CN109112003A - A kind of use in dishwasher washs solidifying pearl and preparation method - Google Patents
A kind of use in dishwasher washs solidifying pearl and preparation method Download PDFInfo
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- CN109112003A CN109112003A CN201811141424.4A CN201811141424A CN109112003A CN 109112003 A CN109112003 A CN 109112003A CN 201811141424 A CN201811141424 A CN 201811141424A CN 109112003 A CN109112003 A CN 109112003A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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Abstract
The present invention relates to field of daily chemicals, a kind of use in dishwasher is provided and washs solidifying pearl and preparation method, for solving the problems, such as that dish washing detergents remain.A kind of use in dishwasher provided by the invention washs solidifying pearl and preparation method, including 0.1 ~ 60 mass parts of surfactant, 0.1 ~ 40 mass parts of washing assisant, 0.1 ~ 50 mass parts of solvent, 0 ~ 10 mass parts of defoaming agent, 0 ~ 20 mass parts of disinfectant, 0 ~ 30 mass parts of dispersing agent, 0 ~ 5 mass parts of enzyme.By the synergistic effect of surfactant, auxiliary agent and solvent, the clean effect for washing solidifying pearl can be significantly improved；Pearl is coagulated in washing after water-setting film package can effectively prevent detergent residual.
Description
Technical field
The present invention relates to field of daily chemicals, and in particular to a kind of use in dishwasher washs solidifying pearl and preparation method.
Background technique
Dish-washing machine is the equipment of the tablewares such as automatic cleaning bowl, chopsticks, disk, dish, knife, fork.Existing dish-washing machine mainly uses powder
The detergent of shape or liquid, the powder block that washes the dishes have the problem of micro substance residual；The bad control of existing liquid dishwasher liquid dosage,
Inconvenient problem with use.
Pearl is coagulated with the washing of water soluble film package detergent support, is had a wide range of applications in the washing field of clothing, nothing
Harmful toxic matter residual, dosage is accurate, easy to use.By the production application for washing solidifying pearl to dish-washing machine field, there is wide answer
Use prospect.
Summary of the invention
Present invention solves the technical problem that the problem of remaining for dish washing detergents, it is solidifying to provide a kind of use in dishwasher washing
Pearl and preparation method.
In order to solve the above technical problem, the present invention provides technical solution are as follows:
A kind of use in dishwasher washs solidifying pearl and preparation method, including 0.1 ~ 60 mass parts of surfactant, washing assisant 0.1 ~ 40
Mass parts, 0.1 ~ 50 mass parts of solvent, 0 ~ 10 mass parts of defoaming agent, 0 ~ 20 mass parts of disinfectant, 0 ~ 30 mass parts of dispersing agent, enzyme
0 ~ 5 mass parts.
Surfactant has the effect of wetting, emulsification and part decontamination；Washing assisant can promote clean effect；
Defoaming agent is for removing the foam generated in production process；Disinfectant is used to improve the disinfection effect for washing solidifying pearl；Dispersion
Agent is used for demineralized water, prevents soil redeposition；Enzyme promotes clean effect for removing tough stains；Solvent is used for dissolved matter
Material improves clean effect.
By the synergistic effect of surfactant, auxiliary agent and solvent, the clean effect for washing solidifying pearl can be significantly improved.
Preferably, including 30 ~ 60 mass parts of surfactant, 20 ~ 40 mass parts of washing assisant, 15 ~ 50 mass parts of solvent,
5 ~ 10 mass parts of defoaming agent, 10 ~ 20 mass parts of disinfectant, 10 ~ 30 mass parts of dispersing agent, 2 ~ 5 mass parts of enzyme.Washing after optimization
Its dirt-removing power can be improved in the formula of solidifying pearl.
Preferably, including 30 mass parts of surfactant, 20 mass parts of washing assisant, 15 mass parts of solvent, 5 matter of defoaming agent
Measure part, 10 mass parts of disinfectant, 10 mass parts of dispersing agent, 2 mass parts of enzyme.Pearl is coagulated in washing after advanced optimizing can be significant
Improve its dirt-removing power.
Preferably, the surfactant is nonionic surfactant；The surfactant is ethylenediamine EO/
PO copolymer, EO/PO polyethers, sucrose ester, fatty alcohol polyoxyethylene ether are one such or several.Nonionic surfactant
Stability is good, can effectively remove dirt.
