アミラーゼ(特にアルカリ雰囲気にお
いて活性を有するアルカリリパーゼ等)などの酵素;第
4級アンモニウム塩、ベントナイト等の柔軟付与剤;漂
白剤、蛍光剤、香料、色素などを使用することができる
。Alkali builders such as silicates; sulfites, sulfates; anti-recontamination agents such as polyethylene glycol; viscosity modifiers such as nickladolene sulfonate, toluene sulfonate, xylene sulfonate, urea; protease, lipase, cellulase. , enzymes such as amylase (such as alkaline lipase which is particularly active in an alkaline atmosphere); softening agents such as quaternary ammonium salts and bentonite; bleaching agents, fluorescent agents, perfumes, pigments, etc. can be used.
本発明のタブレット洗剤組成物は、通常のタブレット成
形法に従って容易にタブレットに成形でき、例えば粉粒
状の(A)アニオン性界面活性剤と(B)カルボキシメ
チルセルロースと、あるいはさらに他の任意成分とを混
合し、直径が約20〜60mm、厚さが約5〜20mm
の形状で、1錠の重量が約5〜60gのタブレットに成
形される。The tablet detergent composition of the present invention can be easily molded into tablets according to a normal tablet molding method, and can be prepared by combining, for example, powdered (A) anionic surfactant and (B) carboxymethyl cellulose, or other optional ingredients. Mixed, diameter is about 20-60mm, thickness is about 5-20mm
It is molded into tablets each weighing approximately 5 to 60 g.
且肌段夏果
本発明によれば、(A)アニオン性界面活性剤に、崩壊
剤として(B)特定粒度範囲の水難溶性カルボキシメチ
ルセルロースを配合することにより、水に投入したとき
に速やかに崩壊し、しかも、製造時の金型からの離型性
に優れたタブレット洗剤が得られ、その商品価値を著し
く高めることができる。According to the present invention, (A) an anionic surfactant is blended with (B) poorly water-soluble carboxymethyl cellulose having a specific particle size range as a disintegrating agent, so that it quickly disintegrates when added to water. Moreover, a tablet detergent with excellent releasability from a mold during production can be obtained, and its commercial value can be significantly increased.
以下1本発明の効果について実施例を挙げてさらに異動
的に説明する。これに先立って、実施例で用いた評価方
法を記す。Hereinafter, the effects of the present invention will be explained in more detail with reference to Examples. Prior to this, the evaluation method used in the examples will be described.
(1)金型からの離型性
粉末成分を均一に混合したのち、この配合物20gを内
径40mmのシリンダーに採り、200〜500kg/
aJで1分間加圧して、直径40mm、重量20gの錠
剤とした際の金型からの離型性を次の基準で評価した。(1) After uniformly mixing the releasable powder components from the mold, 20 g of this mixture is placed in a cylinder with an inner diameter of 40 mm, and the amount of 200 to 500 kg/
AJ was pressurized for 1 minute to form a tablet with a diameter of 40 mm and a weight of 20 g. The releasability from the mold was evaluated based on the following criteria.
A:金型への付着性なし
B:付着ややあり
C:かなり付着あり
(2)崩壊性試験
上記のタブレット洗剤2錠(計40g)を、25℃、3
iの水道水を満たした洗濯機(うず巻型1反転式)に投
入し、10分間洗浄した後、排水し、タブレットの崩壊
性を次の基準で評価した。A: No adhesion to the mold B: Slight adhesion C: Considerable adhesion (2) Disintegration test Two of the above detergent tablets (40 g in total) were heated at 25°C for 30 minutes.
The tablets were placed in a washing machine (spiral type 1 reversal type) filled with tap water, washed for 10 minutes, drained, and the disintegration properties of the tablets were evaluated according to the following criteria.
A:崩壊して塊が認められない
B:塊がやや認められる
C:塊が認められる
大−斑一■
後記表−1に示した(A)成分と任意成分(但し、香料
を除く)を用いて固形分45%の洗剤スラリーを調製し
た。この洗剤スラリーを、向流式噴霧乾燥塔を用い、熱
風温度380℃で、水分が5%となるように乾燥して、
噴霧乾燥品を得た。A: Collapsed and no lumps are observed B: Slight lumps are observed C: Large spots are observed A detergent slurry with a solids content of 45% was prepared using the following methods. This detergent slurry was dried using a countercurrent spray drying tower at a hot air temperature of 380°C to a moisture content of 5%.
A spray-dried product was obtained.
ついで、上記乾燥品に(B)成分の各種崩壊剤および香
料を混合した後、打錠してタブレット洗剤組成物を得た
。Next, various disintegrants and fragrances as component (B) were mixed with the dried product, and the mixture was compressed into tablets to obtain a tablet detergent composition.
これら各洗剤組成物について、金型からの離型性および
崩壊性を評価して、結果を表−1に示した。The releasability and disintegration properties of each of these detergent compositions from the mold were evaluated, and the results are shown in Table 1.
