CN102864040A - High-effect cleaning agent, preparation method thereof and special equipment - Google Patents
High-effect cleaning agent, preparation method thereof and special equipment Download PDFInfo
- Publication number
- CN102864040A CN102864040A CN2012103374981A CN201210337498A CN102864040A CN 102864040 A CN102864040 A CN 102864040A CN 2012103374981 A CN2012103374981 A CN 2012103374981A CN 201210337498 A CN201210337498 A CN 201210337498A CN 102864040 A CN102864040 A CN 102864040A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- percent
- spc
- mother liquor
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention discloses a high-effect cleaning agent, which comprises the following raw materials in percent by weight: 13-18 percent of AES (sodium alcohol ether sulphate), 2-10 percent of cocamidopropyl betaine, 2-10 percent of alkyl glycoside 0810, 0.05-0.2 percent of builder EDTA-2Na (ethylene diaminetetraacetic acid disodium), 0.5-2.5 percent of biological enzyme, 20-40 percent of sodium percarbonate mother liquid and 30-50 percent of water. The invention additionally discloses a production technology and special production equipment of the cleaning agent. According to tests, the cleaning agent is environmental-friendly and has strong decontamination capability.
Description
Technical field
The invention belongs to the sanitising agent technical field, be specifically related to a kind of high duty detergent and production method and professional equipment of being made by the SPC-D mother liquor that contains high density soda ash and NaCl.
Background technology
The SPC-D mother liquor is the waste liquid that produces in the SPC-D production process, at present carries out subsequent disposal behind the materials such as wherein yellow soda ash of general using zeolite adsorption, sodium-chlor again.Because adsorption efficiency is low, the problem that the yellow soda ash in length consuming time and the mother liquor, sodium-chlor can not fully reclaim has also caused the wasting of resources when increasing environmental pressure.
The main component of SPC-D mother liquor is soda ash and sodium-chlor, and other contains a small amount of polymkeric substance, and polymkeric substance also can play good effect to washing composition.Utilize the SPC-D mother liquor to produce sanitising agent, need to overcome the difficult problem of high concentration alkali, high salt concentration, its key is to can not find the cleaning product that suitable active substance and SPC-D mother liquor generate the transparent phenomenon that layering do not occur always.
Summary of the invention
The object of the invention is to provide a kind of efficient cleaning agent and production method and specific equipment that is comprised of high density, high salinity SPC-D mother liquor and suitable active substance, and this sanitising agent soil removability is strong.
For achieving the above object, the present invention adopts following technical scheme:
A kind of efficient cleaning agent, this sanitising agent comprise the raw material of following weight per-cent: 13-18%AES, 2-10% AMONYL 380LC, 2-10% alkyl glycoside 0810,0.05-0.2% washing assistant EDTA-2Na, 0.5-2.5% biological enzyme, 20-40% SPC-D mother liquor and 30-50% water.
Described biological enzyme can be bought usual production, and the used biological enzyme of the present invention mainly is comprised of the crisp outer high alkaline proteases of Serine and Lipase available from the triumphant Chemicals business department that reaches of Jinan City's Licheng District, and both are mixed into good with weight ratio 1:1.
The production method of above-mentioned efficient cleaning agent, it comprises the steps: EDTA-2Na, AES and the temperature SPC-D mother liquor at 60-90 ℃ is mixed, then under agitation condition, add temperature and be 40-60 ℃ water, AMONYL 380LC, alkyl glycoside 0810 and biological enzyme, vacuumize behind the mixing and remove bubble, leave standstill 1-2h, and get final product.
A kind of specific equipment of realizing above-mentioned high-efficiency cleaning agent and process for producing same, it comprises volume pump, dosing chamber, vacuum pump, and vaporizer in sequential series, preheating can, reactor and wrapping machine, wherein, described reactor upper port is connected with dosing chamber through volume pump, and described reactor also links to each other with vacuum pump.
Preferably, be equipped with agitator in described preheating can and the reactor.