Preferably, the washing assisant is sodium carbonate, sodium bicarbonate, sodium metasilicate, sodium hydroxide, triethanolamine, Dan Yi
Hydramine, diethanol amine are one such or several；The solvent is that alcohols, alcohol ether, esters, terpenes are one such or several
Kind.Washing assisant and solvent are for promoting clean effect；Its clean effect of weakly alkaline auxiliary agent is more preferable；Organic solvent can be effective
Part dirt is dissolved, improve its clean effect.
Preferably, the defoaming agent is organosilicon, fatty acid one of which or several；The bleaching and disinfecting agents are chlorine
Amine T, sodium dichloro cyanurate, sodium hypochlorite, SODIUM PERCARBONATE are one of or several；The dispersing agent is polycarboxylate, lemon
Lemon hydrochlorate, gluconate are one of or several.Defoaming agent is mainly used for the foam generated when removal production, organosilicon or rouge
Fat acid can effectively take out foam；Chemosterilant can effective sterilizing；Weakly alkaline salt is dispersing agent, can be with
Clean effect is further increased, by the greasiness removal of indissoluble.
Preferably, the enzyme be protease, amylase, lipase, complex enzyme it is one of or several.Enzyme can have
The stain of the certain macromoleculars of taking-up of effect.
A kind of solidifying pearl preparation method of use in dishwasher washing, includes the following steps: to mix surfactant with washing assisant
Stirring and emulsifying afterwards obtains emulsion；Defoaming agent is added in emulsion, adds dispersing agent after stirring evenly defoaming, is stirred,
Obtain intermediate fluid；Disinfectant, enzyme and solvent are added in intermediate fluid, stirred evenly, detergent is obtained and carries out water soluble film packaging,
Detergent is packaged into water soluble film.
After mixing by surfactant and auxiliary agent, add dispersing agent and improve dispersion effect, be then added disinfectant,
Enzyme and solvent are to increase the disinfecting detergent effect of solidifying pearl；In production process, if defoaming agent need to be added by producing a large amount of foams, mention
Safety in Gao Shengcha；It is finally encapsulated with water soluble film, is used convenient for client.
Preferably, the mixing speed is 15 ~ 40r/min.Mixing speed is to influence water-setting pearl washing effect more
The crucial factor of production.
Preferably, the mixing speed is 20r/min.The effect of 20 rpms of production efficiencys and the product produced
More preferably.
Preferably, it further includes 0.5 ~ 1 mass parts of modified nano zinc oxide that the washing, which is coagulated in pearl,；Described is modified oxidized
Zinc includes that oxidation bi content is 0.5 ~ 10 mass parts, 75 ~ 80 mass parts of zinc oxide；The modified zinc oxide is by the following method
It is made:
By zinc oxide, bismuth nitrate ball milling, control ratio of grinding media to material is 10:1~50:1；
It takes and a small amount of sodium hydroxide solution is added, wherein the molal quantity of sodium hydroxide or potassium hydroxide is equivalent to the first step and weighs nitric acid
0.15 ~ 2.5 mass parts of bismuth molal quantity, are added 0.5 ~ 1 mass parts of deionized water, and ball milling 20min~30min obtains powder；
Powder is put into and is placed in Muffle furnace, at the uniform velocity heating is heat-treated, and heat treatment temperature is 400~650 DEG C, and keeps the temperature 1
~2h obtains a kind of modified oxidized zinc powder, i.e., modified oxidized zinc powder prepared by the present invention.
After modified oxidized zinc powder is stirred together for surfactant and washing assisant, dispersing agent is added, further
The step of after being carried out again after dispersion.
Modified Zinc oxide powder can significantly improve the clean effect for washing solidifying pearl.
Compared with prior art, the device have the advantages that are as follows: cooperateed with by surfactant, auxiliary agent with solvent
Effect can significantly improve the clean effect for washing solidifying pearl；Surfactant has wetting, emulsification and part decontamination
Effect；Washing assisant can promote clean effect；Defoaming agent is for removing the foam generated in production process；Disinfectant is for mentioning
Height washs the disinfection effect of solidifying pearl；Dispersing agent is used for demineralized water, prevents soil redeposition；Enzyme is for removing obstinate dirt
Dirt promotes clean effect；Solvent is used for dissolved material, improves clean effect；Pearl is coagulated in washing after water-setting film package can be effective
Prevent detergent from remaining.
