CN105838515A - Liquid cleanser - Google Patents
Liquid cleanser Download PDFInfo
- Publication number
- CN105838515A CN105838515A CN201510018145.9A CN201510018145A CN105838515A CN 105838515 A CN105838515 A CN 105838515A CN 201510018145 A CN201510018145 A CN 201510018145A CN 105838515 A CN105838515 A CN 105838515A
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- China
- Prior art keywords
- liquid cleaner
- agent
- natural
- water
- cleaning
- Prior art date
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- 239000007788 liquid Substances 0.000 title claims abstract description 47
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 235000013305 food Nutrition 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 12
- VYBYUSNZEMCCFQ-UHFFFAOYSA-N C=CC=CCC.[K] Chemical compound C=CC=CCC.[K] VYBYUSNZEMCCFQ-UHFFFAOYSA-N 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 7
- 229940073499 decyl glucoside Drugs 0.000 claims description 7
- 239000000419 plant extract Substances 0.000 claims description 7
- 229940101011 sodium hydroxymethylglycinate Drugs 0.000 claims description 7
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical class [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229960003237 betaine Drugs 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000341 volatile oil Substances 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001071 citrus reticulata blanco var. mandarin Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- -1 decyl glucose Glycosides Chemical class 0.000 claims description 3
- 238000001212 derivatisation Methods 0.000 claims description 3
- 239000000796 flavoring agent Substances 0.000 claims description 3
- 235000019634 flavors Nutrition 0.000 claims description 3
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 claims description 3
- 238000009795 derivation Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 229930182470 glycoside Natural products 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 11
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 31
- 239000000575 pesticide Substances 0.000 description 19
- 241000219095 Vitis Species 0.000 description 13
- 239000000523 sample Substances 0.000 description 12
- 235000009392 Vitis Nutrition 0.000 description 11
- 239000003085 diluting agent Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- 241001596927 Enoplosus armatus Species 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 235000014787 Vitis vinifera Nutrition 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000013074 reference sample Substances 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000009920 chelation Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000035943 smell Effects 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229940069521 aloe extract Drugs 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000002532 grape seed extract Nutrition 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 235000020569 organic green tea Nutrition 0.000 description 2
- CITBNDNUEPMTFC-UHFFFAOYSA-M sodium;2-(hydroxymethylamino)acetate Chemical compound [Na+].OCNCC([O-])=O CITBNDNUEPMTFC-UHFFFAOYSA-M 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241001116389 Aloe Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241001428166 Eucheuma Species 0.000 description 1
- HXEACLLIILLPRG-YFKPBYRVSA-N L-pipecolic acid Chemical class [O-]C(=O)[C@@H]1CCCC[NH2+]1 HXEACLLIILLPRG-YFKPBYRVSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000283898 Ovis Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 231100000293 acute skin toxicity Toxicity 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006161 blood agar Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000005757 colony formation Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 229940094952 green tea extract Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 108700019599 monomethylolglycine Proteins 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- 229940094944 saccharide isomerate Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
A liquid cleanser includes, by weight, 5-40% of a natural interface activator, 0.1-1% of citric acid, 0.1-0.6% of food-grade potassium hexadienoate or sodium N-hydromethylglycinate, and the balanced being water. The liquid cleanser is suitable for cleaning foods, tableware and kitchen ware, is environment-friendly, and has excellent cleaning effects.
Description
Technical field
The present invention is related to a kind of liquid cleaner, particularly relates to a kind of for cleaning food and tableware or kitchen tools etc.
Liquid cleaner.
Background technology
The typically greasy dirt being used for cleaning contamination on tableware or kitchen tools of cleaning agent, can be provided for cleaning veterinary antibiotics more
The pollutant of contamination, such as pesticide, fertilizer, preservative, antibacterial or dust etc. on surface.
It is commonly used for cleaning the cleaning agent of food, tableware or kitchen tools etc. on the market, mainly includes with petroleum interface
Activating agent is main cleaning agent, such as alkyl benzene sulphonate teepol；And with Oleum Cocois or Cortex cocois radicis oils and fats
Pipecolic acid derivative interfacial agent is main cleaning agent.
Although decontamination pollutant on food can be effectively removed in the aforementioned cleaning agent based on petroleum interfacial agent
Or the greasy dirt on tableware, but it is attached to body surface owing to this type of cleaning agent is relatively easy, therefore it is difficult to rinse and does
Only so that residue in food or the cleaning agent of tableware may enter in human body or animal body, harmful effect is produced.
In addition, the waste water being mixed with this type of cleaning agent also has harmful effect to environment.