The main component of SPC-D mother liquor is exactly soda ash (6-10%) and sodium-chlor (15-17%), and other contains a small amount of hydrogen peroxide (0.5-1.0%) and polymkeric substance.In actual production, comparative optimization, can specifically determine according to the concentration (being its salt alkali content) of SPC-D mother liquor the consumption of corresponding AES.The mensuration of the salt alkali content in the SPC-D mother liquor, concrete, the content of salt (being sodium-chlor) is to detect with the mercuric nitrate complexometry method with the agent of giving instruction of bromjophenol blue, nitric acid, hydrazonium sulfate, the content of alkali can detect with neutralization titration.In general, the addition of AES is about 1/2 of salt total alkali content.
AES another name ethoxylated alkyl sulfate, fatty alcohol-ether sodium sulfate, AES can be water-soluble, has good decontamination, emulsification, foam performance and anti-performance of hard water, and its gentle scourability can injured skin.Please note during use: in the situation that do not contain viscosity modifier, if AES is diluted for containing the aqueous solution of 30% or 60% active substance, often can cause producing the high gel of a kind of viscosity.Alkyl glycoside 0810 is a kind of gentle plant-sourced tensio-active agent non-stimulated to human body skin, and detersive power is good, easily rinsing, and skinfeel is salubrious, and foam is fine and smooth; And the potential resistance to electrolyte contamination of anti-highly basic, without cloud point, can with any type surfactant compound, synergistic effect is obvious, especially can greatly reduce the pungency of other composition of cosmetic formulations system and increase stability of system.AMONYL 380LC is a kind of zwitterionics, all has good stability under acidity and alkaline condition, presents respectively sun and anionic property, normal and yin, yang ion and nonionogenic tenside and usefulness, and its compatibility is good.Its pungency is little soluble in water, and to ph stability, foam is many, strong detergency, has good thickening property, flexibility, bactericidal properties, static resistance, anti-hard water etc., can significantly improve softness, conditioning and the low-temperature stability of washing series products.AMONYL 380LC is as raw material take Oleum Cocois.Condensation by N, N dimethylated propyl diethylenetriamine produce PKO again with the quaternized two-step reaction of sodium chloroacetate, produce AMONYL 380LC.
Decontamination principle and the process of sanitising agent: the adhering to of dirt and article be to realize by different interactions, thereby dirt to remove mechanism also be different.Remove dirt and relate generally to tensio-active agent is adsorbed in dirt and stromal surface in medium effect.Absorption has changed interfacial tension and the electromotive force of dirt, medium interface and matrix, medium interface, can promote the removal of dirt.
Efficient cleaning agent of the present invention, need not additionally add tripoly phosphate sodium STPP, because of remaining in this products material SPC-D mother liquor a small amount of tripoly phosphate sodium STPP and active oxygen arranged, decontamination has preferably effect to cleaning to contain the oxygen sanitising agent, but also has the effect of virus killing, bleaching, and product of the present invention not only can be used for washing, can also be used for dirt, this product contains alkyl glycoside, and this tensio-active agent does not have pungency to skin, and is very soft.
The advantage of specific equipment of the present invention: will cool off and preheating organically combine, soon EDTA-2Na and AES knock down in the preheating can and heat with the SPC-D mother liquor, and concerning the SPC-D mother liquor of heat, belong to simultaneously cooling, when three's mixing is preheating to 40 ℃ of left and right sides, change in the retort and mix the generation reaction with other raw material, this preheating can has been saved the consumption of steam, and simultaneously crystallization goes out saline and alkaline, reduce the consumption of the energy, greatly reduced production cost.Present device is applied widely, can be widely used in the production of cleaning product, liquid chemical product, has good economic and social benefit.
Description of drawings
Fig. 1 is the structural representation of specific equipment of the present invention.
Embodiment
Below by preferred embodiment technique of the present invention being described in further detail, but protection scope of the present invention is not limited to this.
A kind of efficient cleaning agent, each raw material weight proportioning of this sanitising agent is as follows: 60kg AES, 16kg AMONYL 380LC, 16kg alkyl glycoside 0810,0.4kg washing assistant EDTA-2Na, 7.6kg biological enzyme (this biological enzyme is comprised of the crisp outer high alkaline proteases of 4g Serine and 3.6g Lipase), 140kg SPC-D mother liquor and 160kg water.