Specific embodiment
Following implementation column is to further explanation of the invention, is not limitation of the present invention.
Embodiment 1
A kind of use in dishwasher washs solidifying pearl and preparation method, including 30 mass parts of surfactant, 20 mass parts of washing assisant are molten
15 mass parts of agent, 5 mass parts of defoaming agent, 10 mass parts of disinfectant, 10 mass parts of dispersing agent, 2 mass parts of enzyme.The surface is living
Property agent be nonionic surfactant；The surfactant is ethylenediamine EO/PO copolymer.The washing assisant is carbon
Sour sodium, sodium hydroxide, triethanolamine mixture；The solvent is alcohols.The defoaming agent is organosilicon；The drift
White disinfectant is toluene-sodium-sulfonchloramide；The dispersing agent is polycarboxylate.The enzyme is the mixing of amylase, lipase, complex enzyme
Object.
Surfactant has the effect of wetting, emulsification and part decontamination；Washing assisant can promote clean effect；
Defoaming agent is for removing the foam generated in production process；Disinfectant is used to improve the disinfection effect for washing solidifying pearl；Dispersion
Agent is used for demineralized water, prevents soil redeposition；Enzyme promotes clean effect for removing tough stains；Solvent is used for dissolved matter
Material improves clean effect.
By the synergistic effect of surfactant, auxiliary agent and solvent, the clean effect for washing solidifying pearl can be significantly improved.
Its dirt-removing power can be improved in the formula of the solidifying pearl of washing after optimization.Pearl is coagulated in washing after advanced optimizing significantly to improve
Its dirt-removing power.The stability of nonionic surfactant is good, can effectively remove dirt.Washing assisant is with solvent for being promoted
Clean effect；Its clean effect of weakly alkaline auxiliary agent is more preferable；Organic solvent can effectively dissolve part dirt, improve it and go
Dirty effect.Defoaming agent is mainly used for the foam generated when removal production, and organosilicon or fatty acid can effectively take out foam；
Chemosterilant can effective sterilizing；Weakly alkaline salt is dispersing agent, can be further improved clean effect, by indissoluble
Greasiness removal.Enzyme can effectively take out the stain of certain macromoleculars.
A kind of solidifying pearl preparation method of use in dishwasher washing, includes the following steps: to mix surfactant with washing assisant
Stirring and emulsifying afterwards obtains emulsion；Defoaming agent is added in emulsion, adds dispersing agent after stirring evenly defoaming, is stirred,
Obtain intermediate fluid；Disinfectant, enzyme and solvent are added in intermediate fluid, stirred evenly, detergent is obtained and carries out water soluble film packaging,
Detergent is packaged into water soluble film.The mixing speed is 20r/min.
After mixing by surfactant and auxiliary agent, add dispersing agent and improve dispersion effect, be then added disinfectant,
Enzyme and solvent are to increase the disinfecting detergent effect of solidifying pearl；In production process, if defoaming agent need to be added by producing a large amount of foams, mention
Safety in Gao Shengcha；It is finally encapsulated with water soluble film, is used convenient for client.Mixing speed is to influence water-setting pearl washing effect
The more crucial factor of production.20 rpms of production efficiencys and the effect for the product produced are more preferable.
Embodiment 2
Embodiment 2 with embodiment 1 the difference is that, including 0.1 mass parts of surfactant, 0.1 mass parts of washing assisant are molten
0.1 mass parts of agent.
Embodiment 3
Embodiment 3 with embodiment 1 the difference is that, including 60 mass parts of surfactant, 40 mass parts of washing assisant, solvent
50 mass parts, 10 mass parts of defoaming agent, 20 mass parts of disinfectant, 30 mass parts of dispersing agent, 5 mass parts of enzyme.