Compared to the cleaning agent based on petroleum interfacial agent, although with Oleum Cocois or coconut oil fatty acids thing
The cleaning agent that interfacial agent is main is relatively low on the impact of environment, the most less likely skin of harm people surface, but still has
Possibly into human body, human body is produced harmful effect.
It addition, use the prepared interfacial agent of the oxirane (ethylene oxide) that synthesized by petrochemical origin, can
Can remain carcinogen Isosorbide-5-Nitrae-dioxanes (Isosorbide-5-Nitrae-Dioxane), and human body is produced injury.
The 4th, 140, No. 649 a kind of constituent for cleaning food of patent diselosesll of the U.S., aforementioned component thing include 1 to
The cation interfacial active agent of 10wt%；The teepol of 0.1 to 4wt%；The chelating agen of 1 to 25wt%；
The buffer agent of 5 to 30wt% and other compositions.Wherein, aforesaid cations interfacial agent is that one can be via sulphation
Or the petroleum interfacial agent of sulfonation, aforementioned chelating agen then can select citric acid or its esters.
A kind of avirulence cleaning agent component for cleaning fruit and vegetable of the 4th, 808, No. 330 patent diselosesll of the U.S., front
State the sodium chloride that constituent comprises 15 to 30wt%；The ethanol of 10 to 35wt%；The Oleum Cocois of 8 to 25wt% and water.
Aforementioned Oleum Cocois can form emulsifying shape after mixing with above-mentioned proportion with alcohol and water and become opaque liquid so that
This kind of cleaning agent is less accepted by ordinary consumer.It addition, aforementioned cleaning agent is because containing free chlorine, being easier to brokenly
The abnormal smells from the patient of bad food.
Summary of the invention
A kind of can be used for of offer is provided and cleans food, dish and the liquid cleaner of kitchen tools,
It includes the natural interfacial agent of 5 to 40wt%, its without the oxirane that synthesized by petrochemical origin prepare non-from
Son and teepol；The citric acid of 0.1 to 1wt%；The food stage potassium hexadiene of 0.1 to 0.6wt% or N-
Sodium hydroxy methyl glycinate；And the water of surplus.
Aforementioned natural interfacial agent, such as, can use and meet international ecological authentication center of European Union (Ecocert) specification
The interfacial agent of " 100% natural origin ".
" oxirane of petrochemical origin synthesis " addressed herein, refers to ethylene produced by petroleum fractionating, further
The oxirane obtained after oxidation.
In the liquid cleaner of the present invention, this natural interfacial agent is preferably the derivatization reaction thing of natural coconut oleyl alcohol,
Preferably decyl glucoside (Decyl Glucoside), cocamidopropyl propyl amide betaine (Cocamidopropyl
Betaine, CAPB) and sodium laureth sulfate salt (Sodium Lauryl Ether Sulfate, SLES)
In at least one compound.
In the liquid cleaner of the present invention, citric acid is as a kind of acid alkali regulator and chelating agen.It is to metal
There is chelation, can be with the divalent ions such as the calcium in hard water, magnesium or the metal being attached to body surface to be cleaned
Oxide forms misfit thing, reaches effect of secondary.
In liquid cleaner provided by the present invention, this food stage potassium hexadiene or N-sodium hydroxy methyl glycinate
(Sodium N-(hydroxymethyl) glycinate) is as a kind of preservative agent, so as to promoting the liquid of the present invention
The storage stability of cleaning agent.
Owing to fluid present invention cleaning agent is made up of 100% natural component, and without the epoxy synthesized by petrochemical origin
Ethane prepare nonionic and teepol, therefore compared to existing cleaning agent, can not only be greatly reduced
To human body and the injury of environment, and its cleaning effect is good, it is possible to effectively remove the greasy dirt of body surface to be cleaned, thin
Bacterium, pesticide etc..Additionally, the cleaning agent of the present invention can present transparent clarification shape, therefore it is easier to by ordinary consumer
Accepted.
In addition to the above ingredients, in fluid present invention cleaning agent, the most visual actual demand increases other additives, such as, protect
Humectant, aromatic, coloring agent etc..
Aforementioned wetting agent can be selected for the good organic plant extract of moisturizing effect or organic colored water, to provide human body
The moistening effect that skin is good.Aforementioned organic plant extract can be organic aloe extract, organic green-tea extract or
It is that other have the organic plant extract of moisture-keeping efficacy；Aforementioned organic colored water can be organic rose wate or other tools
The organic colored water of Saccharideisomerate.
