CN105907483B - A kind of oxygen containing multifunctional detergent composition - Google Patents
A kind of oxygen containing multifunctional detergent composition Download PDFInfo
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- CN105907483B CN105907483B CN201610301546.XA CN201610301546A CN105907483B CN 105907483 B CN105907483 B CN 105907483B CN 201610301546 A CN201610301546 A CN 201610301546A CN 105907483 B CN105907483 B CN 105907483B
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- triethylamine
- diphosphonic acid
- ferment
- detergent composition
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- 239000003599 detergent Substances 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 12
- 239000001301 oxygen Substances 0.000 title claims abstract description 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 129
- VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 32
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 27
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 27
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 25
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 25
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000005642 Oleic acid Substances 0.000 claims abstract description 25
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 25
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 25
- 239000011574 phosphorus Substances 0.000 claims abstract description 25
- 239000003381 stabilizer Substances 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 17
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000002738 chelating agent Substances 0.000 claims abstract description 16
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 16
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 16
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 16
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims abstract 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000004382 Amylase Substances 0.000 claims description 6
- 102000013142 Amylases Human genes 0.000 claims description 6
- 108010065511 Amylases Proteins 0.000 claims description 6
- 108091005804 Peptidases Proteins 0.000 claims description 6
- 239000004365 Protease Substances 0.000 claims description 6
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 6
- 235000019418 amylase Nutrition 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000003213 activating effect Effects 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 19
- 230000000694 effects Effects 0.000 description 7
- 102000004882 Lipase Human genes 0.000 description 5
- 239000004367 Lipase Substances 0.000 description 5
- 108090001060 Lipase Proteins 0.000 description 5
- 235000019421 lipase Nutrition 0.000 description 5
- 235000019419 proteases Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of oxygen containing multifunctional detergent compositions, are prepared by the raw material of following parts by weight: surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, and 40~50 parts；Chelating agent tetraacetyl ethylene diamine, 6~8 parts；Without phosphorus coated SODIUM PERCARBONATE, 10~14 parts；Ferment, 5~7 parts；Oleic acid, 5~15 parts；It further include totally 0.7~0.9 part of stabilizer hydroxy ethylene diphosphonic acid and triethylamine, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6~8:1.Detergent composition provided by the invention contains active oxygen and ferment, has and goes stain, scale removal, antibacterial, color drift, unclogging, odor function of dispelling, and is suitable for clothing rinsing, utensil cleaning and household care；Moreover, detergent composition property stabilization provided by the invention, long shelf-life, detergency ability are lasting.
Description
Technical field
The invention belongs to daily chemicals fields, and in particular to a kind of oxygen containing multifunctional detergent composition.
Background technique
The main component that detergent is called and (washes adjustment) is surfactant, and surfactant is in molecular structure containing parent
The water base and two-part organic compound of lipophilic group.Can ion be usually decomposed into according to surfactant in aqueous solution,
It is classified as the two major classes of ionic surfactant and nonionic surface active agent again.Ionic surfactant can divide again
For cationic surfactant, anionic surfactant and three kinds of zwitterionic surfactant.
Detergent function at present on the market is relatively simple, often only has advantage in one aspect.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of oxygen containing multifunctional detergent composition,
With stain, scale removal, antibacterial, color drift, unclogging, odor function of dispelling is gone, it is suitable for clothing rinsing, utensil cleaning and household care.
Above-mentioned purpose of the invention is achieved by following technical solution:
A kind of oxygen containing multifunctional detergent composition, is prepared: surfactant by the raw material of following parts by weight
Sodium sulfate of polyethenoxy ether of fatty alcohol, 40~50 parts；Chelating agent tetraacetyl ethylene diamine, 6~8 parts；Without phosphorus coated SODIUM PERCARBONATE,
10~14 parts；Ferment, 5~7 parts；Oleic acid, 5~15 parts；Further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.7~
0.9 part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6~8:1.
Further, the ferment is one of protease, lipase or amylase or a variety of.
Further, the multifunctional detergent composition is prepared by the raw material of following parts by weight: surface is living
Property agent sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus coated SODIUM PERCARBONATE, 12
Part；Ferment, 6 parts；Oleic acid, 10 parts；It further include totally 0.8 part of stabilizer hydroxy ethylene diphosphonic acid and triethylamine, hydroxy ethylene
The weight ratio of di 2 ethylhexyl phosphonic acid and triethylamine is 7:1.
Further, the multifunctional detergent composition is prepared by the raw material of following parts by weight: surface is living
Property agent sodium sulfate of polyethenoxy ether of fatty alcohol, 40 parts；Chelating agent tetraacetyl ethylene diamine, 6 parts；Without phosphorus coated SODIUM PERCARBONATE, 10
Part；Ferment, 5 parts；Oleic acid, 5 parts；It further include totally 0.7 part of stabilizer hydroxy ethylene diphosphonic acid and triethylamine, hydroxy ethylene two
The weight ratio of phosphonic acids and triethylamine is 6:1.