Embodiment 4
Embodiment 4 with embodiment 1 the difference is that, the surfactant be nonionic surfactant；The table
Face activating agent is that ethylenediamine EO/PO copolymer, EO/PO polyethers, sucrose ester, fatty alcohol polyoxyethylene ether are one such or several
Kind.The washing assisant is sodium carbonate, sodium bicarbonate, sodium metasilicate, sodium hydroxide, triethanolamine, monoethanolamine, diethanol amine
It is one such or several；The solvent is that alcohols, alcohol ether, esters, terpenes are one such or several.The defoaming
Agent is organosilicon, fatty acid one of which or several；The bleaching and disinfecting agents are toluene-sodium-sulfonchloramide, sodium dichloro cyanurate, hypochlorous acid
Sodium, SODIUM PERCARBONATE are one of or several；The dispersing agent is polycarboxylate, citrate, gluconate one of which
Or it is several.The enzyme be protease, amylase, lipase, complex enzyme it is one of or several.
Embodiment 5
Embodiment 5 with embodiment 1 the difference is that, the washing coagulate pearl in further include 0.8 mass of modified nano zinc oxide
Part；The modified zinc oxide includes that oxidation bi content is 5 mass parts, 78 mass parts of zinc oxide；The modified zinc oxide is logical
Following methods are crossed to be made:
By zinc oxide, bismuth nitrate ball milling, control ratio of grinding media to material is 15:1；
0.2 mass parts of sodium hydroxide are added, 0.8 mass parts of deionized water are added, ball milling 25min obtains powder；
Powder is put into and is placed in Muffle furnace, at the uniform velocity heating is heat-treated, and heat treatment temperature is 550 DEG C, and keeps the temperature 1.5h, is obtained
To a kind of modified oxidized zinc powder, i.e., modified oxidized zinc powder prepared by the present invention.
After modified oxidized zinc powder is stirred together for surfactant and washing assisant, dispersing agent is added, further
The step of after being carried out again after dispersion.
Modified Zinc oxide powder can significantly improve the clean effect for washing solidifying pearl.
Embodiment 6
Embodiment 6 with embodiment 1 the difference is that, the surfactant be nonionic surfactant；The table
Face activating agent is 35 mass parts of mixture of the 1:1 compounding of EO/PO polyethers, sucrose ester, and the washing assisant is sodium metasilicate, list
Ethanol amine, diethanol amine 1:0.5:1 25 mass parts of mixture；The solvent is 20 mass parts of alcohols, the defoaming
Agent is 7 mass parts of fatty acid；The bleaching and disinfecting agents are 12 mass parts of sodium dichloro cyanurate；The dispersing agent is grape
15 mass parts of sugar lime, the enzyme are 3 mass parts of complex enzyme.
Embodiment 7
Embodiment 7 with embodiment 1 the difference is that, the surfactant be nonionic surfactant；The table
Face activating agent be ethylenediamine EO/PO copolymer, fatty alcohol polyoxyethylene ether 1:1 40 mass parts of mixture；The washing
Auxiliary agent is 23 mass parts of mixture of sodium carbonate, sodium bicarbonate, sodium metasilicate 1:1:0.2；The solvent is 28 mass parts of alcohol ether；
The defoaming agent is 7 mass parts of organosilicon；The bleaching and disinfecting agents are 11 mass parts of SODIUM PERCARBONATE；The dispersing agent is
16 mass parts of mixture of polycarboxylate, citrate, gluconate 1:1:1；The enzyme is amylase, lipase, answers
4 mass parts of mixture of synthase 1:1:1.
Embodiment 8
Embodiment 8 with embodiment 1 the difference is that, the surfactant be nonionic surfactant；The table
Face activating agent is 45 mass parts of mixture of ethylenediamine EO/PO copolymer, EO/PO polyethers, sucrose ester 1:1:1；The washing
Auxiliary agent is triethanolamine, monoethanolamine, 33 mass parts of mixture of diethanol amine 1:1:1；The solvent is terpenes and alcohol
36 mass parts of mixture of class；The defoaming agent is 6 mass parts of organosilicon；The bleaching and disinfecting agents are toluene-sodium-sulfonchloramide, dichloro is different
16 mass parts of NaDCC 1:1 mixture；The dispersing agent is polycarboxylate, citrate, gluconate 1:0.3:2
12 mass parts of mixture.The enzyme is 4 mass parts of protease.