Aforementioned fragrance agent does not use the natural flavor containing synthol and synthetic ester, the most preferably uses and has aromatic odor
Plants essential oil, such as mandarin oil, Fructus Citri Limoniae oil or other this plants essential oils, to be effectively improved the gas of liquid cleaner
Taste, maintains the characteristic of its environmental-friendly natural simultaneously.
Detailed description of the invention
The present invention is described in detail further below.
A kind of liquid cleaner for cleaning the objects such as food, dish and kitchen tools provided by the present invention, it mainly wraps
Containing natural interfacial agent；Citric acid；Food stage potassium hexadiene or N-sodium hydroxy methyl glycinate；And surplus
Water.
The content of this natural interfacial agent is preferably 5 to 40wt%, and without the oxirane system synthesized by petrochemical origin
Nonionic and teepol, more and, this natural interfacial agent is preferably used natural coconut oleyl alcohol
Derivatization reaction thing, its example is preferably (but not limited to) decyl glucoside (Decyl Glucoside), coconut oleoyl amine
Propyl group betaine (Cocamidopropyl betaine, CAPB), sodium laureth sulfate salt (Sodium Lauryl
Ether Sulfate, hereinafter referred to as SLES) or its mixture.Aforementioned SLES can use by the epoxy of 100% biogenetic derivation
Person obtained by ethane, such as, can use and meet Ecocert standard, and 100% is derived from the trade name of Caulis Sacchari sinensisThe SLES of ESB-70/NAT.In the liquid cleaner of one embodiment of the invention, this natural interfacial agent
For decyl glucoside, cocamidopropyl propyl amide betaine and the mixture of sodium laureth sulfate salt, and it mixes
Close weight ratio and be preferably 12:7:16 to 28:16:27.
The present invention uses has hydrophilic group and the natural interfacial agent of lipophilic group composition simultaneously, through its hydrophilic group with
Water is mutually dissolved, it is to avoid produces emulsion, enables the liquid cleaner of the present invention to present clear, and pass through
Its lipophilic group produces emulsification with the greasy dirt of body surface to be cleaned, and greasy dirt is peeled off body surface to be cleaned, so as to
The liquid cleaner making the present invention has environmental protection, more harmless to human body and can the effective advantage such as cleaning.If nature
The content of face activating agent is less than 5wt%, can reduce its cleaning effect；If natural interface active agent content is more than 40wt%,
Then can increase the manufacturing cost of liquid cleaner.
The content of this citric acid is preferably 0.1 to 1wt%, and it is mainly as a kind of acid alkali regulator and chelating agen.Profit
With the citric acid chelation to metal, with divalent ions such as the calcium in hard water, magnesium or be attached to object table to be cleaned
The metal-oxide in face forms misfit thing, improves cleaning effect with auxiliary.If the content of citric acid is less than 0.1wt%, its
Chelation is the best, and cannot be effectively improved cleaning effect；If the content of citric acid is more than 1wt%, then pH value is the lowest,
Cannot use.
This food stage potassium hexadiene or N-sodium hydroxy methyl glycinate (Sodium N-(hydroxymethyl)
Glycinate) content is preferably 0.1 to 0.6wt%, and it is mainly as a kind of preservative agent, to improve the liquid of the present invention
The storage stability of cleaning agent.If the content of potassium hexadiene or N-sodium hydroxy methyl glycinate is less than 0.1wt%, then anticorrosion
Poor effect；If the content of potassium hexadiene or N-sodium hydroxy methyl glycinate is higher than 0.6wt%, then can increase cleaning liquid
The manufacturing cost of agent.
Fluid present invention cleaning agent also can further include wetting agent, to provide the moistening effect that human body skin is good.
The content of this wetting agent is preferably 0.05 to 20wt%, and preferably uses organic plant extract or organic colored water.Aforementioned have
Machine plant extraction liquid can be selected for the good organic aloe extract of (but not limited to) moisturizing effect or organic green-tea extraction
Liquid；Aforementioned organic colored water can use the organic rose wate of (but not limited to).If organic plant extract or organic colored water
Content less than 0.05wt%, then moistening effect is the best；If the content of organic plant extract or organic colored water is more than 20
Wt%, then can increase the manufacturing cost of liquid cleaner.
Fluid present invention cleaning agent also can further include aromatic, to improve the abnormal smells from the patient of liquid cleaner.This fragrance
Agent preferably uses plants essential oil rather than containing synthol and the natural flavor of synthetic ester, and its content is preferably 0.1 to 1
Wt%, to provide liquid cleaner the most pleasant abnormal smells from the patient.Afore-mentioned plants quintessence oil can be selected for (but not limited to) mandarin oil,
Fructus Citri Limoniae oil or other dulcet plants essential oils of tool.