The production method of above-mentioned efficient cleaning agent, it comprises the steps: EDTA-2Na, AES and the temperature SPC-D mother liquor at 80 ℃ is mixed, then under agitation condition, add temperature and be 50 ℃ water, AMONYL 380LC, alkyl glycoside 0810 and biological enzyme, vacuumize behind the mixing and remove bubble, leave standstill 2h, and get final product.
As shown in Figure 1, a kind of specific equipment of realizing above-mentioned high-efficiency cleaning agent and process for producing same, it comprises volume pump 7, dosing chamber 8, vacuum pump 6, and vaporizer 1 in sequential series, preheating can 3, reactor 5 and wrapping machine 9, wherein, described reactor 5 upper port are connected with dosing chamber 8 through volume pump 7, and described reactor 5 also links to each other with vacuum pump 6.Be respectively equipped with agitator 2 and 4 in described preheating can 3 and the reactor 5.
During this equipment work, first flash-pot 1 SPC-D mother liquor is out introduced in the preheating can 3, simultaneously under agitation condition, add EDTA-2Na, AES, after the three mixes, enter in the reactor 5 from the outlet outflow of preheating can 3 lower ends, in dosing chamber 8, mix simultaneously, by water, AMONYL 380LC, the stock liquid that alkyl glycoside 0810 and biological enzyme form is in volume pump 7 enters reactor 5, after stirring, closed reactor 5 vacuumizes to remove bubble in the still with vacuum pump 6 simultaneously, get product after leaving standstill, the outlet of finished product autoreaction tank 5 lower ends is flowed out, and enters in the wrapping machine 9 and packs.This equipment carries out the heating for dissolving of EDTA-2Na, AES and the cooling of hot SPC-D mother liquor simultaneously preheating can 5 is interior, has saved the energy, reduces production costs.
Embodiment 2
SPC-D mother liquor consumption is adjusted into 100kg, and the consumption of water is adjusted into 200kg, the other the same as in Example 1.
Preparation method and equipment are with embodiment 1.
Embodiment 3
With alkyl glycoside 0810 be adjusted into 32kg, SPC-D mother liquor consumption is adjusted into 100kg, the consumption of water is adjusted into 200kg, the other the same as in Example 1.
Preparation method and equipment are with embodiment 1.
The efficient cleaning agent of embodiment 1 to 3 gained is measured according to the testing method of GB GB/T13174-2009 " dress material with the mensuration of washing composition detersive power and circulation cleaning performance ", the relative soil removability value that records sees the following form, can be found out by following table, the soil removability of efficient cleaning agent of the present invention is relatively strong.
Claims (4)
1. efficient cleaning agent, it is characterized in that, this sanitising agent comprises the raw material of following weight per-cent: 13-18%AES, 2-10% AMONYL 380LC, 2-10% alkyl glycoside 0810,0.05-0.2% washing assistant EDTA-2Na, 0.5-2.5% biological enzyme, 20-40% SPC-D mother liquor and 30-50% water.
2. the production method of the described efficient cleaning agent of claim 1, it is characterized in that, comprise the steps: EDTA-2Na, AES and the temperature SPC-D mother liquor at 60-90 ℃ is mixed, then under agitation condition, add temperature and be 40-60 ℃ water, AMONYL 380LC, alkyl glycoside 0810 and biological enzyme, vacuumize behind the mixing and remove bubble, leave standstill 1-2h, and get final product.
3. specific equipment of realizing claims 2 described high-efficiency cleaning agent and process for producing same, it is characterized in that, comprise volume pump, dosing chamber, vacuum pump, and vaporizer in sequential series, preheating can, reactor and wrapping machine, wherein, described reactor upper port is connected with dosing chamber through volume pump, and described reactor also links to each other with vacuum pump.