Comparative example 1
Comparative example 1 with embodiment 1 the difference is that, including 120 mass parts of surfactant, 82 mass parts of washing assisant are molten
55 mass parts of agent, 15 mass parts of defoaming agent, 25 mass parts of disinfectant, 35 mass parts of dispersing agent, 7 mass parts of enzyme.
Comparative example 2
Comparative example 2 with embodiment 1 the difference is that, including 15 mass parts of defoaming agent, 25 mass parts of disinfectant, 35 matter of dispersing agent
Measure part, 7 mass parts of enzyme.
Comparative example 3
Comparative example 3 with embodiment 1 the difference is that, the surfactant, washing assisant, solvent, defoaming agent, disinfection
The solution that agent, dispersing agent, enzyme form does not use water-setting film to coat.
Experimental example 1
With reference to the detergency measuring method of GB9985-2000, the detergency of embodiment 1 ~ 4 and comparative example 1 and 2 is measured, wherein go
The judgement of dirty power is, if tested dish washing detergent goes oil cut rate to go oil cut rate not less than standard brick dish washing detergent, for qualification, mark
The oil cut rate of going of quasi- dish washing detergent is 38.2%.
With reference to the fungistatic effect evaluation method of QB/T2738-2012, measure embodiment 1 ~ 4 and comparative example 1 and 2 to golden yellow
The bactericidal effect of color staphylococcus, Escherichia coli, Candida albicans.Calculate the Antibiotic liquid detergent containing Folium Artemisiae Argyi extract with
Concentration is that the staphylococcus aureus, Escherichia coli, Candida albicans of 106cfu/ml contact the sterilizing rate (%) after 3h.
1 dirt-removing power of table and bacteriostasis
As known from Table 1, using the detergent of water-setting film cladding can effective decontamination greasy dirt, while can effectively inhibit bacterium
Deng growth.
Embodiment 1 ~ 4 can effectively take out greasy dirt and have good fungistatic effect.The clean effect of embodiment 1 with
The additive amount of its enzyme, enzyme can effectively remove the pollutant of macromolecular, can effective decontamination.Enzyme in embodiment 2 and 3 adds
Dosage is weaker than embodiment 1 with 1 different from of embodiment, effect, shows that the total enzyme additive amount of embodiment 1 is more particularly suitable adds
Dosage.The clean effect of comparative example 1 is poor, but still belongs to qualified.The effect of comparative example 2 is poor to be free of surfactant with it, helps
Agent is solvent-related.
Embodiment 5 increases modified zinc oxide, and fungistatic effect has obtained significant raising, therefore multiple with modified zinc oxide
Pearl is coagulated in the washing matched can effectively kill bacterium.
Embodiment 6 ~ 8 is several specific embodiments in this application, it should be understood that the formula of the detergent of the application
Composition should be not limited to pharmaceutical agent combinations described in embodiment 1 ~ 8.
The surfactant of the 1:1 compounding of EO/PO polyethers, sucrose ester in embodiment 6, and it is preferable with its fiting effect
Host and dispersing agent, clean effect are significantly improved compared with embodiment 2 ~ 4；Embodiment 7 selects EO/PO copolymer, fatty alcohol
The mixture of the 1:1 of polyoxyethylene ether, washing assisant are the mixture of sodium carbonate, sodium bicarbonate, sodium metasilicate 1:1:0.2, washing
Effect is better than embodiment 2 ~ 4；The surfactant and dispersing agent and auxiliary agent that embodiment 8 is selected can effectively improve decontamination effect
Fruit.
Embodiment 1, in embodiment 6 ~ 8, various surfactants, auxiliary agent and dispersing agent and corresponding disinfectant and defoaming
Agent be obtain after multiple compounding it is more excellent as a result, detergent described herein should be not limited to above-mentioned specific formula.
Experimental example 2
The mixed liquor of the solidifying pearl of washing of embodiment 1 and comparative example 3 is added separately in dish-washing machine, to the kitchen tools of identical quantity into
Row cleaning after the completion of cleaning, takes out kitchen tools, cleans dish washer interior；Embodiment 1 and the corresponding kitchen tools of comparative example 3 are put respectively
Enter that detergent is not added in dish-washing machine and cleaned, takes cleaning solution, test pH respectively.
The result shows that the pH of comparative example 3 is in alkalescent, the pH of the cleaning solution of embodiment 1 is in neutrality.It can it can be seen that washing solidifying pearl
Effectively to prevent from remaining.