For contributing to understanding the present invention, will transmit through specific embodiment and be described in further detail the present invention, but following embodiment is only
Being the example of the present invention, protection scope of the present invention is not limited to following embodiment.
The preparation of liquid cleaner
[embodiment 1]
By the decyl glucoside of 12g, the cocamidopropyl propyl amide betaine of 7g, the sodium laureth sulfate of 16g
Salt is sufficiently mixed, as natural interfacial agent.Afterwards by the aloe extraction liquid of aforementioned natural interfacial agent and 10g,
The water of the mandarin oil of 0.3g, the citric acid of 0.2g, the potassium hexadiene of 0.5g and 54g is sufficiently stirred for prepare clear
The liquid cleaner of the embodiment 1 of clear transparent liquid.
Residue of pesticide measures examination 1
[reference sample]
Use general sulfur pine (Tokuthion) pesticide (Taiwan Xingnong Co., Ltd is for selling) diluting 500 times through water, front
State oxygen-ethyl-2,4 dichloro benzene base-S-n-butyl-carbophenothion hydrochlorate that pesticide contains 50%.By aforementioned pesticide
It is sprayed on the surface of a string new fresh grape equably, arbitrarily takes the Fructus Vitis viniferae of a portion as reference sample.
[sample 1]
After aforementioned remaining Fructus Vitis viniferae is placed in outdoor 24 hours, arbitrarily take a portion Fructus Vitis viniferae as sample 1.
[sample 2]
Fructus Vitis viniferae after being placed in outdoor 24 hours arbitrarily takes 2 Fructus Vitis viniferaes, is respectively put in the water of 100mL, then with concussion
Device takes out after shaking 30 seconds, as sample 2.
[sample 3]
Fructus Vitis viniferae after being placed in outdoor 24 hours arbitrarily takes 2 Fructus Vitis viniferaes, and carries out with the method identical with described in sample 2
Clean, but use the diluent after the liquid cleaner of embodiment 1 is diluted 100 times with water to clean Fructus Vitis viniferae, after cleaning
Fructus Vitis viniferae is as sample 3.
Above-mentioned sample 1～3 uses mark rate pesticide biochemical investigation method to detect its residue of pesticide amount, and (%, its percentage rate system is with reference
Sample is as benchmark).Test result is as shown in table 1 below.
[table 1]
Residue of pesticide amount (%)
Note) residue of pesticide amount (%) is using the pesticide volume contained by reference sample as benchmark
Can substantially be learnt by the result of table 1, use the Fructus Vitis viniferae that the liquid cleaner diluent of the embodiment of the present invention 1 is cleaned,
The pesticide of 94.5% on its surface removable, the only Fructus Vitis viniferae with clean water then can only remove the pesticide of 41%, obvious
The liquid cleaner of invention can actually remove the pesticide of body surface to be cleaned effectively.
Residue of pesticide measures examination 2
Use liquid cleaner and the clean water green grass or young crops river dish of embodiment 1 respectively, utilize afterwards and defend good fortune portion in TaiWan, China
In the food that on July 3rd, 2014 is issued, the residual pesticide method of inspection-multiple residue analysis method (five) detection is not cleaned
And use the blue or green river dish after embodiment 1 and clean water respectively.Test result is as shown in table 2 below.
[table 2]
As seen from the results in Table 2, the liquid cleaner of the present invention can go effectively for the Multiple Pesticides of vegetable surface
Remove.
Environmental effect is tested
The liquid cleaner of embodiment 1 is diluted 5,000,10,000,50,000 and 100,000 times of one-tenth with water respectively
The diluent of variable concentrations.On the other hand, respectively the cleaning agent buied on the market (is mainly composed of Oleum Cocois interface
Activating agent and coconut oil fatty acids thing), cleaning agent (is mainly composed of and lives with LABS nonionic interface
Property agent) and clear water as comparative example 1,2 and 3, then with above-mentioned such multiple comparative example 1 and 2 is diluted to different dense
The diluent of degree.
Thereafter, in embodiment 1, the diluent of comparative example 1～2 and comparative example 3 (clear water), one is put into respectively greatly
Tripe fish.In the water being not added with any cleaning agent, additionally put into 4 oldwives.Observe and record oldwife existence to live
Dynamic situation, its result is shown in table 3 below.
[table 3]
Extension rate
By table 3 it is apparent that the oldwife being present in the diluent of cleaning agent of the present invention and be present in clear water
Oldwife in (comparative example 3) all impregnable can continue survival, but, it is present in the city of comparative example 1 and 2
Sell the oldwife in detergent dilution and be then difficult to survival.The most in higher concentrations, the time-to-live phase of oldwife
When short.Therefore, the liquid cleaner of the present invention affects far below existing commercially available cleaning agent for environment or human body.