4. realize as claimed in claim 3 the specific equipment of high-efficiency cleaning agent and process for producing same, it is characterized in that, be equipped with agitator in described preheating can and the reactor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210337498.1A CN102864040B (en) | 2012-09-13 | 2012-09-13 | High-effect cleaning agent, preparation method thereof and special equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210337498.1A CN102864040B (en) | 2012-09-13 | 2012-09-13 | High-effect cleaning agent, preparation method thereof and special equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102864040A true CN102864040A (en) | 2013-01-09 |
| CN102864040B CN102864040B (en) | 2014-06-25 |
Family
ID=47443173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210337498.1A Active CN102864040B (en) | 2012-09-13 | 2012-09-13 | High-effect cleaning agent, preparation method thereof and special equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102864040B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320238A (en) * | 2013-07-02 | 2013-09-25 | 武汉理工大学 | Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof |
| CN104629943A (en) * | 2013-11-14 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Improved concentrated detergent |
| CN105255601A (en) * | 2015-10-09 | 2016-01-20 | 湖北穆兰同大科技有限公司 | Coconut oil fruit and vegetable cleaning agent |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN108754521A (en) * | 2018-05-09 | 2018-11-06 | 苏州捷德瑞精密机械有限公司 | A kind of high-effective low foam rust-proof type metal cleaner and preparation method thereof |
| CN109486562A (en) * | 2017-09-13 | 2019-03-19 | 艺康美国股份有限公司 | The detergent of water system for MTO technology |
| CN109762676A (en) * | 2018-11-23 | 2019-05-17 | 北京敬一科技有限公司 | A kind of electrified cleaning agent process units and preparation method thereof for electrical equipment |
| CN109762675A (en) * | 2018-11-23 | 2019-05-17 | 北京敬一科技有限公司 | A kind of electrified cleaning agent use device and preparation method thereof for electrical equipment |
| CN110577863A (en) * | 2019-08-29 | 2019-12-17 | 广州崇豪环保科技有限公司 | multipurpose cleaning powder |
| CN114854506A (en) * | 2021-01-20 | 2022-08-05 | 内蒙古大学 | Green composite CIP cleaning agent and preparation method and use method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5807816A (en) * | 1995-05-10 | 1998-09-15 | Lever Brothers Company, Division Of Conopco, Inc. | Light duty cleaning composition |
| CN1970713A (en) * | 2005-11-25 | 2007-05-30 | 沈阳宏迪科技有限公司 | Cleaning agent for machinery for food industry |
| CN202786198U (en) * | 2012-09-13 | 2013-03-13 | 濮阳宏业汇龙化工有限公司 | Special equipment for producing efficient cleaning agent |
-
2012
- 2012-09-13 CN CN201210337498.1A patent/CN102864040B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5807816A (en) * | 1995-05-10 | 1998-09-15 | Lever Brothers Company, Division Of Conopco, Inc. | Light duty cleaning composition |
| CN1970713A (en) * | 2005-11-25 | 2007-05-30 | 沈阳宏迪科技有限公司 | Cleaning agent for machinery for food industry |
| CN202786198U (en) * | 2012-09-13 | 2013-03-13 | 濮阳宏业汇龙化工有限公司 | Special equipment for producing efficient cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 李东光等编: "《实用洗涤剂配方手册》", 31 March 2004, 化学工业出版社, article "液体洗涤剂的制造方法", pages: 49 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320238A (en) * | 2013-07-02 | 2013-09-25 | 武汉理工大学 | Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof |
| CN104629943A (en) * | 2013-11-14 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Improved concentrated detergent |
| CN105255601B (en) * | 2015-10-09 | 2018-08-28 | 湖北穆兰同大科技有限公司 | Cocounut oil fruits and vegetables detergent |
| CN105255601A (en) * | 2015-10-09 | 2016-01-20 | 湖北穆兰同大科技有限公司 | Coconut oil fruit and vegetable cleaning agent |
| CN105907483B (en) * | 2016-05-08 | 2019-01-15 | 浙江艾卡医学科技有限公司 | A kind of oxygen containing multifunctional detergent composition |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN109486562A (en) * | 2017-09-13 | 2019-03-19 | 艺康美国股份有限公司 | The detergent of water system for MTO technology |