Above-listed detailed description is illustrating for possible embodiments of the present invention, and above embodiments are not to limit this
The scope of the patents of invention, all equivalence enforcements or change without departing from carried out by the present invention, is intended to be limited solely by the scope of the patents of this case.
Claims (10)
1. a kind of use in dishwasher washs solidifying pearl, which is characterized in that including 0.1 ~ 60 mass parts of surfactant, washing assisant 0.1 ~
40 mass parts, 0.1 ~ 50 mass parts of solvent, 0 ~ 10 mass parts of defoaming agent, 0 ~ 20 mass parts of disinfectant, 0 ~ 30 mass parts of dispersing agent,
0 ~ 5 mass parts of enzyme.
2. a kind of use in dishwasher according to claim 1 washs solidifying pearl, which is characterized in that including surfactant 30 ~ 60
Mass parts, 20 ~ 40 mass parts of washing assisant, 15 ~ 50 mass parts of solvent, 5 ~ 10 mass parts of defoaming agent, 10 ~ 20 mass of disinfectant
Part, 10 ~ 30 mass parts of dispersing agent, 2 ~ 5 mass parts of enzyme.
3. a kind of use in dishwasher according to claim 2 washs solidifying pearl, which is characterized in that including 30 mass of surfactant
Part, 20 mass parts of washing assisant, 15 mass parts of solvent, 5 mass parts of defoaming agent, 10 mass parts of disinfectant, 10 mass parts of dispersing agent,
2 mass parts of enzyme.
4. a kind of use in dishwasher according to claim 1 washs solidifying pearl, which is characterized in that the surfactant is non-
Ionic surface active agent；The surfactant is ethylenediamine EO/PO copolymer, EO/PO polyethers, sucrose ester, poly alkyl alcohol
Ethylene oxide ether is one such or several.
5. a kind of use in dishwasher according to claim 1 washs solidifying pearl, which is characterized in that the washing assisant is carbonic acid
Sodium, sodium bicarbonate, sodium metasilicate, sodium hydroxide, triethanolamine, monoethanolamine, diethanol amine are one such or several；Described
Solvent is that alcohols, alcohol ether, esters, terpenes are one such or several.
6. a kind of use in dishwasher according to claim 1 washs solidifying pearl, which is characterized in that the defoaming agent is organic
Silicon, fatty acid are one of or several；The bleaching and disinfecting agents are toluene-sodium-sulfonchloramide, sodium dichloro cyanurate, sodium hypochlorite, cross carbon
Sour sodium is one of or several；The dispersing agent is polycarboxylate, citrate, gluconate one of which or several.
7. a kind of use in dishwasher according to claim 1 washs solidifying pearl, which is characterized in that the enzyme is protease, forms sediment
Powder enzyme, lipase, complex enzyme it is one of or several.
8. a kind of use in dishwasher washs solidifying pearl preparation method, described in any item detergent, feature exist according to claim 1 ~ 7
In including the following steps: stirring and emulsifying after mixing surfactant with washing assisant, obtain emulsion；Defoaming agent is added
Into emulsion, dispersing agent is added after stirring evenly defoaming, stirs, obtains intermediate fluid；Disinfectant, enzyme and solvent are added to
It in intermediate fluid, stirs evenly, obtains detergent and carry out water soluble film packaging, detergent is packaged into water soluble film.
9. a kind of use in dishwasher according to claim 1 washs solidifying pearl preparation method, which is characterized in that the stirring speed
Degree is 15 ~ 40r/min.
10. a kind of use in dishwasher according to claim 9 washs solidifying pearl preparation method, which is characterized in that the stirring
Speed is 20r/min.
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| CN110257180A (en) * | 2019-04-16 | 2019-09-20 | 广东优凯科技有限公司 | Dish washing detergent for dish-washing machine |
| CN111234967A (en) * | 2020-03-11 | 2020-06-05 | 江南大学 | High-activity multifunctional washing gel bead and preparation method thereof |
| CN111893000A (en) * | 2020-08-04 | 2020-11-06 | 韶关浪奇有限公司 | Non-phosphorus detergent for dish-washing machine and preparation process thereof |
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| CN109112003B (en) | 2021-08-06 |
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