Further, the multifunctional detergent composition is prepared by the raw material of following parts by weight: surface is living
Property agent sodium sulfate of polyethenoxy ether of fatty alcohol, 50 parts；Chelating agent tetraacetyl ethylene diamine, 8 parts；Without phosphorus coated SODIUM PERCARBONATE, 14
Part；Ferment, 7 parts；Oleic acid, 15 parts；It further include totally 0.9 part of stabilizer hydroxy ethylene diphosphonic acid and triethylamine, hydroxy ethylene
The weight ratio of di 2 ethylhexyl phosphonic acid and triethylamine is 8:1.
The preparation method of above-mentioned multifunctional detergent composition, includes the following steps:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Advantages of the present invention:
Detergent composition provided by the invention contains active oxygen and ferment, has and goes stain, scale removal, antibacterial, color drift, edible vegetable oil
Dirty, odor function of dispelling is suitable for clothing rinsing, utensil cleaning and household care；Moreover, detergent composition provided by the invention
Property is stablized, long shelf-life, and detergency ability is lasting.
Specific embodiment
Essentiality content of the invention is further illustrated below with reference to embodiment, but present invention protection model is not limited with this
It encloses.Although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should understand that, it can be right
Technical solution of the present invention is modified or replaced equivalently, without departing from the spirit and scope of technical solution of the present invention.
In following embodiments, ferment is the mixture of protease, lipase and amylase weight part ratio 1:1:1.
Embodiment 1: the preparation of detergent composition
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 7:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 2: the preparation of detergent composition
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 40 parts；Chelating agent tetraacetyl ethylene diamine, 6 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 10 parts；Ferment, 5 parts；Oleic acid, 5 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.7
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 3: the preparation of detergent composition
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 50 parts；Chelating agent tetraacetyl ethylene diamine, 8 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 14 parts；Ferment, 7 parts；Oleic acid, 15 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.9
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 8:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 4: the preparation of detergent composition
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 5: the preparation of detergent composition
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 8:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 6: the weight ratio of comparative example, hydroxy ethylene diphosphonic acid and triethylamine is 5:1
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 5:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 7: the weight ratio of comparative example, hydroxy ethylene diphosphonic acid and triethylamine is 9:1
Parts by weight of raw materials ratio:
Surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 9:1.
Preparation method:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
Embodiment 8: effect example
The storage stability for the detergent composition that respectively prepared by testing example 1~7,36 months experiment investigation time limits,
25 ± 5 DEG C of test temperature, test 50 ± 5%RH of humidity.Inspection target: the enzyme activity of protease, lipase and amylase is opposite
The decline percentage (%) of enzyme activity when just producing；Decline percentage of the SODIUM PERCARBONATE content relative to content when just producing
Than (%).
As a result it see the table below.
The storage stability and embodiment 4,5 of detergent composition prepared by embodiment 2 and 3 are almost the same.
The enzyme activity of protease, lipase and amylase, which is easily reduced, even to be inactivated, and dirt-removing power is caused to reduce；Percarbonic acid
Sodium is easy to decompose, and leads to the reduction of Active oxygen release ability.Pass through the comparison of Examples 1 to 7, it was demonstrated that detergent provided by the invention
Protease, lipase and amylase activity are stablized in composition, and active oxygen functional additive SODIUM PERCARBONATE property is stablized, this may
It is related with the weight ratio of hydroxy ethylene diphosphonic acid in raw material and triethylamine, effect when the two weight ratio is 6~8:1
It is best.
Detergent composition provided by the invention contains active oxygen and ferment, has and goes stain, scale removal, antibacterial, color drift, edible vegetable oil
Dirty, odor function of dispelling is suitable for clothing rinsing, utensil cleaning and household care；Moreover, detergent composition provided by the invention
Property is stablized, long shelf-life, and detergency ability is lasting.
The effect of above-described embodiment indicates that essentiality content of the invention, but protection of the invention is not limited with this
Range.Those skilled in the art should understand that can with modification or equivalent replacement of the technical solution of the present invention are made,
Without departing from the essence and protection scope of technical solution of the present invention.
Claims (6)
1. a kind of oxygen containing multifunctional detergent composition, which is characterized in that be prepared by the raw material of following parts by weight: table
Face activating agent sodium sulfate of polyethenoxy ether of fatty alcohol, 40~50 parts；Chelating agent tetraacetyl ethylene diamine, 6~8 parts；Without phosphorus coated
SODIUM PERCARBONATE, 10~14 parts；Ferment, 5~7 parts；Oleic acid, 5~15 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and three second
Totally 0.7~0.9 part of amine, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6~8:1.