(以下余白)(Margin below)
Claims (1)
量% (B)200メッシュ篩目通過のフラクシヨンが80%
以上の粒度を有する水難溶性のカルボキシメチルセルロ
ース粉末:1〜30重量%を含有することを特徴とする
タブレット洗剤組成物。[Claims] 1. (A) Powdered anionic surfactant: 5 to 50% by weight (B) Fraction passing through a 200 mesh sieve is 80%
A tablet detergent composition characterized by containing 1 to 30% by weight of poorly water-soluble carboxymethyl cellulose powder having a particle size of the above particle size.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13412789A JPH02311600A (en) | 1989-05-25 | 1989-05-25 | Detergent composition in tablet form |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13412789A JPH02311600A (en) | 1989-05-25 | 1989-05-25 | Detergent composition in tablet form |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02311600A true JPH02311600A (en) | 1990-12-27 |
Family
ID=15121097
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13412789A Pending JPH02311600A (en) | 1989-05-25 | 1989-05-25 | Detergent composition in tablet form |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02311600A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998040463A1 (en) * | 1997-03-13 | 1998-09-17 | Henkel Kommanditgesellschaft Auf Aktien | Household detergent or cleaning action shaped bodies |
WO1998055583A1 (en) * | 1997-06-06 | 1998-12-10 | Unilever Plc | Cleaning compositions |
WO1999013042A1 (en) * | 1997-09-09 | 1999-03-18 | Henkel Kommanditgesellschaft Auf Aktien | Washing and cleaning agent shaped bodies with improved solubility |
WO2000031231A1 (en) * | 1998-11-19 | 2000-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Additive granule for moulded bodies having a detergent and cleaning action |
WO2000044873A1 (en) * | 1999-01-28 | 2000-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Multiphase detergent tablets |
JP2002535449A (en) * | 1999-01-23 | 2002-10-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | Detergent tablet |
KR100374936B1 (en) * | 2000-01-14 | 2003-03-06 | 주식회사 엘지생활건강 | Laundry tablet detergent composition |
KR100391556B1 (en) * | 2000-05-25 | 2003-07-12 | 애경산업(주) | Tablet-type detergent composition, and detergent produced therefrom |
KR100436171B1 (en) * | 2001-07-04 | 2004-06-12 | 주식회사 엘지생활건강 | Tablet detergent composition and method for preparing the same |
KR100516453B1 (en) * | 1998-02-20 | 2006-02-08 | 주식회사 엘지생활건강 | Manufacturing method of highly concentrated powder detergent with improved storage stability and fluidity |
US7008912B1 (en) | 1997-03-11 | 2006-03-07 | Henkel Kgaa | Pressed piece which disintegrates in liquids |
WO2010103601A1 (en) * | 2009-03-10 | 2010-09-16 | ダイセルポリマー株式会社 | Resin composition for cleaning of resin molding machines |
JP2013224353A (en) * | 2012-04-20 | 2013-10-31 | Kao Corp | Method for producing solid detergent |
JP2019014784A (en) * | 2017-07-04 | 2019-01-31 | 日本製紙株式会社 | Forming type detergent composition |
-
1989
- 1989-05-25 JP JP13412789A patent/JPH02311600A/en active Pending
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7008912B1 (en) | 1997-03-11 | 2006-03-07 | Henkel Kgaa | Pressed piece which disintegrates in liquids |
WO1998040463A1 (en) * | 1997-03-13 | 1998-09-17 | Henkel Kommanditgesellschaft Auf Aktien | Household detergent or cleaning action shaped bodies |
USRE39139E1 (en) * | 1997-03-13 | 2006-06-20 | Henkel Kgaa | Process for preparing household detergent or cleaner shapes |
US6506720B1 (en) | 1997-03-13 | 2003-01-14 | Henkel Kommanditgesellschaft Auf Aktien | Process for preparing household detergent or cleaner shapes |
WO1998055583A1 (en) * | 1997-06-06 | 1998-12-10 | Unilever Plc | Cleaning compositions |
US6051545A (en) * | 1997-06-06 | 2000-04-18 | Lever Brothers Company Division Of Conopco, Inc. | Cleaning compositions |
WO1999013042A1 (en) * | 1997-09-09 | 1999-03-18 | Henkel Kommanditgesellschaft Auf Aktien | Washing and cleaning agent shaped bodies with improved solubility |
KR100516453B1 (en) * | 1998-02-20 | 2006-02-08 | 주식회사 엘지생활건강 | Manufacturing method of highly concentrated powder detergent with improved storage stability and fluidity |
WO2000031231A1 (en) * | 1998-11-19 | 2000-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Additive granule for moulded bodies having a detergent and cleaning action |
JP2002535449A (en) * | 1999-01-23 | 2002-10-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | Detergent tablet |
WO2000044873A1 (en) * | 1999-01-28 | 2000-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Multiphase detergent tablets |
KR100374936B1 (en) * | 2000-01-14 | 2003-03-06 | 주식회사 엘지생활건강 | Laundry tablet detergent composition |
KR100391556B1 (en) * | 2000-05-25 | 2003-07-12 | 애경산업(주) | Tablet-type detergent composition, and detergent produced therefrom |
KR100436171B1 (en) * | 2001-07-04 | 2004-06-12 | 주식회사 엘지생활건강 | Tablet detergent composition and method for preparing the same |
WO2010103601A1 (en) * | 2009-03-10 | 2010-09-16 | ダイセルポリマー株式会社 | Resin composition for cleaning of resin molding machines |
JP2013224353A (en) * | 2012-04-20 | 2013-10-31 | Kao Corp | Method for producing solid detergent |
JP2019014784A (en) * | 2017-07-04 | 2019-01-31 | 日本製紙株式会社 | Forming type detergent composition |
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