| CN108754521A (en) * | 2018-05-09 | 2018-11-06 | 苏州捷德瑞精密机械有限公司 | A kind of high-effective low foam rust-proof type metal cleaner and preparation method thereof |
| CN109762676A (en) * | 2018-11-23 | 2019-05-17 | 北京敬一科技有限公司 | A kind of electrified cleaning agent process units and preparation method thereof for electrical equipment |
| CN109762675A (en) * | 2018-11-23 | 2019-05-17 | 北京敬一科技有限公司 | A kind of electrified cleaning agent use device and preparation method thereof for electrical equipment |
| CN110577863A (en) * | 2019-08-29 | 2019-12-17 | 广州崇豪环保科技有限公司 | multipurpose cleaning powder |
| CN110577863B (en) * | 2019-08-29 | 2022-01-21 | 广州崇豪环保科技有限公司 | Multipurpose cleaning powder |
| CN114854506A (en) * | 2021-01-20 | 2022-08-05 | 内蒙古大学 | Green composite CIP cleaning agent and preparation method and use method thereof |
| CN114854506B (en) * | 2021-01-20 | 2024-03-15 | 内蒙古大学 | Green composite CIP cleaning agent and preparation method and use method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102864040B (en) | 2014-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102864040B (en) | High-effect cleaning agent, preparation method thereof and special equipment | |
| CN101688153B (en) | Surfactant composition | |
| CN102533465B (en) | Low foam fabric liquid detergent and preparation method thereof | |
| CN102242023A (en) | Laundry liquid with washing and caring functions | |
| CN103468429B (en) | A kind of for the natural liquid laundry detergent in ultraviolet washing machine and preparation method | |
| CN103468445B (en) | Washing powder composition and preparation method thereof | |
| CN103468444B (en) | Laundry soap powder composition | |
| CN103194328B (en) | Cosolvent-free high-power concentrated detergent and preparation method thereof | |
| CN106350291A (en) | Laundry condensate beads for washing underclothes, and preparation method of laundry condensate beads | |
| CN110408483A (en) | Solid-state powder ball shaped detergent and its preparation method and application | |
| CN109135958A (en) | A kind of antimicrobial cleaning particle and preparation method thereof with timing | |
| CN106398903B (en) | A kind of hand-wash laundry liquid easily rinsed and preparation method thereof | |
| CN106854513A (en) | A kind of green non-phosphide detergent and preparation method thereof | |
| CN101638612A (en) | Environment-friendly washing powder | |
| CN106047526A (en) | Detergent sheet and preparation method thereof | |
| CN106350271A (en) | Color-protecting clothes washing condensate beads and preparation method thereof | |
| CN103146501A (en) | Environment-friendly high-efficiency laundry detergent and preparation method thereof | |
| CN102746959A (en) | Liquid perfumed soap | |
| CN106350293A (en) | Silky soft laundry condensate bead and preparation method thereof | |
| CN104726215A (en) | Preparation method of sphorus laundry powder | |
| CN106434071A (en) | Laundry detergent capable of effectively removing dirts and preparing method thereof | |
| CN103122279A (en) | Non-phosphorus low-foaming washing powder preparation method | |
| CN104962401A (en) | Waterless nano laundry detergent and manufacturing technique thereof | |
| CN101245287A (en) | Decontamination cleanser | |
| CN103013721A (en) | High efficiency phosphorus-free degerming laundry detergent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: Nanle County of Puyang City, the 457400 industrial agglomeration area in Henan province people's Road North Patentee after: PUYANG HONGYE ENVIRONMENTAL PROTECTION NEW MATERIAL CO., LTD. Address before: Puyang City, Henan province 457400 Nanle county two km north of the city Patentee before: Puyang Hongye Huilong Chemical Co., Ltd. |
|
| CP03 | Change of name, title or address |
Address after: 457400 East Road, 600m north of the intersection of national highway 106 and Minsheng Road, Nanle County, Puyang City, Henan Province Patentee after: Puyang Shengkai environmental protection new material technology Co.,Ltd. Address before: 457400 north of Minsheng Road, Nanle County, Puyang City, Henan Province Patentee before: PUYANG HONGYE ENVIRONMENTAL PROTECTION NEW MATERIAL Co.,Ltd. |
|
| CP03 | Change of name, title or address |