2. multifunctional detergent composition according to claim 1, it is characterised in that: the ferment is protease, fat
One of enzyme or amylase are a variety of.
3. multifunctional detergent composition according to claim 2, which is characterized in that pass through the raw material system of following parts by weight
It is standby to form: surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 45 parts；Chelating agent tetraacetyl ethylene diamine, 7 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 12 parts；Ferment, 6 parts；Oleic acid, 10 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.8
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 7:1.
4. multifunctional detergent composition according to claim 2, which is characterized in that pass through the raw material system of following parts by weight
It is standby to form: surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 40 parts；Chelating agent tetraacetyl ethylene diamine, 6 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 10 parts；Ferment, 5 parts；Oleic acid, 5 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.7
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 6:1.
5. multifunctional detergent composition according to claim 2, which is characterized in that pass through the raw material system of following parts by weight
It is standby to form: surfactant sodium sulfate of polyethenoxy ether of fatty alcohol, 50 parts；Chelating agent tetraacetyl ethylene diamine, 8 parts；Without phosphorus package
Type SODIUM PERCARBONATE, 14 parts；Ferment, 7 parts；Oleic acid, 15 parts；It further include stabilizer hydroxy ethylene diphosphonic acid and triethylamine totally 0.9
Part, the weight ratio of hydroxy ethylene diphosphonic acid and triethylamine is 8:1.
6. the preparation method of any multifunctional detergent composition of Claims 1 to 5, spy is being, including walks as follows
It is rapid:
Surfactant, tetraacetyl ethylene diamine, oleic acid are uniformly mixed by step S1；
Step S2 adds stabilizer hydroxy ethylene diphosphonic acid and triethylamine, is uniformly mixed；
Step S3 adds without phosphorus coated SODIUM PERCARBONATE and ferment, is uniformly mixed.
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| CN106854498A (en) * | 2017-01-04 | 2017-06-16 | 长沙协浩吉生物工程有限公司 | A kind of compound method of anti-mite pregnant woman's clothing machine washing liquid |
| CN106939194A (en) * | 2017-03-17 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of ferment cleaning agent for soot absorber |
| CN106939256A (en) * | 2017-03-17 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of ferment kitchen range cleaning agent |
| CN111154553A (en) * | 2019-12-25 | 2020-05-15 | 斯纳格氏(武汉)科技有限公司 | Multifunctional composite detergent and preparation method thereof |
| CN114525178B (en) * | 2022-01-26 | 2024-06-07 | 晋江市佐净日用品有限责任公司 | Preparation method of oxygen-enriched phosphorus-free concentrated washing liquid |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86106181A (en) * | 1985-09-09 | 1987-06-03 | 阿勒根药品公司 | The method and composition of cleaning and while disinfect contact lense |
| CN1084560A (en) * | 1992-08-01 | 1994-03-30 | 普罗格特-甘布尔公司 | stable bleaching composition |
| CN1124036A (en) * | 1993-05-20 | 1996-06-05 | 普罗格特-甘布尔公司 | Bleaching compounds comprising peroxyacid activators used with enzymes |
| CN102864040A (en) * | 2012-09-13 | 2013-01-09 | 濮阳宏业汇龙化工有限公司 | High-effect cleaning agent, preparation method thereof and special equipment |
| CN103131552A (en) * | 2013-03-15 | 2013-06-05 | 广州立白企业集团有限公司 | Detergent composition containing low-temperature bleaching and activation system |
| CN103131542A (en) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | Active oxygen washing machine tank cleaning agent and preparation method thereof |
| CN104877765A (en) * | 2015-04-30 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for washing machine slot |
-
2016
- 2016-05-08 CN CN201610301546.XA patent/CN105907483B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86106181A (en) * | 1985-09-09 | 1987-06-03 | 阿勒根药品公司 | The method and composition of cleaning and while disinfect contact lense |
| CN1084560A (en) * | 1992-08-01 | 1994-03-30 | 普罗格特-甘布尔公司 | stable bleaching composition |
| CN1124036A (en) * | 1993-05-20 | 1996-06-05 | 普罗格特-甘布尔公司 | Bleaching compounds comprising peroxyacid activators used with enzymes |
| CN102864040A (en) * | 2012-09-13 | 2013-01-09 | 濮阳宏业汇龙化工有限公司 | High-effect cleaning agent, preparation method thereof and special equipment |
| CN103131552A (en) * | 2013-03-15 | 2013-06-05 | 广州立白企业集团有限公司 | Detergent composition containing low-temperature bleaching and activation system |
| CN103131542A (en) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | Active oxygen washing machine tank cleaning agent and preparation method thereof |
| CN104877765A (en) * | 2015-04-30 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for washing machine slot |
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