In addition, the cleaning agent component of the present invention is tested as having LD through acute oral toxicity50＞ 5,000mg/kg with
And acute dermal toxicity test is for having LD50＞ 2,000mg/kg, is consequently belonging to a kind of avirulent cleaning agent.
Removal of bacteria is tested
The cleaning agent of the cleaning agent of embodiment 1 with above-mentioned comparative example 1 is diluted 100 times with sterilized water, respectively afterwards by 2
New fresh grape is respectively put in those diluents cleaning, its cleaning way and residue of pesticide and measures mode phase described in examination 1
With.Thereafter, more respectively with sterile water wash with the washed Fructus Vitis viniferae of such diluent and not washed with those diluents
Fructus Vitis viniferae, respectively as sample 4,5 and 6.Sample 4,5 and 6 is inoculated in containing Sanguis caprae seu ovis Eucheuma gelatinosum bacteria culture media (blood
Agar plate) on, and cultivate 24 hours at a temperature of 37 DEG C.Colony growth result such as table 4 below in culture medium
Shown in.
[table 4]
Total aerobic plate count (CFU/g)
Being clearly visible by table 4 result, the sample 4 after only cleaning with the liquid cleaner of the present invention does not detect bacterium
Fall, and sample 5 and 6 all detects bacterium colony, and total aerobic plate count is respectively 1.3 × 102With 3.7 × 10CFU/g
(colony formation units/g).Aforementioned result fully proves that the liquid cleaner of the present invention can go effectively
Except the antibacterial of attachment on body surface to be cleaned.
Summary, the not only environmental protection of the liquid cleaner of the present invention, harmless, and for such as food, tableware,
Kitchen tools wait that the pollutant such as the greasy dirt on cleaning objects surface, pesticide, antibacterial also have the cleaning effect of excellence.Further,
The cleaning agent of the present invention has the outward appearance of transparent clarification, is easily generally accepted by consumers.
Claims (8)
1. a liquid cleaner, it is characterised in that include:
The natural interfacial agent of 5 to 40wt%, its nonionic prepared without the oxirane that synthesized by petrochemical origin and
Teepol；
The citric acid of 0.1 to 1wt%；
The food stage potassium hexadiene of 0.1 to 0.6wt% or N-sodium hydroxy methyl glycinate；And
The water of surplus.
Liquid cleaner the most according to claim 1, it is characterised in that this natural interfacial agent is natural coconut oil
The derivatization reaction thing of alcohol, and be decyl glucoside, cocamidopropyl propyl amide betaine, sodium laureth sulfate
Salt or aforesaid mixture.
Liquid cleaner the most according to claim 2, it is characterised in that this natural interfacial agent is decyl glucose
Glycosides, cocamidopropyl propyl amide betaine and the mixture of sodium laureth sulfate salt, and its mixed weight ratio is
12:7:16 to 28:16:27.
Liquid cleaner the most according to claim 2, it is characterised in that sodium laureth sulfate salt is by 100%
Obtained by the oxirane of biogenetic derivation.
Liquid cleaner the most according to claim 1, it is characterised in that further include the wetting agent of 0.05 to 20wt%.
Liquid cleaner the most according to claim 5, it is characterised in that this wetting agent is organic plant extract or has
Machine flower water.
Liquid cleaner the most according to claim 1, it is characterised in that further include the aromatic of 0.1 to 1wt%,
This aromatic does not contains synthol and the natural flavor of synthetic ester.
Liquid cleaner the most according to claim 7, it is characterised in that this aromatic is mandarin oil, Fructus Citri Limoniae oil or front
State the plants essential oil of mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510018145.9A CN105838515A (en) | 2015-01-14 | 2015-01-14 | Liquid cleanser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510018145.9A CN105838515A (en) | 2015-01-14 | 2015-01-14 | Liquid cleanser |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105838515A true CN105838515A (en) | 2016-08-10 |
Family
ID=56579781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510018145.9A Pending CN105838515A (en) | 2015-01-14 | 2015-01-14 | Liquid cleanser |
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| Country | Link |
|---|---|
| CN (1) | CN105838515A (en) |
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| CN109957460A (en) * | 2017-12-25 | 2019-07-02 | 浙江神英科技有限公司 | A kind of cleaning agent for dinnerware and preparation method thereof containing bactericide |
| CN112403140A (en) * | 2020-10-19 | 2021-02-26 | 傅光明 | Smoke-eliminating and dust-removing agent and preparation method thereof |
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Application publication date: 20160810 |